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1. 发明授权

US4851307A Ionically conductive material 失效
标题翻译：离子导电材料
公开(公告)号：US4851307A
公开(公告)日：1989-07-25
申请号：US114721
申请日：1987-10-30
申请人： Michel Armand , Michel Gauthier , Daniel Muller
发明人： Michel Armand , Michel Gauthier , Daniel Muller
IPC分类号： C08K5/43 , C08L77/00 , C08L101/00 , H01B1/12 , H01M6/16 , H01M6/18 , H01M10/40
CPC分类号： H01B1/122 , H01M6/164 , H01M6/181 , H01M6/166
摘要： An ionically conductive material useful in electrochemical generators is disclosed. This ionically material comprises a salt in solution in a solvent. The solvent comprises a sulfonated derivative of Formula (I):R.sub.1 R.sub.2 N--SO.sub.2 NR.sub.3 R.sub.4wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently a C.sub.1-10 alkyl group or a C.sub.1-10 oxaalkyl group.
摘要翻译：公开了一种用于电化学发生器的离子导电材料。该离子材料包括在溶剂中的溶液中的盐。溶剂包括式（I）的磺化衍生物：R1R2N-SO2NR3R4，其中R1，R2，R3和R4各自独立地为C1-10烷基或C1-10氧杂烷基。

2. 发明授权

US5162177A Ion conductive material composed of a salt in solution in a liquid electrolyte 失效
标题翻译：离子导电材料由液体电解质溶液中的盐组成
公开(公告)号：US5162177A
公开(公告)日：1992-11-10
申请号：US672327
申请日：1991-03-20
申请人： Michel Armand , Michel Gauthier , Daniel Muller
发明人： Michel Armand , Michel Gauthier , Daniel Muller
IPC分类号： H01M6/16
CPC分类号： H01M6/166
摘要： Ionically conductive material consisting essentially of a salt diluted in a liquid aprotic solvent. The salt is represented by one of the following formulas: ##STR1## where M is an alkaline or alkaline earth metal, a transition metal or a rare earth metal.
摘要翻译：基本上由在液体非质子溶剂中稀释的盐组成的离子导电材料。盐由下式表示：M [RFSO2NSO2R'F]（I）M [RFSO2NCOR'F]（II）M [RFCONCOR'F]（III）其中M是碱性或碱土金属，过渡金属或稀土金属。

3. 发明授权

US5021308A New ion conductive material composed of a salt in solution in a liquid electrolyte 失效
标题翻译：新型离子导电材料由液体电解质溶液中的盐组成
公开(公告)号：US5021308A
公开(公告)日：1991-06-04
申请号：US467358
申请日：1990-01-23
申请人： Michel Armand , Michel Gauthier , Daniel Muller
发明人： Michel Armand , Michel Gauthier , Daniel Muller
IPC分类号： H01M6/16
CPC分类号： H01M6/166 , H01G11/56 , Y02E60/13
摘要： An electrochemical cell with an electrolyte of an ionically conductive material comprised of a salt diluted in a liquid solvent. The salt is represented by one of the following formulas: ##STR1##
摘要翻译：具有离子导电材料的电解质的电化学电池由在液体溶剂中稀释的盐组成。盐由下式表示：M [RFSO 2 NSO 2 R'F]; M [RFSO2NCOR'F]; [RFCONCOR'F];

4. 发明授权

US5260145A Production of organic cation radicals in an electrochemical cell 失效
标题翻译：在电化学电池中生产有机阳离子自由基
公开(公告)号：US5260145A
公开(公告)日：1993-11-09
申请号：US941555
申请日：1992-09-08
申请人： Michel Armand , Michel Gauthier , Daniel Muller
发明人： Michel Armand , Michel Gauthier , Daniel Muller
IPC分类号： H01M6/16
CPC分类号： H01M6/166
摘要： Process for producing organic cation radicals using anodic oxidation of an organic molecule in an electrochemical cell containing two electrodes upon which opposite polarity may be established and a liquid electrolyte which is an ion conductive material comprising a salt in solution in a liquid consisting essentially of at least one polar aprotic solvent selected from the group consisting of linear ethers, cyclic ethers, esters, carbonates, lactones, nitrate derivatives, amides, sulfones and sulfolanes, wherein said salt is represented by one of the following formulas: ##STR1## wherein M is an alkaline or alkaline earth metal, a transition metal or a rare earth metal,RF and R'F are identical or different and each represent a perhalogen radical having from 1 to 12 carbon atoms,QF is a perfluorinated bivalent radical having from 2 to 6 carbon atoms.
摘要翻译：在含有两个电极的电化学电池中使用有机分子的阳极氧化制备有机阳离子自由基的方法，其中可以建立相反极性的电极，以及作为离子导电材料的液体电解质，所述液体电解质包含基本上至少由一种选自直链醚，环醚，酯，碳酸酯，内酯，硝酸酯衍生物，酰胺，砜和环丁砜的极性非质子溶剂，其中所述盐由下式表示：M [RFSO 2 NSO 2 R'F]（ I）M [RFSO2NCOR'F]（II）M [RFCONCOR'F]（III）其中M是碱金属或碱土金属，过渡金属或稀土金属，RF和R'F 相同或不同，并且各自表示具有1至12个碳原子的全卤基团，QF是具有2至6个碳原子的全氟化二价基团。

5. 发明授权

US5063124A Ionically conductive material 失效
标题翻译：离子导电材料
公开(公告)号：US5063124A
公开(公告)日：1991-11-05
申请号：US338949
申请日：1989-04-17
申请人： Michel Gauthier , Michel Armand , Daniel Muller
发明人： Michel Gauthier , Michel Armand , Daniel Muller
IPC分类号： C08K5/43 , C08L77/00 , C08L101/00 , H01B1/12 , H01M6/16 , H01M6/18 , H01M10/40
CPC分类号： H01B1/122 , H01M6/164 , H01M6/181 , H01M6/166
摘要： An ionically conductive material useful in electrochemical generators is disclosed. This ionically material comprises a salt in solution in a solvent. The solvent comprises a sulfonated derivative of Formula (I):R.sub.1 R.sub.2 N--SO.sub.2 NR.sub.3 R.sub.4wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently a C.sub.1-10 alkyl group or a C.sub.1-10 oxaalkyl group.

6. 发明授权

US08647780B2 Materials useful as electrolytic solutes 有权
标题翻译：可用作电解溶质的材料
公开(公告)号：US08647780B2
公开(公告)日：2014-02-11
申请号：US13042296
申请日：2011-03-07
申请人： Christophe Michot , Michel Armand , Michel Gauthier , Nathalie Ravet
发明人： Christophe Michot , Michel Armand , Michel Gauthier , Nathalie Ravet
IPC分类号： H01M10/0563 , H01M10/0566 , C01B25/00 , C07F9/02 , C07C23/00
CPC分类号： C07C211/63 , C07C45/46 , C07C45/72 , C07C211/64 , C07C317/04 , C07C317/12 , C07C381/00 , C07D213/20 , C07D213/74 , C07D231/12 , C07D233/56 , C07D249/08 , C07D311/82 , C07D339/06 , C07F9/54 , H01G9/038 , H01G9/20 , H01G9/2004 , H01G11/62 , H01M4/13 , H01M4/505 , H01M4/525 , H01M4/58 , H01M4/5825 , H01M4/587 , H01M4/60 , H01M4/602 , H01M4/624 , H01M6/164 , H01M6/166 , H01M6/168 , H01M6/181 , H01M8/1048 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0566 , H01M10/0568 , H01M10/0569 , H01M10/36 , H01M2300/0022 , H01M2300/0082 , Y02E10/542 , Y02E60/122 , Y02E60/13
摘要： The invention concerns novel ionic compounds with low melting point whereof the onium type cation having at least a heteroatom such as N, 0, S or P bearing the positive charge and whereof the anion includes, wholly or partially, at least an ion imidide such as (FXI0)N—(OX2F) wherein X1 and X2 are identical or different and comprise SO or PF, and their use as solvent in electrochemical devices. Said composition comprises a salt wherein the anionic charge is delocalised, and can be used, inter alia, as electrolyte.
摘要翻译：本发明涉及具有低熔点的新型离子化合物，其中具有至少具有正电荷的N，O，S或P的杂原子的鎓型阳离子及其阴离子全部或部分至少包含一个离子酰亚胺，例如（FXI0）N-（OX2F）其中X1和X2相同或不同并且包含SO或PF，以及它们在电化学装置中作为溶剂的用途。所述组合物包含盐，其中阴离子电荷是离域的，并且可以特别地用作电解质。

7. 发明授权

US07906235B2 Pentacyclic anion salts or tetrazapentalene derivatives and their uses as ionic conducting materials 有权
标题翻译：五环阴离子盐或四氮杂蒽衍生物及其用作离子导电材料
公开(公告)号：US07906235B2
公开(公告)日：2011-03-15
申请号：US10926283
申请日：2004-08-25
申请人： Christophe Michot , Michel Armand , Michel Gauthier , Yves Choquette
发明人： Christophe Michot , Michel Armand , Michel Gauthier , Yves Choquette
IPC分类号： C07C309/85 , C07C317/12 , C07C245/00 , H01M6/04
CPC分类号： B01J31/0224 , B01J31/0215 , B01J31/0222 , B01J31/0225 , B01J31/0227 , B01J31/0235 , B01J31/0239 , B01J31/0247 , B01J31/0251 , B01J31/0252 , B01J31/0267 , B01J31/0271 , B01J31/0281 , B01J31/0288 , B01J31/0289 , B01J31/04 , B01J31/06 , B01J31/068 , B01J31/124 , B01J31/1815 , B01J31/2208 , B01J2231/122 , B01J2231/14 , B01J2231/326 , B01J2231/341 , B01J2231/348 , B01J2231/4205 , B01J2231/543 , B01J2531/35 , B01J2531/824 , C07B37/02 , C07B37/12 , C07C45/46 , C07C45/69 , C07C67/00 , C07C255/10 , C07C255/17 , C07C255/27 , C07C255/46 , C07C255/65 , C07C257/14 , C07C311/03 , C07C311/04 , C07C311/09 , C07C311/48 , C07C317/04 , C07C317/08 , C07C317/14 , C07C317/22 , C07C317/24 , C07C317/34 , C07C317/44 , C07C2601/10 , C07C2602/42 , C07D207/452 , C07D213/76 , C07D219/10 , C07D231/18 , C07D233/90 , C07D239/60 , C07D241/42 , C07D249/04 , C07D249/10 , C07D249/12 , C07D251/70 , C07D277/64 , C07D277/82 , C07D285/125 , C07D285/135 , C07D285/15 , C07D285/16 , C07D303/34 , C07D307/54 , C07D307/64 , C07D311/52 , C07D311/58 , C07D311/82 , C07D319/06 , C07D333/16 , C07D333/24 , C07D405/06 , C07D409/12 , C07D417/10 , C07D417/14 , C07F17/02 , C08F4/04 , C08G65/3344 , C09B69/00 , C09B69/02 , C09B69/10 , G02F1/1525 , G02F2001/151 , H01B1/122 , H01B1/128 , H01G9/022 , H01G9/038 , H01G11/02 , H01G11/62 , H01M4/00 , H01M4/02 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/382 , H01M4/405 , H01M4/48 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5815 , H01M4/5825 , H01M4/60 , H01M4/625 , H01M4/661 , H01M6/00 , H01M6/04 , H01M6/164 , H01M6/166 , H01M6/168 , H01M6/181 , H01M6/183 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M10/0568 , Y02E60/13 , Y10S430/127 , Y10T29/49108 , Y10T428/2918 , C07C49/84 , C07C49/553
摘要： The invention relates to ionic compounds in which the anionic load has been delocalized. A compound disclosed by the invention includes an anionic portion combined with at least one cationic portion Mm+ in sufficient numbers to ensure overall electronic neutrality; the compound is further comprised of M as a hydroxonium, a nitrosonium NO+, an ammonium —NH4+, a metallic cation with the valence m, an organic cation with the valence m, or an organometallic cation with the valence m. The anionic load is carried by a pentacyclical nucleus of tetrazapentalene derivative bearing electroattractive substituents. The compounds can be used notably for ionic conducting materials, electronic conducting materials, colorant, and the catalysis of various chemical reactions.
摘要翻译：本发明涉及其中阴离子负荷已经离域的离子化合物。本发明公开的化合物包括与足够数量的至少一个阳离子部分Mm +组合的阴离子部分以确保整体电子中性; 该化合物还包含作为氢氧化物的M，亚硝鎓NO +，铵NH4 +，价数m的金属阳离子，价数m的有机阳离子或价数m的有机金属阳离子。阴离子负载由带有电吸引取代基的四嗪基衍生物的五环核承载。这些化合物可以特别用于离子导电材料，电子导电材料，着色剂和各种化学反应的催化。

8. 发明申请

US20080251754A1 NOVEL MATERIALS USEFUL AS ELECTROLYTIC SOLUTES 有权
标题翻译：新材料作为电解液有用
公开(公告)号：US20080251754A1
公开(公告)日：2008-10-16
申请号：US12057934
申请日：2008-03-28
申请人： CHRISTOPHE MICHOT , Michel Armand , Michel Gauthier , Nathalie Ravet
发明人： CHRISTOPHE MICHOT , Michel Armand , Michel Gauthier , Nathalie Ravet
IPC分类号： H01G9/022 , C07D233/56 , C07D213/72 , C07D207/06
CPC分类号： C07C211/63 , C07C45/46 , C07C45/72 , C07C211/64 , C07C317/04 , C07C317/12 , C07C381/00 , C07D213/20 , C07D213/74 , C07D231/12 , C07D233/56 , C07D249/08 , C07D311/82 , C07D339/06 , C07F9/54 , H01G9/038 , H01G9/20 , H01G9/2004 , H01G11/62 , H01M4/13 , H01M4/505 , H01M4/525 , H01M4/58 , H01M4/5825 , H01M4/587 , H01M4/60 , H01M4/602 , H01M4/624 , H01M6/164 , H01M6/166 , H01M6/168 , H01M6/181 , H01M8/1048 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0566 , H01M10/0568 , H01M10/0569 , H01M10/36 , H01M2300/0022 , H01M2300/0082 , Y02E10/542 , Y02E60/122 , Y02E60/13
摘要： The invention concerns novel ionic compounds with low melting point whereof the onium type cation having at least a heteroatom such as N, O, S or P bearing the positive charge and whereof the anion includes, wholly or partially, at least an ion imidide such as (FX1O)N−(OX2F) wherein X1 and X2 are identical or different and comprise SO or PF, and their use as solvent in electrochemical devices. Said composition comprises a salt wherein the anionic charge is delocalised, and can be used, inter alia, as electrolyte.
摘要翻译：本发明涉及具有低熔点的新型离子化合物，其中具有至少具有正电荷的N，O，S或P的杂原子的鎓型阳离子及其阴离子全部或部分至少包含一个离子酰亚胺，例如（FX 1 O）N - （OX 2 F）其中X 1和X 2， / SUP>相同或不同，包含SO或PF，以及它们在电化学装置中作为溶剂的用途。所述组合物包含盐，其中阴离子电荷是离域的，并且可以特别地用作电解质。

9. 发明授权

US06806002B2 Electrolytic composition with polymer base for electrochemical generator 失效
标题翻译：电化学发生器用电解质组合物
公开(公告)号：US06806002B2
公开(公告)日：2004-10-19
申请号：US09878356
申请日：2001-06-12
申请人： Alain Vallee , Michel Armand , Yves Choquette , Andre Belanger , Michel Gauthier , Michel Perrier , Karim Zaghib , Estelle Potvin , Simon Besner
发明人： Alain Vallee , Michel Armand , Yves Choquette , Andre Belanger , Michel Gauthier , Michel Perrier , Karim Zaghib , Estelle Potvin , Simon Besner
IPC分类号： H01M462
CPC分类号： H01M2/1686 , H01M2/1673 , H01M6/181 , Y10T29/49108 , Y10T29/49115
摘要： The invention concerns an aprotic electrolytic composition located in the separator and in at least one composite electrode containing a powder of an active electrode material, and if necessary an electronic conduction additive of an electrochemical generator. The electrolytic composition comprises a first polymer matrix consisting of a polyether and at least a second polymer matrix, macroscopically separated, and also at least an alkaline salt as well as a polar aprotic solvent: The polymer matrices are capable of being swollen by at least one of the polar aprotic solvents. The solvent or mixture of solvents is unevenly distributed between the polymer matrices. The invention also concerns an electrochemical generator comprising a negative electrode and positive electrode reversible to alkaline ions and a separator with polymer electrolyte, the electrolytic component of which is the composition described above. The invention further concerns the manufacture in two or three steps of a sub-assembly of an electrochemical generator by coating an electrode support with a composite electrode containing the second matrix, followed by a surface coating on the electrode resulting from the preceding step with a solution containing the first polymer matrix so as to form the separator wholly or partly.
摘要翻译：本发明涉及位于分离器中的非质子电解组合物和至少一个含有活性电极材料的粉末的复合电极，如果需要的话，电化学发生器的电子导电添加剂。电解质组合物包括由聚醚和至少第二聚合物基质组成的宏观分离的第一聚合物基质，以及至少一种碱性盐以及极性非质子溶剂。聚合物基质能够被至少一种的极性非质子溶剂。溶剂或溶剂混合物不均匀地分布在聚合物基质之间。本发明还涉及一种电化学发生器，其包括负极和碱性离子可逆的正极和具有聚合物电解质的隔膜，其电解组分是上述组成。本发明还涉及通过用包含第二基质的复合电极涂覆电极载体，然后在前述步骤中由溶液形成的电极上的表面涂层的方法，在电化学发生器的子组件的两个或三个步骤中制造两个或三个步骤含有第一聚合物基质以全部或部分形成隔膜。

10. 发明授权

US06620546B1 Materials for use as electrolytic solutes 有权
标题翻译：用作电解溶质的材料
公开(公告)号：US06620546B1
公开(公告)日：2003-09-16
申请号：US09355454
申请日：1999-09-24
申请人： Christophe Michot , Michel Armand , Yves Choquette , Michel Gauthier
发明人： Christophe Michot , Michel Armand , Yves Choquette , Michel Gauthier
IPC分类号： H01M616
CPC分类号： H01G9/038 , C07C211/63 , C07C211/64 , C07C317/04 , C07C317/12 , C07C381/00 , C07D213/20 , C07D213/74 , C07D231/12 , C07D233/56 , C07D249/08 , C07D311/82 , C07D339/06 , C07F9/54 , H01G9/028 , H01G9/2004 , H01G11/48 , H01G11/56 , H01G11/62 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/60 , H01M4/624 , H01M4/661 , H01M6/164 , H01M6/168 , H01M6/181 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/1067 , H01M10/052 , H01M10/054 , H01M10/0565 , H01M10/0568 , H01M10/36 , Y02E10/542 , Y02E60/122 , Y02E60/13
摘要： The invention relates to ionic compositions having a high ionic conductivity comprising a salt with a delocalized anionic charge. An ionic composition comprises a salt in solution in a solvent and has a conductivity of greater than 10−5 S.cm−1 between −30° C. and 150° C. The cation is a proton, a hydronium, a hydroxonium, a nitrosonium NO+, an ammonium NH4+ or a metal, organic or organometallic cation. The anion is a carbanion carrying a perfluorinated substituent or a substituent carrying at least one F on the carbon &agr; to the carbanion and two nonperfluorinated electron-withdrawing substituents. Use as electrolyte in electrochemical devices, as catalyst of chemical reactions, or as photochemical or thermochemical initiator for polymerization or crosslinking reactions.
摘要翻译：本发明涉及具有高离子电导率的离子组合物，其包含具有离域阴离子电荷的盐。离子组合物包含在溶剂中的溶液中的盐，并且在-30℃之间具有大于10 -5 S.cm -1的电导率 C.和150℃。阳离子是质子，水合氢，氢氧化物，亚硝酸铵NO +，NH 4 +或金属，有机或有机金属阳离子。阴离子是携带全氟化取代基的碳负离子或在碳负离子和两个非全氟化吸电子取代基上带有至少一个F的取代基。在电化学装置中作为电解质，作为化学反应的催化剂，或作为光化学或热化学用于聚合或交联反应的引发剂。

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