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1. 发明授权

US4657991A Precursor composition of silicon carbide 失效
标题翻译：前体组成的碳化硅
公开(公告)号：US4657991A
公开(公告)日：1987-04-14
申请号：US787328
申请日：1985-10-15
申请人： Minoru Takamizawa , Taishi Kobayashi , Toshinobu Ishihara , Yoshihumi Takeda , Akira Hayashida
发明人： Minoru Takamizawa , Taishi Kobayashi , Toshinobu Ishihara , Yoshihumi Takeda , Akira Hayashida
IPC分类号： C08L83/00 , C04B35/571 , C08G79/00 , C08L83/02 , C08L83/16 , D01F9/10 , C08F283/00
CPC分类号： C08G79/00 , C04B35/571 , C08L83/16
摘要： The precursor composition of silicon carbide fibers provided by the invention has greatly improved spinnability and can be spun at a very high spinning velocity to give a green filament which has a much larger tensile strength than those of conventional precursor materials and is capable of giving silicon carbide fibers having increased tensile strength by the infusibilization and calcination of the green filament of the composition under tension. The composition comprises from 80 to 99.9 parts by weight of a polycarbosilane polymer and from 20 to 0.01 part by weight of a silmethylene polymer having a degree of polymerization larger than the specified lower limit.
摘要翻译：由本发明提供的碳化硅纤维的前体组合物大大提高了可纺性，并且可以以非常高的纺丝速度纺丝，得到具有比常规前体材料高的拉伸强度的绿色长丝，并且能够提供碳化硅纤维通过在张力下的组合物的绿色细丝的不熔化和煅烧而具有增加的拉伸强度。该组合物包含80-99.9重量份的聚碳硅烷聚合物和20至0.01重量份具有大于规定下限的聚合度的硅亚甲基聚合物。

2. 发明授权

US4604367A Method for the preparation of an inorganic fiber containing silicon, carbon, boron and nitrogen 失效
标题翻译：制备含有硅，碳，硼和氮的无机纤维的方法
公开(公告)号：US4604367A
公开(公告)日：1986-08-05
申请号：US682796
申请日：1984-12-18
申请人： Minoru Takamizawa , Taishi Kobayashi , Akira Hayashida , Yoshihumi Takeda
发明人： Minoru Takamizawa , Taishi Kobayashi , Akira Hayashida , Yoshihumi Takeda
IPC分类号： D01F9/10 , C04B35/571 , C08G79/00 , C08G79/08 , D01F9/08 , C04B35/02
CPC分类号： D01F9/08 , C04B35/571 , C08G79/08
摘要： The invention provides a novel inorganic fiber composed of the elements of silicon, carbon, boron and nitrogen of which the Si/B molar ratio is 2:1 to 200:1. The inorganic fiber is obtained by a method comprising the steps of: (a) preparing an organoborosilicon polymer by heating a mixture of an organopolysilane and an organoborazine compound, e.g. B-trimethyl-N-triphenyl borazine, to effect thermal decomposition and polycondensation reaction; (b) spinning the polymer into a fibrous form; (c) infusibilizing the fiber of the polymer by thermally oxidizing in an oxidizing atmosphere or by irradiating with ionizing radiations; and (d) calcining the infusibilized fiber at 900.degree. to 1800.degree. C. The inventive inorganic fiber is more stable at high temperatures than conventional silicon carbide fibers.
摘要翻译：本发明提供一种由硅，碳，硼和氮元素组成的新型无机纤维，Si / B摩尔比为2：1至200：1。无机纤维通过包括以下步骤的方法获得：（a）通过加热有机聚硅烷和有机硼嗪化合物的混合物制备有机硼硅聚合物，例如 B-三甲基-N-三苯基环硼氮烷进行热分解和缩聚反应; （b）将聚合物纺丝成纤维状; （c）通过在氧化气氛中热氧化或通过照射电离辐射来使聚合物的纤维熔融化; 和（d）在900〜1800℃煅烧不熔化纤维。本发明的无机纤维在高温下比常规碳化硅纤维更稳定。

3. 发明授权

US4550151A Organoborosilicon polymer and a method for the preparation thereof 失效
标题翻译：有机硼硅聚合物及其制备方法
公开(公告)号：US4550151A
公开(公告)日：1985-10-29
申请号：US678221
申请日：1984-12-05
申请人： Minoru Takamizawa , Taishi Kobayashi , Akira Hayashida , Yoshihumi Takeda
发明人： Minoru Takamizawa , Taishi Kobayashi , Akira Hayashida , Yoshihumi Takeda
IPC分类号： C08G77/00 , C08G77/48 , C08G77/56 , C08G77/60 , C08G79/00 , C08G79/02 , C08G79/08
CPC分类号： C08G77/60 , C08G79/08
摘要： The invention provides a novel organoborosilicon polymer comprising two types of the recurring monomeric units represented by the general formulas of, one, --SiR.sup.1.sub.2 --CH.sub.2 -- and, the other, --BR.sup.2 --NR.sup.3 --, in which R.sup.1, R.sup.2 and R.sup.3 are each a hydrogen atom or a monovalent hydrocarbon group. Such an organoborosilicon polymer is readily prepared by the thermal decomposition polymerization reaction of an organopolysilane compound and a borazine compound at 250.degree. to 500.degree. C. and useful as a precursor of an inorganic ceramic material or inorganic fibers or as a binder of ceramics.
摘要翻译：本发明提供了一种新型的有机硼硅聚合物，其包含由以下通式表示的两种类型的重复单体单元：一个，-SiR 12 -CH 2 - 和另一个-BR 2 -NR 3 - ，其中R 1，R 2和R 3各自为氢原子或一价烃基。这种有机硼硅聚合物可以容易地通过有机聚硅烷化合物和环硼氮烷化合物的热分解聚合反应在250-500℃下制备，并且可用作无机陶瓷材料或无机纤维或陶瓷的粘合剂的前体。

4. 发明授权

US4571331A Ultrafine powder of silicon carbide, a method for the preparation thereof and a sintered body therefrom 失效
标题翻译：超细碳化硅粉末，其制备方法和烧结体
公开(公告)号：US4571331A
公开(公告)日：1986-02-18
申请号：US560389
申请日：1983-12-12
申请人： Morinobu Endou , Minoru Takamizawa , Tatsuhiko Hongu , Taishi Kobayashi , Akira Hayashida , Nobuaki Urasato , Hiromi Ohsaki , Nichiro Suzuki , Takasi Toide
发明人： Morinobu Endou , Minoru Takamizawa , Tatsuhiko Hongu , Taishi Kobayashi , Akira Hayashida , Nobuaki Urasato , Hiromi Ohsaki , Nichiro Suzuki , Takasi Toide
IPC分类号： C01B31/36 , C04B35/565 , C04B35/575
CPC分类号： B82Y30/00 , C01B31/36 , C04B35/565 , C04B35/575 , C01P2002/72 , C01P2002/82 , C01P2004/62 , C01P2004/64 , C01P2006/40
摘要： The invention provides a method for the preparation of an ultrafine powder of silicon carbide having an extremely fine and uniform particle size distribution of spherical agglomerate particles each formed of crystallites of 5 nm or smaller in size. The silicon carbide powder is prepared by the vapor phase pyrolysis of a specified methyl hydrogen(poly)silane as diluted with a carrier gas, e.g. hydrogen, to give a concentration of 40% by volume or lower at a temperature of 750.degree. to 1600.degree. C. The silicon carbide powder can readily be sintered at a temperature of 1750.degree. to 2500.degree. C. even without addition of a sintering aid to give a sintered body of extremely high density reaching 80% or larger of the theoretical value which can never be obtained of the conventional silicon carbide powders.
摘要翻译：本发明提供一种制备碳化硅超细粉末的方法，其具有均匀的颗粒尺寸分布的球形聚集体颗粒，它们各自由5nm或更小的微晶形成。碳化硅粉末通过气相热分解制备，所述气相热分解用载气稀释的特定甲基氢（聚）硅烷。氢气，在750〜1600℃的温度下浓度为40体积％以下。碳化硅粉末可以容易地在1750〜2500℃的温度下烧结，即使不添加烧结助剂得到非常高密度的烧结体达到常规碳化硅粉末不可获得的理论值的80％以上。

5. 发明授权

US4461908A Method for the preparation of methyl hydrogensilanes 失效
标题翻译：甲基氢硅烷的制备方法
公开(公告)号：US4461908A
公开(公告)日：1984-07-24
申请号：US481867
申请日：1983-04-04
申请人： Minoru Takamizawa , Mitsuo Umemura , Taishi Kobayashi
发明人： Minoru Takamizawa , Mitsuo Umemura , Taishi Kobayashi
IPC分类号： C07F7/08
CPC分类号： C07F7/0896
摘要： The invention provides a novel and efficient method for the preparation of methyl hydrogensilanes, e.g. dimethyl silane, 1,1,2,2-tetramethyl disilane and 1,1,2,2,3,3-hexamethyl trisilane, with large demand in the industry of silicones as an intermediate for the synthesis of other valuable organosilicon compounds such as methyl hydrogenchlorosilanes. The inventive method comprises pyrolysis of a methyl polysilane composed of at least 60% by moles of dimethylsilicon units, the balance being monomethyl- and trimethylsilicon units, at a temperature in the range from 350.degree. to 800.degree. C.
摘要翻译：本发明提供了一种制备甲基氢硅烷的新型和有效的方法，例如二甲基硅烷，1,1,2,2-四甲基乙硅烷和1,1,2,2,3,3-六甲基丙硅烷，其中硅氧烷作为合成其它有价值的有机硅化合物的中间体有很大的需求，如甲基氢氯硅烷。本发明的方法包括在350℃至800℃的温度范围内热解由至少60摩尔％的二甲基硅单元组成的甲基聚硅烷，余量为单甲基和三甲基硅单元。

6. 发明授权

US4676966A Method for the preparation of a fine powder of silicon carbide 失效
标题翻译：制备碳化硅细粉的方法
公开(公告)号：US4676966A
公开(公告)日：1987-06-30
申请号：US706238
申请日：1985-02-27
申请人： Morinobu Endo , Minoru Takamizawa , Tatsuhiko Hongu , Taishi Kobayashi
发明人： Morinobu Endo , Minoru Takamizawa , Tatsuhiko Hongu , Taishi Kobayashi
IPC分类号： C01B31/36
CPC分类号： C01B31/36 , C01P2002/72 , C01P2002/82 , C01P2004/62 , C01P2006/60
摘要： The invention provides a novel method for the preparation of a finely divided powder of silicon carbide as a promising material for sintered ceramic products of silicon carbide. The method comprises vapor-phase pyrolysis of a vaporizable organosilicon compound having, in a molecule, at least two, e.g. 2, 3 or 4, silicon atoms and at least one hydrogen atom directly bonded to the silicon atom but having no oxygen or halogen atom directly bonded to the silicon atom at a temperature of 750.degree. C. or higher.
摘要翻译：本发明提供了一种制备碳化硅细碎粉末作为碳化硅烧结陶瓷产品有希望的材料的新方法。该方法包括在一分子中具有至少两个例如至少两个的可汽化的有机硅化合物的气相热解。 2,3或4，硅原子和至少一个氢原子直接键合到硅原子上，但是在750℃或更高的温度下没有直接与硅原子键合的氧或卤素原子。

7. 发明授权

US4560589A Method for providing a coating layer of silicon carbide on substrate surface 失效
标题翻译：在基板表面上提供碳化硅涂层的方法
公开(公告)号：US4560589A
公开(公告)日：1985-12-24
申请号：US533649
申请日：1983-09-19
申请人： Morinobu Endou , Minoru Takamizawa , Tatsuhiko Hongu , Taishi Kobayashi
发明人： Morinobu Endou , Minoru Takamizawa , Tatsuhiko Hongu , Taishi Kobayashi
IPC分类号： C04B41/50 , C04B41/87 , C23C16/32 , D01F11/12 , D06M11/00
CPC分类号： C04B41/009 , C04B41/5059 , C04B41/87 , C23C16/325 , D01F11/126 , Y10S438/931
摘要： The invention provides a method for providing a highly protective coating layer of silicon carbide on to the surface of a substrate. The method comprises pyrolyzing the vapor of an organosilicon compound having at least one hydrogen atom directly bonded to the silicon atom in a molecule but having no halogen or oxygen atom directly bonded to the silicon atom at a temperature of 700.degree. to 1400.degree. C. in contact with the substrate surface to deposit silicon carbide thereon. In particular, the method is useful to form a sheath-and-core structure composed of the core of carbon filament and the coating layer of silicon carbide so that the carbon fibers are imparted with greatly improved resistance against oxidation and chemicals including molten metals when the carbon fibers are used as a reinforcing material of a fiber-reinforced metal composite as well as with improved affinity with molten resins and metals which is also an advantageous property as a reinforcing material for such matrix materials.
摘要翻译：本发明提供了一种在基材表面上提供碳化硅高保护性涂层的方法。该方法包括将分子中具有至少一个与硅原子键合的至少一个氢原子的有机硅化合物的蒸气热分解，但在700℃至1400℃的温度下直接与硅原子键合的卤原子或氧原子，与基底表面接触以在其上沉积碳化硅。特别地，该方法可用于形成由碳丝芯和碳化硅的涂层组成的皮 - 芯结构，从而使得碳纤维在氧化时具有极大的改善的抗性和包括熔融金属在内的化学物质碳纤维用作纤维增强金属复合材料的增强材料，并且与熔融树脂和金属具有改进的亲和性，这也是作为这种基体材料的增强材料的有利特性。

8. 发明授权

US4492681A Method for the preparation of silicon carbide fibers 失效
标题翻译：碳化硅纤维的制备方法
公开(公告)号：US4492681A
公开(公告)日：1985-01-08
申请号：US505250
申请日：1983-06-17
申请人： Morinobu Endou , Minoru Takamizawa , Tatsuhiko Hongu , Taishi Kobayashi
发明人： Morinobu Endou , Minoru Takamizawa , Tatsuhiko Hongu , Taishi Kobayashi
IPC分类号： C01B31/36 , C04B35/571 , C30B25/00 , D01F9/10
CPC分类号： D01F9/10 , C04B35/571 , C30B25/005 , C30B29/36
摘要： The invention provides a novel method for the preparation of silicon carbide fibers capable of being performed at a relatively low temperature and giving fibers of relatively large lengths by the vapor-phase pyrolysis of an organosilicon compound on a substrate. The method comprises contacting an organosilicon compound, which should have no halogen and oxygen atoms directly bonded to the silicon atoms and have preferably at least one hydrogen atom directly bonded to the silicon atom in a molecule, with a finely divided powder of a metal or a compound of a metal, such as copper, silver, vanadium, niobium, tantalum, iron, cobalt, nickel, palladium and platinum, at a temperature of 700.degree. to 1450.degree. C. so that the powder serves simultaneously as a catalyst and nucleus for the growth of the silicon carbide fibers thereon formed by the pyrolysis of the organosilicon compound. When the organosilicon compound is deficient of the carbon content relative to the silicon so that free silicon may be formed by the pyrolysis, admixing of a hydrocarbon to the feed of the organosilicon compound can solve the problem.
摘要翻译：本发明提供了一种制备能够在较低温度下进行的碳化硅纤维的新方法，并且通过基底上的有机硅化合物的气相热解产生相当长的纤维。该方法包括将不具有卤素和氧原子的有机硅化合物直接键合到硅原子上，并且优选具有至少一个与分子中的硅原子键合的至少一个氢原子，与金属或金属的化合物，例如铜，银，钒，铌，钽，铁，钴，镍，钯和铂，在700°至1450℃的温度下，使粉末同时作为催化剂和核通过有机硅化合物的热解形成的碳化硅纤维的生长。当有机硅化合物相对于硅缺乏碳含量时，可以通过热解形成游离硅，将烃与有机硅化合物的进料混合可以解决问题。

9. 发明申请

US20100041824A1 Water absorbent resin production method and usage thereof 有权
标题翻译：吸水树脂的制造方法及其用途
公开(公告)号：US20100041824A1
公开(公告)日：2010-02-18
申请号：US12530976
申请日：2008-03-14
申请人： Kazushi Torii , Taishi Kobayashi
发明人： Kazushi Torii , Taishi Kobayashi
IPC分类号： C08L33/02 , C08G69/00 , C08G63/00
CPC分类号： C08J3/245 , B01J20/267 , C08F20/06 , C08J2333/02 , C08L33/02 , C08L71/02 , C08L2666/22
摘要： A method for producing a water absorbent resin comprises the steps of: (i) polymerizing a monomer including an unsaturated monomer containing a carboxyl group, in the presence of an internal cross-linking agent (A) having two or more radical polymerizable unsaturated groups in its single molecule and in the presence of a non-polymeric internal cross-linking agent (B) having in its single molecule two or more functional groups each of which allows formation of an ester bond or an amide bond by reacting with a carboxyl group so as to obtain a cross-linked polymer hydrogel; (ii) crushing the cross-linked polymer hydrogel obtained in the step (i); and (iii) drying crushed cross-linked polymer hydrogel products obtained in the step (ii), wherein: an amount of the internal cross-linking agent (A) is 0.01 mol % or more and 0.2 mol % or less relative to an amount of the unsaturated monomer containing a carboxyl group, and a molar ratio (B)/(A) of the internal cross-linking agent (A) and the non-polymeric internal cross-linking agent (B) is 0.01 or more and 1.8 or less.
摘要翻译：一种吸水性树脂的制造方法，其特征在于：（i）在具有2个以上自由基聚合性不饱和基团的内部交联剂（A）的存在下，使含有羧基的不饱和单体的单体聚合，其单分子和在其单分子中具有两个或多个官能团的非聚合内部交联剂（B）的存在下，每个可通过与羧基反应形成酯键或酰胺键，因此获得交联聚合物水凝胶; （ii）粉碎步骤（i）中获得的交联聚合物水凝胶; 和（iii）干燥步骤（ii）中获得的粉碎的交联聚合物水凝胶产物，其中：内部交联剂（A）的量相对于一定量的0.01mol％以上且0.2mol％以下的含有羧基的不饱和单体，内部交联剂（A）与非聚合内部交联剂（B）的摩尔比（B）/（A）为0.01以上1.8以下减。

10. 发明授权

US4592856A Liquid detergent composition 失效
标题翻译：液体洗涤剂组合物
公开(公告)号：US4592856A
公开(公告)日：1986-06-03
申请号：US667537
申请日：1984-11-02
申请人： Taishi Kobayashi , Shinichiro Akase
发明人： Taishi Kobayashi , Shinichiro Akase
IPC分类号： C11D3/30 , C11D3/43 , C11D7/22
CPC分类号： C11D3/30 , C11D3/43
摘要： The liquid detergent composition of the invention comprises a halogenated hydrocarbon solvent, e.g. methylene chloride, an anionic and/or non-ionic surface active agents, a quaternary ammonium hydroxide, e.g. tetramethyl ammonium hydroxide and choline, and, optionally, a lower aliphatic alcohol, e.g. methyl alcohol, each in a limited proportion. The detergent composition is very effective in the cleaning works of articles of a transparent plastic resin, e.g. polycarbonate resin, and metal or glass molds for the preparation of such resin articles by casting polymerization, of which uppermost cleanness on the surface is very essential in respect of oily, greasy and resinous contaminants.
摘要翻译：本发明的液体洗涤剂组合物包括卤代烃溶剂，例如，二氯甲烷，阴离子和/或非离子表面活性剂，季铵氢氧化物，例如。四甲基氢氧化铵和胆碱，以及任选的低级脂族醇，例如。甲醇，各有限。洗涤剂组合物在透明塑料树脂制品的清洁工程中是非常有效的，例如，聚碳酸酯树脂，以及用于通过浇铸聚合制备这种树脂制品的金属或玻璃模具，其表面上最清洁度在油性，油脂和树脂污染物方面是非常必要的。

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