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    • 8. 发明申请
    • METHOD OF PRODUCING CORE/SHELL COMPOSITE NANO-PARTICLES
    • 生产核/壳复合纳米颗粒的方法
    • US20100215851A1
    • 2010-08-26
    • US12596994
    • 2007-04-25
    • Tetsuya ShojiNaoki NakamuraAkira KatoShinpei YamamotoMikio TakanoTeruo Ono
    • Tetsuya ShojiNaoki NakamuraAkira KatoShinpei YamamotoMikio TakanoTeruo Ono
    • B05D7/00
    • B22F1/025B22F1/0018B22F9/24B22F9/305B82Y30/00
    • A method of producing core/shell composite nano-particles exhibiting superior characteristics, by using as cores nano-particles heat treated in advance so as to give them a specific crystal structure in a state using a barrier layer to prevent sintering and forming shells on their surface, which eliminates hindrances to the shell forming reaction due to the phase transfer catalyst or other strongly sticky dispersant, is provided. A method of producing core/shell composite nano-particles comprising nano-sized core particles covered by shells, the method comprising dispersing core particles heat treated in advance to give them a crystal structure expressing the necessary characteristics in a first organic solvent by a first dispersant to prepare a first solution, adding a polar solvent to peel off the first dispersant from the core particles and making the nano-particles agglomerate to recover them, making the recovered core particles disperse in a second organic solvent by a second dispersant to form a second solution, and adding a precursor of the shells to the second solution and forming shells on the surfaces of the core particles.
    • 通过使用预先热处理的核心纳米粒子来制造具有优异特性的核/壳复合纳米粒子的方法,以便在使用阻挡层的状态下给予其特定的晶体结构,以防止烧结和形成壳体 表面,其消除了由于相转移催化剂或其它强粘性分散剂而导致的壳形成反应的障碍。 一种制造核壳复合纳米颗粒的方法,其包括由壳覆盖的纳米尺寸的核心颗粒,该方法包括将预先热处理的芯颗粒分散在第一有机溶剂中,通过第一分散剂给予它们表达必要特性的晶体结构 制备第一溶液,加入极性溶剂以从芯颗粒上剥离第一分散剂并使纳米颗粒凝聚回收,使回收的芯颗粒通过第二分散剂分散在第二有机溶剂中以形成第二溶剂 溶液,并将壳的前体添加到第二溶液中并在芯颗粒的表面上形成壳。