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    • 1. 发明授权
    • Fungicidal N-substituted 3-arylpyrrolidine derivatives
    • 杀真菌剂N-取代的3-氨基吡啶衍生物
    • US5068245A
    • 1991-11-26
    • US251243
    • 1988-09-30
    • Matthias ZippliesHubert SauterFranz RoehlWalter HimmeleEberhard AmmermannErnst-Heinrich Pommer
    • Matthias ZippliesHubert SauterFranz RoehlWalter HimmeleEberhard AmmermannErnst-Heinrich Pommer
    • C07D207/06C07D207/08C07D405/04C07D405/08
    • C07D405/08C07D207/06C07D207/08
    • N-Substituted 3-arylpyrrolidine derivatives of the formula ##STR1## where R.sup.1 is 2,2-dimethylpropyl, 3,3-dimethylbutyl, 4,4-dimethylpentyl, 2,4,4-trimethylpentyl, 6-methylhept-2-yl, 3,5,5-trimethylhexyl, 6,10-dimethylundec-2-yl, 3-methylcyclohexyl, 3,3-dimethylcyclohexyl, 3,3,5-trimethylcyclohexyl, 3,3,5,5-tetramethylcyclohexyl, 4-methylcyclohexyl, 4-ethylcyclohexyl, 4-propylcyclohexyl, 4-isopropylcyclohexyl, 4-tert.-butylcyclohexyl, trans-4-tert.-butylcyclohexyl, 4(2-methylbut-2-yl)cyclohexyl, 4(2,4,4-trimethylpent-2-yl)-cyclohexyl, cyclododecanyl, C.sub.3 -C.sub.9 -trialkylsilyl-substituted C.sub.4 -C.sub.12 -cycloalkyl, 4-hydroxycyclohexyl, 4-hydroxy-3-methylcyclohexyl, 4-hydroxy-3,5-dimethylcyclohexyl, 4-hydroxy-3,3-dimethylcyclohexyl, 4-hydroxy-3,3,5-trimethylcyclohexyl, unsubstituted or hydroxy-, C.sub.1 -C.sub.9 -alkyl-, C.sub.1 -C.sub.5 -alkoxy- or C.sub.3 -C.sub.9 -trialkylsilyl-substituted C.sub.5 -C.sub.12 -cycloalkenyl,R.sup.1 is further bicycloalkyl,R.sup.1 is further 4-tert.-butyl-benzyl, 4-chlorobenzyl, 4-tert.-butoxybenzyl, 1,4-dioxaspiro[4,5]decan-8-yl,5 to 7-membered heterocycloalkyl,5 to 7-membered heterocycloalkylmethyl,R.sup.2 is alkyl, alkoxy or trialkylsilyl,R.sup.3 is alkyl, alkenyl, alkynyl or arylalkyl,X- is a plant-tolerated anion,n is 0 or 1,and plant-tolerated salts thereof, and fungicides containing these compounds.
    • 其中R 1是2,2-二甲基丙基,3,3-二甲基丁基,4,4-二甲基戊基,2,4,4-三甲基戊基,6-甲基庚-2-基, 3,5,5-三甲基己基,6,10-二甲基十一烷基-2-基,3-甲基环己基,3,3-二甲基环己基,3,3,5-三甲基环己基,3,3,5,5-四甲基环己基,4-甲基环己基, 4-乙基环己基,4-丙基环己基,4-异丙基环己基,4-叔丁基环己基,反式-4-叔丁基环己基,4(2-甲基丁-2-基)环己基,4(2,4,4-三甲基 - 2-环己基,环十二烷基,C 3 -C 9 - 三烷基甲硅烷基取代的C 4 -C 12环烷基,4-羟基环己基,4-羟基-3-甲基环己基,4-羟基-3,5-二甲基环己基,4-羟基-3, 4-羟基-3,3,5-三甲基环己基,未取代或羟基 - ,C 1 -C 9 - 烷基 - ,C 1 -C 5 - 烷氧基 - 或C 3 -C 9 - 三烷基甲硅烷基取代的C 5 -C 12 - 环烯基,R 1是 进一步的双环烷基,R 1还是4-叔丁基 - 苄基,4-氯苄基,4-叔丁氧基苄基,1,4-二氧杂螺[4,5]癸烷-8- 芳基,5至7元杂环烷基,5至7元杂环烷基甲基,R2为烷基,烷氧基或三烷基甲硅烷基,R3为烷基,烯基,炔基或芳烷基,X为植物耐受阴离子,n为0或1, 及其耐受植物的盐,以及含有这些化合物的杀真菌剂。
    • 8. 发明授权
    • Fungicidal mixture
    • 真菌混合物
    • US5064828A
    • 1991-11-12
    • US470229
    • 1990-01-25
    • Matthias ZippliesHubert SauterRandall E. GoldAlan AkersEberhard AmmermannGisela Lorenz
    • Matthias ZippliesHubert SauterRandall E. GoldAlan AkersEberhard AmmermannGisela Lorenz
    • A01N43/40A01N43/84
    • A01N43/40A01N43/84
    • A fungicidal mixture ofa) a compound of the formula I ##STR1## where R.sup.a =tridecyl or 3-(p-tert-butyl-(phenyl)-2-methylpropyl,R.sup.b =H, CH.sub.3 andX=O, CH.sub.2andb) a compound of the formula II ##STR2## where R.sup.1 is substituted or unsubstituted phenyl, naphthyl, tetrahydronaphthyl, benzothiophenyl, benzofuranyl, anthracenyl, acenaphthenyl, hexahydroindacenyl, tetrahydrophenanthrenyl, stilbenyl or benzodioxolanyl,R.sup.2 is hydrogen or methyl,R.sup.3 is hydrogen,R.sup.4 is alkyl, cyclopropyl, haloalkyl or alkenyl,W is alkenylene, fluoroalkenylene or a single bond,R.sup.5 is substituted or unsubstituted phenyl, or is naphthyl, substituted or unsubstituted alkenyl, or alkynyl, where the radical ##STR3## may denote the acenaphthenyl radical ##STR4## and the radical ##STR5## may also be part of a heterocyclic ring.
    • a)式Ⅰ化合物的杀真菌混合物,其中R a =十三烷基或3-(对叔丁基 - (苯基)-2-甲基丙基,R b = H,CH 3和X = O,CH 2和 b)式II的化合物其中R1是取代或未取代的苯基,萘基,四氢萘基,苯并噻吩基,苯并呋喃基,蒽基,苊基,六氢茚基,四氢菲基,茋基或苯并二氧杂环戊烷基,R 2是氢或甲基, R4是烷基,环丙基,卤代烷基或烯基,W是亚烯基,氟亚烷基或单键,R5是取代或未取代的苯基,或是萘基,取代或未取代的烯基或炔基,其中基团可以表示苊基 < IMAGE>和激进的也可以是杂环的一部分。