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    • 1. 发明授权
    • Manufacture of transition metal carbide, nitride, and carbonitride
whiskers containing two or more transition metals
    • 制造含有两种或更多种过渡金属的过渡金属碳化物,氮化物和碳氮化物晶须
    • US5851285A
    • 1998-12-22
    • US770849
    • 1996-12-20
    • Mats JohnssonNiklas AhlenMats NygrenMagnus EkelundGunnar Brandt
    • Mats JohnssonNiklas AhlenMats NygrenMagnus EkelundGunnar Brandt
    • C30B29/62C30B25/00C30B21/06
    • C30B25/005C30B29/36C30B29/38Y10S977/734Y10S977/762Y10S977/776Y10S977/90
    • There is disclosed a method of producing whiskers in large volumes and at low cost to be used as reinforcing material. The whiskers are solid solutions between two or more transition metal carbides, nitrides and carbonitrides, (Me.sub.1-X-Y.sub.Me'.sub.X+Y)C.sub.1-Z N.sub.Z, having preferably submicron diameters, where Me' is one or more transition metals other than Me. The whiskers are suitable for use as a reinforcement material in a wide range of materials, including metals, intermetallics, plastics, ceramics and metallic bonded hard material. Transition metal oxides, hydroxides or alkali compounds thereof are mixed with carbon powder. The carbon source is added in an amount to satisfy the stoichiometric requirements of the carbide or nitride. A halogenide salt is used as a volatilization agent for the transition metals and a catalyst such as Ni or Co that is able to dissolve transition metals plus C and/or N. The reactant powders are blended so as to intimately mix them. Finally, the mixed starting material is subjected to nitriding, carbonizing or carbonitriding heat treatments in order to produce the desired whiskers.
    • 公开了一种以大量且低成本生产晶须以用作增强材料的方法。 晶须是两个或更多个过渡金属碳化物,氮化物和碳氮化物之间的固溶体(Me1-X-YMe'X + Y)C1-ZNZ,优选亚微米直径,其中Me'是除Me以外的一种或多种过渡金属。 晶须适用于各种材料中的增强材料,包括金属,金属间化合物,塑料,陶瓷和金属粘结的硬质材料。 过渡金属氧化物,氢氧化物或其碱金属化合物与碳粉混合。 碳源以满足碳化物或氮化物的化学计量要求的量加入。 卤化物盐用作过渡金属的挥发剂和能够溶解过渡金属加上C和/或N的催化剂如Ni或Co。将反应物粉末混合以便将它们紧密混合。 最后,将混合起始材料进行氮化,碳化或碳氮共渗处理,以产生所需的晶须。
    • 2. 发明授权
    • Manufacture of titanium carbide, nitride and carbonitride whiskers
    • 制造碳化钛,氮化物和碳氮化物晶须
    • US06110275A
    • 2000-08-29
    • US772102
    • 1996-12-20
    • Mats NygrenMats JohnssonNiklas AhlenMagnus Ekelund
    • Mats NygrenMats JohnssonNiklas AhlenMagnus Ekelund
    • C30B25/00C30B29/62
    • C30B25/005C30B29/36C30B29/38
    • There is disclosed a method of producing, in large volume and at low cost, titanium carbide, nitride and carbonitride whiskers, with preferably submicron diameters, to be used as reinforcing material. The whiskers are suitable for use as a reinforcement material in a wide range of materials, including metals, intermetallics, plastics, ceramics and metallic bonded hard material. Titanium oxide, hydroxide or alkali compounds thereof are mixed with a carbon source with a volatile part which volatiles at temperatures exceeding 500.degree. C. and in an amount to satisfy the stoichiometric requirements of the carbide or nitride. A halogenide salt is used as a volatilization agent for titanium as well as a catalyst able to dissolve Ti plus C and/or N, such as Ni or Co. The reactant powders are blended in some typical manner, e.g., by using a high speed blender so as to intimately mix them. Finally, the mixed starting material is subjected to nitriding, carbonizing or carbonitriding heat treatments in order to produce the desired whiskers.
    • 公开了以大量且低成本生产优选亚微米直径的碳化钛,氮化物和碳氮化物晶须作为增强材料的方法。 晶须适用于各种材料中的增强材料,包括金属,金属间化合物,塑料,陶瓷和金属粘结的硬质材料。 氧化钛,氢氧化物或碱性化合物与碳源与挥发性物质混合,挥发物在超过500℃的温度下挥发,并且其量足以满足碳化物或氮化物的化学计量要求。 使用卤化物盐作为钛的挥发剂以及能够溶解Ti和C和/或N的催化剂,例如Ni或Co。将反应物粉末以一些典型的方式混合,例如通过使用高速 搅拌机,以便将它们紧密混合。 最后,将混合起始材料进行氮化,碳化或碳氮共渗处理,以产生所需的晶须。
    • 3. 发明授权
    • Manufacture of transition metal carbide, nitride and carbonitride
whiskers
    • 过渡金属碳化物,氮化物和碳氮化物晶须的制造
    • US5853477A
    • 1998-12-29
    • US772099
    • 1996-12-20
    • R. Tom CoyleMagnus EkelundMats NygrenMats Johnsson
    • R. Tom CoyleMagnus EkelundMats NygrenMats Johnsson
    • C30B29/62C30B25/00
    • C30B25/005C30B29/36C30B29/38Y10S977/734Y10S977/762Y10S977/776Y10S977/90
    • There is disclosed a method of producing, in large volumes and at low cost, Ta, Nb, Zr and Hf carbide, nitride or carbonitride whiskers, preferably submicron, having excellent reinforcing properties, suitable as reinforcement in a wide range of materials, including metals, intermetallics, plastics, ceramics and metallic bonded hard material. Oxides of Ta, Nb, Zr and Hf or alkali compounds thereof in an amount to satisfy the stoichiometric requirements of the desired carbide or nitride are mixed with the carbon source along with an alkali and/or alkali earth metal halogenide as a volatilization agent for the metal and a catalyst for the whisker growth such as Ni and/or Co. The reactant powders are blended in some typical manner using a high speed blender so as to intimately mix them. Finally, the starting material is subjected to nitriding, carbonizing or carbonitriding heat treatments in order to produce the desired whiskers.
    • 公开了大量且低成本地生产具有优异的增强性能的Ta,Nb,Zr和Hf碳化物,氮化物或碳氮化物晶须,优选亚微米级的方法,适用于在宽范围的材料(包括金属)中的增强 ,金属间化合物,塑料,陶瓷和金属粘结硬质材料。 将满足所需碳化物或氮化物的化学计量要求的量的Ta,Nb,Zr和Hf的氧化物或其碱金属化合物与作为挥发剂的碱和/或碱土金属卤化物一起与碳源一起混合 金属和用于晶须生长的催化剂如Ni和/或Co.使用高速混合器以一些典型的方式将反应物粉末混合,以便将它们紧密混合。 最后,对原料进行氮化,碳化或碳氮共渗处理,以产生所需的晶须。