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1. 发明申请

US20050154121A1 Poly(ethylene-butylene) (meth)acrylates and related compositions 有权
标题翻译：聚（乙烯 - 丁烯）（甲基）丙烯酸酯和相关组合物
公开(公告)号：US20050154121A1
公开(公告)日：2005-07-14
申请号：US11035357
申请日：2005-01-12
申请人： Mingxin Fan , Jeffrey Allan Klang , Gary Ceska , James Horgan
发明人： Mingxin Fan , Jeffrey Allan Klang , Gary Ceska , James Horgan
IPC分类号： C08C19/00 , C08C19/38 , C08G18/62 , C08G18/69 , C08K3/00 , C08L15/00 , C08L19/00
CPC分类号： C08C19/38 , B33Y70/00 , C08G18/69 , C08L15/00 , C08L19/006
摘要： A composition comprising a polymer according to Structure 1 wherein R is H, Me, Et or C6H5; R′ is H or Me; n is a number from 1 to 100; and Z is a number from 1 to 3; f is a number from 1 to 5, with f=1 if B is nothing; A is residue of a hydrogenated polybutadiene backbone; and B nothing or it is a difunctional organic linking group is disclosed. The composition can be cured and used in a wide range of articles such as a photopolymer printing plate, sealant, caulk, encapsulent, road marking paint, photoresist, binder, impact modifier, polymer modifier, oxygen or water vapor barrier coating, conformal coating, solder mask, pigment dispersion, stereolithograph, laminating resin, grafted co-polymer, composite, optical fiber coating, paper coating, metal coating, glass coating, plastic coating, wood coating, waterproofing material, electrical insulating material, automotive belt or hose, tire, engine mount, gasket, golf ball core, and rubber roll.
摘要翻译：一种组合物，其包含根据结构1的聚合物，其中R是H，Me，Et或C 6 H 5; R'是H或Me; n是1至100的数字; Z为1〜3的数; f是从1到5的数字，如果B没有，f = 1; A是氢化聚丁二烯骨架的残基; 和B无关，或者是双官能的有机连接基。该组合物可以固化并用于宽范围的制品中，例如光聚合物印刷版，密封剂，填缝剂，密封剂，道路标线漆，光致抗蚀剂，粘合剂，抗冲改性剂，聚合物改性剂，氧气或水蒸气阻隔涂料，保形涂层，焊料掩模，颜料分散体，立体光刻胶，层压树脂，接枝共聚物，复合材料，光纤涂层，纸张涂层，金属涂层，玻璃涂层，塑料涂层，木器涂料，防水材料，电绝缘材料，汽车皮带或软管，轮胎发动机支架，垫片，高尔夫球芯和橡胶辊。

2. 发明授权

US06469071B1 Radiation curable acrylate-terminated polymers having polycarbonate repeating units 有权
标题翻译：具有聚碳酸酯重复单元的可辐射固化的丙烯酸酯封端聚
公开(公告)号：US06469071B1
公开(公告)日：2002-10-22
申请号：US09835240
申请日：2001-04-13
申请人： Mingxin Fan , Gary Ceska , James Horgan , Robert Adams , William Schaeffer , Josh Oliver
发明人： Mingxin Fan , Gary Ceska , James Horgan , Robert Adams , William Schaeffer , Josh Oliver
IPC分类号： C08F248
CPC分类号： C08G64/045 , C08F299/0492 , C08G64/42 , C09D169/00 , Y10T428/249982 , Y10T428/31504 , Y10T428/31507 , Y10T428/31786 , Y10T428/31826 , Y10T428/31855
摘要： Polyester based polycarbonate (meth)acrylates prepared by the reaction of a alkylene or arylene diol polycarbonate with an anhydride or its dicarboxylic acid to form a carboxyl terminated diester, reacting the diester with a diglycidyl ether and an acrylic or methacrylic acid to form an acrylate terminate polymer which is useful for radiation cured coatings which have superior adhesion and reverse impact strength when applied to plastic substrates.
摘要翻译：通过亚烷基或亚芳基二醇聚碳酸酯与酸酐或其二羧酸的反应制备的聚酯基聚碳酸酯（甲基）丙烯酸酯以形成羧基封端的二酯，使二酯与二缩水甘油醚和丙烯酸或甲基丙烯酸反应形成丙烯酸酯末端可用于辐射固化涂层的聚合物，其在施加到塑料基材上时具有优异的粘附性和反冲击强度。

3. 发明授权

US06451958B1 Radiation curable acrylate-terminated polymers having polycarbonate repeating units 有权
标题翻译：具有聚碳酸酯重复单元的可辐射固化的丙烯酸酯封端的聚合物
公开(公告)号：US06451958B1
公开(公告)日：2002-09-17
申请号：US09932559
申请日：2001-04-06
申请人： Mingxin Fan , Gary Ceska , James Horgan
发明人： Mingxin Fan , Gary Ceska , James Horgan
IPC分类号： C08G6400
CPC分类号： C09D175/16 , C08G18/672 , Y10T428/31504 , Y10T428/31507 , Y10T428/31551 , C08G18/44
摘要： Polymer having repeating polycarbonate moieties of the formula (I) (Acr)y(A)(Q)(PC)[(Q)(PC)]x(Q)(A)(Acr)y (I) wherein (Acr)y(A) is the residue of hydroxyalkyl acrylate or hydroxyalkyl methacrylate having an alkyl moiety, A, and where said alkyl, A, has 2 to 5 carbon atoms and wherein Acr is an acrylate or methacrylate moiety; Q is the residue of one or more organic polyisocyantes which are connected with A via a urethane linkage; PC is the residue of an alkylene diol polycarbonate of the formula (II) HO(ROCOO)nROH (II) R is one or more (C2 to C10) alkylene or one or more (C6 to C12) aromatic group; y is an integer from 1 to 5; x is from 1 to 20; PC and Q are connected via a urethane group. The acrylate terminate polymers are useful for radiation cured coatings which have superior adhesion and reverse impact strength, especially when applied to plastic substrates.
摘要翻译：具有式（I）的重复聚碳酸酯部分的聚合物其中（Acr）y（A）是具有烷基部分A的丙烯酸羟烷基酯或甲基丙烯酸羟烷基酯的残基，并且其中所述烷基A具有2至5个碳原子，其中 Acr是丙烯酸酯或甲基丙烯酸酯部分; Q是通过氨基甲酸酯键与A连接的一种或多种有机聚异氰酸酯的残基; PC是式（II）的亚烷基二醇聚碳酸酯的残基R是一个或多个（C2 至C10）亚烷基或一个或多个（C6至C12）芳族基团; y为1至5的整数; x为1至20; PC和Q通过氨基甲酸酯基团连接。丙烯酸酯末端聚合物可用于辐射具有优异的附着力和反冲击强度的固化涂层，特别是当应用于塑料基材时。

4. 发明授权

US06124483A Process for preparing unsaturated esters containing cyclic epoxy group 失效
标题翻译：制备含环状环氧基的不饱和酯的方法
公开(公告)号：US06124483A
公开(公告)日：2000-09-26
申请号：US773524
申请日：1996-12-23
申请人： Mingxin Fan , Gary W. Ceska , James Horgan
发明人： Mingxin Fan , Gary W. Ceska , James Horgan
IPC分类号： B01J31/24 , B01J31/34 , C07D301/12 , C07D303/16 , C07D303/24 , C07D303/40 , C08F20/32 , C08G59/24
CPC分类号： C07D303/40 , C07D301/12 , C07D303/16 , C07D303/24 , C08G59/24
摘要： Process of making compounds of the formula ##STR1## wherein R.sub.1 =(C.sub.1 -C.sub.6) alkyl;X=O, S, NH;R.sub.2 =divalent saturated organic group;Y=O, S, NH, ester;R.sub.3 =cyclic moiety containing oxirane group;comprising reacting a compound of the formula ##STR2## wherein R.sub.4 is a cyclic moiety containing C.dbd.C group with hydrogen peroxide in the presence of (a) tungstic acid, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst;polymers of compounds of formula I; andcompounds of formula I except for compounds wherein R.sub.4 is a dicyclopentenyl epoxide, Y is O, R.sub.2 is --CH.sub.2 CH.sub.2 --, X is O, and R.sub.1 is H or methyl.
摘要翻译：制备下式化合物的方法其中R1 =（C1-C6）烷基; X = O，S，NH; R2 =二价饱和有机基团; Y = O，S，NH，酯; R3 =含环氧乙烷基团的环状部分; 包括在（a）钨酸，（b）磷酸或其金属盐存在下使下式化合物其中R 4是含有C = C基团的环状部分与过氧化氢反应，和（c）至少一种相转移催化剂; 式I化合物的聚合物; 和式I化合物，除了其中R 4是二环戊烯基环氧化物，Y是O，R 2是-CH 2 CH 2 - ，X是O，R 1是H或甲基的化合物。

5. 发明授权

US07569641B2 Poly(ethylene-butylene) (meth)acrylates and related compositions 有权
标题翻译：聚（乙烯 - 丁烯）（甲基）丙烯酸酯和相关组合物
公开(公告)号：US07569641B2
公开(公告)日：2009-08-04
申请号：US11035357
申请日：2005-01-12
申请人： Mingxin Fan , Jeffrey Allan Klang , Gary W. Ceska , James Horgan
发明人： Mingxin Fan , Jeffrey Allan Klang , Gary W. Ceska , James Horgan
IPC分类号： C08C19/02 , C08C19/04 , C08C19/28 , C08C19/38 , C08F36/06
CPC分类号： C08C19/38 , B33Y70/00 , C08G18/69 , C08L15/00 , C08L19/006
摘要： A composition comprising a polymer according to Structure 1 wherein R is H, Me, Et or C6H5; R′ is H or Me; n is a number from 1 to 100; and Z is a number from 1 to 3; f is a number from 1 to 5, with f=1 if B is nothing; A is residue of a hydrogenated polybutadiene backbone; and B nothing or it is a difunctional organic linking group is disclosed. The composition can be cured and used in a wide range of articles such as a photopolymer printing plate, sealant, caulk, encapsulent, road marking paint, photoresist, binder, impact modifier, polymer modifier, oxygen or water vapor barrier coating, conformal coating, solder mask, pigment dispersion, stereolithograph, laminating resin, grafted co-polymer, composite, optical fiber coating, paper coating, metal coating, glass coating, plastic coating, wood coating, waterproofing material, electrical insulating material, automotive belt or hose, tire, engine mount, gasket, golf ball core, and rubber roll.
摘要翻译：一种组合物，其包含根据结构1的聚合物，其中R是H，Me，Et或C 6 H 5; R'是H或Me; n是1至100的数字; Z为1〜3的数; f是从1到5的数字，如果B没有，f = 1; A是氢化聚丁二烯骨架的残基; 和B无关，或者是双官能的有机连接基。该组合物可以固化并用于宽范围的制品中，例如光聚合物印刷版，密封剂，填缝料，密封剂，道路标线漆，光致抗蚀剂，粘合剂，抗冲改性剂，聚合物改性剂，氧气或水蒸气阻隔涂料，保形涂层，焊料掩模，颜料分散体，立体光刻胶，层压树脂，接枝共聚物，复合材料，光纤涂层，纸张涂层，金属涂层，玻璃涂层，塑料涂层，木器涂料，防水材料，电绝缘材料，汽车皮带或软管，轮胎发动机支架，垫片，高尔夫球芯和橡胶辊。

6. 发明授权

US5767150A Cycloaliphatic epoxide compounds 失效
标题翻译：环脂族环氧化合物
公开(公告)号：US5767150A
公开(公告)日：1998-06-16
申请号：US831677
申请日：1997-04-10
申请人： Mingxin Fan , Gary W. Ceska , James Horgan , Henri Strub
发明人： Mingxin Fan , Gary W. Ceska , James Horgan , Henri Strub
IPC分类号： C07D301/12 , C07D303/16 , C07D303/40 , C08G59/24 , C08G59/32 , A61K31/335 , C07D303/00
CPC分类号： C08G59/24 , C07D301/12 , C07D303/16 , C07D303/40 , C08G59/3218
摘要： Compounds having the formula ##STR1## wherein X is selected from O, (CH.sub.2).sub.m O, S, (CH.sub.2).sub.m S, NH, (CH.sub.2).sub.m NH, COO.sup.-, (CH.sub.2).sub.m COO.sup.-, .sup.- OOC and .sup.- OOC (CH.sub.2).sub.m ; m is 1 to 6; n is 1 to 100; R.sub.1 is (C.sub.1 -C.sub.20) ester; and A is a saturated organic linking group selected from residues of polyol, polythiol, polyamine, and polyacid, are prepared by reacting compounds according to formula II ##STR2## with hydrogen peroxide in the presence of (a) tungstic acid or its metal salts, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst.
摘要翻译：具有式（I）的化合物其中X选自O，（CH 2）m O，S，（CH 2）m S，NH，（CH 2）m NH，COO-，（CH 2）m COO-， - OOC和 -OOC（CH 2）m; m为1〜6; n为1〜100; R1是（C1-C20）酯; 并且A是选自多元醇，多硫醇，多胺和多元酸的残基的饱和有机连接基团，其通过使式II（II）的化合物与（a）钨酸或其金属盐，（b）磷酸或其金属盐，和（c）至少一种相转移催化剂。

7. 发明授权

US06559260B1 Allyl urethane resin compositions 有权
标题翻译：烯丙基聚氨酯树脂组合物
公开(公告)号：US06559260B1
公开(公告)日：2003-05-06
申请号：US09535176
申请日：2000-03-27
申请人： Mingxin Fan , Gary W. Ceska , James Horgan
发明人： Mingxin Fan , Gary W. Ceska , James Horgan
IPC分类号： C08L7516
CPC分类号： C09D175/16 , C08G18/6715
摘要： The present invention is for a new class of allyl urethane resin which can be cured with peroxide at high temperature alone or in combination with some accelerators. These allyl urethane resins can be sued alone or in combination with other free radically polymerizable materials such as allyl monomers and ligomers or (meth)acrylate monomers and oligomers. These new allyl urethane resins contain at least two allyl functional groups.
摘要翻译：本发明是一种新的烯丙基聚氨酯树脂，其可以单独或与一些加速剂组合使用，可以在高温下用过氧化物固化。这些烯丙基聚氨酯树脂可以单独或与其它可自由基聚合的材料如烯丙基单体和连接体或（甲基）丙烯酸酯单体和低聚物组合起来。这些新的烯丙基聚氨酯树脂含有至少两个烯丙基官能团。

8. 发明授权

US6084111A Method for making cycloaliphatic epoxides 失效
标题翻译：制备脂环族环氧化物的方法
公开(公告)号：US6084111A
公开(公告)日：2000-07-04
申请号：US62593
申请日：1998-04-17
申请人： Mingxin Fan , Gary W. Ceska , James Horgan , Henri Strub
发明人： Mingxin Fan , Gary W. Ceska , James Horgan , Henri Strub
IPC分类号： C07D301/12 , C07D303/16 , C07D303/40 , C08G59/24 , C08G59/32 , C07D303/00
CPC分类号： C08G59/24 , C07D301/12 , C07D303/16 , C07D303/40 , C08G59/3218
摘要： Compounds having the formula ##STR1## wherein X is selected from O, (CH.sub.2).sub.m O, S, (CH.sub.2).sub.m S, NH, (CH.sub.2).sub.m NH, COO.sup.-, (CH.sub.2).sub.m COO.sup.-, .sup.- OOC and .sup.- OOC (CH.sub.2).sub.m ;m is 1 to 6;n is 1 to 100;R.sub.1 is selected from H, (C.sub.1 -C.sub.20) alkyl, (C.sub.1 -C.sub.20) alkoxy and (C.sub.1 -C.sub.20) ester; andA is a saturated organic linking group selected from residues of polyol, polythiol, polyamine, and polyacid, are prepared by reacting compounds according to formula II ##STR2## with hydrogen peroxide in the presence of (a) tungstic acid or its metal salts, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst.
摘要翻译：具有下式的化合物其中X选自O，（CH 2）m O，S，（CH 2）m S，NH，（CH 2）m NH，COO-，（CH 2）m COO-， - OOC和-OOC（CH 2）m; m为1〜6; n为1〜100; R1选自H，（C1-C20）烷基，（C1-C20）烷氧基和（C1-C20）酯; （a）钨酸或其金属盐的存在下，通过使根据式II的化合物与过氧化氢反应制备A是选自多元醇，多硫醇，多胺和多元酸的残基的饱和有机连接基团，（b）磷酸或其金属盐，以及（c）至少一种相转移催化剂。

9. 发明授权

US5763629A Alkoxylated glycidyl (meth)acrylates and method of preparation 失效
标题翻译：（甲基）丙烯酸缩水甘油酯及其制备方法
公开(公告)号：US5763629A
公开(公告)日：1998-06-09
申请号：US772979
申请日：1996-12-23
申请人： Mingxin Fan , Gary W. Ceska , James Horgan , Thomas W. Hazell
发明人： Mingxin Fan , Gary W. Ceska , James Horgan , Thomas W. Hazell
IPC分类号： C07D303/16 , C08F20/32 , C08G65/14 , C08L71/02 , C07D301/12
CPC分类号： C08G65/14 , C07D303/16 , C08F20/32 , C08L71/02
摘要： Compounds of the formula ##STR1## wherein R.sub.1 32 H, CH.sub.3 ; R.sub.2 =H, (C.sub.1 -C.sub.6)alkyl; and x=1-20; and process for preparing such compounds by reacting a compound of the formula ##STR2## with hydrogen peroxide in the presence of (a) tungstic acid or its metal salts, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst.
摘要翻译：式（I）的化合物其中R 13 2 H，CH 3; R2 = H，（C1-C6）烷基; 和x = 1-20; 和（a）钨酸或其金属盐，（b）磷酸或其金属盐的存在下，使式（II）化合物与过氧化氢反应制备此类化合物的方法，和（c）至少一种相转移催化剂。

10. 发明授权

US06391463B1 Silicon-containing alkoxylated (meth)acrylate monomers 失效
标题翻译：含硅烷氧基化（甲基）丙烯酸酯单体
公开(公告)号：US06391463B1
公开(公告)日：2002-05-21
申请号：US08772980
申请日：1996-12-23
申请人： Mingxin Fan , Gary W. Ceska , James Horgan , Thomas Hazell
发明人： Mingxin Fan , Gary W. Ceska , James Horgan , Thomas Hazell
IPC分类号： C08F3008
CPC分类号： C08F30/08 , C07F7/081 , C07F7/12 , C07F7/1804 , C09D4/00 , Y10T428/31663 , C08F230/08
摘要： Compounds of the formula wherein R1=H, CH3 R2=H, CH3, CH2CH3, or CH2CH2CH3 n=1-10 X=halogen, (C1-C6) alkyl, (C1-C6) alkoxy, or aromatic radical are shown to be useful as coupling agents or adhesion promotors in free radically curable compositions such as UV curable and peroxide curable (meth)acrylate based coating compositions. The associated methods, curable compositions, coatings, adhesives and coated articles are also disclosed.
摘要翻译：化合物R1 = H，CH3R2 = H，CH3，CH2CH3或CH2CH2CH3n = 1-10X =卤素，（C1-C6）烷基，（C1-C6）烷氧基或芳族基团可用作偶联剂或可自由基固化组合物中的粘合促进剂，例如UV可固化和可过氧化物固化的（甲基）丙烯酸酯基涂料组合物。还公开了相关方法，可固化组合物，涂料，粘合剂和涂覆制品。

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