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1. 发明授权

US06689733B1 Manganese complexes of salen ligands and the use thereof 失效
标题翻译：萨伦配体的锰配合物及其用途
公开(公告)号：US06689733B1
公开(公告)日：2004-02-10
申请号：US09914911
申请日：2001-09-05
申请人： Frank Bachmann , Rachel Allemann , Josef Dannacher , Marie-Josée Dubs , Cornelia Makowka , Grit Richter , Gunther Schlingloff , Peter Weingartner , Menno Hazenkamp
发明人： Frank Bachmann , Rachel Allemann , Josef Dannacher , Marie-Josée Dubs , Cornelia Makowka , Grit Richter , Gunther Schlingloff , Peter Weingartner , Menno Hazenkamp
IPC分类号： C11D320
CPC分类号： C07F13/005 , C07C251/24 , C07C2601/14 , C11D3/168 , C11D3/3932
摘要： The present invention relates to novel manganese complexes of salen ligands and the use thereof as catalysts that enhance the action of peroxy compounds in washing, cleaning, and disinfecting processes.
摘要翻译：本发明涉及新型的salen配体的锰络合物及其作为催化剂的用途，其可增强洗涤，清洗和消毒过程中过氧化合物的作用。

2. 发明授权

US06387863B1 Process for treating textile materials 失效
标题翻译：处理纺织材料的方法
公开(公告)号：US06387863B1
公开(公告)日：2002-05-14
申请号：US09914865
申请日：2001-09-04
申请人： Menno Hazenkamp , Frank Bachmann , Cornelia Makowka , Marie-Josée Dubs , Grit Richter , Gunther Schlingloff , Josef Dannacher , Peter Weingartner
发明人： Menno Hazenkamp , Frank Bachmann , Cornelia Makowka , Marie-Josée Dubs , Grit Richter , Gunther Schlingloff , Josef Dannacher , Peter Weingartner
IPC分类号： C11D732
CPC分类号： C11D3/0021 , C11D3/168 , C11D3/3932 , C11D3/3947
摘要： The inventions is drawn to mixtures of manganese complexes and organic ligands which significantly improve the bleaching effect of hydrogen peroxide in washing liquours and prevent the reabsorption of migrating dyes in peroxide-containing washing liquors.
摘要翻译：本发明涉及锰络合物和有机配体的混合物，其显着改善过氧化氢在洗涤液中的漂白效果，并防止迁移染料在含过氧化物的洗涤液中的再吸收。

3. 发明授权

US07692004B2 Use of metal complex compounds as oxidation catalysts 失效
标题翻译：使用金属络合物作为氧化催化剂
公开(公告)号：US07692004B2
公开(公告)日：2010-04-06
申请号：US12214491
申请日：2008-06-19
申请人： Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
发明人： Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
IPC分类号： C07F15/00 , C07F15/02 , C07F15/04 , C07F15/06
CPC分类号： B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要： Use of metal complex compounds of formula [LnMemXp]zYq (1), wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —SO2R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14R15 or —N⊕R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).
摘要翻译：使用式[LnMemXp] zYq（1）的金属络合物，其中Me是锰，钛，铁，钴，镍或铜，X是配位或桥连基团，n和m各自独立地为具有值为1〜8，p为0〜32的整数，z为金属络合物的电荷，Y为抗衡离子，q = z /（电荷Y），L为其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基 -COOR 12或-SO 3 R 12，其中R 12在各种情况下为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13，-SO 2 R 13或-OR 13，其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -N（R 13）-NR'13R“13其中R 13，R 13和R 13如对R 13所定义; -NR14R15或-N⊕R14R15R16，其中R14，R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基，或者R14和R15与其键合的氮原子一起形成未取代或取代的5 可以任选地含有其它杂原子的6-或7-元环; 条件是R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11不同时为氢，作为氧化反应的催化剂，并且式（1）和新颖的新型金属络合物式（2）的配体。

4. 发明授权

US07456285B2 Use of metal complex compounds as oxidation catalysts 失效
公开(公告)号：US07456285B2
公开(公告)日：2008-11-25
申请号：US11497444
申请日：2006-08-01
申请人： Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
发明人： Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
IPC分类号： C07F15/00
CPC分类号： B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要： Use of metal complex compounds of formula [LnMemXp]zYq, (1) wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11, are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —SO2R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14R15 or —N⊕R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).

5. 发明授权

US07161005B2 Use of metal complex compounds as oxidation catalysts 失效
公开(公告)号：US07161005B2
公开(公告)日：2007-01-09
申请号：US10476043
申请日：2002-04-25
申请人： Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
发明人： Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josef Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler (-Richter) , Brigitte Schmidt , Albert Schneider , Peter Weingartner
IPC分类号： C07F15/00
CPC分类号： B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要： Use of metal complex compounds of formula [LnMemXp]zYq (1) wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, y is a counter-ion, q=z/(charge Y), and L is a ligand of formula wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1–C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1–C18alkyl or aryl; —SR13, —OR13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1–C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14R15 or —N⊕R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1–C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).

6. 发明授权

US06486110B2 Fabric care method 失效
标题翻译：织物护理方法
公开(公告)号：US06486110B2
公开(公告)日：2002-11-26
申请号：US09835176
申请日：2001-04-13
申请人： Frank Bachmann , Josef Dannacher , Martin Studer , Beat Freiermuth , Cornelia Makowka , Peter Weingartner , Grit Richter , Gunther Schlingloff
发明人： Frank Bachmann , Josef Dannacher , Martin Studer , Beat Freiermuth , Cornelia Makowka , Peter Weingartner , Grit Richter , Gunther Schlingloff
IPC分类号： C11D326
CPC分类号： C07F13/005 , C07C251/24 , C11D3/0021 , C11D3/3932
摘要： The present invention provides a process for inhibiting the re-absorption of migrating dyes in the wash liquor, comprising introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150, preferably from 1.5 to 75, especially from 7.5 to 40 mg, per liter of wash liquor, of one or more compounds having the formula: in which n is 1, 2 or 3; A is an anion; Y is —(CH2)m in which m is an integer ranging from 1 to 8; —(CH2)p—CH(R1)— in which p is an integer ranging from 1 to 7 and R1 is linear or branched C1-C4-alkyl, preferably methyl; —CX═CX— in which X is cyano, linear or branched C1-C8-alkyl or di(linear or branched C1-C8-alkyl)-amino; —(CH2)q—NR1—(CH2)q— in which R1 has its previous significance and q is 1, 2, 3 or 4; or a 1,2-cyclohexylene residue having the formula: R is cyano; halogen; hydroxy; OR1 in which R1 has its previous significance; CO2R2 in which R2 is hydrogen or linear or branched C1-C4-alkyl; nitro; linear or branched C1-C8-alkyl; di-(C4-C12alkyl)amino; NR3R4 in which R3 and R4 are the same or different and each is linear or branched C1-C12-alkyl; or —N⊕R1R3R4 in which R1, R3 and R4 have their previous significance.
摘要翻译：本发明提供了一种抑制迁移染料在洗涤液中的再吸收的方法，包括将含有过氧化物的洗涤剂的洗涤液加入到0.5至150，优选1.5至75，特别是7.5至40mg 每升洗涤液中的一种或多种具有下式的化合物：其中n为1,2或3; A是阴离子; Y是 - （CH2）m，其中m是1到8的整数; - （CH 2）p -CH（R 1） - ，其中p是1至7的整数，R 1是直链或支链C 1 -C 4烷基，优选甲基; -CX = CX-，其中X是氰基，直链或支链C 1 -C 8 - 烷基或二（直链或支链C 1 -C 8 - 烷基） - 氨基; - （CH 2）q -NR 1 - （CH 2）q - 具有以前的意义，q为1,2,3或4; 或具有下式的1,2-亚环己基残基：R是氰基; 卤素; 羟基; OR1，其中R1具有其先前的意义; CO 2 R 2，其中R 2是氢或直链或支链C 1 -C 4 - 烷基; 硝基直链或支链C 1 -C 8 - 烷基;二 - （C 4 -C 12烷基）氨基; NR 3 R 4，其中R 3和R 4相同或不同，并且各自为直链或支链C 1 -C 12 - 烷基; 或其中R1，R3和R4具有其先前含义的-N⊕R1R3R4。

7. 发明授权

US06413926B2 Process for treating textile materials 失效
标题翻译：处理纺织材料的方法
公开(公告)号：US06413926B2
公开(公告)日：2002-07-02
申请号：US09835245
申请日：2001-04-13
申请人： Frank Bachmann , Josef Dannacher , Cornelia Makowka , Gunther Schlingloff , Peter Weingartner , Grit Richter
发明人： Frank Bachmann , Josef Dannacher , Cornelia Makowka , Gunther Schlingloff , Peter Weingartner , Grit Richter
IPC分类号： C11D726
CPC分类号： C07C251/24 , C07F13/005 , C11D3/0021 , C11D3/168 , C11D3/3932
摘要： A process for preventing the redeposition of migrant dyes in a washing liquor by adding to each liter of the washing liquor, which comprises a peroxide-containing detergent, from 0.5 to 150 mg of one or more asymmetric manganese complexes of the salen type.
摘要翻译：通过向每升含有过氧化物的洗涤剂的洗涤液中加入0.5至150mg一种或多种萨伦类型的不对称锰配合物来防止移动染料在洗涤液中再沉积的方法。

8. 发明授权

US06737391B2 Process for treating textile materials 失效
标题翻译：处理纺织材料的方法
公开(公告)号：US06737391B2
公开(公告)日：2004-05-18
申请号：US10140530
申请日：2002-05-07
申请人： Frank Bachmann , Josef Dannacher , Cornelia Makowka , Gunther Schlingloff , Peter Weingartner , Grit Richter
发明人： Frank Bachmann , Josef Dannacher , Cornelia Makowka , Gunther Schlingloff , Peter Weingartner , Grit Richter
IPC分类号： C11D183
CPC分类号： C07C251/24 , C07F13/005 , C11D3/0021 , C11D3/168 , C11D3/3932
摘要： A process for preventing the redeposition of migrant dyes in a washing liquor by adding to each liter of the washing liquor, which comprises a peroxide-containing detergent, from 0.5 to 150 mg of one or more asymmetric manganese complexes of the salen type.
摘要翻译：通过向每升含有过氧化物的洗涤剂的洗涤液中加入0.5至150mg一种或多种萨伦类型的不对称锰配合物来防止移动染料在洗涤液中再沉积的方法。

9. 发明授权

US06562775B2 Fabric care method 失效
标题翻译：织物护理方法
公开(公告)号：US06562775B2
公开(公告)日：2003-05-13
申请号：US10067001
申请日：2002-02-04
申请人： Frank Bachmann , Josef Dannacher , Martin Studer , Beat Freiermuth , Cornelia Makowka , Peter Weingartner , Grit Richter , Gunther Schlingloff
发明人： Frank Bachmann , Josef Dannacher , Martin Studer , Beat Freiermuth , Cornelia Makowka , Peter Weingartner , Grit Richter , Gunther Schlingloff
IPC分类号： C11D113
CPC分类号： C07F13/005 , C07C251/24 , C11D3/0021 , C11D3/3932
摘要： The present invention provides a process for inhibiting the re-absorption of migrating dyes in the wash liquor, comprising introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150 mg per liter of wash liquor, of one or more manganese containing compounds.
摘要翻译：本发明提供了一种抑制迁移染料在洗涤液中的再吸收的方法，包括将含有过氧化物的洗涤剂的洗涤液，每升洗涤液0.5至150mg，一种或多种含锰化合物。

10. 发明授权

US08044013B2 Use of metal complex compounds as oxidation catalysts 失效
标题翻译：使用金属络合物作为氧化催化剂
公开(公告)号：US08044013B2
公开(公告)日：2011-10-25
申请号：US12288382
申请日：2008-10-20
申请人： Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josée Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler-Richter , Brigitte Schmidt , Albert Schneider , Peter Weingartner
发明人： Gunther Schlingloff , Torsten Wieprecht , Frank Bachmann , Josée Dannacher , Marie-Josée Dubs , Menno Hazenkamp , Grit Hänsler-Richter , Brigitte Schmidt , Albert Schneider , Peter Weingartner
IPC分类号： C11D7/32 , C11D7/38 , C11D7/54 , B08B3/04
CPC分类号： B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要： The present invention relates to the use of metal complex compounds with terpyridine ligands as oxidation catalysts. The present invention relates also to formulations comprising such metal complex compounds, to novel metal complex compounds, and to novel ligands. The metal complex compounds are used especially tor improving the action of peroxides, for example in the treatment of textile material, without at the same time causing any appreciable damage to fibres and dyeings.
摘要翻译：本发明涉及金属络合物与三联吡啶配体作为氧化催化剂的用途。本发明还涉及包含这种金属络合物的制剂，新颖的金属络合物和新配体。金属络合物特别用于改善过氧化物的作用，例如在纺织材料的处理中，而不会同时对纤维和染色造成任何明显的损害。

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