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    • 4. 发明授权
    • Lithographic printing plate
    • 平版印刷版
    • US4480549A
    • 1984-11-06
    • US454554
    • 1982-12-30
    • Kiyomi SakuraiSeiji Arimatsu
    • Kiyomi SakuraiSeiji Arimatsu
    • B41N1/08
    • B41N1/08Y10T428/12438Y10T428/12993
    • A lithographic printing plate which comprises:(a) a support comprising an iron foil prepared by electroforming,wherein one surface of said foil is in contact with an electrolyte and the opposite surface is in contact with a negative electrode,said foil being electroplated with a hydrophilic metal on both surfaces, and(b) an oleophilic image area formed from a photo-sensitive resin on said surface of the hydrophilic metal coated iron foil, which was in contact with said electrolyte and a non-image area where said resin is not present on said surface of said hydrophilic metal coated iron foil which was in contact with said electrolyte,said non-image area exhibiting good hydrophilic and water retentive properties in lithographic printing.
    • 一种平版印刷版,其特征在于,包括:(a)包含通过电铸制备的铁箔的载体,其中所述箔的一个表面与电解质接触并且所述相对表面与负极接触,所述箔被电镀 亲水金属在两个表面上,以及(b)亲水性影像区域,由感光树脂形成在与所述电解质接触的亲水性金属涂覆的铁箔的所述表面上,以及所述树脂不是的非图像区域 存在于与所述电解质接触的所述亲水性金属被覆铁箔的所述表面上,所述非图像区域在平版印刷中表现出良好的亲水和保水性。
    • 6. 发明授权
    • Water developable photopolymerizable composition and printing plate
element containing same
    • 水可显影光聚合组合物和含有它的印版元件
    • US4540649A
    • 1985-09-10
    • US649905
    • 1984-09-12
    • Kiyomi Sakurai
    • Kiyomi Sakurai
    • C08F2/00C08F2/48G03C1/08G03F7/004G03F7/027G03F7/038G03C1/68
    • G03F7/027Y10S430/106Y10S430/107Y10S430/11
    • A water developable, photopolymerizable composition and printing plates prepared from such composition are disclosed. The photopolymerizable composition includes at least one water soluble polymer, such as polyvinyl alcohol or partially saponified polyvinyl acetate, at least one photopolymerization initiator, and the condensation reaction product of N-methylol acrylamide, N-methylol methacrylamide, N-alkyloxymethyl acrylamide or N-alkyloxymethyl methacrylamide with a melamine derivative of the following formula: ##STR1## wherein, R.sub.1 is CH.sub.2 OR, R.sub.2 is H or CH.sub.2 OR, and R is C.sub.1 -C.sub.4 alkyl. A thermal polymerization inhibitor may also be included in the composition.Plates prepared from the composition demonstrate improved hardness and water resistance, compared to previously known photopolymerizable compositions, and also achieve excellent image quality.
    • 公开了由这种组合物制备的可显影水的可光聚合组合物和印刷板。 可光聚合组合物包括至少一种水溶性聚合物,例如聚乙烯醇或部分皂化的聚乙酸乙烯酯,至少一种光聚合引发剂,以及N-羟甲基丙烯酰胺,N-羟甲基甲基丙烯酰胺,N-烷氧基甲基丙烯酰胺或N-烷氧基甲基丙烯酰胺的缩合反应产物, 烷氧基甲基甲基丙烯酰胺与下式的三聚氰胺衍生物:其中,R 1为CH 2 OR,R 2为H或CH 2 O,R为C 1 -C 4烷基。 组合物中也可以包括热聚合抑制剂。 与以前已知的可光聚合组合物相比,由组合物制备的板显示出改善的硬度和耐水性,并且还实现优异的图像质量。
    • 7. 发明授权
    • Flexographic printing plates and process for making the same
    • 柔版印刷版和制作相同的工艺
    • US4517278A
    • 1985-05-14
    • US407825
    • 1982-08-13
    • Kiyomi Sakurai
    • Kiyomi Sakurai
    • G03F7/033G03C1/72
    • G03F7/033Y10S430/119
    • A photosensitive resin composition useful for preparation of flexographic printing plates, which comprises syndiotactic 1,2-polybutadiene, an ethylenically unsaturated monomer and a photo-polymerization initiator, the syndiotactic 1,2-polybutadiene having an average molecular weight of from about 10,000 to 300,000, a 1,2-unit content of at least about 80 percent and a crystallinity of about 10 to 30 percent, said ethylenically unsaturated monomer being an ester of acrylic or methacrylic acid with an alkanol having from 4 to 20 carbon atoms, and the photo-polymerization initiator being benzoin or an alkyl ether thereof. The photosensitive resin composition, when formed into sheets, exhibits satisfactory resistance to liquids used for washing out the uncured areas and at also to aqueous or alcoholic printing inks, thereby producing patterns in relief that give excellent overall sharpness. It also possesses desired hardness and elasticity for flexographic printing plates.
    • 用于制备柔性版印刷版的感光性树脂组合物,其包含间规1,2-聚丁二烯,烯属不饱和单体和光聚合引发剂,间同立构1,2-聚丁二烯的平均分子量为约10,000〜300,000 ,至少约80%的1,2-单元含量和约10至30%的结晶度,所述烯键式不饱和单体是丙烯酸或甲基丙烯酸与具有4至20个碳原子的链烷醇的酯,和照片 聚合引发剂是苯偶姻或其烷基醚。 感光性树脂组合物形成片状时,对未固化区域以及水性或醇类印刷油墨的洗涤用液体表现出良好的耐受性,从而产生赋予优异的整体清晰度的图案。 它还具有柔性版印刷版所需的硬度和弹性。
    • 10. 发明授权
    • Photopolymer intaglio printing plate
    • 光聚合物凹版印刷版
    • US4275143A
    • 1981-06-23
    • US175859
    • 1980-08-06
    • Kiyomi Sakurai
    • Kiyomi Sakurai
    • G03F7/30B41N1/20G03F5/20G03C5/00
    • B41N1/20G03F5/20
    • A photopolymer intaglio printing plate comprising a support member and a photopolymer layer provided thereon, said layer having concave portions of a constant depth as ink cells and the lowermost part of each of the concave portions reaching to the surface of the support member so that the surface of the support member is exposed to air at least as a point at said lowermost part, prepared by subjecting a photosensitive plate comprising the support member and a layer of a photopolymerizable composition provided thereon to exposure through a halftone negative or positive film to such an extent that the photopolymerizable composition at the exposed parts is cured down to the bottom of the photopolymerizable composition layer but the photopolymerizable composition at the non-exposed part having a minimum area remains uncured at the lowermost part corresponding to the center of the said non-exposed part and washing out completely the photopolymerizable composition at the non-exposed parts.
    • 一种光聚合物凹版印刷版,其特征在于,包括支撑部件和设置在其上的光聚合物层,所述层具有作为墨水池的恒定深度的凹部,并且每个凹部的最下部到达支撑部件的表面, 至少在所述最低部分处的空气暴露于空气,其通过使包含支撑构件的感光性板和设置在其上的可光聚合组合物的层通过半色调负片或正片曝光而达到这样的程度 暴露部分的光聚合组合物固化到可光聚合组合物层的底部,但是在具有最小面积的未曝光部分处的光聚合组合物在对应于所述非曝光部分的中心的最下部分保持未固化 并在非曝光部分完全洗出可光聚合组合物。