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1. 发明授权

US5863879A Dye transfer inhibitors for detergents 失效
标题翻译：用于洗涤剂的染料转移抑制剂
公开(公告)号：US5863879A
公开(公告)日：1999-01-26
申请号：US722145
申请日：1996-10-17
申请人： Michael Zirnstein , Wolfgang Trieselt , Knut Oppenlander , Claudia Nilz , Michael Kroner , Wolfgang Gunther
发明人： Michael Zirnstein , Wolfgang Trieselt , Knut Oppenlander , Claudia Nilz , Michael Kroner , Wolfgang Gunther
IPC分类号： C08F8/00 , C11D3/00 , C11D3/37
CPC分类号： C11D3/3776 , C08F8/00 , C11D3/0021 , C11D3/3769 , C11D3/3773
摘要： The use of polymers which are preparable by reaction of(a) polymers that contain vinylamine units, with(b) compounds that contain aldehyde or keto groups, and optionally(c) NH- and/or OH-containing compoundsand which contain aminal, hemiaminal and/or aminal-acetal structures with or without unconverted vinylamine units, as detergent additive for inhibiting dye transfer during the wash, and polymers containing aminal, hemiaminal and/or aminal-acetal structures, obtainable by reaction of(a) polymers that contain vinylamine units, with(b) compounds that contain aldehyde or keto groups, and(c) NH- and/or OH-containing compounds,and detergents which contain the abovementioned polymers in amounts from 0.05 to 10% by weight.
摘要翻译： PCT No.PCT / EP95 / 01251 Sec。 371日期1996年10月17日第 102（e）日期1996年10月17日PCT提交1995年4月6日PCT公布。 WO95 / 29221 PCT出版物日期1995年11月2日使用可通过（a）含有乙烯胺单元的聚合物与（b）含有醛或酮基的化合物和任选的（c）含NH-和/或OH-的化合物并且其含有具有或不具有未转化的乙烯胺单元的氨基，半缩醛和/或缩醛缩氨酸结构作为用于抑制洗涤过程中染料转移的洗涤剂添加剂以及含有中和，半缩醛和/或缩醛缩醛结构的聚合物，可通过（ a）含有乙烯胺单元的聚合物，（b）含有醛或酮基的化合物，和（c）含有NH和/或OH的化合物，和含有上述聚合物的洗涤剂，其量为0.05-10重量％。

2. 发明授权

US5677384A Grafted polyamidoamines and grafted polyethyleneimines, preparation thereof, and use thereof as detergent additives 失效
标题翻译：接枝聚酰胺胺和接枝聚乙烯亚胺，其制备及其用作洗涤剂添加剂
公开(公告)号：US5677384A
公开(公告)日：1997-10-14
申请号：US513800
申请日：1995-09-07
申请人： Juergen Detering , Christian Schade , Knut Oppenlaender , Michael Zirnstein , Guenter Scherr , Wolfgang Trieselt , Volker Schwendemann
发明人： Juergen Detering , Christian Schade , Knut Oppenlaender , Michael Zirnstein , Guenter Scherr , Wolfgang Trieselt , Volker Schwendemann
IPC分类号： C08F226/06 , C08F283/00 , C08F283/04 , C08G73/02 , C11D3/37 , C08L77/00
CPC分类号： C11D3/3788 , C08F283/00 , C08G73/0206 , C08G73/0213 , C08G73/028
摘要： Grafted polyamidoamines and grafted polyethyleneimines obtainable by free-radically initiated polymerization of (a) 1-vinylpyrrolidone, 1-vinyltriazole, 1-vinylimidazoles, mixtures of said monomers or mixtures of at least one of said monomers with up to 20% by weight of other monoethylenically unsaturated monomers in the presence of (b) water-soluble or -dispersible polyamidoamines, polyethyleneimines or mixtures thereof in a weight ratio of (a):(b) from 5:95 to 95:5, are useful as dye transfer inhibitors in surfactant-based detergents when included therein in an amount from 0.05 to 10% by weight.
摘要翻译： PCT No.PCT / EP94 / 01801 Sec。 371 1995年9月7日第 102（e）1995年9月7日PCT PCT 1994年6月3日PCT公布。第WO94 / 29422号公报日期1994年12月22日通过（a）1-乙烯基吡咯烷酮，1-乙烯基三唑，1-乙烯基咪唑，所述单体的混合物或至少一种所述单体的混合物自由引发聚合得到的接枝聚酰亚胺和接枝聚乙烯亚胺与多达20个在（b）水溶性或可分散的聚酰胺胺，聚乙烯亚胺或其混合物（重量比为（a）：（b））5:95至95:5的存在下，其它单烯属不饱和单体的重量百分数是有用的作为基于表面活性剂的洗涤剂中的染料转移抑制剂，当其中包含0.05至10重量％的量时。

3. 发明授权

US5972237A Use of heterocyclic compounds as activators for inorganic peroxy compounds 失效
标题翻译：使用杂环化合物作为无机过氧化合物的活化剂
公开(公告)号：US5972237A
公开(公告)日：1999-10-26
申请号：US952076
申请日：1997-11-17
申请人： Reinhard Muller , Thomas Wehlage , Wolfgang Trieselt , Alfred Oftring , Elisabeth Kappes , Gunter Oetter , Dieter Boeckh , Roland Ettl , Albert Hettche
发明人： Reinhard Muller , Thomas Wehlage , Wolfgang Trieselt , Alfred Oftring , Elisabeth Kappes , Gunter Oetter , Dieter Boeckh , Roland Ettl , Albert Hettche
IPC分类号： C11D7/26 , C11D3/39 , C11D3/42 , C11D7/32 , C11D7/34 , C11D7/36 , C11D7/54 , D06L3/12 , A61L2/18
CPC分类号： C11D3/42 , C11D3/3907 , C11D3/393 , D06L3/1207 , D06L3/1257 , D06L3/1271
摘要： Heterocyclic compounds IR.sup.1 --X--L (I)whereL is a cyclic carbamate residue, a lactonoxy residue or a lactam residue,X is an oxygen-containing group ##STR1## where A is a linker, and R.sup.1 is an organic radical or a group L,are used as activators for inorganic peroxy compounds, in particular as cold bleach activators or optical brighteners in detergents, cleaners and bleaches and in disinfectants.
摘要翻译： PCT No.PCT / EP96 / 01863 Sec。 371日期：1997年11月17日 102（e）日期1997年11月17日PCT提交1996年5月4日PCT公布。 WO96 / 36686 PCT公开号日期：1996年11月21日杂环化合物I R1-XL（I）其中L是环状氨基甲酸酯残基，内酯氧基残基或内酰胺残基，X是含氧基团，其中A是连接基，R1是有机基团或一组L用作无机过氧化合物的活化剂，特别是作为洗涤剂，清洁剂和漂白剂以及消毒剂中的冷漂白活化剂或荧光增白剂。

4. 发明授权

US5175361A Preparation of copolymers of monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids 失效
标题翻译：单烯属不饱和一元羧酸和二羧酸的共聚物的制备
公开(公告)号：US5175361A
公开(公告)日：1992-12-29
申请号：US625621
申请日：1990-11-30
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
IPC分类号： C08F220/04 , C08F222/02
CPC分类号： C08F222/02 , C08F220/04
摘要： A process for the preparation of copolymers which contain monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids as copolymerized monomer units, which comprises copolymerizinga) 10 to 60% by weight, based on the sum of the monomers, of a monoethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms, -or an alkali metal salt thereof or, an anhydride thereof,b) 90 to 40% by weight of a monoethylenically unsaturated monocarboxylic acid of 3 to 10 carbon atoms or an alkali metal salt thereof andc) 0 to 20% by weight of another monoethylenically unsaturated monomer, not having carboxyl groups and which is copolymerizable with a) and b);in an aqueous medium in the presence of from 0.5 to 5% by weight, based on monomers, of a water-soluble initiator.
摘要翻译：一种制备包含单烯属不饱和一元羧酸和二羧酸作为共聚单体单元的共聚物的方法，其包括将基于单体总量的10-60重量％的单烯属不饱和二羧酸与4- 6个碳原子，或其碱金属盐或其酸酐，b）90〜40重量％的3〜10个碳原子的单烯属不饱和一元羧酸或其碱金属盐，c）0〜20重量％重量的不具有羧基且可与a）和b）共聚的另一单烯属不饱和单体; 在水介质中，以0.5至5重量％的单体为基础，存在水溶性引发剂。

5. 发明授权

US5130476A Preparation of .beta.-alaninediacetic acid or its alkali metal or ammonium salts 失效
标题翻译：（BETA） - 亚氨酸或其碱金属或氨盐的制备
公开(公告)号：US5130476A
公开(公告)日：1992-07-14
申请号：US674149
申请日：1991-03-25
申请人： Richard Baur , Charalampos Gousetis , Wolfgang Trieselt , Werner Bochnitschek , Alfred Oftring
发明人： Richard Baur , Charalampos Gousetis , Wolfgang Trieselt , Werner Bochnitschek , Alfred Oftring
IPC分类号： C07C227/06 , C07C227/14 , C07C229/16
CPC分类号： C07C227/14
摘要： .beta.-Alaninediacetic acid (Ia) or its alkali metal or ammonium salts (Ib) are prepared by a process in which iminodiacetic acid and acrylic acida) for the preparation of Ia, are reacted with one another in a nonbasic aqueous medium andb) for the preparation of Ib, are reacted with one another in an alkaline aqueous medium or an aqueous medium containing a nitrogen base, or the Ia formed in the nonbasic medium is converted with an alkali metal base, ammonia or an amine into Ib.

6. 发明授权

US4997587A Washing and cleaning agents containing .beta.-alanine-N,N-diacetic acid 失效
标题翻译：含有β-丙氨酸-N，N-二乙酸的洗涤剂和清洁剂
公开(公告)号：US4997587A
公开(公告)日：1991-03-05
申请号：US394935
申请日：1989-08-17
申请人： Richard Baur , Charalampos Gousetis , Wolfgang Trieselt , Werner Bochnitschek , Alfred Oftring
发明人： Richard Baur , Charalampos Gousetis , Wolfgang Trieselt , Werner Bochnitschek , Alfred Oftring
IPC分类号： C11D3/30 , C11D3/00 , C11D3/33 , C11D7/32
CPC分类号： C11D3/33
摘要： Washing and cleaning agents for aqueous use contain from 2 to 25% by weight, based on the total weight of the agent, of .beta.-alanine-N,N-diacetic acid or an alkali metal or ammonium salt thereof as water softener. The washing and cleaning agent is effective in preventing hardness deposits on textiles and fabrics.
摘要翻译：水性洗涤剂和洗涤剂含量为2至25重量％，基于该试剂的总重量，β-丙氨酸-N，N-二乙酸或其碱金属或铵盐作为软水剂。洗涤剂和清洁剂有效防止纺织品和织物上的硬度沉积。

7. 发明授权

US4952655A Water-soluble copolymers, their preparation and their use 失效
标题翻译：水溶性共聚物，其制备及其用途
公开(公告)号：US4952655A
公开(公告)日：1990-08-28
申请号：US183611
申请日：1988-04-19
申请人： Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann , Wolfgang Trieselt , Alexander Kud
发明人： Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann , Wolfgang Trieselt , Alexander Kud
IPC分类号： A01N25/26 , C08F2/10 , C08F20/10 , C08F220/04 , C08F220/20 , C08F290/00 , C08F299/00 , C08L101/16
CPC分类号： C08F220/04 , A01N25/26
摘要： Water-soluble copolymers having a K value of from 15 to 120 (determined on the sodium salt according to H. Fikentscher in aqueous solution at 25.degree. C., a pH of 7 and a polymer concentration of the Na salt of 1% by weight) contain, in the polymerized form,(a) from 99.5 to 80 mol % of one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids and(b) from 0.5 to 20 mol % of one or more comonomers which possess two or more ethylenically unsaturated, non-conjugated double bonds, are derived from esters and are obtainable by esterification of(b1) monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids with(b2) polyhydric alcohols of 2 to 6 carbon atoms, polyalkylene glycols, polyglycerols, polyvinyl alcohol and monohydric, monoethylenically unsaturated C.sub.3 -C.sub.6 -alcohols and(c) from 0 to 30 mol % of other water-soluble, monoethylenically unsaturated monomers which are copolymerizable with (a) and (b),the copolymers containing polymer segments which consist of units of the monomers (a) and (c), have a weight average molecular weight of not more than 15,000 and are bonded to one another via units of (b).
摘要翻译： K值为15〜120的水溶性共聚物（根据H.Fikentscher的钠盐在25℃的水溶液中测定，pH为7，Na盐的聚合物浓度为1重量％）包含（a）99.5-80mol％的一种或多种单烯属不饱和C 3 -C 6 - 单羧酸和（b）0.5至20摩尔％的一种或多种具有两个或多个烯键式的共聚单体的共聚单体不饱和的非共轭双键衍生自酯，可通过（b1）单烯属不饱和C3-C6-单羧酸与（b2）2至6个碳原子的多元醇酯，聚亚烷基二醇，聚甘油，聚乙烯醇和一元，单烯属不饱和C 3 -C 6醇和（c）0至30摩尔％可与（a）和（b）共聚的其它水溶性单烯属不饱和单体，所述共聚物含有聚合物链段， monom （a）和（c）的重均分子量不大于15,000，通过（b）单元彼此结合。

8. 发明授权

US4897220A Detergents containing water-soluble copolymers containing as copolymerized units monomers having two or more ethylenically unsaturated double bonds 失效
标题翻译：含有含有共聚单元的含有两个或更多个烯属不饱和双键的单体的水溶性共聚物的洗涤剂
公开(公告)号：US4897220A
公开(公告)日：1990-01-30
申请号：US191979
申请日：1988-05-10
申请人： Wolfgang Trieselt , Richard Baur , Ekhard Winkler , Paul Diessel , Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann
发明人： Wolfgang Trieselt , Richard Baur , Ekhard Winkler , Paul Diessel , Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann
IPC分类号： C08L33/02 , C08F20/10 , C08F220/04 , C08F220/06 , C08F222/16 , C11D3/37
CPC分类号： C11D3/3761
摘要： A surfactant-based detergent contains water-soluble copolymers which contain(a) from 99.5 to 15 mol % of one or more monoethylenically unsaturated C.sub.3 - to C.sub.6 -monocarboxylic acids,(b) from 0.5 to 20 mol % of one or more comonomers which contain two or more ethylenically unsaturated nonconjugated double bonds and have one or more --CO--OX groups where X is hydrogen, an alkali metal, one equivalent of an alkaline earth metal or ammonium,(c) from 0 to 84.5 mol % of one or more monoethylenically unsaturated C.sub.4 - to C.sub.6 -dicarboxylic acids,(d) from 0 to 20 mol % of one or more hydroxyalkyl esters of monoethylenically unsaturated C.sub.3 - to C.sub.6 -carboxylic acids and(e) from 0 to 30 mol % of other water-soluble monoethylenically unsaturated monomers copolymerizable with (a) to (d)as copolymerized units, with the proviso that the sum of the mol % ages (a) to (e) is always 100 and which have a Finkentscher K value of from 8 to 120.
摘要翻译：基于表面活性剂的洗涤剂含有水溶性共聚物，其含有（a）99.5〜15摩尔％的一种或多种单烯属不饱和C3〜C6-一元羧酸，（b）0.5〜20摩尔％的一种或多种共聚单体，含有两个或多个烯键式不饱和非共轭双键，并且具有一个或多个-CO-OX基团，其中X为氢，碱金属，1当量碱土金属或铵，（c）0至84.5摩尔％更多的单烯属不饱和C 4 -C 6 - 二羧酸，（d）0至20摩尔％的一种或多种单烯属不饱和C 3 -C 6羧酸的羟烷基酯和（e）0至30摩尔％可与（a）至（d）共聚的可溶性单烯属不饱和单体作为共聚单元，条件是mol％年龄（a）至（e）的总和始终为100，Finkentscher K值为8至120 。

9. 发明授权

US4846994A Use of graft polymers based on polyalkylene oxides as grayness inhibitors in the wash and aftertreatment of textile material containing synthetic fibers 失效
标题翻译：在含有合成纤维的纺织材料的洗涤和后处理中使用基于聚环氧烷作为灰色抑制剂的接枝聚合物
公开(公告)号：US4846994A
公开(公告)日：1989-07-11
申请号：US175175
申请日：1988-03-31
申请人： Alexander Kud , Wolfgang Trieselt , Heinrich Hartmann
发明人： Alexander Kud , Wolfgang Trieselt , Heinrich Hartmann
IPC分类号： C08F283/10 , C11D3/00 , C11D3/37 , D06M13/02 , D06M13/184 , D06M13/203 , D06M13/224 , D06M15/53
CPC分类号： C11D3/3788 , C08F283/10 , C11D3/0036
摘要： A detergent containing as grayness inhibitor in the wash and aftertreatment of textile material containing synthetic fibers graft polymers obtainable by grafting(a) polyalkylene oxides which have a number average molecular weight of from 300 to 100,000 and are based on ethylene oxide, propylene oxide and/or butylene oxide, with(b) at least one vinyl ester derived from a saturated monocarboxylic acid containing 3 to 6 carbon atoms, a methyl or ethyl ester of (meth)acrylic acid and optionally mixtures of at least one of the monomers mentioned and up to 95% by weight of vinyl acetate in a weight ratio (a):(b) of from 1:02 to 1:10.
摘要翻译：在含有合成纤维的纺织材料的洗涤和后处理中含有灰色抑制剂的洗涤剂，其可通过接枝（a）数均分子量为300至100,000的聚环氧烷并且基于环氧乙烷，环氧丙烷和/ 或环氧丁烷与（b）至少一种衍生自含有3-6个碳原子的饱和一元羧酸的乙烯基酯，（甲基）丙烯酸的甲酯或乙酯和至少一种所提及的单体的混合物至95重量％的重量比（a）：（b）为1:02至1:10的乙酸乙烯酯。

10. 发明授权

US4725655A Preparation of copolymers of monoethylenically unsaturated mono- and dicarboxylic acids and anhydrides 失效
公开(公告)号：US4725655A
公开(公告)日：1988-02-16
申请号：US919583
申请日：1986-10-16
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
IPC分类号： C08F2/00 , C08F2/10 , C08F8/00 , C08F8/12 , C08F8/44 , C08F20/00 , C08F20/02 , C08F120/04 , C08F220/04 , C08F222/02 , C08F220/06 , C08F222/04
CPC分类号： C08F220/04 , C08F222/02
摘要： Copolymers which contain, as copolymerized monomer units, monoethylenically unsaturated mono- and dicarboxylic acids are prepared by a process in which(a) from 10 to 60% by weight of a monoethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms, its salt and/or, if appropriate, its anhydride,(b) from 90 to 40% by weight of a monothylenically unsaturated monocarboxylic acid of 3 to 10 carbon atoms and/or its salt and(c) from 0 to 20% by weight of another, carboxyl-free monoethylenically unsaturated monomer which is copolymerizable with (a) and (b),the percentages being based on the sum of the monomers, are polymerized in the presence of from 0.5 to 5% by weight of a water-soluble free-radical-forming initiator in an aqueous medium at from 60.degree. to 150.degree. C., and, if appropriate, their anhydride groups are hydrolyzed, the monomers (a) and (b) being employed in a form such that from 20 to 80% of their amount is neutralized during the polymerization reaction, wherein the copolymerization is carried out continuously in a reactor cascade comprising several reactors, and an aqueous solution of a pre-prepared copolymer of (a), (b) and, if appropriate, (c) is initially introduced into all the reactors and heated to the required reaction temperature, the total amount of unneutralized or partially neutralized (a), not less than 40% by weight of unneutralized or partially neutralized (b), where relevant, all or some of (c), and some or all of the amount of initiator required for polymerization, with or without the amount of neutralizing agent required for the neutralization according to the definition, are metered into the first reactor, the remaining amount of unneutralized or neutralized (b) and, where relevant, (c), and any remaining amount of initiator and neutralizing agent which may be required are introduced into the second reactor or are distributed over the second reactor and the downstream reactors, and the reactants are allowed to react together during a residence time of from 0.5 to 8 hours. The above copolymers can be used as incrustation inhibitors or for scaling inhibition.

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