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1. 发明授权

US5091443A Composition for gelling liquids 失效
标题翻译：凝胶液组合物
公开(公告)号：US5091443A
公开(公告)日：1992-02-25
申请号：US476869
申请日：1990-02-07
申请人： Mutlu Karakelle , Carl D. Benson , Robert A. Taller , David E. Spielvogel
发明人： Mutlu Karakelle , Carl D. Benson , Robert A. Taller , David E. Spielvogel
IPC分类号： A61L15/00 , C02F1/00 , C08B31/00 , C08L1/00 , C08L1/08 , C08L3/00 , C08L3/04 , C08L33/02 , C08L51/02 , C09K3/00
CPC分类号： C08L33/02 , C08L51/02
摘要： A gelling composition for an aqueous liquid includes ungellated starch which has been reacted with a silane coupling agent. In preferred compositions, the starch is a starch-polyacrylate graft copolymer and the composition includes a polyacrylate gelling agent. A disinfectant may be added to the composition for compositions intended for use with medical waste.

2. 发明授权

US5453099A Catheter tubing of controlled in vivo softening 失效
标题翻译：导管可控制体内软化
公开(公告)号：US5453099A
公开(公告)日：1995-09-26
申请号：US245883
申请日：1994-05-18
申请人： Min-Shiu Lee , Mutlu Karakelle , David E. Spielvogel , Robert A. Taller
发明人： Min-Shiu Lee , Mutlu Karakelle , David E. Spielvogel , Robert A. Taller
IPC分类号： A61L29/08 , A61L29/14 , A61M25/00
CPC分类号： A61M25/0054 , A61L29/085 , A61L29/14 , A61M2025/0064
摘要： A catheter tubing has a layer of a hydrophobic stiffening polymer encapsulated by a layer of hydrophilic thermoplastic base polymer. Preferred stiffening polymers are polyesterpolyether block copolymers. Preferred base polymers are thermoplastic polyetherurethanes. The encapsulated layer may be a stripe or an annular layer having base polymer layers laminated on both surfaces thereof.
摘要翻译：导管管具有由一层亲水性热塑性基础聚合物包封的疏水硬化聚合物层。优选的加强聚合物是聚酯聚醚嵌段共聚物。优选的基础聚合物是热塑性聚醚氨基甲酸酯。封装层可以是带状或具有层压在其两个表面上的基础聚合物层的环形层。

3. 发明授权

US5226899A Catheter tubing of controlled in vivo softening 失效
标题翻译：导管可控制体内软化
公开(公告)号：US5226899A
公开(公告)日：1993-07-13
申请号：US746813
申请日：1991-08-15
申请人： Min-Shiu Lee , Mutlu Karakelle , David E. Spielvogel , Robert A. Taller
发明人： Min-Shiu Lee , Mutlu Karakelle , David E. Spielvogel , Robert A. Taller
IPC分类号： A61L29/08 , A61L29/14 , A61M25/00
CPC分类号： A61M25/0054 , A61L29/085 , A61L29/14 , B29C47/0023 , B29C47/065 , A61M2025/0064 , B29L2031/7542
摘要： A catheter tubing has a layer of a hydrophobic stiffening polymer encapsulated by a layer of hydrophilic thermoplastic base polymer. Preferred stiffening polymers are polyesterpolyether block copolymers. Preferred base polymers are thermoplastic polyetherurethanes. The encapsulated layer may be a stripe or an annular layer having base polymer layers laminated on both surfaces thereof.
摘要翻译：导管管具有由一层亲水性热塑性基础聚合物包封的疏水硬化聚合物层。优选的加强聚合物是聚酯聚醚嵌段共聚物。优选的基础聚合物是热塑性聚醚氨基甲酸酯。封装层可以是带状或具有层压在其两个表面上的基础聚合物层的环形层。

4. 发明授权

US5084315A Lubricious coatings, medical articles containing same and method for their preparation 失效
标题翻译：润滑涂料，含有其的医药制品及其制备方法
公开(公告)号：US5084315A
公开(公告)日：1992-01-28
申请号：US473506
申请日：1990-02-01
申请人： Houshang Karimi , Stanley C. Wells , David E. Spielvogel , Mutlu Karakelle , Robert A. Taller
发明人： Houshang Karimi , Stanley C. Wells , David E. Spielvogel , Mutlu Karakelle , Robert A. Taller
IPC分类号： A61L29/00 , A61L29/08 , A61L29/14 , A61L31/00 , A61L33/06
CPC分类号： A61L29/14 , A61L29/085 , A61L33/068 , A61L2400/10
摘要： An article which becomes lubricious when wet includes a base polymer and a coating composition thereon. The composition includes a lubricating polymer and a matrix polymer which adheres to the base polymer and serves as a carrier for the lubricating polymer. The composition may also include a homogenizing polymer to enhance the compatibility of the matrix and lubricating polymer. The invention includes a method to make the article of the invention by coextruding the base polymer and the coating composition.

5. 发明授权

US5266359A Lubricative coating composition, article and assembly containing same and method thereof 失效
标题翻译：润滑涂料组合物，含有其的制品和组合物及其方法
公开(公告)号：US5266359A
公开(公告)日：1993-11-30
申请号：US811476
申请日：1991-12-20
申请人： David E. Spielvogel
发明人： David E. Spielvogel
IPC分类号： A61L29/08 , A61L29/16 , C09D183/06 , C09D183/08 , C10M173/02 , B32B15/02 , A61M25/01 , B05D1/18 , B32B15/08
CPC分类号： C10M173/02 , A61L29/085 , A61L29/16 , C09D183/06 , C09D183/08 , A61L2300/404 , A61L2300/452 , C10M2201/02 , C10M2207/023 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/284 , C10M2207/285 , C10M2207/286 , C10M2207/289 , C10M2209/104 , C10M2209/108 , C10M2209/109 , C10M2215/14 , C10M2229/02 , C10M2229/025 , C10M2229/04 , C10M2229/0405 , C10M2229/041 , C10M2229/0415 , C10M2229/042 , C10M2229/0425 , C10M2229/043 , C10M2229/0435 , C10M2229/044 , C10M2229/0445 , C10M2229/045 , C10M2229/0455 , C10M2229/046 , C10M2229/0465 , C10M2229/047 , C10M2229/0475 , C10M2229/048 , C10M2229/0485 , C10M2229/05 , C10M2229/0505 , C10M2229/051 , C10M2229/0515 , C10M2229/052 , C10M2229/0525 , C10M2229/053 , C10M2229/0535 , C10M2229/054 , C10M2229/0545 , C10N2220/02 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2250/02 , Y10T428/1352 , Y10T428/1355
摘要： A lubricating composition includes an emulsion of a noncuring polysiloxane, a surfactant and water. Preferred polysiloxanes include a polar group, most preferably an aminoalkyl or carboxylalkyl terminating group. Preferred surfactants are copolymers of polysiloxane and polyoxyethylene. A metal article such as a needle, blade, cannula or quidewire includes a coating of the polysiloxane and the surfactant which renders the article surface lubricious. The article may be in a sliding relationship with a plastic article in an assembly such as a catheter-quidewire or a catheter-cannula assembly. The plastic portion of the assembly may also include a lubricant. The invention includes a method of making the lubricated article.
摘要翻译：润滑组合物包括非固化性聚硅氧烷，表面活性剂和水的乳液。优选的聚硅氧烷包括极性基团，最优选氨基烷基或羧基烷基端基。优选的表面活性剂是聚硅氧烷和聚氧乙烯的共聚物。金属制品如针，刀片，插管或绞线包括聚硅氧烷和表面活性剂的涂层，使得制品表面光滑。制品可以与组件中的塑料制品形成滑动关系，诸如导管 - 短管或导管插管组件。组件的塑料部分还可以包括润滑剂。本发明包括制造润滑制品的方法。

6. 发明授权

US5066284A Vent for flashback plug 失效
标题翻译：电子邮件
公开(公告)号：US5066284A
公开(公告)日：1991-11-19
申请号：US350960
申请日：1989-05-11
申请人： Steve H. Mersch , David E. Spielvogel , Charles W. Daugherty
发明人： Steve H. Mersch , David E. Spielvogel , Charles W. Daugherty
IPC分类号： A61M5/158 , A61M5/32 , A61M25/00 , A61M25/06 , A61M39/00
CPC分类号： A61M25/0693
摘要： A flashback vent plug is provided for catheters with air vents drilled by a laser beam which allow venting of the hollow plug upon venous entry, but which vents are so small that blood cannot pass. As a result, no leakage ever takes place. As a further feature of the invention, is the addition of a component to the resin making up the vent plug body which optimizes absorption of the laser beam wave length. The air vent design of this invention provides sufficient cross-section for achieving the required air flow, and therefore rapid flashback and venous entry indication, yet its cost of manufacture is considerably reduced when compared to plug designs that involve multi-step assembly.

7. 发明授权

US4720521A Film-forming silicone compositions having lubricating properties 失效
标题翻译：具有润滑性能的成膜硅酮组合物
公开(公告)号：US4720521A
公开(公告)日：1988-01-19
申请号：US804209
申请日：1985-12-03
申请人： David E. Spielvogel , Richard J. Zdrahala
发明人： David E. Spielvogel , Richard J. Zdrahala
IPC分类号： C08J5/18 , A61L29/08 , A61M5/32 , B32B15/08 , B32B27/00 , C08L83/07 , C09D183/04 , C09D183/07 , C08L83/04
CPC分类号： A61L29/085 , C09D183/04
摘要： A film-forming siloxane composition having excellent adherent and lubricating properties comprising a reactive component having a combination of three siloxane polymers chemically crosslinked, and a non-reactive component dispersed therein. Substrates are dipped or otherwise coated with the compositions, at which time they are cured quickly under heat to a durable, adherent lubricating surface which is dry to the touch. Of particular advantage is the use of these films on hypodermic needles, razor blades, catheters and the like.
摘要翻译：具有优异的粘附性和润滑性的成膜硅氧烷组合物包括具有三种经过化学交联的硅氧烷聚合物和分散在其中的非反应性组分的组合的反应性组分。底物被浸渍或以其他方式涂覆组合物，此时它们在加热下快速固化成耐干燥的粘合润滑表面，该表面是干燥的。特别的优点是在皮下注射针，剃刀刀片，导管等上使用这些膜。

8. 发明授权

US3954823A Interconversion of stereoisomeric cycloorganosiloxanes 失效
标题翻译：立体异构环绕有机硅氧烷的相互转化
公开(公告)号：US3954823A
公开(公告)日：1976-05-04
申请号：US583304
申请日：1975-06-02
申请人： Cecil L. Frye , David E. Spielvogel
发明人： Cecil L. Frye , David E. Spielvogel
IPC分类号： B01J27/00 , C07B61/00 , C07F7/08 , C07F7/21 , C07F7/02 , C07F7/20
CPC分类号： C07F7/21 , C07F7/0874
摘要： Stereoisomers of cycloorganosiloxanes are interconverted without siloxane bond redistribution by reacting the cyclic siloxane with anhydrous zinc chloride, zinc bromide, ferric chloride, aluminum chloride or aryl phosphonium chlorides in the presence of nitro compounds or aryl phosphate esters as solvents. A typical example is the conversion of 2,6-trans-diphenylhexamethylcyclotetrasiloxane to the 2,6-cis-isomer by heating in 2-nitropropane solvent in the presence of anhydrous zinc chloride.
摘要翻译：环氧硅氧烷的立体异构体通过在硝基化合物或芳基磷酸酯作为溶剂的存在下使环状硅氧烷与无水氯化锌，溴化锌，氯化铁，氯化铝或芳基氯化鏻反应而相互转化而不发生硅氧烷键的再分布。典型的实例是在无水氯化锌存在下，通过在2-硝基丙烷溶剂中加热，将2,6-反式二苯基六甲基环四硅氧烷转化成2,6-顺式异构体。

9. 发明授权

US5185006A Lubricated metal articles and assembly containing same 失效
标题翻译：润滑金属制品及其装配
公开(公告)号：US5185006A
公开(公告)日：1993-02-09
申请号：US628139
申请日：1990-12-17
申请人： Victor A. Williamitis , David E. Spielvogel
发明人： Victor A. Williamitis , David E. Spielvogel
IPC分类号： A61B17/04 , A61B17/00 , A61B17/34 , A61L29/08 , A61M5/32 , A61M25/00 , B05D7/14 , B05D7/24 , C09D183/06 , C09D183/08
CPC分类号： C09D183/08 , A61L29/085 , A61M25/0045 , A61M5/32 , C09D183/06 , A61B2017/00845
摘要： A metal article has a coating of a noncuring polar lubricant. Preferred articles are of stainless steel and may be cutting devices such as needles, lancets and cannulas or sliding devices such as stylets and guidewires. Preferred noncuring polar lubricants are polysiloxanes terminated with a polar group. Particularly preferred lubricants are aminoalkyl or carboxyalkyl polysiloxanes. The lubricated metal article may be in a sliding relationship with a plastic article such as a catheter-guidewire or a catheter-cannula assembly. The plastic portion of the assembly may also include a lubricant.

10. 发明授权

US5038708A Apparatus for coating the internal surfaces of tubular structures 失效
标题翻译：用于涂覆管状结构的内表面的装置
公开(公告)号：US5038708A
公开(公告)日：1991-08-13
申请号：US468037
申请日：1990-01-22
申请人： Stanley C. Wells , David E. Spielvogel , Paul M. Hendess
发明人： Stanley C. Wells , David E. Spielvogel , Paul M. Hendess
IPC分类号： B05B13/06
CPC分类号： B05B13/0627 , Y10S118/10
摘要： Apparatus designed to coat the internal surfaces of tubular structures, and particularly for coating small diameter tubular structures having porous walls with a controlled coating material which may be a polymer, for example. The arrangement includes structure for rotating the tube to be coated simultaneously with structure for moving a coating applicator apparatus longitudinally through the tube for imparting an evenly dispersed coating throughout the longitudinally extent thereof. The arrangement is such that the apparatus may, selectively, impart a water or other solvent spray against, the already formed coating for extraction of a solvent from the coating. The coating characteristics (i.e., uniformity, thickness and pattern) are controlled by the use of a sintered metal and/or porous applicator, together with a controlled pressurized source of coating material.
摘要翻译：设计用于涂覆管状结构的内表面的装置，特别是用于涂覆具有多孔壁的小直径管状结构，其具有例如可以是聚合物的可控涂层材料。该装置包括用于同时旋转待涂覆的管的结构，用于使涂布器纵向移动通过管的结构，用于在其纵向范围内赋予均匀分散的涂层。该装置使得该装置可以选择性地将水或其它溶剂喷雾抵靠已经形成的涂层，用于从涂层中提取溶剂。通过使用烧结金属和/或多孔施加器以及受控加压的涂覆材料源来控制涂层特性（即，均匀性，厚度和图案）。

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