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    • 3. 发明申请
    • Poly(ethylene-butylene) (meth)acrylates and related compositions
    • 聚(乙烯 - 丁烯)(甲基)丙烯酸酯和相关组合物
    • US20050154121A1
    • 2005-07-14
    • US11035357
    • 2005-01-12
    • Mingxin FanJeffrey Allan KlangGary CeskaJames Horgan
    • Mingxin FanJeffrey Allan KlangGary CeskaJames Horgan
    • C08C19/00C08C19/38C08G18/62C08G18/69C08K3/00C08L15/00C08L19/00
    • C08C19/38B33Y70/00C08G18/69C08L15/00C08L19/006
    • A composition comprising a polymer according to Structure 1 wherein R is H, Me, Et or C6H5; R′ is H or Me; n is a number from 1 to 100; and Z is a number from 1 to 3; f is a number from 1 to 5, with f=1 if B is nothing; A is residue of a hydrogenated polybutadiene backbone; and B nothing or it is a difunctional organic linking group is disclosed. The composition can be cured and used in a wide range of articles such as a photopolymer printing plate, sealant, caulk, encapsulent, road marking paint, photoresist, binder, impact modifier, polymer modifier, oxygen or water vapor barrier coating, conformal coating, solder mask, pigment dispersion, stereolithograph, laminating resin, grafted co-polymer, composite, optical fiber coating, paper coating, metal coating, glass coating, plastic coating, wood coating, waterproofing material, electrical insulating material, automotive belt or hose, tire, engine mount, gasket, golf ball core, and rubber roll.
    • 一种组合物,其包含根据结构1的聚合物,其中R是H,Me,Et或C 6 H 5; R'是H或Me; n是1至100的数字; Z为1〜3的数; f是从1到5的数字,如果B没有,f = 1; A是氢化聚丁二烯骨架的残基; 和B无关,或者是双官能的有机连接基。 该组合物可以固化并用于宽范围的制品中,例如光聚合物印刷版,密封剂,填缝剂,密封剂,道路标线漆,光致抗蚀剂,粘合剂,抗冲改性剂,聚合物改性剂,氧气或水蒸气阻隔涂料,保形涂层, 焊料掩模,颜料分散体,立体光刻胶,层压树脂,接枝共聚物,复合材料,光纤涂层,纸张涂层,金属涂层,玻璃涂层,塑料涂层,木器涂料,防水材料,电绝缘材料,汽车皮带或软管,轮胎 发动机支架,垫片,高尔夫球芯和橡胶辊。
    • 6. 发明授权
    • Radiation curable acrylate-terminated polymers having polycarbonate repeating units
    • 具有聚碳酸酯重复单元的可辐射固化的丙烯酸酯封端的聚合物
    • US06451958B1
    • 2002-09-17
    • US09932559
    • 2001-04-06
    • Mingxin FanGary CeskaJames Horgan
    • Mingxin FanGary CeskaJames Horgan
    • C08G6400
    • C09D175/16C08G18/672Y10T428/31504Y10T428/31507Y10T428/31551C08G18/44
    • Polymer having repeating polycarbonate moieties of the formula (I) (Acr)y(A)(Q)(PC)[(Q)(PC)]x(Q)(A)(Acr)y  (I) wherein (Acr)y(A) is the residue of hydroxyalkyl acrylate or hydroxyalkyl methacrylate having an alkyl moiety, A, and where said alkyl, A, has 2 to 5 carbon atoms and wherein Acr is an acrylate or methacrylate moiety; Q is the residue of one or more organic polyisocyantes which are connected with A via a urethane linkage; PC is the residue of an alkylene diol polycarbonate of the formula (II) HO(ROCOO)nROH  (II) R is one or more (C2 to C10) alkylene or one or more (C6 to C12) aromatic group; y is an integer from 1 to 5; x is from 1 to 20; PC and Q are connected via a urethane group. The acrylate terminate polymers are useful for radiation cured coatings which have superior adhesion and reverse impact strength, especially when applied to plastic substrates.
    • 具有式(I)的重复聚碳酸酯部分的聚合物其中(Acr)y(A)是具有烷基部分A的丙烯酸羟烷基酯或甲基丙烯酸羟烷基酯的残基,并且其中所述烷基A具有2至5个碳原子,其中 Acr是丙烯酸酯或甲基丙烯酸酯部分; Q是通过氨基甲酸酯键与A连接的一种或多种有机聚异氰酸酯的残基; PC是式(II)的亚烷基二醇聚碳酸酯的残基R是一个或多个(C2 至C10)亚烷基或一个或多个(C6至C12)芳族基团; y为1至5的整数; x为1至20; PC和Q通过氨基甲酸酯基团连接。丙烯酸酯末端聚合物可用于辐射 具有优异的附着力和反冲击强度的固化涂层,特别是当应用于塑料基材时。