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1. 发明授权

US4535071A Catalyst for methanol synthesis and method of preparing the catalyst 失效
标题翻译：甲醇合成催化剂及其制备方法
公开(公告)号：US4535071A
公开(公告)日：1985-08-13
申请号：US610745
申请日：1984-05-16
申请人： Michael Schneider , Karel Kochloefl , Jurgen Ladebeck
发明人： Michael Schneider , Karel Kochloefl , Jurgen Ladebeck
IPC分类号： C07C29/15 , B01J23/80 , C07B61/00 , C07C27/00 , C07C29/154 , C07C31/04 , C07C67/00 , B01J21/04 , B01J23/06 , B01J23/72
CPC分类号： B01J23/80 , C07C29/154 , Y02P20/52
摘要： Catalyst for methanol synthesis, containing(a) as catalytically active substances copper oxide and zinc oxide, which, if desired, may be at least partially reduced, and(b) as thermostabilizing substance aluminum oxide.The proportion of pores with a diameter of 20 to 75 .ANG. (mesopores) is at least 20% and the proportion of pores with a diameter of more than 75 .ANG. (macropores) is at most 80%. The desired pore distribution can be obtained by using colloidally dispersed aluminum oxide or hydroxide in the production of the catalyst.
摘要翻译：用于甲醇合成的催化剂，其包含（a）作为催化活性物质的氧化铜和氧化锌，如果需要，其可以至少部分还原，和（b）作为热稳定物质氧化铝。直径为20〜75（介孔）的孔的比例为20％以上，直径大于75（大孔）的孔的比例为80％以下。所需的孔分布可通过使用胶体分散的氧化铝或氢氧化物在催化剂的制备中获得。

2. 发明授权

US5830425A Chromium-free catalyst based on iron oxide for conversion of carbon monoxide 失效
标题翻译：基于氧化铁的无铬催化剂用于转化一氧化碳
公开(公告)号：US5830425A
公开(公告)日：1998-11-03
申请号：US766391
申请日：1996-12-12
申请人： Michael Schneider , Karl Kochloefl , Gerd J. Maletz , Jurgen Ladebeck , Christoph Heinisch
发明人： Michael Schneider , Karl Kochloefl , Gerd J. Maletz , Jurgen Ladebeck , Christoph Heinisch
IPC分类号： B01J23/745 , B01J23/83 , B01J23/89 , C01B3/16 , C01B31/20
CPC分类号： B01J23/8946 , B01J23/745 , B01J23/83 , B01J23/8926 , C01B3/16 , Y02P20/52
摘要： The invention relates to a catalyst for conversion of carbon monoxide with steam into hydrogen, carbon dioxide and hydrogen-rich synthesis gases. The conversion can be done at temperatures above roughly 300.degree. C. In addition, a chromium-free catalyst for the aforementioned purpose is described which contains the following in "application form:" (a) 30-98% by weight iron oxide, computed as Fe.sub.2 O.sub.3 ; (b) 0.1-20% by weight copper oxide, computed as CuO; (c) 0.1-20% by weight of an oxide of the rare earth levels computed as Me.sub.2 O.sub.3 (in which Me is a rare earth metal) and/or zirconium oxide, computed as ZrO.sub.2 ; (d) 0.1-30% by weight of at least one oxide of one or several other base metals with an ionic radius from 50 to 72 pm (other than chromium) (e) 0-0.1% by weight of at least one oxide of one or several precious metals from the platinum group; (f) 0-30% by weight barium oxide.
摘要翻译：本发明涉及一氧化碳与蒸汽转化为氢气，二氧化碳和富氢合成气体的催化剂。该转化可以在高于约300℃的温度下进行。此外，描述了用于上述目的的无铬催化剂，其在“申请形式”中包含以下内容：（a）30-98重量％的氧化铁，计算作为Fe2O3; （b）0.1-20重量％的氧化铜，以CuO计算; （c）以ZrO 2计算的作为Me 2 O 3（其中Me是稀土金属）和/或氧化锆计算的稀土含量的0.1-20重量％（d）0.1-30重量％的至少一种氧化物，其一种或多种其它贱金属的氧化物，其离子半径为50至72μm（不同于铬）（e）0-0.1重量％的至少一种氧化物来自铂族的一种或几种贵金属; （f）0-30重量％的氧化钡。

3. 发明授权

US4906602A Catalyst for the selective hydrogenation of polyunsaturated hydrocarbons and process for preparing the catalyst 失效
标题翻译：用于多不饱和烃的选择性氢化的催化剂和制备催化剂的方法
公开(公告)号：US4906602A
公开(公告)日：1990-03-06
申请号：US261674
申请日：1988-10-24
申请人： Michael Schneider , Karl Kochloefl , Jurgen Ladebeck , Gerd Maletz
发明人： Michael Schneider , Karl Kochloefl , Jurgen Ladebeck , Gerd Maletz
IPC分类号： B01J23/50 , B01J23/48 , B01J23/52 , B01J23/66 , B01J23/89 , B01J35/10 , C10G45/52
CPC分类号： B01J23/66 , B01J23/8926
摘要： A catalyst for the selective hydrogenation of polyunsaturated hydrocarbons which contain entirely or predominantly more than five carbon atoms, containing palladium with a promotor on a metal oxide support. The promotor is a metal from the subgroup IB of the periodic system (preferably silver) and the metal oxide support (TiO.sub.2 optionally mixed with CeO.sub.2 and/or ZrO.sub.2) is macroporous, the pore volume being about 0.2 to 0.4, preferably about 0.25 to 0.30 ml per g of carrier and the proportion of the macropores having a diameter of more than 14 nm being at least 65%.
摘要翻译：用于选择氢化多不饱和烃的催化剂，其含有完全或主要多于五个碳原子，在金属氧化物载体上含有启动子的钯。促进剂是来自周期系统（优选为银）的亚组IB的金属，并且金属氧化物载体（任选与CeO 2和/或ZrO 2混合的TiO 2）是大孔的，孔体积为约0.2至0.4，优选约0.25至0.30 ml，并且直径大于14nm的大孔的比例为至少65％。

4. 发明授权

US5063187A Catalyst based on crystalline aluminosilicate 失效
标题翻译：基于结晶铝氧化物的催化剂
公开(公告)号：US5063187A
公开(公告)日：1991-11-05
申请号：US436477
申请日：1989-11-14
申请人： Gotz Burgfels , Karl Kochloefl , Jurgen Ladebeck , Friedrich Schmidt , Michael Schneider , Hans J. Wernicke
发明人： Gotz Burgfels , Karl Kochloefl , Jurgen Ladebeck , Friedrich Schmidt , Michael Schneider , Hans J. Wernicke
IPC分类号： C10G3/00 , B01J29/40 , C07C1/20
CPC分类号： B01J29/40 , B01J35/023 , C07C1/20 , C07C2529/40 , Y02P30/20
摘要： A catalyst based on crystalline aluminosilicates of the pentasil type, having an Si/Al atomic ratio of at least 10, has the structure of primary crystallites of a mean diameter of at least 0.1 micron and at most 0.9 micron, which crystallites are partially combined into agglomerates the primary crystallites and/or agglomerates being mutually joined by finely disperse alumina obtainable by hydrolysis of aluminum-organic compounds, the BET surface area of the catalyst being 300 to 600 m.sup.2 /g and its pore volume (determined by mercury porosimetry) being 0.3 to 0.8 cm.sup.3 /g.
摘要翻译：具有Si / Al原子比至少为10的pentasil型结晶硅铝酸盐的催化剂具有平均直径为至少0.1微米且至多0.9微米的初级微晶的结构，该微晶部分组合成通过铝 - 有机化合物的水解得到的细分散氧化铝相互连接的初级微晶和/或附聚物，催化剂的BET表面积为300〜600m 2 / g，孔体积（通过水银孔率法测定）为0.3 至0.8cm 3 / g。

5. 发明授权

US07754651B2 Cu/Zn/Al catalyst for methanol synthesis 有权
标题翻译：用于甲醇合成的Cu / Zn / Al催化剂
公开(公告)号：US07754651B2
公开(公告)日：2010-07-13
申请号：US10497865
申请日：2002-11-06
申请人： Jurgen Ladebeck , Jurgen Koy , Tiberius Regula
发明人： Jurgen Ladebeck , Jurgen Koy , Tiberius Regula
IPC分类号： B01J23/80 , B01J23/72 , B01J23/06
CPC分类号： C07C29/154 , B01J23/80 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J35/1014 , B01J35/1019 , Y02P20/52 , C07C31/04
摘要： Disclosed is an Cu/Zn/Al-catalyst containing copper oxide and zinc oxide as catalytically active components and aluminium oxide as thermostabilising component. The catalyst is characterized in that the Cu/Zn atomic ratio is
摘要翻译：公开了含有氧化铜和氧化锌作为催化活性组分和氧化铝作为热稳定组分的Cu / Zn / Al催化剂。催化剂的特征在于Cu / Zn原子比<2.8，氧化铝组分由氢氧化铝溶胶获得。

6. 发明申请

US20100116717A1 METHOD FOR THE DESULFURIZATION OF FUELS AND HIGHLY ACTIVE NICKEL CARRIER CATALYST BASED ON ALUMINUM OXIDE SUITABLE FOR SAID METHOD 有权
标题翻译：基于氧化铝的燃料和高活性镍催化剂的脱硫方法，适用于合适的方法
公开(公告)号：US20100116717A1
公开(公告)日：2010-05-13
申请号：US12531540
申请日：2008-03-13
申请人： Jurgen Ladebeck , Tiberius Regula , Klaus Wanninger , Wolfgang Gabriel , Frank Grossmann , Jürgen Koy
发明人： Jurgen Ladebeck , Tiberius Regula , Klaus Wanninger , Wolfgang Gabriel , Frank Grossmann , Jürgen Koy
IPC分类号： C10G45/06 , B01J23/755 , B01J21/04 , C10G29/16
CPC分类号： C10G25/003 , B01J20/08 , B01J20/28007 , B01J20/28014 , B01J20/2803 , B01J20/28057 , B01J20/28069 , B01J20/28078 , B01J23/755 , B01J23/78 , B01J23/892 , B01J35/0053 , B01J35/006 , B01J35/10 , B01J35/1019 , B01J35/1038 , B01J35/108 , B01J37/0009 , B01J37/03 , B82Y30/00 , C10G45/06 , C10G45/48 , C10G45/52 , C10G2300/202 , C10G2300/701 , C10G2400/02
摘要： A highly active nickel carrier catalyst based on aluminium oxide has a nickel content of approximately 20 to 70 wt.-% (as Ni) and optionally comprises a bonding agent and optionally a promoter, selected from the compounds of Mg, Ti, Pb, Pt, Ba, Ca and/or Cu, wherein the size of the Ni crystallites in the reduced state is in the range of approximately 3.5 to 4.5 nm and the distortion factor of the Ni crystallites is approximately 2 to 5%. In a method for the reduction of the content of sulphur compounds in hydrocarbon-based fuels by selective adsorption of the sulphur compounds on a nickel catalyst, a nickel catalyst based on aluminium oxide is used, particularly the nickel catalyst described above. A nickel catalyst based on aluminium oxide may be used for reducing the sulphur compound content in hydrocarbon-based fuels by selective adsorption of the sulphur compounds on said catalyst and/or for the hydrogenation of aromatic compounds.
摘要翻译：基于氧化铝的高活性镍载体催化剂的镍含量为约20至70重量％（如Ni），并且任选地包含粘合剂和任选的助催化剂，其选自Mg，Ti，Pb，Pt ，Ba，Ca和/或Cu，其中处于还原态的Ni微晶的尺寸在约3.5至4.5nm的范围内，并且Ni微晶的变形系数约为2％至5％。在通过硫化合物选择性吸附在镍催化剂上来降低烃基燃料中硫化合物含量的方法中，使用基于氧化铝的镍催化剂，特别是上述镍催化剂。基于氧化铝的镍催化剂可用于通过选择性吸附所述催化剂上的硫化合物和/或芳族化合物的氢化来还原烃基燃料中的硫化合物含量。

7. 发明申请

US20080103338A1 Method for the Hydrogenation of Ketones 有权
标题翻译：酮加氢方法
公开(公告)号：US20080103338A1
公开(公告)日：2008-05-01
申请号：US11718356
申请日：2005-11-16
申请人： Jurgen Ladebeck
发明人： Jurgen Ladebeck
IPC分类号： C07C29/145
CPC分类号： B01J23/868 , B01J37/0009 , B01J37/0045 , B01J37/03 , C07C29/145 , C07C33/22
摘要： The invention relates to a method for the hydrogenation of ketones. According to said method, the ketone is supplied, in a mixture with hydrogen, to a catalyst bed containing a copper chromite catalyst containing SiO2.
摘要翻译：本发明涉及一种氢化酮的方法。根据所述方法，将酮与氢气的混合物供给到含有含SiO 2的亚铬酸铜催化剂的催化剂床上。

8. 发明申请

US20070231243A1 METHOD FOR THE PRODUCTION OF HYDROTALCITES 有权
标题翻译：生产水合物的方法
公开(公告)号：US20070231243A1
公开(公告)日：2007-10-04
申请号：US11741847
申请日：2007-04-30
申请人： MAX EISGRUBER , Jurgen Ladebeck , Jurgen Koy , Hubert Schiessling , Wolfgang Buckl , Herrmann Ebert
发明人： MAX EISGRUBER , Jurgen Ladebeck , Jurgen Koy , Hubert Schiessling , Wolfgang Buckl , Herrmann Ebert
IPC分类号： C01B31/30 , C07F11/00
CPC分类号： B01J23/007 , B01J21/10 , C01F7/005 , C01P2002/22 , C01P2004/61 , C01P2004/62 , C01P2006/12 , C09C1/42
摘要： A method is described for the manufacture of hydrotalcites by using at least one compound of a bivalent metal (Component A) and at least one compound of a trivalent metal (Component B), wherein at least one of these components is not used in the form of a solution, characterized in that a) at least one of the Components A and/or B which is not used in the form of a solution, shortly before or during mixing of the components, and/or b) the mixture containing the Components A and B is subjected to intensive grinding until an average particle size (D50) in the range of approx. 0.1 to 5 μm is obtained, and optionally, after aging treatment or hydrothermal treatment, the resulting hydrotalcite product is separated, dried, and optionally calcinated. The hydrotalcite precursors and/or fine-particle crystalline hydrotalcites which can be obtained by using the method in accordance with this present invention may be used in particular as catalysts or catalyst carriers or as nanocomposite filling agents or co-stabilizers in a polymer matrix.
摘要翻译：描述了通过使用至少一种二价金属化合物（组分A）和至少一种三价金属化合物（组分B）制备水滑石的方法，其中这些组分中的至少一种不以其形式使用的溶液，其特征在于a）组分A和/或B中至少一种在组分混合之前或期间不以溶液的形式使用，和/或b）含有组分对A和B进行强力研磨，直至平均粒径（D≤50）在约并且任选地，在时效处理或水热处理之后，将所得水滑石产物分离，干燥并任选地煅烧。可以通过使用本发明的方法获得的水滑石前体和/或细颗粒结晶水滑石特别可以用作催化剂或催化剂载体，或作为聚合物基质中的纳米复合填充剂或共稳定剂使用。

9. 发明申请

US20050080148A1 Cu/zn/al catalyst for methanol synthesis 有权
标题翻译：用于甲醇合成的Cu / zn / Al催化剂
公开(公告)号：US20050080148A1
公开(公告)日：2005-04-14
申请号：US10497865
申请日：2002-11-06
申请人： Jurgen Ladebeck , Jurgen Koy , Tiberius Regula
发明人： Jurgen Ladebeck , Jurgen Koy , Tiberius Regula
IPC分类号： B01J23/80 , B01J35/10 , B01J37/03 , C07B61/00 , C07C29/154 , C07C31/04 , C07C27/06 , B01J23/70 , B01J23/72
CPC分类号： C07C29/154 , B01J23/80 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J35/1014 , B01J35/1019 , Y02P20/52 , C07C31/04
摘要： Disclosed is an Cu/Zn/Al-catalyst containing copper oxide and zinc oxide as catalytically active components and aluminium oxide as thermostabilising component. The catalyst is characterized in that the Cu/Zn atomic ratio is
摘要翻译：公开了含有氧化铜和氧化锌作为催化活性组分和氧化铝作为热稳定组分的Cu / Zn / Al催化剂。催化剂的特征在于Cu / Zn原子比<2.8，氧化铝组分由氢氧化铝溶胶获得。

10. 发明授权

US07378369B2 Nickel supported on titanium stabilized promoted calcium aluminate carrier 有权
标题翻译：镍负载钛稳定的促进铝酸钙载体
公开(公告)号：US07378369B2
公开(公告)日：2008-05-27
申请号：US10806259
申请日：2004-03-22
申请人： Shizhong Zhao , Yeping Cai , Jurgen Ladebeck
发明人： Shizhong Zhao , Yeping Cai , Jurgen Ladebeck
IPC分类号： B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： B01J23/78 , B01J21/04 , B01J21/063 , B01J23/005 , B01J23/8946 , B01J35/0053 , B01J35/1009 , B01J35/1014 , B01J35/1038 , B01J37/0009 , B01J37/0205 , B01J37/0207 , C01B3/40 , C01B2203/0233 , C01B2203/0238 , C01B2203/1041 , C01B2203/1052 , C01B2203/1058 , C01B2203/1094 , C01B2203/127 , Y02P20/52
摘要： A calcium-promoted alumina supported nickel reforming catalyst stabilized with titanium is disclosed. The catalyst is particularly useful for reforming reaction in feed streams containing significant quantities of CO and CO2, low quantities of steam (the feed stream having a H2O/CH4 of less than 0.8 and a CO2/CH4 of greater than 0.5) and relatively high quantities of sulfur compounds (up to about 20 ppm). The catalyst comprises from about 25 wt % to about 98 wt % alumina as a support, from about 2 wt % to about 40 wt % nickel oxide, which is promoted with from about 0.5 wt % to about 35 wt % calcium oxide, and which is stabilized with from about 0.01 wt % to about 20 wt % titanium, wherein the calcium oxide is combined with the alumina to form calcium aluminate. The catalyst can be used in reforming reactions to produce syngas and has advantages in producing low hydrogen to carbon monoxide ratio syngas for applications such as iron ore reduction.
摘要翻译：公开了一种用钛稳定的钙促进氧化铝负载镍重整催化剂。该催化剂特别适用于在含有大量CO和CO 2的少量蒸汽（含有H 2 O / CH 3）的进料流中的重整反应中， SUB> 4 小于0.8且CO 2/2 / CH 4大于0.5）和相对较高量的硫化合物（高达约20ppm ）。催化剂包含约25重量％至约98重量％的作为载体的氧化铝，约2重量％至约40重量％的氧化镍，其以约0.5重量％至约35重量％的氧化钙促进，其中用约0.01重量％至约20重量％的钛稳定，其中氧化钙与氧化铝组合以形成铝酸钙。催化剂可用于重整反应以产生合成气，并且具有生产低氢至一氧化碳比的合成气的优点，用于诸如铁矿石还原的应用。

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