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1. 发明授权

US5731094A Hydroxy-phenoxyether polyester coextruded laminates 失效
标题翻译：羟基 - 苯氧基醚聚酯共挤出层压板
公开(公告)号：US5731094A
公开(公告)日：1998-03-24
申请号：US735284
申请日：1996-10-22
申请人： David J. Brennan , Jerry E. White , Mark A. Barger , H. Craig Silvis
发明人： David J. Brennan , Jerry E. White , Mark A. Barger , H. Craig Silvis
IPC分类号： B32B27/00 , B32B27/08 , B32B27/34 , B32B27/36 , C08G65/42
CPC分类号： B32B27/36 , B32B27/34 , Y10T428/31725 , Y10T428/31739 , Y10T428/31786
摘要： A laminate structure comprises one or more layers of a polyester and one or more layers of a hydroxy-phenoxyether polymer. The laminate structure can be prepared by coextruding one or more layers of a polyester and one or more layers of a hydroxy-phenoxyether polymer. The laminate structure can be fabricated into articles using conventional fabrication techniques such as compression molding, injection molding, blow molding, extrusion, solvent casting, calendering and thermoforming.
摘要翻译：层压结构包括一层或多层聚酯和一层或多层羟基 - 苯氧基醚聚合物。层压结构可以通过共挤出一层或多层聚酯和一层或多层羟基 - 苯氧基醚聚合物来制备。层压结构可以使用常规的制造技术如压塑，注塑，吹塑，挤出，溶剂浇铸，压延和热成型制成制品。

2. 发明授权

US5814373A Heat-resistant hydroxy-functional polyethers as thermoplastic barrier resins 失效
标题翻译：耐热羟基官能聚醚作为热塑性阻隔树脂
公开(公告)号：US5814373A
公开(公告)日：1998-09-29
申请号：US131110
申请日：1993-10-01
申请人： Jerry E. White , H. Craig Silvis , Stephen E. Bales , Michael N. Mang , Muthiah N. Inbasekaran
发明人： Jerry E. White , H. Craig Silvis , Stephen E. Bales , Michael N. Mang , Muthiah N. Inbasekaran
IPC分类号： C08G59/06 , C08G59/62 , C08L71/00 , B65B55/00
CPC分类号： C08G59/066 , C08G59/621 , C08L71/00 , Y10T428/1307 , Y10T428/1341 , Y10T428/1379 , Y10T428/1383
摘要： Hydroxy-functional polyethers having a "cardo" diphenylene group in their backbones are prepared by contacting at least one dinucleophilic monomer with at least one diglycidyl ether of a cardo bisphenol, such as bis(hydroxyphenyl)fluorene, phenolphthalein, or phenolphthalimidine or a substituted cardo bisphenol, such as a substituted bis(hydroxyphenyl)fluorene, a substituted phenolphthalein or a substituted phenolphthalimidine, under conditions sufficient to cause the nucleophilic moieties of the dinucleophilic monomer to react with epoxy moieties to form a polymer backbone containing pendant hydroxy moieties and ether, imino, amino, sulfonamido or ester linkages. These polyethers possess a combination of high barrier to oxygen transmission (i.e., oxygen transmission rate less than 10.0 cm.sup.3 -mil/100 in.sup.2 -atm-day to oxygen) and high heat resistance (i.e., Tg above 120.degree. C.). These polyethers are suitable for use in the manufacture of retort-sterilizable packaging materials exhibiting high barrier to oxygen.
摘要翻译：在其主链中具有“cardo”二亚苯基的羟基官能聚醚通过使至少一种亲核性单体与双酚（如双（羟基苯基）芴，酚酞或苯酚苯并咪唑或取代的cardo双酚的至少一种二缩水甘油醚双酚，例如取代的双（羟基苯基）芴，取代的酚酞或取代的苯酚苯酞，在足以使亲核单体的亲核部分与环氧部分反应形成含有侧羟基部分和醚的聚合物主链的条件下，亚氨基，氨基，亚磺酰氨基或酯键。这些聚醚具有高的透氧阻隔性（氧气透过率低于氧气的氧气渗透速度小于10.0立方厘米/ 100英寸/天）和高耐热性（即高于120℃的Tg）。这些聚醚适用于制造显示出高阻隔氧的蒸煮灭菌包装材料。

3. 发明授权

US6051294A Heat-resistant hydroxy-functional polyethers as thermoplastic barrier resins 失效
标题翻译：耐热羟基官能聚醚作为热塑性阻隔树脂
公开(公告)号：US6051294A
公开(公告)日：2000-04-18
申请号：US21058
申请日：1998-02-09
申请人： Jerry E. White , H. Craig Silvis , Stephen E. Bales , Michael N. Mang , Muthiah N. Inbasekaran
发明人： Jerry E. White , H. Craig Silvis , Stephen E. Bales , Michael N. Mang , Muthiah N. Inbasekaran
IPC分类号： C08L71/00 , B65B55/00
CPC分类号： C08L71/00 , Y10T428/1352
摘要： Hydroxy-functional polyethers having a "cardo" diphenylene group in their backbones are prepared by contacting at least one dinucleophilic monomer with at least one dtglycidyl ether of a cardo bisphenol, such as bis(hydroxyphenyl)fluorene, phenolphthalein, or phenolphthalimidine or a substituted cardo bisphenol, such as a substituted bis(hydroxyphenyl)fluorene, a substituted phenolphthalein or a substituted phenolphthalimidine, under conditions sufficient to cause the nucleophillo moieties of the dinucleophilic monomer to react with epoxy moieties to form a polymer backbone containing pendant hydroxy moieties and ether, imino, amino, sulfonamido or ester linkages. These polyethers possess a combination of high barrier to oxygen transmission (i.e., oxygen transmission rate less than 10.0 cm.sup.3 -mil/100 in.sup.2 -atm-day to oxygen) and high heat resistance (i.e., Tg above 120.degree. C.). These polyethers are suitable for use in the manufacture of retort-sterilizable packaging materials exhibiting high barrier to oxygen.
摘要翻译：在其主链中具有“cardo”二亚苯基的羟基官能的聚醚通过使至少一种双亲性单体与双酚（如双（羟基苯基）芴，酚酞或苯酚苯并咪唑或取代的cardo双酚的至少一种dt缩水甘油醚双酚，例如取代的双（羟基苯基）芴，取代的酚酞或取代的苯酚苯酞，在足以使双亲单体的亲核部分与环氧部分反应形成含有侧羟基部分和醚的聚合物主链的条件下，亚氨基，氨基，亚磺酰氨基或酯键。这些聚醚具有高的透氧阻隔性（氧气透过率低于氧气的氧气渗透速度小于10.0立方厘米/ 100英寸/天）和高耐热性（即高于120℃的Tg）。这些聚醚适用于制造显示出高阻隔氧的蒸煮灭菌包装材料。

4. 发明授权

US5834078A Hydroxy-functionalized poly(amino ether) salts 失效
标题翻译：羟基官能化聚（氨基醚）盐
公开(公告)号：US5834078A
公开(公告)日：1998-11-10
申请号：US916976
申请日：1997-08-14
申请人： Michael B. Cavitt , Jerry E. White , John M. Beckerdite , H. Craig Silvis
发明人： Michael B. Cavitt , Jerry E. White , John M. Beckerdite , H. Craig Silvis
IPC分类号： C08G59/50 , C08G73/02 , B29D22/00 , C08F6/00 , C08K3/02
CPC分类号： C08G59/50 , C08G73/024 , Y10T428/1341 , Y10T428/1352 , Y10T428/1355 , Y10T428/249953 , Y10T428/31786
摘要： Poly(hydroxyaminoether) ammonium salts are prepared by contacting a poly(hydroxy amino ether) with a protonic acid or an alkyl halide in an amount and under reaction conditions sufficient to form a poly(hydroxy amino ether) ammonium salt having an oxygen transmission rate of less than about 0.5 cm.sup.3 -mil/100 in.sup.2 -atm(O.sub.2)-day.
摘要翻译：聚（羟基氨基醚）铵盐通过使聚（羟基氨基醚）与质子酸或烷基卤化物接触，其量和反应条件足以形成具有氧传递速率的聚（羟基氨基醚）铵盐小于约0.5cm 3密耳/ 100in 2 atm（O 2） - 天。

5. 发明授权

US5275853A Hydroxyl functionalized polyetheramines as barrier packaging for oxygen-sensitive materials 失效
标题翻译：羟基官能化聚醚胺作为氧敏感材料的屏障包装
公开(公告)号：US5275853A
公开(公告)日：1994-01-04
申请号：US864975
申请日：1992-04-07
申请人： H. Craig Silvis , Jerry E. White
发明人： H. Craig Silvis , Jerry E. White
IPC分类号： C08G59/50 , C08G59/64 , C08G73/02 , C08G73/06 , B65D25/00 , B32B27/08 , C08G59/40 , C08G59/62
CPC分类号： C08G59/64 , C08G59/50 , C08G73/024 , Y10T428/1341 , Y10T428/1379 , Y10T428/1383 , Y10T428/31507 , Y10T428/31511 , Y10T428/31786 , Y10T428/31913 , Y10T428/31938
摘要： Polyetheramines having improved barrier to oxygen are thermoplastic polymers having aromatic ether/amine repeating units in their backbones and pendant hydroxyl moieties. Such polyetheramines are prepared by reacting diglycidyl ethers of dihydric aromatic compounds such as the diglycidyl ether of bisphenol-A, hydroquinone, or resorcinol with amines having no more than two amine hydrogens per molecule, such as piperazine or ethanolamine.
摘要翻译：具有改善的氧阻隔性的聚醚胺是在其主链和侧羟基部分具有芳族醚/胺重复单元的热塑性聚合物。这样的聚醚胺通过二元芳族化合物的二缩水甘油醚如双酚A的二缩水甘油醚，氢醌或间苯二酚与每分子不超过两个胺氢的胺如哌嗪或乙醇胺反应来制备。

6. 发明授权

US5686551A Hydroxy ether polymers as thermoplastic barrier resins 失效
标题翻译：羟基醚聚合物作为热塑性阻隔树脂
公开(公告)号：US5686551A
公开(公告)日：1997-11-11
申请号：US179029
申请日：1994-01-07
申请人： Jerry E. White , H. Craig Silvis , Michael N. Mang , Shari L. Kram , Robert E. Hefner, Jr.
发明人： Jerry E. White , H. Craig Silvis , Michael N. Mang , Shari L. Kram , Robert E. Hefner, Jr.
IPC分类号： C08G59/14 , C08G59/24 , C08G59/42 , C08G59/44 , C08G59/50 , C08G59/62 , C08G59/66 , C08G59/10 , C08G59/20 , C08G65/14
CPC分类号： C08G59/66 , C08G59/1433 , C08G59/245 , C08G59/42 , C08G59/444 , C08G59/50 , C08G59/621
摘要： Thermoplastic hydroxy ether polymers containing inertly substituted or unsubstituted stilbene and ether linkages in the backbone chain and pendant hydroxyl moieties are prepared by reacting (a) an inertly substituted or unsubstituted dihydroxy-stilbene with (b) a diglycidyl ether and, optionally, (c) a difunctional monomer under conditions sufficient to cause the hydroxyl moieties to react with the epoxy moieties to form ether linkages and pendant hydroxyl moieties. The polymers exhibit excellent oxygen barrier properties and are useful in packaging oxygen-sensitive materials.
摘要翻译：通过使（a）惰性取代或未取代的二羟基 - 二苯乙烯与（b）二缩水甘油醚和任选地（c）的二缩水甘油醚反应，制备在主链和侧羟基部分含惰性取代或未取代的二苯乙烯和醚键的热塑性羟基醚聚合物，双官能单体在足以使羟基部分与环氧部分反应以形成醚键和侧羟基部分的条件下进行。聚合物表现出优异的氧气阻隔性能，并且可用于包装氧敏感材料。

7. 发明授权

US4647648A Polyhydroxyethers from hydroxybiphenyls 失效
标题翻译：来自羟基联苯的聚羟基醚
公开(公告)号：US4647648A
公开(公告)日：1987-03-03
申请号：US768988
申请日：1985-08-26
申请人： H. Craig Silvis , Jody R. Berman , Jerry E. White
发明人： H. Craig Silvis , Jody R. Berman , Jerry E. White
IPC分类号： C08G59/30 , C08G59/62 , C08G65/28 , C08G65/34 , C08G59/02
CPC分类号： C08G59/621 , C08G59/30
摘要： Polyhydroxyethers formed by reacting a diglycidyl ether of biphenol, such as diglycidyl ethers of bisphenol-A, and a dihydroxybiphenyl, such as dihydroxybiphenyl, tetramethyldihydroxybiphenyl, and tetrabromotetramethyldihydroxybiphenyl, exhibit high heat distortion temperatures. These compositions could find utility in extruded films, packaging and coatings.
摘要翻译：通过双酚A的二缩水甘油醚与双酚A的二缩水甘油醚和二羟基联苯如二羟基联苯，四甲基二羟基联苯和四溴四甲基二羟基联苯反应形成的多羟基醚表现出高的热变形温度。这些组合物可用于挤出薄膜，包装和涂料。

8. 发明授权

US08288470B2 Polyolefin compositions and articles prepared therefrom, and methods for making the same 有权
标题翻译：聚烯烃组合物及其制备的制品及其制备方法
公开(公告)号：US08288470B2
公开(公告)日：2012-10-16
申请号：US12520380
申请日：2007-12-21
申请人： Patricia Ansems , Ashish Batra , Laura Bauerle Weaver , Lawrence J. Effler , H. Craig Silvis , Hamed Lakrout , Laura K. Mergenhagen
发明人： Patricia Ansems , Ashish Batra , Laura Bauerle Weaver , Lawrence J. Effler , H. Craig Silvis , Hamed Lakrout , Laura K. Mergenhagen
IPC分类号： C08G63/48 , C08J3/22 , C08K3/34 , C08F8/00 , C08F32/00 , C08F132/00 , C08F232/00 , C08F8/32 , C08C19/22
CPC分类号： C08L51/06 , B32B27/08 , B32B27/32 , C08F8/32 , C08F10/00 , C08F255/00 , C08F255/02 , C08F287/00 , C08L23/36 , C08L51/00 , C08L51/003 , C08L51/006 , C08L53/00 , C08L75/04 , C08L2205/02 , C08L2666/02 , C08L2666/04 , C08L2666/06 , C08L2666/14 , C08L2666/20 , C08L2666/24
摘要： The invention provides a composition comprising at least one olefin multi-block interpolymer; at least one functionalized olefin-based polymer; and optionally at least one thermoplastic polyurethane. The invention also provides for articles prepared from the inventive compositions and for methods for making the same.
摘要翻译：本发明提供包含至少一种烯烃多嵌段互聚物的组合物; 至少一种官能化烯烃基聚合物; 和任选的至少一种热塑性聚氨酯。本发明还提供了由本发明组合物制备的制品及其制备方法。

9. 发明授权

US06777502B2 Rheology modification of polymers prepared using metallocenes 有权
标题翻译：使用金属茂制备的聚合物的流变改性
公开(公告)号：US06777502B2
公开(公告)日：2004-08-17
申请号：US10347713
申请日：2003-01-21
申请人： Thoi H. Ho , Wendy D. Hoenig , Che-l Kao , Michael E. Rowland , Clark H. Cummins , Michael J. Mullins , H. Craig Silvis
发明人： Thoi H. Ho , Wendy D. Hoenig , Che-l Kao , Michael E. Rowland , Clark H. Cummins , Michael J. Mullins , H. Craig Silvis
IPC分类号： C08C1900
CPC分类号： C08L23/02 , C08G81/02 , C08K5/43 , C08L23/04 , C08L23/06 , C08L23/08 , C08L23/0815 , C08L23/0838 , C08L23/0853 , C08L23/16 , C08L2205/22 , C08L2312/00 , C08L2314/06 , Y10T428/1334 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/31913 , Y10T428/31917 , C08L2666/04
摘要： Coupled polymers are prepared by a process comprising heating an admixture containing (1) at least one polyolefin comprising ethylene and optionally at least one comonomer and (2) a coupling amount at least one poly(sulfonyl azide) to at least the decomposition temperature of the poly(sulfonyl azide) for a period sufficient for decomposition of at least 80 weight percent of the poly(sulfonyl azide) and sufficient to result in a coupled polymer; particularly where the polyolefin is the product of polymerization of ethylene and optionally at least one other alpha-olefin in the presence of a single site catalyst.
摘要翻译：通过包括加热含有（1）至少一种包含乙烯和任选的至少一种共聚单体的聚烯烃和（2）偶联量的至少一种聚（磺酰基叠氮化物）的聚烯烃至少至少分解温度的混合物来制备偶联聚合物聚（磺酰基叠氮化物）足以分解至少80重量％的聚（磺酰基叠氮化物）并足以产生偶联聚合物的时间; 特别是当聚烯烃是在单一位点催化剂存在下乙烯和任选的至少一种其它α-烯烃聚合的产物时。

10. 发明授权

US06521306B1 Rheology modification of low density polyethylene 有权
标题翻译：低密度聚乙烯的流变改性
公开(公告)号：US06521306B1
公开(公告)日：2003-02-18
申请号：US09129163
申请日：1998-08-05
申请人： Wendy D. Hoenig , Teresa Karjala , Li-Min Tau , Clark H. Cummins , Michael J. Mullins , H. Craig Silvis , Thoi H. Ho
发明人： Wendy D. Hoenig , Teresa Karjala , Li-Min Tau , Clark H. Cummins , Michael J. Mullins , H. Craig Silvis , Thoi H. Ho
IPC分类号： B29D2200
CPC分类号： C08L23/02 , C08G81/02 , C08K5/43 , C08L23/04 , C08L23/06 , C08L23/08 , C08L23/0815 , C08L23/0838 , C08L23/0853 , C08L23/16 , C08L2205/22 , C08L2312/00 , C08L2314/06 , Y10T428/1334 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/31913 , Y10T428/31917 , C08L2666/04
摘要： The invention includes a process of preparing a coupled polymer characterized by heating an admixture containing (1) at least one ethylene polymer or blend of ethylene polymers having a density of at least about 0.89 g/mL and less than about 0.935 g/mL and a comonomer content between about 0.5 and 50 weight percent of an alpha olefin having greater than 2 and less than 20 carbon atoms per molecule and (2) a coupling amount of at least one poly(sulfonyl azide) to at least the decomposition temperature of the poly(sulfonyl azide) for a period sufficient for decomposition of at least about 80 weight percent of the poly(sulfonyl azide) and sufficient to result in a coupled polymer. The amount of poly(sulfonyl azide) is preferably from about 0.01 to about 5 weight percent of polymers in the admixture. The invention also includes any composition which is the product of any of the processes of the invention and articles made from those compositions, particularly any film of any composition of the invention. Additionally the invention includes a use of any composition of the invention in a process of blowing, casting or calendaring a film. More particularly the invention includes articles of compositions of the invention which are trash bags, agricultural films, construction films, or geomembranes, grocery sacks, sealant layers, tie layers, produce bags, garment bags, shipping sacks, medical films, stretch films, shrink films, agricultural films, greenhouse films, construction films, or stretch hooders.
摘要翻译：本发明包括一种制备偶联聚合物的方法，其特征在于加热含有（1）至少一种乙烯聚合物或密度为至少约0.89g / mL且小于约0.935g / mL的乙烯聚合物的共混物的混合物，共聚单体含量为约0.5至50重量％的每分子具有大于2个且小于20个碳原子的α-烯烃，和（2）至少一个聚（磺酰基叠氮化物）的偶联量至少达到聚（磺酰基叠氮化物）足以分解至少约80重量％的聚（磺酰基叠氮化物）并足够导致偶联聚合物的时间。聚（磺酰基叠氮化物）的量优选为混合物中约0.01至约5重量％的聚合物。本发明还包括任何组合物，其是本发明任何方法的产物和由这些组合物制成的制品，特别是本发明任何组合物的任何薄膜。此外，本发明包括在吹塑，浇铸或压延膜的方法中使用本发明的任何组合物。更具体地，本发明包括本发明的制品，其为垃圾袋，农用膜，建筑膜或土工膜，杂货袋，密封剂层，连接层，生产袋，服装袋，运输袋，医疗膜，拉伸膜，收缩电影，农膜，温室膜，建筑膜或拉伸罩。

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