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    • 6. 发明申请
    • POSITIVE ELECTRODE FOR LITHIUM SECONDARY BATTERIES AND LITHIUM SECONDARY BATTERY
    • 锂二次电池和锂二次电池的正极
    • US20100297503A1
    • 2010-11-25
    • US12783746
    • 2010-05-20
    • Kan KitagawaAtsushi UedaToyotaka YuasaTatsuya Toyama
    • Kan KitagawaAtsushi UedaToyotaka YuasaTatsuya Toyama
    • H01M4/58
    • H01M4/5825H01M4/136H01M4/621H01M10/0525
    • A positive electrode for lithium secondary batteries and a lithium secondary battery are provided in which, by using an olivine Mn based positive-electrode active material and an optimal binder for the olivine Mn based positive-electrode active material, peel-off of the electrode and gelatinization of the slurry can be prevented, with large energy density, excellent in rate characteristic and cycle life. The positive electrode includes a positive-electrode composite including at least a positive-electrode active material and a binder; and a positive-electrode current collector. The positive-electrode active material includes a lithium composite oxide having an olivine-type structure, which is represented by the formula LiMnxM1−xPO4 (where 0.3≦x≦1 and M is one or more elements selected from the group consisting of Li, Fe, Ni, Co, Ti, Cu, Zn, Mg, and Zr) . The binder includes an acrylonitrile-based copolymer.
    • 提供了一种锂二次电池用正极和锂二次电池,其中,通过使用橄榄石Mn系正极活性物质和橄榄石Mn系正极活性物质的最佳粘合剂,电极剥离和 可以防止浆料糊化,能量密度大,速率特性和循环寿命优异。 正极包括至少包含正极活性物质和粘合剂的正极复合体; 和正极集电体。 正极活性物质包括具有橄榄石型结构的锂复合氧化物,其由式LiMn x M 1-x PO 4表示(其中,0.3< 1lE; x≦̸ 1和M是选自Li, Fe,Ni,Co,Ti,Cu,Zn,Mg和Zr)。 粘合剂包括丙烯腈基共聚物。
    • 8. 发明授权
    • Secondary lithium battery
    • 二次锂电池
    • US08530087B2
    • 2013-09-10
    • US13015061
    • 2011-01-27
    • Kan KitagawaToyotaka YuasaTatsuya Tooyama
    • Kan KitagawaToyotaka YuasaTatsuya Tooyama
    • H01M4/62H01M4/50H01M4/52
    • H01M4/26H01M4/62Y10T29/49108Y10T29/49115
    • It is an object to provide a cathode for a secondary lithium battery in which adhesiveness and flexibility thereof are simultaneously achieved and the thickness thereof is made large, and the secondary lithium ion battery that has a large capacity and is excellent in safety and cycle life using the cathode.The cathode includes a current collector and a cathode mixture layer formed on the surface of the current collector. The cathode mixture layer is formed by stacking two layers one on another, each of which contains a cathode active material, a conductive material and a binder, and the cathode active material contains a lithium-containing composite oxide that forms a polyanion. Of the two layers, the binder that composes a first layer that is in contact with the current collector contains a polymer formed by polymerizing at least one of monomers consisting of a monomer derived from 1-olefin and a monomer derived from a vinyl compound; and the binder that forms a second layer formed on the first layer contains a fluorine resin.
    • 本发明的目的是提供一种用于二次锂电池的阴极,其中同时实现其粘附性和柔性并且其厚度变大,并且具有大容量并且安全性和循环寿命优异的二次锂离子电池使用 阴极。 阴极包括在集电体的表面上形成的集电体和阴极混合层。 阴极混合层通过层叠两层而形成,其中每层包含阴极活性材料,导电材料和粘合剂,并且阴极活性材料含有形成聚阴离子的含锂复合氧化物。 在两层中,构成与集电体接触的第一层的粘合剂含有通过使由至少一种由1-烯烃衍生的单体和由乙烯基化合物衍生的单体聚合而形成的聚合物, 形成在第一层上的第二层的粘合剂含有氟树脂。