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    • 2. 发明申请
    • MEMBRANE ELECTRODE ASSEMBLY AND METHOD OF PRODUCING THE SAME AND FUEL CELL
    • 膜电极组件及其制造方法和燃料电池
    • US20100291460A1
    • 2010-11-18
    • US12833760
    • 2010-07-09
    • SHINYA ADACHIDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • SHINYA ADACHIDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • H01M8/10
    • H01M8/1004H01M8/0297H01M8/04197H01M8/1011H01M8/1025H01M8/1039H01M8/1053H01M8/1067H01M8/241H01M2300/0094Y02E60/523Y02P70/56Y10T156/1092
    • It is an object of the present invention to provide a method of producing a membrane electrode assembly using an interface resistance reducing composition which can simply reduce the resistance of the interface between an electrode and an electrolyte membrane in a short time at low temperatures at low pressure without polimerization while maintaining an effect of suppressing a fuel crossover even with an electrolyte membrane having high heat resistance, high strength, a high tensile elastic modulus and a low water content. This is achieved by a method of producing a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, comprising the steps of bonding at least one electrode to the electrolyte membrane sandwiching an interface resistance reducing composition containing a plasticizer between the electrode and the electrolyte membrane, and a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, wherein the membrane electrode assembly has a layer (A) at least between one electrode and the electrolyte membrane, and the value of the storage modulus C is 1 GPA or more when the storage moduli of the electrolyte membrane and the layer (A), which are measured with an ultramicro penetrometer, are regarded as C and D, respectively.
    • 本发明的目的是提供一种使用界面电阻降低组合物制造膜电极组件的方法,其可以在低压下在短时间内简单地降低电极和电解质膜之间的界面的电阻 即使使用具有高耐热性,高强度,高拉伸弹性模量和低含水量的电解质膜,也保持抑制燃料分选的效果。 这是通过制造通过将电解质膜夹在一对电极之间而形成的膜电极组件的方法来实现的,包括以下步骤:将至少一个电极粘合到电解质膜上,该电解质膜夹着含有增塑剂的界面电阻降低组合物, 所述电解质膜和通过将电解质膜夹在一对电极之间而形成的膜电极组件,其中所述膜电极组件具有至少在一个电极和所述电解质膜之间的层(A),并且所述储能模量C 当用超微量透度计测量的电解质膜和层(A)的存储模量分别被认为是C和D时,为1GPA或更高。
    • 3. 发明授权
    • Film electrode composite element and production method therefor, and fuel cell
    • 薄膜电极复合元件及其制备方法和燃料电池
    • US07838164B2
    • 2010-11-23
    • US11721143
    • 2005-11-24
    • Shinya AdachiDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • Shinya AdachiDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • H01M8/10H01M4/86
    • H01M8/1004H01M8/0297H01M8/04197H01M8/1011H01M8/1025H01M8/1039H01M8/1053H01M8/1067H01M8/241H01M2300/0094Y02E60/523Y02P70/56Y10T156/1092
    • It is an object of the present invention to provide a method of producing a membrane electrode assembly using an interface resistance reducing composition which can simply reduce the resistance of the interface between an electrode and an electrolyte membrane in a short time at low temperatures at low pressure without polimerization while maintaining an effect of suppressing a fuel crossover even with an electrolyte membrane having high heat resistance, high strength, a high tensile elastic modulus and a low water content. This is achieved by a method of producing a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, comprising the steps of bonding at least one electrode to the electrolyte membrane sandwiching an interface resistance reducing composition containing a plasticizer between the electrode and the electrolyte membrane, and a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, wherein the membrane electrode assembly has a layer (A) at least between one electrode and the electrolyte membrane, and the value of the storage modulus C is 1 GPA or more when the storage moduli of the electrolyte membrane and the layer (A), which are measured with an ultramicro penetrometer, are regarded as C and D, respectively.
    • 本发明的目的是提供一种使用界面电阻降低组合物制造膜电极组件的方法,其可以在低压下在短时间内简单地降低电极和电解质膜之间的界面的电阻 即使使用具有高耐热性,高强度,高拉伸弹性模量和低含水量的电解质膜,也保持抑制燃料分选的效果。 这是通过制造通过将电解质膜夹在一对电极之间而形成的膜电极组件的方法来实现的,包括以下步骤:将至少一个电极粘合到电解质膜上,该电解质膜夹着含有增塑剂的界面电阻降低组合物, 所述电解质膜和通过将电解质膜夹在一对电极之间而形成的膜电极组件,其中所述膜电极组件具有至少在一个电极和所述电解质膜之间的层(A),并且所述储能模量C 当用超微量透度计测量的电解质膜和层(A)的存储模量分别被认为是C和D时,为1GPA或更高。
    • 6. 发明授权
    • Membrane electrode assembly and method of producing the same and fuel cell
    • 膜电极组件及其制造方法和燃料电池
    • US08278004B2
    • 2012-10-02
    • US12833760
    • 2010-07-09
    • Shinya AdachiDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • Shinya AdachiDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • H01M8/10C09D7/00
    • H01M8/1004H01M8/0297H01M8/04197H01M8/1011H01M8/1025H01M8/1039H01M8/1053H01M8/1067H01M8/241H01M2300/0094Y02E60/523Y02P70/56Y10T156/1092
    • It is an object of the present invention to provide a method of producing a membrane electrode assembly using an interface resistance reducing composition which can simply reduce the resistance of the interface between an electrode and an electrolyte membrane in a short time at low temperatures at low pressure without polymerization while maintaining an effect of suppressing a fuel crossover even with an electrolyte membrane having high heat resistance, high strength, a high tensile elastic modulus and a low water content. This is achieved by a method of producing a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, comprising the steps of bonding at least one electrode to the electrolyte membrane sandwiching an interface resistance reducing composition containing a plasticizer between the electrode and the electrolyte membrane, and a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, wherein the membrane electrode assembly has a layer (A) at least between one electrode and the electrolyte membrane, and the value of the storage modulus C is 1 GPa or more when the storage moduli of the electrolyte membrane and the layer (A), which are measured with an ultramicro penetrometer, are regarded as C and D, respectively.
    • 本发明的目的是提供一种使用界面电阻降低组合物制造膜电极组件的方法,其可以在低压下在短时间内简单地降低电极和电解质膜之间的界面的电阻 即使使用具有高耐热性,高强度,高拉伸弹性模量和低含水量的电解质膜,也保持抑制燃料交换的效果。 这是通过制造通过将电解质膜夹在一对电极之间而形成的膜电极组件的方法来实现的,包括以下步骤:将至少一个电极粘合到电解质膜上,该电解质膜夹着含有增塑剂的界面电阻降低组合物, 所述电解质膜和通过将电解质膜夹在一对电极之间而形成的膜电极组件,其中所述膜电极组件具有至少在一个电极和所述电解质膜之间的层(A),并且所述储能模量C 当用超微量渗透计测量的电解质膜和层(A)的储存模量分别被认为是C和D时,为1GPa或更高。
    • 7. 发明申请
    • FILM ELECTRODE COMPOSITE ELEMENT AND PRODUCTION METHOD THEREFOR, AND FUEL CELL
    • 薄膜电极复合材料及其制备方法及燃料电池
    • US20100015493A1
    • 2010-01-21
    • US11721143
    • 2005-11-24
    • Shinya AdachiDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • Shinya AdachiDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • H01M8/10B32B37/00B32B27/08
    • H01M8/1004H01M8/0297H01M8/04197H01M8/1011H01M8/1025H01M8/1039H01M8/1053H01M8/1067H01M8/241H01M2300/0094Y02E60/523Y02P70/56Y10T156/1092
    • It is an object of the present invention to provide a method of producing a membrane electrode assembly using an interface resistance reducing composition which can simply reduce the resistance of the interface between an electrode and an electrolyte membrane in a short time at low temperatures at low pressure without polimerization while maintaining an effect of suppressing a fuel crossover even with an electrolyte membrane having high heat resistance, high strength, a high tensile elastic modulus and a low water content. This is achieved by a method of producing a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, comprising the steps of bonding at least one electrode to the electrolyte membrane sandwiching an interface resistance reducing composition containing a plasticizer between the electrode and the electrolyte membrane, and a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, wherein the membrane electrode assembly has a layer (A) at least between one electrode and the electrolyte membrane, and the value of the storage modulus C is 1 GPA or more when the storage moduli of the electrolyte membrane and the layer (A), which are measured with an ultramicro penetrometer, are regarded as C and D, respectively.
    • 本发明的目的是提供一种使用界面电阻降低组合物制造膜电极组件的方法,其可以在低压下在短时间内简单地降低电极和电解质膜之间的界面的电阻 即使使用具有高耐热性,高强度,高拉伸弹性模量和低含水量的电解质膜,也保持抑制燃料分选的效果。 这是通过制造通过将电解质膜夹在一对电极之间而形成的膜电极组件的方法来实现的,包括以下步骤:将至少一个电极粘合到电解质膜上,该电解质膜夹着含有增塑剂的界面电阻降低组合物, 所述电解质膜和通过将电解质膜夹在一对电极之间而形成的膜电极组件,其中所述膜电极组件具有至少在一个电极和所述电解质膜之间的层(A),并且所述储能模量C 当用超微量透度计测量的电解质膜和层(A)的存储模量分别被认为是C和D时,为1GPA或更高。