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    • 3. 发明授权
    • Process for isolation of dicarboxylic acids and hydroxycarboxlic acids
    • 分离二羧酸和羟基羧酸的方法
    • US06444108B1
    • 2002-09-03
    • US09591479
    • 2000-06-09
    • Joel David CitronMichael Robert Samuels
    • Joel David CitronMichael Robert Samuels
    • B01D6144
    • F26B21/14B01D61/44C07C51/02C07C51/15F26B11/12C07C65/03C07C65/11C07C65/05C07C65/105
    • A first process involves the partial electrodialysis of a dialkali metal salt of an aromatic hydroxycarboxylic acid or a dicarboxylic acid to produce the approximate monoalkali metal salt and the alkali metal hydroxide. The monoalkali metal salt is then treated with an acid such as a bisulfate to recover the aromatic hydroxycarboxylic acid or dicarboxylic acid. The resulting inorganic salt such as sodium sulfate may then be electrolyzed to sodium bisulfate and NaOH. A second process involves the electrodialysis at elevated temperatures of a (di)alkali metal salt of p-hydroxybenzoic acid produce free p-hydroxybenzoic acid and the alkali metal hydroxide. These are efficient and economical methods for recovering the acid and alkali metal hydroxide values, as well as the parent organic compound, from these dialkali metal salts.
    • 第一种方法包括对芳族羟基羧酸或二羧酸的二碱金属盐进行部分电渗析以产生大致的单碱金属盐和碱金属氢氧化物。 然后用酸如硫酸氢盐处理单碱金属盐,以回收芳族羟基羧酸或二羧酸。 然后将得到的无机盐如硫酸钠电解为硫酸氢钠和NaOH。 第二种方法包括在对羟基苯甲酸的(二)碱金属盐的升高的温度下进行电渗析,产生游离的对羟基苯甲酸和碱金属氢氧化物。 这些是从这些二碱金属盐中回收酸和碱金属氢氧化物值以及母体有机化合物的有效和经济的方法。