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1. 发明授权

US5260145A Production of organic cation radicals in an electrochemical cell 失效
标题翻译：在电化学电池中生产有机阳离子自由基
公开(公告)号：US5260145A
公开(公告)日：1993-11-09
申请号：US941555
申请日：1992-09-08
申请人： Michel Armand , Michel Gauthier , Daniel Muller
发明人： Michel Armand , Michel Gauthier , Daniel Muller
IPC分类号： H01M6/16
CPC分类号： H01M6/166
摘要： Process for producing organic cation radicals using anodic oxidation of an organic molecule in an electrochemical cell containing two electrodes upon which opposite polarity may be established and a liquid electrolyte which is an ion conductive material comprising a salt in solution in a liquid consisting essentially of at least one polar aprotic solvent selected from the group consisting of linear ethers, cyclic ethers, esters, carbonates, lactones, nitrate derivatives, amides, sulfones and sulfolanes, wherein said salt is represented by one of the following formulas: ##STR1## wherein M is an alkaline or alkaline earth metal, a transition metal or a rare earth metal,RF and R'F are identical or different and each represent a perhalogen radical having from 1 to 12 carbon atoms,QF is a perfluorinated bivalent radical having from 2 to 6 carbon atoms.
摘要翻译：在含有两个电极的电化学电池中使用有机分子的阳极氧化制备有机阳离子自由基的方法，其中可以建立相反极性的电极，以及作为离子导电材料的液体电解质，所述液体电解质包含基本上至少由一种选自直链醚，环醚，酯，碳酸酯，内酯，硝酸酯衍生物，酰胺，砜和环丁砜的极性非质子溶剂，其中所述盐由下式表示：M [RFSO 2 NSO 2 R'F]（ I）M [RFSO2NCOR'F]（II）M [RFCONCOR'F]（III）其中M是碱金属或碱土金属，过渡金属或稀土金属，RF和R'F 相同或不同，并且各自表示具有1至12个碳原子的全卤基团，QF是具有2至6个碳原子的全氟化二价基团。

2. 发明授权

US5063124A Ionically conductive material 失效
标题翻译：离子导电材料
公开(公告)号：US5063124A
公开(公告)日：1991-11-05
申请号：US338949
申请日：1989-04-17
申请人： Michel Gauthier , Michel Armand , Daniel Muller
发明人： Michel Gauthier , Michel Armand , Daniel Muller
IPC分类号： C08K5/43 , C08L77/00 , C08L101/00 , H01B1/12 , H01M6/16 , H01M6/18 , H01M10/40
CPC分类号： H01B1/122 , H01M6/164 , H01M6/181 , H01M6/166
摘要： An ionically conductive material useful in electrochemical generators is disclosed. This ionically material comprises a salt in solution in a solvent. The solvent comprises a sulfonated derivative of Formula (I):R.sub.1 R.sub.2 N--SO.sub.2 NR.sub.3 R.sub.4wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently a C.sub.1-10 alkyl group or a C.sub.1-10 oxaalkyl group.

3. 发明授权

US4851307A Ionically conductive material 失效
标题翻译：离子导电材料
公开(公告)号：US4851307A
公开(公告)日：1989-07-25
申请号：US114721
申请日：1987-10-30
申请人： Michel Armand , Michel Gauthier , Daniel Muller
发明人： Michel Armand , Michel Gauthier , Daniel Muller
IPC分类号： C08K5/43 , C08L77/00 , C08L101/00 , H01B1/12 , H01M6/16 , H01M6/18 , H01M10/40
CPC分类号： H01B1/122 , H01M6/164 , H01M6/181 , H01M6/166
摘要： An ionically conductive material useful in electrochemical generators is disclosed. This ionically material comprises a salt in solution in a solvent. The solvent comprises a sulfonated derivative of Formula (I):R.sub.1 R.sub.2 N--SO.sub.2 NR.sub.3 R.sub.4wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently a C.sub.1-10 alkyl group or a C.sub.1-10 oxaalkyl group.
摘要翻译：公开了一种用于电化学发生器的离子导电材料。该离子材料包括在溶剂中的溶液中的盐。溶剂包括式（I）的磺化衍生物：R1R2N-SO2NR3R4，其中R1，R2，R3和R4各自独立地为C1-10烷基或C1-10氧杂烷基。

4. 发明授权

US5162177A Ion conductive material composed of a salt in solution in a liquid electrolyte 失效
标题翻译：离子导电材料由液体电解质溶液中的盐组成
公开(公告)号：US5162177A
公开(公告)日：1992-11-10
申请号：US672327
申请日：1991-03-20
申请人： Michel Armand , Michel Gauthier , Daniel Muller
发明人： Michel Armand , Michel Gauthier , Daniel Muller
IPC分类号： H01M6/16
CPC分类号： H01M6/166
摘要： Ionically conductive material consisting essentially of a salt diluted in a liquid aprotic solvent. The salt is represented by one of the following formulas: ##STR1## where M is an alkaline or alkaline earth metal, a transition metal or a rare earth metal.
摘要翻译：基本上由在液体非质子溶剂中稀释的盐组成的离子导电材料。盐由下式表示：M [RFSO2NSO2R'F]（I）M [RFSO2NCOR'F]（II）M [RFCONCOR'F]（III）其中M是碱性或碱土金属，过渡金属或稀土金属。

5. 发明授权

US5021308A New ion conductive material composed of a salt in solution in a liquid electrolyte 失效
标题翻译：新型离子导电材料由液体电解质溶液中的盐组成
公开(公告)号：US5021308A
公开(公告)日：1991-06-04
申请号：US467358
申请日：1990-01-23
申请人： Michel Armand , Michel Gauthier , Daniel Muller
发明人： Michel Armand , Michel Gauthier , Daniel Muller
IPC分类号： H01M6/16
CPC分类号： H01M6/166 , H01G11/56 , Y02E60/13
摘要： An electrochemical cell with an electrolyte of an ionically conductive material comprised of a salt diluted in a liquid solvent. The salt is represented by one of the following formulas: ##STR1##
摘要翻译：具有离子导电材料的电解质的电化学电池由在液体溶剂中稀释的盐组成。盐由下式表示：M [RFSO 2 NSO 2 R'F]; M [RFSO2NCOR'F]; [RFCONCOR'F];

6. 发明授权

US5130842A Method for rapid and uniform heating of a transparent and/or reflecting multilayer optical system with polymeric solid electrolyte 失效
标题翻译：具有聚合物固体电解质的透明和/或反射多层光学系统的快速均匀加热方法
公开(公告)号：US5130842A
公开(公告)日：1992-07-14
申请号：US635521
申请日：1991-02-21
申请人： Michel Gauthier , Philippe Ricoux , Daniel Muller
发明人： Michel Gauthier , Philippe Ricoux , Daniel Muller
IPC分类号： G02F1/15 , B29C35/02 , B32B7/02 , B32B17/10 , G02F1/163 , H01M6/18 , H01M10/0565 , H01M10/50 , H01M14/00 , H05B3/00 , H05B3/14 , H05B3/36 , H05B3/60 , H05B3/86
CPC分类号： H05B3/86 , B29C35/02 , B32B17/10174 , B32B37/06 , G02F1/163 , H01M10/0565 , H01M10/615 , H01M10/6571 , H01M6/181 , H05B3/0004 , H05B3/146 , H05B3/36 , H05B3/60 , B29C2035/0211 , B32B2310/022 , H05B2203/009 , H05B2203/017
摘要： The optical system, which is comprised of a thin layer of ion conducting, macromolecular material, or solid polymer electrolyte sandwiched between two electrodes presenting each a conducting deposition carried by a support plate such that at least one of the conductor depositions and the associated support plate are transparent, is heated by applying between the conductor depositions of said electrodes an electric voltage signal of which at least one portion includes an alternating component which has an amplitude between 0.05 and 100 volts and a frequency lower than 5 kHz and preferably between 2 and 2000 Hz so as to generate within said optical system an alternating ionic current susceptible of producing a heating of the ion conducting macromolecular material by Joule effect. The optical system to be heated, which may be an electrochromium device, may have particularly a glazing type structure or a mirror type structure.
摘要翻译： PCT No.PCT / FR90 / 00327 Sec。 371日期1991年2月21日 102（e）1991年2月21日PCT PCT 1990年5月10日PCT公布。出版物WO90 / 13844 日期：1990年11月15日。该光学系统由离子传导性高分子材料的薄层或夹在两个电极之间的固体聚合物电解质构成，每个电极呈现由支撑板承载的导电沉积，使得至少一个导电体沉积物和相关的支撑板是透明的，通过在所述电极的导体沉积之间施加电压信号来加热，电压信号至少一部分包括具有在0.05和100伏之间的振幅和低于5的频率的交替分量 kHz，优选在2和2000Hz之间，以便在所述光学系统内产生易于通过焦耳效应产生离子传导性高分子材料的加热的交替离子电流。可以是电铬装置的被加热的光学系统可以具有特别的玻璃类型结构或镜面结构。

7. 发明授权

US5302810A Method for rapid and uniform heating of a multilayer assembly comprising at least one thin layer based on an ion-conducting macromolecular material interleaved between two structures with high electronic conduction 失效
标题翻译：一种用于快速和均匀加热多层组件的方法，包括至少一层基于离子传导性高分子材料的薄层，所述材料在具有高电子传导性的两个结构之间交错
公开(公告)号：US5302810A
公开(公告)日：1994-04-12
申请号：US635522
申请日：1991-02-14
申请人： Michel Gauthier , Philippe Ricoux , Daniel Muller
发明人： Michel Gauthier , Philippe Ricoux , Daniel Muller
IPC分类号： G02F1/15 , B29C35/02 , B32B7/02 , B32B17/10 , G02F1/163 , H01M6/18 , H01M10/0565 , H01M10/50 , H01M14/00 , H05B3/00 , H05B3/14 , H05B3/36 , H05B3/60 , H05B3/86 , H05B3/16 , H05B1/00
CPC分类号： H05B3/86 , B29C35/02 , B32B17/10174 , B32B37/06 , G02F1/163 , H01M10/0565 , H01M10/615 , H01M10/6571 , H01M6/181 , H05B3/0004 , H05B3/146 , H05B3/36 , H05B3/60 , B29C2035/0211 , B32B2310/022 , H05B2203/009 , H05B2203/017
摘要： Between the high electronic conduction structures of the multilayer assembly an electric voltage signal is applied of which at least one portion includes an alternating component which has an amplitude between 0.05 and 100 volts and a frequency lower than 5 kHz and preferably between 2 and 2000 Hz so as to generate within the multilayer assembly an alternating ion current susceptible of producing a heating of the ion conducting macromolecular material by Joule effect. Application to the heating of electrochemical current generators in thin layers with solid polymer electrolyte or to the surface heating of elements of various regular or irregular shapes of which the surface is coated with the multilayer assembly.
摘要翻译： PCT No.PCT / FR90 / 00326 Sec。 371日期1991年2月14日 102（e）1991年2月14日PCT PCT 1990年5月10日PCT公布。出版物WO90 / 日本1990年11月15日。在多层组件的高电子传导结构之间，施加电压信号，其中至少一部分包括具有0.05至100伏特和低于5kHz频率的振幅的交替分量，以及优选在2和2000Hz之间，以便在多层组件内产生易于通过焦耳效应产生离子传导性高分子材料的加热的交变离子电流。应用于用固体聚合物电解质薄层化学电化学发电机的加热或表面用多层组件涂覆的各种规则或不规则形状的元件的表面加热。

8. 发明授权

US5100746A Process for production of a multi-layer assembly for an electrochemical generator 失效
标题翻译：用于生产电化学发生器的多层组件的方法
公开(公告)号：US5100746A
公开(公告)日：1992-03-31
申请号：US337522
申请日：1989-02-21
申请人： Daniel Muller , Michel Gauthier , Bruno Kapfer
发明人： Daniel Muller , Michel Gauthier , Bruno Kapfer
IPC分类号： H01M4/04 , H01M6/18 , H01M10/04
CPC分类号： H01M10/0436 , H01M10/0431 , H01M6/181 , Y10T29/49112 , Y10T29/49115
摘要： Electrochemical cells containing lithium and a solid polymer electrolyte in the form of thin films are produced by making multilayer assemblies from double-layer solid polymer electrolyte/composite positive electrode sub-assemblies which are subsequently associated with the other constituent layers of the cell so that the multilayer assembly so obtained comprises a layer of a metal of low ductility. Cells may be made from multilayer assemblies by stacking, rolling or bending techniques.
摘要翻译： PCT No.PCT / FR88 / 00312 Sec。 371日期1989年2月21日 102（e）日期1989年2月21日PCT Filed 1988年6月16日PCT Pub。出版物WO88 / 10519 日期为1988年12月29日。含有锂和以薄膜形式的固体聚合物电解质的电化学电池通过制备来自双层固体聚合物电解质/复合正极子组件的多层组件而产生，随后与其它成分使得如此获得的多层组件包含低延展性的金属层。电池可以通过堆叠，轧制或弯曲技术由多层组件制成。

9. 发明授权

US4578326A Novel macromolecular material for use in realizing electrolytes and/or electrodes 失效
标题翻译：用于实现电解质和/或电极的新型大分子材料
公开(公告)号：US4578326A
公开(公告)日：1986-03-25
申请号：US584535
申请日：1984-02-28
申请人： Michel Armand , Daniel Muller , Michel Duval , Paul-Etienne Harvey
发明人： Michel Armand , Daniel Muller , Michel Duval , Paul-Etienne Harvey
IPC分类号： C08G65/04 , C08L71/02 , H01B1/12 , H01M6/18 , H01M4/62
CPC分类号： C08L71/02 , C08G65/04 , H01B1/122 , H01M6/181
摘要： The present invention relates to novel macromolecular materials constituted by a salt in solution in a copolymer of ethylene oxide and of a second monomeric unit the structure of which preserves on the chain a polyether structure.The application of the invention is particularly useful in the realization of composite electrodes and electrolyte of primary or secondary electrochemical generators, thus necessitating the excellent conductivities of these materials.
摘要翻译：本发明涉及由环氧乙烷和第二单体单元的共聚物中的溶液中的盐构成的新型高分子材料，其结构在链上保留了聚醚结构。本发明的应用特别可用于实现一次或二次电化学发生器的复合电极和电解质，从而需要这些材料的优异电导率。

10. 发明授权

US4758483A Novel macromolecular material for use in realizing electrolytes and/or electrodes 失效
标题翻译：用于实现电解质和/或电极的新型大分子材料
公开(公告)号：US4758483A
公开(公告)日：1988-07-19
申请号：US774915
申请日：1985-09-11
申请人： Michel Armand , Daniel Muller , Michel Duval , Paul E. Harvey , Jean M. Chabagno
发明人： Michel Armand , Daniel Muller , Michel Duval , Paul E. Harvey , Jean M. Chabagno
IPC分类号： C08G65/04 , C08L71/02 , H01B1/12 , H01M6/18 , H01M10/40
CPC分类号： C08L71/02 , C08G65/04 , H01B1/122 , H01M6/181
摘要： A solid polymeric electrolyte comprises a macromolecular material in which there is dissolved an ionic compound, particularly an ionic compound in solution in a copolymer of ethylene oxide and a second unit selected so that the copolymer chain maintains a polyether characteristic. Also a high performance composite electrode embodying this electrolyte, and a process for obtaining this electrolyte.
摘要翻译：固体高分子电解质包含大分子材料，其中溶解离子化合物，特别是溶解在环氧乙烷和第二单元的共聚物中的溶液中的离子化合物，使得共聚物链保持聚醚特性。还有一种体现该电解质的高性能复合电极，以及获得该电解质的方法。

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