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1. 发明授权

US5834078A Hydroxy-functionalized poly(amino ether) salts 失效
标题翻译：羟基官能化聚（氨基醚）盐
公开(公告)号：US5834078A
公开(公告)日：1998-11-10
申请号：US916976
申请日：1997-08-14
申请人： Michael B. Cavitt , Jerry E. White , John M. Beckerdite , H. Craig Silvis
发明人： Michael B. Cavitt , Jerry E. White , John M. Beckerdite , H. Craig Silvis
IPC分类号： C08G59/50 , C08G73/02 , B29D22/00 , C08F6/00 , C08K3/02
CPC分类号： C08G59/50 , C08G73/024 , Y10T428/1341 , Y10T428/1352 , Y10T428/1355 , Y10T428/249953 , Y10T428/31786
摘要： Poly(hydroxyaminoether) ammonium salts are prepared by contacting a poly(hydroxy amino ether) with a protonic acid or an alkyl halide in an amount and under reaction conditions sufficient to form a poly(hydroxy amino ether) ammonium salt having an oxygen transmission rate of less than about 0.5 cm.sup.3 -mil/100 in.sup.2 -atm(O.sub.2)-day.
摘要翻译：聚（羟基氨基醚）铵盐通过使聚（羟基氨基醚）与质子酸或烷基卤化物接触，其量和反应条件足以形成具有氧传递速率的聚（羟基氨基醚）铵盐小于约0.5cm 3密耳/ 100in 2 atm（O 2） - 天。

2. 发明授权

US5686551A Hydroxy ether polymers as thermoplastic barrier resins 失效
标题翻译：羟基醚聚合物作为热塑性阻隔树脂
公开(公告)号：US5686551A
公开(公告)日：1997-11-11
申请号：US179029
申请日：1994-01-07
申请人： Jerry E. White , H. Craig Silvis , Michael N. Mang , Shari L. Kram , Robert E. Hefner, Jr.
发明人： Jerry E. White , H. Craig Silvis , Michael N. Mang , Shari L. Kram , Robert E. Hefner, Jr.
IPC分类号： C08G59/14 , C08G59/24 , C08G59/42 , C08G59/44 , C08G59/50 , C08G59/62 , C08G59/66 , C08G59/10 , C08G59/20 , C08G65/14
CPC分类号： C08G59/66 , C08G59/1433 , C08G59/245 , C08G59/42 , C08G59/444 , C08G59/50 , C08G59/621
摘要： Thermoplastic hydroxy ether polymers containing inertly substituted or unsubstituted stilbene and ether linkages in the backbone chain and pendant hydroxyl moieties are prepared by reacting (a) an inertly substituted or unsubstituted dihydroxy-stilbene with (b) a diglycidyl ether and, optionally, (c) a difunctional monomer under conditions sufficient to cause the hydroxyl moieties to react with the epoxy moieties to form ether linkages and pendant hydroxyl moieties. The polymers exhibit excellent oxygen barrier properties and are useful in packaging oxygen-sensitive materials.
摘要翻译：通过使（a）惰性取代或未取代的二羟基 - 二苯乙烯与（b）二缩水甘油醚和任选地（c）的二缩水甘油醚反应，制备在主链和侧羟基部分含惰性取代或未取代的二苯乙烯和醚键的热塑性羟基醚聚合物，双官能单体在足以使羟基部分与环氧部分反应以形成醚键和侧羟基部分的条件下进行。聚合物表现出优异的氧气阻隔性能，并且可用于包装氧敏感材料。

3. 发明授权

US4647648A Polyhydroxyethers from hydroxybiphenyls 失效
标题翻译：来自羟基联苯的聚羟基醚
公开(公告)号：US4647648A
公开(公告)日：1987-03-03
申请号：US768988
申请日：1985-08-26
申请人： H. Craig Silvis , Jody R. Berman , Jerry E. White
发明人： H. Craig Silvis , Jody R. Berman , Jerry E. White
IPC分类号： C08G59/30 , C08G59/62 , C08G65/28 , C08G65/34 , C08G59/02
CPC分类号： C08G59/621 , C08G59/30
摘要： Polyhydroxyethers formed by reacting a diglycidyl ether of biphenol, such as diglycidyl ethers of bisphenol-A, and a dihydroxybiphenyl, such as dihydroxybiphenyl, tetramethyldihydroxybiphenyl, and tetrabromotetramethyldihydroxybiphenyl, exhibit high heat distortion temperatures. These compositions could find utility in extruded films, packaging and coatings.
摘要翻译：通过双酚A的二缩水甘油醚与双酚A的二缩水甘油醚和二羟基联苯如二羟基联苯，四甲基二羟基联苯和四溴四甲基二羟基联苯反应形成的多羟基醚表现出高的热变形温度。这些组合物可用于挤出薄膜，包装和涂料。

4. 发明授权

US5814373A Heat-resistant hydroxy-functional polyethers as thermoplastic barrier resins 失效
标题翻译：耐热羟基官能聚醚作为热塑性阻隔树脂
公开(公告)号：US5814373A
公开(公告)日：1998-09-29
申请号：US131110
申请日：1993-10-01
申请人： Jerry E. White , H. Craig Silvis , Stephen E. Bales , Michael N. Mang , Muthiah N. Inbasekaran
发明人： Jerry E. White , H. Craig Silvis , Stephen E. Bales , Michael N. Mang , Muthiah N. Inbasekaran
IPC分类号： C08G59/06 , C08G59/62 , C08L71/00 , B65B55/00
CPC分类号： C08G59/066 , C08G59/621 , C08L71/00 , Y10T428/1307 , Y10T428/1341 , Y10T428/1379 , Y10T428/1383
摘要： Hydroxy-functional polyethers having a "cardo" diphenylene group in their backbones are prepared by contacting at least one dinucleophilic monomer with at least one diglycidyl ether of a cardo bisphenol, such as bis(hydroxyphenyl)fluorene, phenolphthalein, or phenolphthalimidine or a substituted cardo bisphenol, such as a substituted bis(hydroxyphenyl)fluorene, a substituted phenolphthalein or a substituted phenolphthalimidine, under conditions sufficient to cause the nucleophilic moieties of the dinucleophilic monomer to react with epoxy moieties to form a polymer backbone containing pendant hydroxy moieties and ether, imino, amino, sulfonamido or ester linkages. These polyethers possess a combination of high barrier to oxygen transmission (i.e., oxygen transmission rate less than 10.0 cm.sup.3 -mil/100 in.sup.2 -atm-day to oxygen) and high heat resistance (i.e., Tg above 120.degree. C.). These polyethers are suitable for use in the manufacture of retort-sterilizable packaging materials exhibiting high barrier to oxygen.
摘要翻译：在其主链中具有“cardo”二亚苯基的羟基官能聚醚通过使至少一种亲核性单体与双酚（如双（羟基苯基）芴，酚酞或苯酚苯并咪唑或取代的cardo双酚的至少一种二缩水甘油醚双酚，例如取代的双（羟基苯基）芴，取代的酚酞或取代的苯酚苯酞，在足以使亲核单体的亲核部分与环氧部分反应形成含有侧羟基部分和醚的聚合物主链的条件下，亚氨基，氨基，亚磺酰氨基或酯键。这些聚醚具有高的透氧阻隔性（氧气透过率低于氧气的氧气渗透速度小于10.0立方厘米/ 100英寸/天）和高耐热性（即高于120℃的Tg）。这些聚醚适用于制造显示出高阻隔氧的蒸煮灭菌包装材料。

5. 发明授权

US5731094A Hydroxy-phenoxyether polyester coextruded laminates 失效
标题翻译：羟基 - 苯氧基醚聚酯共挤出层压板
公开(公告)号：US5731094A
公开(公告)日：1998-03-24
申请号：US735284
申请日：1996-10-22
申请人： David J. Brennan , Jerry E. White , Mark A. Barger , H. Craig Silvis
发明人： David J. Brennan , Jerry E. White , Mark A. Barger , H. Craig Silvis
IPC分类号： B32B27/00 , B32B27/08 , B32B27/34 , B32B27/36 , C08G65/42
CPC分类号： B32B27/36 , B32B27/34 , Y10T428/31725 , Y10T428/31739 , Y10T428/31786
摘要： A laminate structure comprises one or more layers of a polyester and one or more layers of a hydroxy-phenoxyether polymer. The laminate structure can be prepared by coextruding one or more layers of a polyester and one or more layers of a hydroxy-phenoxyether polymer. The laminate structure can be fabricated into articles using conventional fabrication techniques such as compression molding, injection molding, blow molding, extrusion, solvent casting, calendering and thermoforming.
摘要翻译：层压结构包括一层或多层聚酯和一层或多层羟基 - 苯氧基醚聚合物。层压结构可以通过共挤出一层或多层聚酯和一层或多层羟基 - 苯氧基醚聚合物来制备。层压结构可以使用常规的制造技术如压塑，注塑，吹塑，挤出，溶剂浇铸，压延和热成型制成制品。

6. 发明授权

US6051294A Heat-resistant hydroxy-functional polyethers as thermoplastic barrier resins 失效
标题翻译：耐热羟基官能聚醚作为热塑性阻隔树脂
公开(公告)号：US6051294A
公开(公告)日：2000-04-18
申请号：US21058
申请日：1998-02-09
申请人： Jerry E. White , H. Craig Silvis , Stephen E. Bales , Michael N. Mang , Muthiah N. Inbasekaran
发明人： Jerry E. White , H. Craig Silvis , Stephen E. Bales , Michael N. Mang , Muthiah N. Inbasekaran
IPC分类号： C08L71/00 , B65B55/00
CPC分类号： C08L71/00 , Y10T428/1352
摘要： Hydroxy-functional polyethers having a "cardo" diphenylene group in their backbones are prepared by contacting at least one dinucleophilic monomer with at least one dtglycidyl ether of a cardo bisphenol, such as bis(hydroxyphenyl)fluorene, phenolphthalein, or phenolphthalimidine or a substituted cardo bisphenol, such as a substituted bis(hydroxyphenyl)fluorene, a substituted phenolphthalein or a substituted phenolphthalimidine, under conditions sufficient to cause the nucleophillo moieties of the dinucleophilic monomer to react with epoxy moieties to form a polymer backbone containing pendant hydroxy moieties and ether, imino, amino, sulfonamido or ester linkages. These polyethers possess a combination of high barrier to oxygen transmission (i.e., oxygen transmission rate less than 10.0 cm.sup.3 -mil/100 in.sup.2 -atm-day to oxygen) and high heat resistance (i.e., Tg above 120.degree. C.). These polyethers are suitable for use in the manufacture of retort-sterilizable packaging materials exhibiting high barrier to oxygen.
摘要翻译：在其主链中具有“cardo”二亚苯基的羟基官能的聚醚通过使至少一种双亲性单体与双酚（如双（羟基苯基）芴，酚酞或苯酚苯并咪唑或取代的cardo双酚的至少一种dt缩水甘油醚双酚，例如取代的双（羟基苯基）芴，取代的酚酞或取代的苯酚苯酞，在足以使双亲单体的亲核部分与环氧部分反应形成含有侧羟基部分和醚的聚合物主链的条件下，亚氨基，氨基，亚磺酰氨基或酯键。这些聚醚具有高的透氧阻隔性（氧气透过率低于氧气的氧气渗透速度小于10.0立方厘米/ 100英寸/天）和高耐热性（即高于120℃的Tg）。这些聚醚适用于制造显示出高阻隔氧的蒸煮灭菌包装材料。

7. 发明授权

US5275853A Hydroxyl functionalized polyetheramines as barrier packaging for oxygen-sensitive materials 失效
标题翻译：羟基官能化聚醚胺作为氧敏感材料的屏障包装
公开(公告)号：US5275853A
公开(公告)日：1994-01-04
申请号：US864975
申请日：1992-04-07
申请人： H. Craig Silvis , Jerry E. White
发明人： H. Craig Silvis , Jerry E. White
IPC分类号： C08G59/50 , C08G59/64 , C08G73/02 , C08G73/06 , B65D25/00 , B32B27/08 , C08G59/40 , C08G59/62
CPC分类号： C08G59/64 , C08G59/50 , C08G73/024 , Y10T428/1341 , Y10T428/1379 , Y10T428/1383 , Y10T428/31507 , Y10T428/31511 , Y10T428/31786 , Y10T428/31913 , Y10T428/31938
摘要： Polyetheramines having improved barrier to oxygen are thermoplastic polymers having aromatic ether/amine repeating units in their backbones and pendant hydroxyl moieties. Such polyetheramines are prepared by reacting diglycidyl ethers of dihydric aromatic compounds such as the diglycidyl ether of bisphenol-A, hydroquinone, or resorcinol with amines having no more than two amine hydrogens per molecule, such as piperazine or ethanolamine.
摘要翻译：具有改善的氧阻隔性的聚醚胺是在其主链和侧羟基部分具有芳族醚/胺重复单元的热塑性聚合物。这样的聚醚胺通过二元芳族化合物的二缩水甘油醚如双酚A的二缩水甘油醚，氢醌或间苯二酚与每分子不超过两个胺氢的胺如哌嗪或乙醇胺反应来制备。

8. 发明授权

US5780582A Hydroxy-functionalized polyester and poly(ester ether) oligomers 失效
标题翻译：羟基官能化聚酯和聚（酯醚）低聚物
公开(公告)号：US5780582A
公开(公告)日：1998-07-14
申请号：US775657
申请日：1996-12-31
申请人： David S. Wang , Michael N. Mang , Jerry E. White , John M. Beckerdite
发明人： David S. Wang , Michael N. Mang , Jerry E. White , John M. Beckerdite
IPC分类号： C08L1/00 , C08G59/42 , C08G59/62 , C08G63/60 , C08G63/66 , C08G63/672 , C08L3/00 , C08L5/00 , C08L67/02 , C08G59/00
CPC分类号： C08G63/60 , C08G59/4207 , C08G59/625 , C08G63/66
摘要： Hydroxy-functional polyester oligomers are prepared by contacting a hydroxy-functional aliphatic dicarboxylic acid or a mixture of dicarboxylic acids containing hydroxy-functional aliphatic diacids, with a diglycidyl ether or diglycidyl ester in the presence of an onium catalyst in an ether solvent under conditions suitable for forming the oligomer. The oligomers can be used as hot melt adhesives, adhesive tackifiers, plasticizers, heat-curable adhesives and heat-curable coatings. Some of these materials are biodegradable and are therefore suitable for application to compostable end products.
摘要翻译：羟基官能的聚酯低聚物是通过使羟基官能的脂族二羧酸或含有羟基官能的脂族二酸的二羧酸的混合物与二缩水甘油醚或二缩水甘油酯在鎓催化剂存在下在醚溶剂中在适合的条件下接触来制备的用于形成低聚物。低聚物可用作热熔粘合剂，粘合剂增粘剂，增塑剂，热固化粘合剂和热固化涂料。这些材料中的一些是可生物降解的，因此适用于可堆肥的最终产品。

9. 发明授权

US06589621B1 Thermally stable polyetheramines 失效
标题翻译：热稳定的聚醚胺
公开(公告)号：US06589621B1
公开(公告)日：2003-07-08
申请号：US09108620
申请日：1998-07-01
申请人： John M. Beckerdite , Terry W. Glass , Joe F. Sanford , David S. Wang , Jerry E. White , Peter T. Keillor, III , Thomas E. Moseman
发明人： John M. Beckerdite , Terry W. Glass , Joe F. Sanford , David S. Wang , Jerry E. White , Peter T. Keillor, III , Thomas E. Moseman
IPC分类号： B29D2200
CPC分类号： C08G73/024 , C08G59/64 , Y10T428/1352 , Y10T428/1397
摘要： Compositions comprising a blend of an inorganic base, an organic base, a monofunctional organic nucleophile or a multifunctional organic nucleophile and a thermoplastic hydroxy-functionalized polyetheramine can be formed into films and laminate structures by using conventional extrusion techniques. Containers and other molded parts can be fabricated from the films or laminate structures by using conventional fabricating techniques for thermoplastic polymers such as compression molding, injection molding, extrusion, thermoforming, blow molding and solvent casting.
摘要翻译：通过使用常规挤出技术，可以将包含无机碱，有机碱，单官能有机亲核试剂或多官能有机亲核试剂和热塑性羟基官能化聚醚胺的混合物的组合物形成为膜和层压结构。通过使用常规的热塑性聚合物的制造技术，例如压塑，注射成型，挤出，热成型，吹塑和溶剂浇铸，可以通过膜或层压结构来制造容器和其它模塑部件。

10. 发明授权

US5962621A Process for preparing hydroxy-functionalized polyesters 失效
标题翻译：羟基官能化聚酯的制备方法
公开(公告)号：US5962621A
公开(公告)日：1999-10-05
申请号：US69015
申请日：1998-04-28
申请人： John M. Beckerdite , Shari L. Kram , Ramki Subramania , Jerry E. White , Michael N. Mang
发明人： John M. Beckerdite , Shari L. Kram , Ramki Subramania , Jerry E. White , Michael N. Mang
IPC分类号： C08G63/42 , C08G63/00
CPC分类号： C08G63/42
摘要： A process for preparing a thermoplastic hydroxy-functionalized polyester comprises contacting a dicarboxylic acid or a mixture of dicarboxylic acids with a diepoxide in a given solvent in the presence of an end-capping agent and a catalyst under conditions sufficient to form the hydroxy-functionalized polyesters or polyethers.
摘要翻译：制备热塑性羟基官能化聚酯的方法包括使二羧酸或二羧酸的混合物在给定的溶剂中，在封端剂和催化剂存在下，在足以形成羟基官能化聚酯的条件下，或聚醚。

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