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1. 发明授权

US5214097A Fluororubber composition 失效
标题翻译：氟橡胶组合物
公开(公告)号：US5214097A
公开(公告)日：1993-05-25
申请号：US700419
申请日：1991-05-15
申请人： Masayasu Tomoda , Shigeru Morita , Etsuo Minamino , Eisuke Yamada , Hiroshi Okamoto , Shinji Inagaki , Junji Furukawa
发明人： Masayasu Tomoda , Shigeru Morita , Etsuo Minamino , Eisuke Yamada , Hiroshi Okamoto , Shinji Inagaki , Junji Furukawa
IPC分类号： C08L9/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L27/12 , C08L53/00 , C08L57/00
CPC分类号： C08L21/00 , C08L27/12 , C08L23/16 , C08L53/00 , C08L9/06
摘要： A fluororubber composition comprising 100 parts by weight of a rubber mixture which comprises 5 to 70% by weight of at least one rubber selected from the group consisting of diene rubbers and polyolefin rubbers and 95 to 30 by weight of a fluororubber and 1 to 20 parts by weight of a block copolymer which comprises a vinyl monomer and a fluorovinyl monomer, which has good compatibility between the rubber components and gives a cured material having improved chemical resistance, heat resistance, oil resistance, and the like.

2. 发明授权

US5430103A Crosslinkable composition 失效
标题翻译：可交联成分
公开(公告)号：US5430103A
公开(公告)日：1995-07-04
申请号：US157065
申请日：1993-12-07
申请人： Hiroyuki Ohata , Satoshi Terasaki , Etsuo Minamino , Masayasu Tomoda , Yoshihiro Shirai , Tsuyoshi Noguchi , Kazuhisa Matsumoto
发明人： Hiroyuki Ohata , Satoshi Terasaki , Etsuo Minamino , Masayasu Tomoda , Yoshihiro Shirai , Tsuyoshi Noguchi , Kazuhisa Matsumoto
IPC分类号： C08K5/14 , C08L27/12 , C08L33/00 , C08L33/04 , C08L43/00 , C08L43/04 , C08J3/24 , C08L27/22
CPC分类号： C08L27/12 , C08L43/04
摘要： The present invention provides a crosslinkable composition which comprises an internally crosslinked acrylic elastomer which is crosslinkable with a peroxide, a fluoroelastomer and a crosslinking agent for at least one of the elastomers.A crosslinkable composition of the present invention can afford a molding which are excellent in physical properties such as mechanical strength and compression set, heat resistance and workability.
摘要翻译： PCT No.PCT / JP93 / 00451 Sec。 371日期：1993年12月7日 102（e）日期1993年12月7日PCT 1993年4月8日PCT PCT。公开号WO93 / 21271 日期：1993年10月28日。本发明提供了一种可交联组合物，其包含可与至少一种弹性体的过氧化物，含氟弹性体和交联剂交联的内部交联的丙烯酸类弹性体。本发明的可交联组合物可以提供机械强度和压缩永久变形，耐热性和可加工性等物理性能优异的成型体。

3. 发明授权

US4530972A Fluoride-containing polymer and composition containing same 失效
标题翻译：含氟聚合物和含有其的组合物
公开(公告)号：US4530972A
公开(公告)日：1985-07-23
申请号：US428703
申请日：1982-09-30
申请人： Masayoshi Tatemoto , Yasuyoshi Furukawa , Masayasu Tomoda , Masahiko Oka , Shigeru Morita
发明人： Masayoshi Tatemoto , Yasuyoshi Furukawa , Masayasu Tomoda , Masahiko Oka , Shigeru Morita
IPC分类号： C08F14/00 , C08F14/16 , C08F14/18 , C08F214/16 , C08F214/18 , C08F214/28 , C08F216/14 , C08F220/02 , C08K3/10 , C08K3/22 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L27/12 , C08L33/00 , C08L33/02 , C08L101/00
CPC分类号： C08F216/1408 , C08F214/18 , C08F220/02
摘要： A fluorine-containing polymer substantially comprising (A) at least one fluorine-containing olefin of the formula:CF.sub.2 =CXYwherein X is a hydrogen atom or a fluorine atom and Y is a hydrogen atom, a chlorine atom, a fluorine atom, a trifluoromethyl group, a difluoromethyl group, a C.sub.1 -C.sub.3 perfluoroalkoxy group or a group of the formula:--(CF.sub.2).sub.m COOMwherein m is an integer of 0 to 3 and M is a hydrogen atom, a C.sub.1 -C.sub.4 alkyl group, a sodium atom or a potassium atom but when X is a hydrogen atom, Y is always a hydrogen atom, (B) one or more C.sub.4 -C.sub.8 fluorine-containing dienes, (C) at least one iodine atom and (D) at least one saturated or unsaturated fluoro or chlorofluorohydrocarbon group, the molar ratio of the diene (B) and the olefin (A) being from 1.times.10.sup.-4 to 5.times.10.sup.-2, the iodine atom(s) (C) being from 0.001 to 10% by weight based on the weight of the polymer and the molar ratio of the group (D) and the olefin (A) being from 1.times.10.sup.-5 to 5.times.10.sup.-2, can be cross-linked at atmospheric pressure at a cross-linking temperature in the presence of a cross-linking agent. The fluorine-containing polymer may be prepared by polymerizing (B) with the polymerization reaction product of (A) and an iodide compound.
摘要翻译：一种含氟聚合物，其基本上包含（A）至少一种下式的含氟烯烃：CF2 = CXY其中X是氢原子或氟原子，Y是氢原子，氯原子，氟原子，三氟甲基，二氟甲基，C1-C3全氟烷氧基或下式的基团： - （CF2）mCOOM其中m为0-3的整数，M为氢原子，C1-C4烷基，钠原子或钾原子，但当X为氢原子时，Y始终为氢原子，（B）一种或多种C 4 -C 8含氟二烯，（C）至少一个碘原子和（D）至少一个饱和或不饱和氟代或氯氟烃基，二烯（B）和烯烃（A）的摩尔比为1×10 -4至5×10 -2，碘原子（C）为0.001至10重量％关于聚合物的重量和（D）和烯烃（A）的摩尔比为1×10-5至5×10-2的摩尔比可以在大气压下在cro 在交联剂存在下的β-连接温度。含氟聚合物可以通过（B）与（A）的聚合反应产物和碘化物化合物聚合来制备。

4. 发明授权

US4766190A Novel elastomeric fluoropolymer and preparation thereof 失效
标题翻译：新型弹性体氟聚合物及其制备
公开(公告)号：US4766190A
公开(公告)日：1988-08-23
申请号：US917500
申请日：1986-10-10
申请人： Shigeru Morita , Kazuhiko Kuwahara , Masayasu Tomoda , Masahiko Oka
发明人： Shigeru Morita , Kazuhiko Kuwahara , Masayasu Tomoda , Masahiko Oka
IPC分类号： C08F214/18 , C08F14/18 , C08F16/14 , C08F214/26 , C08F216/14 , C08F16/24
CPC分类号： C08F214/262 , C08F2438/01
摘要： An elastomeric fluoropolymer comprising 12 to 50% by mole of repeating units derived from a perfluorovinyl ether of the formula:CF.sub.2 .dbd.CFO--(CF.sub.2 CFXO).sub.m --R.sub.f (I)wherein R.sub.f is a C.sub.1 -C.sub.6 perfluoroalkyl group, X is a fluorine atom or a trifluoromethyl group and m is an integer of 1 to 5, 50 to 88% by mole of repeating units derived from tetrafluoroethylene and 0.1 to 5% by mole of repeating units of hexafluoropropylene having improved strength and compression set.
摘要翻译：包含12-50％（摩尔）衍生自下列通式的全氟乙烯基醚的重复单元：CF 2 = CFO-（CF 2 CFXO）m -R f（I）的弹性体含氟聚合物，其中Rf是C1-C6全氟烷基，X是氟原子或三氟甲基，m为1至5的整数，50至88摩尔％的衍生自四氟乙烯的重复单元和0.1至5摩尔％的具有改进的强度和压缩永久变形的六氟丙烯的重复单元。

5. 发明授权

US5891941A Fluororubber composition and molded article thereof 失效
标题翻译：氟橡胶组合物及其模塑制品
公开(公告)号：US5891941A
公开(公告)日：1999-04-06
申请号：US669287
申请日：1996-06-28
申请人： Hiroyuki Tanaka , Koji Matsumoto , Yutaka Ueta , Masayasu Tomoda
发明人： Hiroyuki Tanaka , Koji Matsumoto , Yutaka Ueta , Masayasu Tomoda
IPC分类号： C08K5/02 , C08K5/00 , C08K5/04 , C08K5/17 , C08K5/20 , C08L27/12
CPC分类号： C08K5/17
摘要： A fluororubber composition comprising a fluororubber, a vulcanizing agent and 0.1 to 5 wt. parts of a fatty acid monoamide per 100 wt. parts of said fluororubber. This fluororubber composition is excellent in mold releasability, and a molded article obtained by vulcanizing and molding the composition suffers less deterioration of mechanical properties caused by the addition of an internal mold release agent.
摘要翻译： PCT No.PCT / JP94 / 02180 Sec。 371日期：1996年6月28日 102（e）日期1996年6月28日PCT 1994年12月22日PCT公布。 WO95 / 18182 PCT出版物日期1995年7月6日一种氟橡胶组合物，其包含氟橡胶，硫化剂和0.1至5重量％每100重量份的脂肪酸单酰胺部分部分所述氟橡胶。这种氟橡胶组合物的脱模性优异，通过硫化和成型组合物得到的成型体的加入内部脱模剂引起的机械性能的劣化较少。

6. 发明授权

US5470917A Vulcanizable bromine-containing fluororubber composition containing a peroxy-benzoate 失效
标题翻译：含有过氧苯甲酸酯的可硫化含溴氟橡胶组合物
公开(公告)号：US5470917A
公开(公告)日：1995-11-28
申请号：US177860
申请日：1994-01-04
申请人： Shuji Suyama , Hideyo Ishigaki , Masayasu Tomoda , Yoshihiro Shirai , Hiroyuki Tanaka , Masaharu Komai
发明人： Shuji Suyama , Hideyo Ishigaki , Masayasu Tomoda , Yoshihiro Shirai , Hiroyuki Tanaka , Masaharu Komai
IPC分类号： C08J3/24 , C08K5/14 , C08L15/02 , C08L21/00 , C08F8/06
CPC分类号： C08K5/14
摘要： A vulcanizable rubber composition which contains an iodine- or bromine-containing rubber and an organic peroxide of the formula. ##STR1## wherein R.sup.1 is a hydrogen atom, a chlorine atom or methyl group, R.sup.2 is a linear or branched alkyl group having 2 to 5 carbon atoms, and n is an integer of 1 to 3, generates only a small amount of methyl iodide or methyl bromide during the vulcanization.
摘要翻译：一种可硫化的橡胶组合物，其含有含碘或溴的橡胶和下式的有机过氧化物。（I）其中R1为氢原子，氯原子或甲基，R2为碳原子数2〜5的直链或支链烷基，n为1〜3的整数，仅生成少量的硫化过程中的甲基碘或甲基溴。

7. 发明授权

US4931511A Cross-linkable coating composition 失效
标题翻译：可交联涂料组合物
公开(公告)号：US4931511A
公开(公告)日：1990-06-05
申请号：US245669
申请日：1988-09-16
申请人： Shoji Kawachi , Masayasu Tomoda , Masahiko Oka , Yasuyoshi Furukawa , Hiroyuki Tanaka
发明人： Shoji Kawachi , Masayasu Tomoda , Masahiko Oka , Yasuyoshi Furukawa , Hiroyuki Tanaka
IPC分类号： C08F214/24 , C08F14/24 , C08F214/26 , C08J3/09 , C09D127/12
CPC分类号： C08J3/091 , C09D127/12 , C08J2327/12
摘要： A cross-linkable coating composition comprising a fluorine-containing elastomeric copolymer which comprises (a) 50 to 95% by mole of repeating units derived from a fluoroolefin of the formula:CF.sub.2 .dbd.CXY (I)wherein X and Y are the same or different and a fluorine atom or a chlorine atom, (b) 50 to 5% by mole of repeating units derived from a perfluorovinyl ether of the formula:R.sub.f --[OCFZCF.sub.2 (CF.sub.2).sub.m ].sub.n --OCF.dbd.CF.sub.2 (II)wherein R.sub.f is a C.sub.1 -C.sub.6 perfluoroalkyl group, Z is a fluorine atom or a trifluoromethyl group, n is an integer of 0 to 5 and m is 0 to 1 provided that when m is 1 (one), X is not a trifluoromethyl group and a cross-linking agent for the copolymer, the copolymer and the cross-linking agent being dissolved or dispersed in a fluorosolvent is provided.

8. 发明授权

US4250278A Fluorinated rubber composition 失效
标题翻译：氟化橡胶组合物
公开(公告)号：US4250278A
公开(公告)日：1981-02-10
申请号：US35006
申请日：1979-05-01
申请人： Takeshi Suzuki , Yasuyoshi Furukawa , Masayasu Tomoda , Yutaka Ueta , Akira Ohmori
发明人： Takeshi Suzuki , Yasuyoshi Furukawa , Masayasu Tomoda , Yutaka Ueta , Akira Ohmori
IPC分类号： C08L27/12 , C08K5/00 , C08K5/02 , C08K5/04 , C08K5/05 , C08K5/053 , C08L1/00 , C08L27/00 , C08F8/18 , C08F8/34
CPC分类号： C08K5/053 , C08K5/05
摘要： A vulcanizable fluorinated rubber composition comprising a fluorinated rubber containing --CH.sub.2 --CF.sub.2 -- units in the polymeric chain, a vulcanizing agent and a vulcanization accelerator as the essential components, characterized in that the vulcanizing agent is a fluorine-containing polyhydroxy aliphatic compound.
摘要翻译：一种可硫化氟化橡胶组合物，其包含在所述聚合物链中含有-CH 2 -CF 2 - 单元的氟化橡胶，硫化剂和硫化促进剂作为必需组分，其特征在于所述硫化剂为含氟多羟基脂族化合物。

9. 发明授权

US5296549A Vulcanizable rubber composition containing a peroxide crosslinker 失效
标题翻译：含有过氧化物交联剂的可硫化橡胶组合物
公开(公告)号：US5296549A
公开(公告)日：1994-03-22
申请号：US858505
申请日：1992-03-27
申请人： Shuji Suyama , Hideyo Ishigaki , Masayasu Tomoda , Yoshihiro Shirai , Hiroyuki Tanaka , Masaharu Komai
发明人： Shuji Suyama , Hideyo Ishigaki , Masayasu Tomoda , Yoshihiro Shirai , Hiroyuki Tanaka , Masaharu Komai
IPC分类号： C08J3/24 , C08K5/14 , C08L15/02 , C08L21/00 , C08F8/00
CPC分类号： C08K5/14
摘要： A vulcanizable rubber composition which contains an iodine- or bromine-containing rubber and an organic peroxide of the formula: ##STR1## wherein R.sup.1 is a hydrogen atom, a chlorine atoms or methyl group, R.sup.2 is a linear or branched alkyl group having 2 to 5 carbon atoms, and n is an integer of 1 to 3, generates only a small amount of methyl iodide or methyl bromide during the vulcanization.
摘要翻译：一种可硫化的橡胶组合物，其含有碘或溴的橡胶和下式的有机过氧化物：（*化学结构*）（I）其中R1是氢原子，氯原子或甲基，R2是直链或具有2至5个碳原子的支链烷基，n为1至3的整数，在硫化期间仅产生少量甲基碘或甲基溴。

10. 发明授权

US4501869A Cross linkable fluorine-containing polymer 失效
标题翻译：可交联的含氟聚合物
公开(公告)号：US4501869A
公开(公告)日：1985-02-26
申请号：US517334
申请日：1983-07-26
申请人： Masayoshi Tatemoto , Masahiko Oka , Hideo Kano , Masayasu Tomoda , Yutaka Ueta
发明人： Masayoshi Tatemoto , Masahiko Oka , Hideo Kano , Masayasu Tomoda , Yutaka Ueta
IPC分类号： C08L27/12 , C08F2/38 , C08F4/00 , C08F4/28 , C08F14/00 , C08F14/18 , C08K5/04 , C08K5/17 , C08L1/00 , C08L7/00 , C08L21/00 , C08L25/18 , C08L27/00 , C08L29/10 , C08L33/00 , C08L33/02 , C08L47/00 , C08F214/16
CPC分类号： C08F14/18 , C08F2438/01
摘要： An easily cross linkable fluorine-containing polymer comprising: (1) a polymeric chain comprising one or more polymer segments, at least one polymer segment of which consists of units of at least one fluorine-containing ethylenically unsaturated compound having 2 to 8 carbon atoms, or units of said fluorine-containing ethylenically unsaturated compound and at least one other monomer selected from the group consisting a fluorine-free ethylenically unsaturated compound having 2 to 4 carbon atoms and a fluorine-containing diene having 4 to 8 carbon atoms, (2) at least one bromine atom liberated from a brominated compound of the formula: RBr.sub.x (wherein R is a saturated hydrocarbon residue and x is a number corresponding to the bonding valency of the residue R) in an amount of 0.001 to 10% by weight based on the polymer weight and (3) a fragment of the brominated compound excluding the said liberated bromine atom therefrom, bonded to the polymeric chain, the polymer being prepared by polymerizing said fluorine-containing ethylenically unsaturated compound with or without said other monomer in the presence of a radical producing source and the brominated compound in at least one step.
摘要翻译：一种易交联的含氟聚合物，包括：（1）包含一个或多个聚合物链段的聚合物链，其至少一个聚合物链段由至少一个具有2-8个碳原子的含氟烯属不饱和化合物的单元组成，或所述含氟烯键式不饱和化合物的单元和选自具有2-4个碳原子的无氟烯键式不饱和化合物和具有4-8个碳原子的含氟二烯烃的至少一种其它单体，（2）从以下式的溴化化合物释放的至少一个溴原子：基于以下化学式的溴化化合物：RBrx（其中R是饱和烃残基，x是对应于残基R的键合化合价的数），其量为0.001至10重量％，基于聚合物重量和（3）除了结合到聚合物链上的所述释放的溴原子的溴化化合物的片段，聚合物由聚合物在自由基产生源和溴化化合物的存在下，在至少一个步骤中使含有或不含所述其它单体的含氟烯键式不饱和化合物的化学化。

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