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1. 发明授权

US4260829A Preparation of carbonyl compounds 失效
标题翻译：羰基化合物的制备
公开(公告)号：US4260829A
公开(公告)日：1981-04-07
申请号：US067706
申请日：1979-08-17
申请人： Michael Horner , Axel Nissen , Peter R. Laurer , Matthias Irgang , Heinrich Pasedach
发明人： Michael Horner , Axel Nissen , Peter R. Laurer , Matthias Irgang , Heinrich Pasedach
IPC分类号： B01J31/00 , C07B31/00 , C07B35/02 , C07B61/00 , C07C45/00 , C07C45/62 , C07C67/00
CPC分类号： C07C45/62
摘要： Carbonyl compounds R.sup.1 --CHR.sup.2 --CHR.sup.3 --CR.sup.4 O (I, R.sup.1 =H or an organic radical; R.sup.2 -R.sup.4 =H or C.sub.1 -C.sub.4 -alkyl) are prepared by selective hydrogenation of the .alpha.,.beta.-unsaturated carbonyl compounds R.sup.1 --CR.sup.2 =CR.sup.3 --CR.sup.4 O (II) in the liquid phase by means of hydrogen in the presence of a palladium catalyst and of from 15 to 50% by weight, based on (II), of a tertiary amine.
摘要翻译：通过α，β-不饱和羰基化合物的选择性氢化制备羰基化合物R1-CHR2-CHR3-CR4O（I，R1 = H或有机基; R2-R4 = H或C1-C4-烷基）R1-CR2 = CR 3 -CR 4 O（II）在氢气存在下在钯催化剂和15至50重量％（基于（II））叔胺的液相中。

2. 发明授权

US4455442A Preparation of unsaturated alcohols 失效
标题翻译：不饱和醇的制备
公开(公告)号：US4455442A
公开(公告)日：1984-06-19
申请号：US166857
申请日：1980-07-08
申请人： Michael Horner , Matthias Irgang , Axel Nissen
发明人： Michael Horner , Matthias Irgang , Axel Nissen
IPC分类号： C07C29/136 , B01J23/00 , B01J23/40 , B01J31/00 , B01J31/02 , C07B31/00 , C07B41/02 , C07B61/00 , C07C27/00 , C07C29/141 , C07C29/145 , C07C33/02 , C07C33/03 , C07C33/30 , C07C67/00 , C07C29/14 , C07C33/20
CPC分类号： C07C29/145 , C07C29/141
摘要： Olefinically unsaturated alcohols (I) are prepared by selective hydrogenation of the corresponding carbonyl compounds (II) in the liquid phase with hydrogen, using an Ru, Rh, Os, Ir or Pt catalyst and carrying out the hydrogenation in the presence of from 5 to 40% by weight, based on (II), of a tertiary amine.The process is of particular importance for the selective hydrogenation of .alpha.,.beta.-unsaturated carbonyl compounds (IIa) and amongst these specifically for the hydrogenation of citral to geraniol and nerol.The preferred amine is trimethylamine.
摘要翻译：烯属不饱和醇（I）通过使用Ru，Rh，Os，Ir或Pt催化剂用液相中相应的羰基化合物（II）选择性氢化制备，并在5〜 40重量％，基于（II）的叔胺。该方法对α，β-不饱和羰基化合物（IIa）的选择性氢化特别重要，其中特别用于将柠檬醛氢化成香叶醇和橙花醇。优选的胺是三甲胺。

3. 发明授权

US4320228A Preparation of olefinically unsaturated carbonyl compounds and alcohol 失效
标题翻译：烯属不饱和羰基化合物和醇的制备
公开(公告)号：US4320228A
公开(公告)日：1982-03-16
申请号：US166858
申请日：1980-07-08
申请人： Michael Horner , Matthias Irgang , Axel Nissen
发明人： Michael Horner , Matthias Irgang , Axel Nissen
IPC分类号： C07C47/21 , B01J23/00 , B01J23/40 , B01J31/02 , C07B61/00 , C07C27/00 , C07C29/136 , C07C29/145 , C07C29/17 , C07C33/02 , C07C33/025 , C07C45/00 , C07C45/62 , C07C49/203 , C07C67/00
CPC分类号： C07C45/62 , C07C29/175 , C07B2200/09
摘要： Olefinically unsaturated carbonyl compounds R.sup.1 --CHR.sup.2 --CHR.sup.3 --C(R.sup.4)O (I) and alcohols R.sup.1 --CHR.sup.2 --CHR.sup.3 --CH(R.sup.4)--OH (II) (where R.sup.1 is an olefinically unsaturated organic radical, and R.sup.2, R.sup.3 and R.sup.4 are H or C.sub.1 -C.sub.4 -alkyl) are prepared by hydrogenating the carbonyl compounds R.sup.1 --CR.sup.2 .dbd.CR.sup.3 --C(R.sup.4)O (III) in the liquid phase with hydrogen, using a catalyst system comprising, firstly, Pd and, secondly, Ru, Rh, Os, Ir or Pt, in the presence of from 5 to 40% by weight, based on (III), of a tertiary amine, under a hydrogen pressure of from 1 to 20 bar is predominantly (I) is to be obtained and from 20 to 150 bar if predominantly (II) is to be obtained.The process is of particular importance for the hydrogenation of citral (IIIa) to give citronellal (Ia) or citronellol (IIa), the preferred amine being trimethylamine.
摘要翻译：烯属不饱和羰基化合物R1-CHR2-CHR3-C（R4）O（Ⅰ）和醇R1-CHR2-CHR3-CH（R4）-OH（Ⅱ）（其中R1是烯属不饱和有机基团，R2，R3和 R 4是H或C 1 -C 4 - 烷基）是通过使用包含以下的催化剂体系氢气氢化羰基化合物R1-CR2 = CR3-C（R4）O（Ⅲ）来制备的，首先是Pd，其次是，Ru，Rh，Os，Ir或Pt在1-5重量％的存在下，在（III）的叔胺的存在下，在1至20巴的氢气压力下，主要是（I）如果要获得主要（II），则为20至150巴。该方法对于柠檬醛（IIIa）的氢化以产生香茅醛（Ia）或香茅醇（IIa）是特别重要的，优选的胺是三甲胺。

4. 发明授权

US4173588A Manufacture of 2-methyl-2-hepten-6-one 失效
标题翻译：制备2-甲基-2-庚烯-6-酮
公开(公告)号：US4173588A
公开(公告)日：1979-11-06
申请号：US848211
申请日：1977-11-03
申请人： Heinrich Pasedach , Rudolf Mohr , Axel Nissen
发明人： Heinrich Pasedach , Rudolf Mohr , Axel Nissen
IPC分类号： C07C45/00 , B01J31/00 , C07B61/00 , C07C45/67 , C07C49/203 , C07C67/00 , C07C45/18
CPC分类号： C07C45/676
摘要： An improved process for the manufacture of 2-methyl-2-hepten-6-one by reacting an alkyl acetoacetate with 2-methyl-3-buten-2-ol in the presence of an organic aluminum compound such as aluminum trialcoholate, aluminum triacetoacetate, aluminum alkylacetoacetate or aluminum triaryloxylate. 2-Methyl-2-hepten-6-one is an intermediate for the manufacture of vitamins.
摘要翻译：通过使乙酰乙酸烷基酯与2-甲基-3-丁烯-2-醇在有机铝化合物如仲醇酸铝，三乙酰乙酸铝的存在下反应来制备2-甲基-2-庚烯-6-酮的改进方法，烷基乙酰乙酸铝或三芳氧基铝。 2-甲基-2-庚烯-6-酮是制造维生素的中间体。

5. 发明授权

US4720327A Distillative separation of liquid mixtures of substances 失效
标题翻译：物质液体混合物的蒸馏分离
公开(公告)号：US4720327A
公开(公告)日：1988-01-19
申请号：US420485
申请日：1982-09-20
申请人： Werner Aquila , Axel Nissen , Gerd Kaibel , Michael Horner , Walter Rebafka
发明人： Werner Aquila , Axel Nissen , Gerd Kaibel , Michael Horner , Walter Rebafka
IPC分类号： A61K8/33 , A61Q13/00 , B01D3/34 , C07B31/00 , C07B63/00 , C07C27/00 , C07C29/141 , C07C29/80 , C07C31/04 , C07C33/025 , C07C45/00 , C07C45/82 , C07C47/21 , C07C67/00 , C11B9/00 , C11B9/02 , B01D3/38
CPC分类号： C07C45/82 , B01D3/34 , C11B9/027 , Y10S203/24 , Y10S203/90
摘要： Distillative separation of liquid mixtures of one or more water-insoluble substances which have boiling points higher than that of water and one or more substances which have boiling points lower than that of water or which form azeotropes having boiling points lower than that of water, wherein the mixture to be distilled is mixed with a quantity of water such that the boiling point of the water under the pressure applied limits the bottom temperature of the mixture of substances to be separated.
摘要翻译：沸点高于水的一种或多种水不溶性物质的液体混合物的蒸馏分离和一种或多种沸点低于水的沸点或者沸点低于水的沸点的物质，其中将要蒸馏的混合物与一定量的水混合，使得在施加压力下的水的沸点限制待分离物质的混合物的底部温度。

6. 发明授权

US4268446A Preparation of chromane derivatives 失效
标题翻译：色烯衍生物的制备
公开(公告)号：US4268446A
公开(公告)日：1981-05-19
申请号：US121170
申请日：1980-02-13
申请人： Michael Horner , Axel Nissen
发明人： Michael Horner , Axel Nissen
IPC分类号： C07D311/72 , C07D311/66 , C07D311/58
CPC分类号： C07D311/66
摘要： Chromane derivatives (I) ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are H or C.sub.1 -C.sub.8 -alkyl, R.sup.4 is H, C.sub.1 -C.sub.8 -alkyl or C.sub.1 -C.sub.8 -acyl and R.sup.5 is C.sub.1 -C.sub.8 -alkyl are prepared by reacting a hydroquinone (II) ##STR2## with a Lewis acid or a Lewis acid derivative having the same action, and with a nitrile CH.sub.2 .dbd.CH--C(R.sup.5)(OR.sup.6)CN (III), where R.sup.6 is H, C.sub.1 -C.sub.4 -acyl or C.sub.1 -C.sub.4 -alkyl, or with a compound from which III is formed in situ, in the presence of an inert solvent.
摘要翻译：色原烷衍生物（I）其中R 1，R 2和R 3是H或C 1 -C 8 - 烷基，R 4是H，C 1 -C 8 - 烷基或C 1 -C 8酰基，R 5是C 1 -C 8 - 烷基是通过使氢醌（II）II与具有相同作用的路易斯酸或路易斯酸衍生物反应，并与腈CH2 = CH-C（R5）（OR6）CN（III）反应，其中R6为H，C1 -C 1-4酰基或C 1 -C 4 - 烷基，或与惰性溶剂存在下原位形成III的化合物反应。

7. 发明授权

US4511685A Chroman derivatives and stabilized polypropylene composition 失效
标题翻译：色甘烷衍生物和稳定的聚丙烯组合物
公开(公告)号：US4511685A
公开(公告)日：1985-04-16
申请号：US238593
申请日：1981-02-26
申请人： Axel Nissen , Michael Horner , Dieter Horn , Erik Lueddecke , Gernot Teege
发明人： Axel Nissen , Michael Horner , Dieter Horn , Erik Lueddecke , Gernot Teege
IPC分类号： C07D311/72 , C07D311/20 , C07D311/58 , C07D311/66 , C07D311/70 , C09K15/08 , C09K15/14 , C09K15/24 , C09K15/28 , C08K5/09
CPC分类号： C07D311/58 , C07D311/66 , C09K15/08
摘要： Chroman derivatives of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each H or C.sub.1 -C.sub.4 -alkyl, R.sup.5 is C.sub.10 -C.sub.30 -alkyl or C.sub.10 -C.sub.30 -alkenyl, X and Y are each O, NH or S, m is 0, 1, 2 or 3 and n and r are each 0 or 1, the preparation of compounds I by various methods known per se, and the use of the compounds as stabilizers for organic materials.
摘要翻译：其中R 1，R 2，R 3和R 4各自为H或C 1 -C 4 - 烷基，R 5为C 10 -C 30 - 烷基或C 10 -C 30 - 烯基，通式I的色原衍生物，X和Y各自为O， NH或S，m为0,1,2或3，n和r各自为0或1，通过本身已知的各种方法制备化合物I，以及将化合物用作有机材料的稳定剂。

8. 发明授权

US4353836A 4-(2,5-Dihydroxyphen-1-yl)-crotonic acid and its derivatives, and the preparation of these compounds 失效
标题翻译： 4-（2,5-二羟基苯基-1-基） - 巴豆酸及其衍生物，以及这些化合物的制备
公开(公告)号：US4353836A
公开(公告)日：1982-10-12
申请号：US238609
申请日：1981-02-26
申请人： Michael Horner , Axel Nissen
发明人： Michael Horner , Axel Nissen
IPC分类号： C07C69/73 , C07C51/00 , C07C59/52 , C07C59/58 , C07C59/64 , C07C67/00 , C07C69/28 , C07C69/734
CPC分类号： C07C59/64 , C07C59/52
摘要： 4-(2,5-Dihydroxyphen-1-yl)-crotonic acid and its derivative (I) ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each H or C.sub.1 -C.sub.8 -alkyl, R.sup.5 is H, C.sub.1 -C.sub.30 -alkyl or C.sub.2 -C.sub.30 -alkenyl, and R' is H or an organic radical which can be split off hydrogenolytically, and a process for the preparation of the compounds I, wherein a hydroquinone II ##STR2## is reacted, in the presence of from 0.1 to 2 moles of a Lewis acid per mole of II, with(a) a vinylglycolic acid derivative IIIa ##STR3## or (b) a crotonic acid derivative IIIb ##STR4## where X is halogen, hydroxyl or C.sub.1 -C.sub.4 -alkoxy or acyloxy.
摘要翻译： 4-（2,5-二羟基苯基-1-基） - 巴豆酸及其衍生物（Ⅰ）其中R1，R2，R3和R4分别为H或C1-C8-烷基，R5为H，C1- C30-烷基或C2-C30-烯基，R'是H或可以被氢解分解的有机基团，以及制备化合物I的方法，其中氢醌II II在每摩尔II存在0.1至2摩尔路易斯酸，（a）乙烯基乙醇酸衍生物IIIa或（b）巴豆酸衍生物IIIb IIIb其中X为卤素，羟基或C1 -C 1-4 - 烷氧基或酰氧基。

9. 发明授权

US4344886A Preparation of 2-hydroxyalkylchromans 失效
标题翻译： 2-羟基烷基苯并二氢吡喃的制备
公开(公告)号：US4344886A
公开(公告)日：1982-08-17
申请号：US238608
申请日：1981-02-26
申请人： Michael Horner , Axel Nissen
发明人： Michael Horner , Axel Nissen
IPC分类号： C07D311/72 , B01J27/08 , C07B61/00 , C07D311/58
CPC分类号： C07D311/58
摘要： 2-Hydroxyalkylchromans (I) ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each H or C.sub.1 -C.sub.8 -alkyl, R' is H or an organic radical which can be split off hydrolytically or hydrogenolytically as R'-OH or R'-COOH, and m is 1, 2 or 3, are prepared by reacting a hydroquinone II ##STR2## (a) with an alkenediol IIIa ##STR3## or (b) with an alkenediol IIIb ##STR4## or (c) with an alkenediol IIIc ##STR5## where R.sup.4' is a radical which during the condensation with II is converted to the radical R.sup.4,at from -50.degree. C. to 120.degree. C., in an inert solvent, in the presence of from 10 to 300 mole %, based on II, of a Lewis acid or of an adduct of a Lewis acid with a Lewis base which has a lower basicity than compound II.
摘要翻译： 2-羟基烷基苯并二氢吡喃（I）其中R 1，R 2，R 3和R 4各自为H或C 1 -C 8 - 烷基，R'为H或可以作为R'-OH水解或氢解分解的有机基团 R'-COOH，m为1,2或3，通过使氢醌II（a）与烯二醇IIIa IIIa或（b）与烯二醇IIIb IIIb或（ c）具有烯二醇IIIc IIIc，其中R 4'是在与C的缩合过程中，在-50℃至120℃下，在惰性溶剂中，在存在 10至300摩尔％，基于II，路易斯酸或路易斯酸与路易斯碱的加合物具有比化合物II低的碱性。

10. 发明授权

US4273945A Preparation of saturated aliphatic, cycloaliphatic and araliphatic aldehydes 失效
标题翻译：饱和脂肪族，脂环族和芳脂肪醛的制备
公开(公告)号：US4273945A
公开(公告)日：1981-06-16
申请号：US54889
申请日：1979-07-05
申请人： Gerd Heilen , Axel Nissen , Wolfgang Koernig , Michael Horner , Werner Fliege , Guenter Boettger
发明人： Gerd Heilen , Axel Nissen , Wolfgang Koernig , Michael Horner , Werner Fliege , Guenter Boettger
IPC分类号： B01J23/00 , B01J23/56 , C07B61/00 , C07C45/00 , C07C45/50 , C07C45/62 , C07C47/02 , C07C47/228 , C07C47/28 , C07C67/00
CPC分类号： C07C45/62
摘要： Saturated aliphatic, cycloaliphatic and araliphatic aldehydes are prepared by selective hydrogenation of the corresponding olefinically unsaturated aldehydes with hydrogen in the liquid phase over a palladium-containing catalyst, using a catalyst system in which the active constituents are from 2 to 90% by weight of palladium and from 10 to 98% by weight of an oxide or a salt of a rare earth metal or of a mixture of different oxides and/or salts of this type.
摘要翻译：饱和脂肪族，脂环族和芳脂族醛通过使用催化剂体系在含钯催化剂中的液相中用氢气选择性氢化相应的烯属不饱和醛来制备，其中活性组分为2-90重量％的钯和10至98重量％的氧化物或稀土金属的盐或这种类型的不同氧化物和/或盐的混合物。

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