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1. 发明授权

US4481211A Microbiocidal substituted benzylimidazolium salts 失效
标题翻译：杀微生物取代的苄基咪唑鎓盐
公开(公告)号：US4481211A
公开(公告)日：1984-11-06
申请号：US441803
申请日：1982-11-15
申请人： Toni Dockner , Ernst-Heinrich Pommer , Matthias Wetzler
发明人： Toni Dockner , Ernst-Heinrich Pommer , Matthias Wetzler
IPC分类号： A01N43/50 , C07D233/68 , C07D233/00
CPC分类号： A01N43/50 , C07D233/68
摘要： Substituted benzylimidazolium salts of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different and are each hydrogen, C.sub.1 -C.sub.4 -alkyl or halogen, R.sup.4 is alkyl of 8 to 14 carbon atoms or benzyl which is unsubstituted or substituted by halogen or alkyl, R.sup.5 is hydrogen, alkyl of 1 to 8 carbon atoms, phenyl or benzyl, R.sup.6 is alkyl of 1 to 4 carbon atoms or halogen, R.sup.7 is alkyl of 1 to 4 carbon atoms or halogen and X is an anion of an acid, in particular of a hydrohalic acid, and microbicides containing these compounds.
摘要翻译：取代的式“IMAGE”的苄基咪唑鎓盐，其中R 1，R 2和R 3相同或不同并且各自为氢，C 1 -C 4 - 烷基或卤素，R 4为8至14个碳原子的烷基或未被取代或被卤素取代的苄基或烷基，R 5为氢，1至8个碳原子的烷基，苯基或苄基，R 6为1至4个碳原子的烷基或卤素，R 7为1至4个碳原子的烷基或卤素，X为酸的阴离子，特别是氢卤酸，以及含有这些化合物的杀微生物剂。

2. 发明授权

US4239895A Process for producing 1-hydroxymethylimidazoles 失效
标题翻译： 1-羟甲基咪唑的制备方法
公开(公告)号：US4239895A
公开(公告)日：1980-12-16
申请号：US64860
申请日：1979-08-08
申请人： Toni Dockner , Anton Frank , Uwe Kempe , Matthias Wetzler , Helmut Karn
发明人： Toni Dockner , Anton Frank , Uwe Kempe , Matthias Wetzler , Helmut Karn
IPC分类号： C07D233/64 , C07D233/54 , C07D233/60 , C07D521/00 , C08G12/26 , C08G59/40 , C08G59/50 , C10L1/32
CPC分类号： C07D233/64 , C07D231/12 , C07D233/56 , C07D249/08 , C08G12/26 , C10L1/328
摘要： 1-Hydroxymethylimidazoles which are unsubstituted or alkyl-substituted in the 2-position, their manufacture and their use as chemical intermediates, e.g. for other imidazole derivatives or for the drug cimetidine.
摘要翻译：在2-位未被取代或被烷基取代的1-羟基甲基咪唑，它们的制备及其作为化学中间体的用途。用于其他咪唑衍生物或药物西咪替丁。

3. 发明授权

US4145553A Manufacture of 4-nitroimidazoles 失效
标题翻译：制备4-硝基咪唑
公开(公告)号：US4145553A
公开(公告)日：1979-03-20
申请号：US834414
申请日：1977-09-19
申请人： Matthias Wetzler , Toni Dockner
发明人： Matthias Wetzler , Toni Dockner
IPC分类号： C07D233/92 , C07D233/02
CPC分类号： C07D233/92
摘要： Manufacture of 4-nitroimidazoles by nitrating imidazoles with nitric acid in the presence of urea while at the same time removing water from the mixture by distillation. The compounds which can be manufactured by the process of the invention are catalysts for polymerization reactions and condensation reactions, especially for reactions with epoxides, the aldol condensation, the manufacture of polyurethanes, condensation reactions with malonic esters or acetoacetic esters and intermediates for the manufacture of dyes, textile auxiliaries and insecticides.
摘要翻译：在尿素存在下用硝酸硝化咪唑制造4-硝基咪唑，同时通过蒸馏从混合物中除去水分。

4. 发明授权

US4242517A Process for preparing 4-methyl-5[(2-aminoethyl)thiomethyl)]-imidazole 失效
标题翻译：制备4-甲基-5 [（2-氨基乙基）硫代甲基）] - 咪唑的方法
公开(公告)号：US4242517A
公开(公告)日：1980-12-30
申请号：US64909
申请日：1979-08-08
申请人： Toni Dockner , Anton Frank , Uwe Kempe , Matthias Wetzler , Helmut Karn
发明人： Toni Dockner , Anton Frank , Uwe Kempe , Matthias Wetzler , Helmut Karn
IPC分类号： C07D233/64 , C07D233/54 , C07D233/60 , C07D521/00 , C08G12/26 , C08G59/40 , C08G59/50 , C10L1/32
CPC分类号： C07D233/64 , C07D231/12 , C07D233/56 , C07D249/08 , C08G12/26 , C10L1/328
摘要： 1-Hydroxymethylimidazoles which are unsubstituted or alkyl-substituted in the 2-position, their manufacture and their use as chemical intermediates, e.g. for other imidazole derivatives or for the drug cimetidine.
摘要翻译：在2-位未被取代或被烷基取代的1-羟基甲基咪唑，它们的制备及其作为化学中间体的用途。用于其他咪唑衍生物或药物西咪替丁。

5. 发明授权

US06072076A Continuous preparation of alkyl esters of (meth)acrylic acid 失效
标题翻译：连续制备（甲基）丙烯酸的烷基酯
公开(公告)号：US06072076A
公开(公告)日：2000-06-06
申请号：US789542
申请日：1997-01-27
申请人： Willi Schmidt , Matthias Geisendorfer , Alexander Weck , Toni Dockner , Holger Herbst , Gerhard Nestler
发明人： Willi Schmidt , Matthias Geisendorfer , Alexander Weck , Toni Dockner , Holger Herbst , Gerhard Nestler
IPC分类号： B01J31/02 , C07B61/00 , C07C67/08 , C07C67/54 , C07C69/54 , C07C69/52
CPC分类号： C07C67/08
摘要： In a process for the continuous preparation of alkyl esters of (meth)acrylic acid by reacting (meth)acrylic acid with alkanols having from 1 to 8 carbon atoms in a homogeneous, liquid, solvent-free phase at elevated temperature and in the presence of an acid esterification catalyst, in which the (meth)acrylic acid, the alkanol and the acid catalyst are fed to a reaction zone, the water formed is removed by rectification during a residence time as constituent of a mixture comprising starting alkanol in a rectification unit (III) superposed on the reaction zone, the distillate obtained is separated into an organic phase comprising alkanol and an aqueous phase comprising water, the organic phase is essentially completely returned to the rectification unit (III), the reaction mixture is discharged from the reaction zone and conveyed into a distillative separation zone comprising further rectification units and in the latter the alkyl (meth)acrylate formed is separated off.a) (Meth)acrylic acid and alkanol are reacted in a molar ratio of from 1:0.75 to 1:2, b) part of the aqueous phase obtained at the top of the rectification unit (III) is returned to the rectification unit, c) the reaction mixture discharged from the reaction zone is fed to a further rectification unit (I) and in this the reaction mixture is separated into a product (II) comprising the catalyst and a product (I) comprising the alkyl ester of (meth)acrylic acid, remaining alkanol and remaining (meth)acrylic acid, and d) the product (I) is fed to a further rectification unit (II) and in this the alkyl ester of (meth)acrylic acid is separated from the remaining alkanol and from the remaining (meth)acrylic acid and the remaining alkanol and the remaining (meth)acrylic acid are returned to the reaction zone.
摘要翻译：在（甲基）丙烯酸的烷基酯的连续制备方法中，通过使（甲基）丙烯酸与具有1至8个碳原子的链烷醇在均相，液体，无溶剂相中在升高的温度下和在将（甲基）丙烯酸，链烷醇和酸催化剂进料到反应区中的酸酯化催化剂，在停留时间内通过精馏除去形成的水，作为在精馏单元中起始烷醇的混合物的组分（III），将获得的馏出物分离成包含链烷醇和含水的水相的有机相，有机相基本上完全返回到精馏单元（III），将反应混合物从反应物中排出并输送到包含进一步精馏单元的蒸馏分离区中，后者分离形成的（甲基）丙烯酸烷基酯。 a）（甲基）丙烯酸和链烷醇的摩尔比为1:0.75至1:2，b）将在精馏单元（III）顶部获得的部分水相返回至精馏单元， c）将从反应区排出的反应混合物加入到另一精馏单元（I）中，并将反应混合物分离成包含催化剂的产物（II）和包含（甲基）丙烯酸烷基酯的产物（I））丙烯酸，残留的链烷醇和剩余的（甲基）丙烯酸，以及d）将产物（I）加入到另一精馏单元（II）中，在此将（甲基）丙烯酸的烷基酯与剩余的链烷醇和剩余的（甲基）丙烯酸和剩余的链烷醇和剩余的（甲基）丙烯酸返回到反应区。

6. 发明授权

US5877326A Aqueous phase process for preparing N-substituted imidazoles 失效
标题翻译：制备N-取代咪唑的水相方法
公开(公告)号：US5877326A
公开(公告)日：1999-03-02
申请号：US914187
申请日：1997-08-19
申请人： Gisela Hieber , Klaus Ebel , Jurgen Schroder , Toni Dockner , Carsten Groning , Bernd Ruge
发明人： Gisela Hieber , Klaus Ebel , Jurgen Schroder , Toni Dockner , Carsten Groning , Bernd Ruge
IPC分类号： C07D233/58 , B01J21/12 , B01J27/16 , C07D233/54 , C07D233/68 , C07D233/90 , C07D233/91 , C07D233/92 , C07D235/06 , C07D235/08 , C07D233/56
CPC分类号： C07D235/08 , C07D233/54 , C07D233/56 , C07D233/64 , C07D233/68 , C07D233/90 , C07D233/91 , C07D233/92 , C07D235/06
摘要： A process for preparing substituted imidazoles of the formula I ##STR1## R.sup.1, R.sup.2 and R.sup.3 are identical or different and are each hydrogen, halogen, NO.sub.2, CN or a C.sub.1 -C.sub.20 -hydrocarbon radical which is unsubstituted or substituted by one or more halogens or R.sup.1 and R.sup.2 together are members of a 3- to 20-membered hydrocarbon ring which is unsubstituted or substituted by one or more halogens and/or C.sub.1 -C.sub.8 -alkyl groups and which may contain 1, 2 or 3 heteroatoms from the group consisting of nitrogen, oxygen and sulfur, andR.sup.4 is a C.sub.1 -C.sub.20 -hydrocarbon radical which is unsubstituted or substituted by one or more halogens,comprises using an aqueous phase of the imidazoles of the formula II ##STR2## where R.sup.1, R.sup.2 and R.sup.3 are as defined above with compounds of the formula IIIR.sup.4 --O--R.sup.5 IIIwhereR.sup.4 is as defined above andR.sup.5 is hydrogen or R.sup.4, it being possible in the latter case for the two R.sup.4 substituents to be identical or different,and reacting it at from 200.degree. to 550.degree. C. in the presence of a catalyst comprising oxides and/or phosphates of one or more metals of the 2nd, 3rd and 4th main group and the 4th subgroup of the Periodic Table in the presence or absence of phosphoric acid and/or phosphoric esters.
摘要翻译：制备式I的取代咪唑的方法R1，R2和R3相同或不同，各自为氢，卤素，NO2，CN或C1-C20-烃基，其未被取代或被一个或多个卤素或R 1和R 2一起是3至20元烃环的成员，其未被取代或被一个或多个卤素和/或C 1 -C 8烷基取代，并且可以含有1,2或3个来自该基团的杂原子由氮，氧和硫组成，R4是未被取代或被一个或多个卤素取代的C 1 -C 20烃基，包括使用式II的咪唑的水相，其中R 1，R 2和 R 3如上所定义，与式III的R4-O-R5III化合物，其中R 4如上定义，R 5是氢或R 4，在后一种情况下，两个R 4取代基可以相同或不同，在约200℃〜550℃下，在磷酸和/或磷酸酯存在或不存在的条件下，包含第2，第3和第4主族和第4族的周期表中的一种或多种金属的氧化物和/或磷酸盐。

7. 发明授权

US5468871A Preparation of N-substituted pyrazoles 失效
标题翻译： N-取代吡唑的制备
公开(公告)号：US5468871A
公开(公告)日：1995-11-21
申请号：US334613
申请日：1994-11-07
申请人： Klaus Ebel , Juergen Schroeder , Carsten Groening , Toni Dockner , Hans R. Merkle
发明人： Klaus Ebel , Juergen Schroeder , Carsten Groening , Toni Dockner , Hans R. Merkle
IPC分类号： B01J21/12 , C07B61/00 , C07D231/12 , C07D521/00
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08
摘要： N-substituted-pyrazoles of the formula ##STR1## wherein R.sup.1 is C.sub.1 -C.sub.12 -alkyl or C.sub.7 -C.sub.20 -alkyl, and R.sup.2, R.sup.3 and R.sup.4 independently denote hydrogen, C.sub.1 -C.sub.12 -alkyl, phenyl, C.sub.7 -C.sub.20 -alkylphenyl and C.sub.7 -C.sub.20 -phenylalkyl, are prepared by reacting a pyrazole of the formula ##STR2## wherein R.sup.2, R.sup.3 and R.sup.4 have the meanings above, with an alcohol or ether of the formulaR.sup.1 --O--R.sup.5 III,wherein R.sup.5 is hydrogen or R.sup.1, at a temperature of from 200.degree. to 550.degree. C. and a pressure of from 0.001 to 50 bar in the presence of a heterogeneous catalyst, preferably one which contains acid centers such as the oxides of aluminum, silicon, titanium and/or zirconium, optionally doped with phosphoric acid.
摘要翻译：其中R 1是C 1 -C 12 - 烷基或C 7 -C 20 - 烷基，R 2，R 3和R 4独立地表示氢，C 1 -C 12 - 烷基，苯基，C 7 -C 20 - 烷基苯基和C 7 -C 20 - 苯基烷基，其通式如下：其中R2，R3和R4具有上述含义的吡唑与式R1-O-R5III的醇或醚反应制备，其中R 5是氢或 R1在200〜550℃的温度和0.001〜50巴的压力下，在非均相催化剂存在下，优选含有酸中心的铝，硅，钛和/或氧化物的氧化物锆，任选掺杂有磷酸。

8. 发明授权

US5117004A Preparation of imidazole-2-carboxylic acids 失效
标题翻译：咪唑-2-羧酸的制备
公开(公告)号：US5117004A
公开(公告)日：1992-05-26
申请号：US309089
申请日：1989-02-10
申请人： Uwe Kempe , Toni Dockner , Hermann Koehler
发明人： Uwe Kempe , Toni Dockner , Hermann Koehler
IPC分类号： C07D233/90 , C07D235/24
CPC分类号： C07D235/24 , C07D233/90
摘要： 4,5-Disubstituted imidazole-2-carboxylic acids are prepared by reacting 4,5-disubstituted imidazoles with carbon dioxide under superatmospheric pressure at from 150.degree. to 300.degree. C. in the presence of a base.
摘要翻译： 4,5-二取代的咪唑-2-羧酸是通过使4,5-二取代的咪唑与二氧化碳在超大气压下在150℃至300℃下在碱的存在下反应来制备的。

9. 发明授权

US4950763A Preparation of ketones 失效
标题翻译：酮的制备
公开(公告)号：US4950763A
公开(公告)日：1990-08-21
申请号：US381469
申请日：1989-07-18
申请人： Charles Schommer , Klaus Ebel , Toni Dockner , Matthias Irgang , Wolfgang Hoelderich , Harald Rust
发明人： Charles Schommer , Klaus Ebel , Toni Dockner , Matthias Irgang , Wolfgang Hoelderich , Harald Rust
IPC分类号： B01J21/06 , B01J23/04 , C07B61/00 , C07C45/00 , C07C45/48 , C07C45/74 , C07C49/04 , C07C49/76 , C07C49/792 , C07C67/00 , C07D213/50
CPC分类号： B01J23/04 , C07C45/48 , C07D213/50
摘要： Ketones of the general formula (I) ##STR1## where R.sup.1 and R.sup.2 independently of one another are each alkyl, cycyloalkyl, arylalkyl, aryl or hetaryl, and one or more of the radicals R.sup.1 and R.sup.2 carry one or more hydrogen atoms on the .alpha.-carbon atom, are prepared by reacting two carboxylic acids of the general formulae (IIa/IIb), R.sup.1 --COOH (IIa) and R.sup.2 --COOH (IIb) or by reacting a carboxylic acid R.sup.1 --COOH (IIa) and a ketone ##STR2## or by reacting a mixture of IIa, IIb and Ib, in the gas phase in the presence of a catalyst, by a process in which a catalyst is used whose active material contains at least 50% by weight of titanium dioxide having a specific surface area greater than 10 m.sup.2 /g.0.
摘要翻译：其中R 1和R 2彼此独立地为烷基，氰基烷基，芳基烷基，芳基或杂芳基的通式（I）的酮，其中R 1和R 2中的一个或多个携带一个或多个氢原子通过使通式（IIa / IIb），R1-COOH（IIa）和R2-COOH（IIb）的两种羧酸反应或通过使羧酸R1-COOH（IIa）和酮（Ib）或IIa，IIb和Ib的混合物在气相中，在催化剂存在下，通过使用活性物质含有至少50重量％的催化剂的方法的比表面积大于10m 2 / g的二氧化钛。

10. 发明授权

US4924000A Preparation of acylated imidazoles 失效
标题翻译：酰化咪唑的制备
公开(公告)号：US4924000A
公开(公告)日：1990-05-08
申请号：US321110
申请日：1989-03-09
申请人： Michael Hesse , Wolfgang Hoelderich , Toni Dockner , Hermann Koehler
发明人： Michael Hesse , Wolfgang Hoelderich , Toni Dockner , Hermann Koehler
IPC分类号： B01J21/00 , B01J21/04 , B01J21/06 , B01J21/08 , B01J23/20 , B01J27/18 , B01J29/04 , C07B61/00 , C07D233/54 , C07D233/64
CPC分类号： C07D233/64
摘要： Acylated imidazoles of the formula ##STR1## where R.sup.1 and R.sup.3 are each H, alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, R.sup.4 is H, alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, and R.sup.5 is alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl, alkylaryl or carboxyl, are prepared by reacting imidazoles of the formula ##STR2## where R.sup.1, R.sup.2 and R.sup.3 are each alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, at least one of the radicals R.sup.1, R.sup.2 and R.sup.3 being hydrogen, and R.sup.4 is H, alkyl of from 1 to 12 carbon atoms, alkenyl of from 1 to 12 carbon atoms, aryl, aralkyl or alkylaryl, with widely used acylating agents of the formula ##STR3## where R.sup.5 is as defined above and Y is halide, alkoxy, acyloxy or hydroxyl, in the presence of acidic metal oxides and/or phosphates, preferably in the gas phase.
摘要翻译：其中R 1和R 3各自为H，具有1至12个碳原子的烷基，1至12个碳原子的烯基，芳基，芳烷基或烷基芳基，R 4为H，1至12的烷基，碳原子，1至12个碳原子的烯基，芳基，芳烷基或烷基芳基，R5是1至12个碳原子的烷基，1至12个碳原子的烯基，芳基，芳烷基，烷基芳基或羧基，使式（Ia）的咪唑与R1，R2和R3各自为1至12个碳原子的烷基，1至12个碳原子的烯基，芳基，芳烷基或烷基芳基，基团R1，R2和 R3为氢，R4为H，1至12个碳原子的烷基，1至12个碳原子的烯基，芳基，芳烷基或烷基芳基，以及广泛使用的通式为“IMAGE”的酰化剂，其中R5如上定义在酸性金属氧化物和/或磷酸盐的存在下，优选在气相中，Y是卤化物，烷氧基，酰氧基或羟基。

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