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    • 1. 发明申请
    • MEMBRANE ELECTRODE ASSEMBLY AND METHOD OF PRODUCING THE SAME AND FUEL CELL
    • 膜电极组件及其制造方法和燃料电池
    • US20100291460A1
    • 2010-11-18
    • US12833760
    • 2010-07-09
    • SHINYA ADACHIDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • SHINYA ADACHIDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • H01M8/10
    • H01M8/1004H01M8/0297H01M8/04197H01M8/1011H01M8/1025H01M8/1039H01M8/1053H01M8/1067H01M8/241H01M2300/0094Y02E60/523Y02P70/56Y10T156/1092
    • It is an object of the present invention to provide a method of producing a membrane electrode assembly using an interface resistance reducing composition which can simply reduce the resistance of the interface between an electrode and an electrolyte membrane in a short time at low temperatures at low pressure without polimerization while maintaining an effect of suppressing a fuel crossover even with an electrolyte membrane having high heat resistance, high strength, a high tensile elastic modulus and a low water content. This is achieved by a method of producing a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, comprising the steps of bonding at least one electrode to the electrolyte membrane sandwiching an interface resistance reducing composition containing a plasticizer between the electrode and the electrolyte membrane, and a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, wherein the membrane electrode assembly has a layer (A) at least between one electrode and the electrolyte membrane, and the value of the storage modulus C is 1 GPA or more when the storage moduli of the electrolyte membrane and the layer (A), which are measured with an ultramicro penetrometer, are regarded as C and D, respectively.
    • 本发明的目的是提供一种使用界面电阻降低组合物制造膜电极组件的方法,其可以在低压下在短时间内简单地降低电极和电解质膜之间的界面的电阻 即使使用具有高耐热性,高强度,高拉伸弹性模量和低含水量的电解质膜,也保持抑制燃料分选的效果。 这是通过制造通过将电解质膜夹在一对电极之间而形成的膜电极组件的方法来实现的,包括以下步骤:将至少一个电极粘合到电解质膜上,该电解质膜夹着含有增塑剂的界面电阻降低组合物, 所述电解质膜和通过将电解质膜夹在一对电极之间而形成的膜电极组件,其中所述膜电极组件具有至少在一个电极和所述电解质膜之间的层(A),并且所述储能模量C 当用超微量透度计测量的电解质膜和层(A)的存储模量分别被认为是C和D时,为1GPA或更高。
    • 2. 发明授权
    • Film electrode composite element and production method therefor, and fuel cell
    • 薄膜电极复合元件及其制备方法和燃料电池
    • US07838164B2
    • 2010-11-23
    • US11721143
    • 2005-11-24
    • Shinya AdachiDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • Shinya AdachiDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • H01M8/10H01M4/86
    • H01M8/1004H01M8/0297H01M8/04197H01M8/1011H01M8/1025H01M8/1039H01M8/1053H01M8/1067H01M8/241H01M2300/0094Y02E60/523Y02P70/56Y10T156/1092
    • It is an object of the present invention to provide a method of producing a membrane electrode assembly using an interface resistance reducing composition which can simply reduce the resistance of the interface between an electrode and an electrolyte membrane in a short time at low temperatures at low pressure without polimerization while maintaining an effect of suppressing a fuel crossover even with an electrolyte membrane having high heat resistance, high strength, a high tensile elastic modulus and a low water content. This is achieved by a method of producing a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, comprising the steps of bonding at least one electrode to the electrolyte membrane sandwiching an interface resistance reducing composition containing a plasticizer between the electrode and the electrolyte membrane, and a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, wherein the membrane electrode assembly has a layer (A) at least between one electrode and the electrolyte membrane, and the value of the storage modulus C is 1 GPA or more when the storage moduli of the electrolyte membrane and the layer (A), which are measured with an ultramicro penetrometer, are regarded as C and D, respectively.
    • 本发明的目的是提供一种使用界面电阻降低组合物制造膜电极组件的方法,其可以在低压下在短时间内简单地降低电极和电解质膜之间的界面的电阻 即使使用具有高耐热性,高强度,高拉伸弹性模量和低含水量的电解质膜,也保持抑制燃料分选的效果。 这是通过制造通过将电解质膜夹在一对电极之间而形成的膜电极组件的方法来实现的,包括以下步骤:将至少一个电极粘合到电解质膜上,该电解质膜夹着含有增塑剂的界面电阻降低组合物, 所述电解质膜和通过将电解质膜夹在一对电极之间而形成的膜电极组件,其中所述膜电极组件具有至少在一个电极和所述电解质膜之间的层(A),并且所述储能模量C 当用超微量透度计测量的电解质膜和层(A)的存储模量分别被认为是C和D时,为1GPA或更高。
    • 3. 发明授权
    • Membrane electrode assembly and method of producing the same and fuel cell
    • 膜电极组件及其制造方法和燃料电池
    • US08278004B2
    • 2012-10-02
    • US12833760
    • 2010-07-09
    • Shinya AdachiDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • Shinya AdachiDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • H01M8/10C09D7/00
    • H01M8/1004H01M8/0297H01M8/04197H01M8/1011H01M8/1025H01M8/1039H01M8/1053H01M8/1067H01M8/241H01M2300/0094Y02E60/523Y02P70/56Y10T156/1092
    • It is an object of the present invention to provide a method of producing a membrane electrode assembly using an interface resistance reducing composition which can simply reduce the resistance of the interface between an electrode and an electrolyte membrane in a short time at low temperatures at low pressure without polymerization while maintaining an effect of suppressing a fuel crossover even with an electrolyte membrane having high heat resistance, high strength, a high tensile elastic modulus and a low water content. This is achieved by a method of producing a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, comprising the steps of bonding at least one electrode to the electrolyte membrane sandwiching an interface resistance reducing composition containing a plasticizer between the electrode and the electrolyte membrane, and a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, wherein the membrane electrode assembly has a layer (A) at least between one electrode and the electrolyte membrane, and the value of the storage modulus C is 1 GPa or more when the storage moduli of the electrolyte membrane and the layer (A), which are measured with an ultramicro penetrometer, are regarded as C and D, respectively.
    • 本发明的目的是提供一种使用界面电阻降低组合物制造膜电极组件的方法,其可以在低压下在短时间内简单地降低电极和电解质膜之间的界面的电阻 即使使用具有高耐热性,高强度,高拉伸弹性模量和低含水量的电解质膜,也保持抑制燃料交换的效果。 这是通过制造通过将电解质膜夹在一对电极之间而形成的膜电极组件的方法来实现的,包括以下步骤:将至少一个电极粘合到电解质膜上,该电解质膜夹着含有增塑剂的界面电阻降低组合物, 所述电解质膜和通过将电解质膜夹在一对电极之间而形成的膜电极组件,其中所述膜电极组件具有至少在一个电极和所述电解质膜之间的层(A),并且所述储能模量C 当用超微量渗透计测量的电解质膜和层(A)的储存模量分别被认为是C和D时,为1GPa或更高。
    • 4. 发明申请
    • FILM ELECTRODE COMPOSITE ELEMENT AND PRODUCTION METHOD THEREFOR, AND FUEL CELL
    • 薄膜电极复合材料及其制备方法及燃料电池
    • US20100015493A1
    • 2010-01-21
    • US11721143
    • 2005-11-24
    • Shinya AdachiDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • Shinya AdachiDaisuke IzuharaMasataka NakamuraNaoki ShimoyamaTakao UeteMasayuki Kidai
    • H01M8/10B32B37/00B32B27/08
    • H01M8/1004H01M8/0297H01M8/04197H01M8/1011H01M8/1025H01M8/1039H01M8/1053H01M8/1067H01M8/241H01M2300/0094Y02E60/523Y02P70/56Y10T156/1092
    • It is an object of the present invention to provide a method of producing a membrane electrode assembly using an interface resistance reducing composition which can simply reduce the resistance of the interface between an electrode and an electrolyte membrane in a short time at low temperatures at low pressure without polimerization while maintaining an effect of suppressing a fuel crossover even with an electrolyte membrane having high heat resistance, high strength, a high tensile elastic modulus and a low water content. This is achieved by a method of producing a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, comprising the steps of bonding at least one electrode to the electrolyte membrane sandwiching an interface resistance reducing composition containing a plasticizer between the electrode and the electrolyte membrane, and a membrane electrode assembly formed by sandwiching an electrolyte membrane between a pair of electrodes, wherein the membrane electrode assembly has a layer (A) at least between one electrode and the electrolyte membrane, and the value of the storage modulus C is 1 GPA or more when the storage moduli of the electrolyte membrane and the layer (A), which are measured with an ultramicro penetrometer, are regarded as C and D, respectively.
    • 本发明的目的是提供一种使用界面电阻降低组合物制造膜电极组件的方法,其可以在低压下在短时间内简单地降低电极和电解质膜之间的界面的电阻 即使使用具有高耐热性,高强度,高拉伸弹性模量和低含水量的电解质膜,也保持抑制燃料分选的效果。 这是通过制造通过将电解质膜夹在一对电极之间而形成的膜电极组件的方法来实现的,包括以下步骤:将至少一个电极粘合到电解质膜上,该电解质膜夹着含有增塑剂的界面电阻降低组合物, 所述电解质膜和通过将电解质膜夹在一对电极之间而形成的膜电极组件,其中所述膜电极组件具有至少在一个电极和所述电解质膜之间的层(A),并且所述储能模量C 当用超微量透度计测量的电解质膜和层(A)的存储模量分别被认为是C和D时,为1GPA或更高。
    • 7. 发明申请
    • Polyelectrolyte Material, Polyelectrolyte Component, Membrane Electrode Composite Body, and Polyelectrolyte Type Fuel Cell
    • 聚电解质材料,聚电解质成分,膜电极复合体和聚电解质型燃料电池
    • US20080075999A1
    • 2008-03-27
    • US11661423
    • 2005-08-30
    • Daisuke IzuharaShinya AdachiMasataka Nakamura
    • Daisuke IzuharaShinya AdachiMasataka Nakamura
    • H01M8/10C08G61/02C08G75/20
    • C08J5/2218H01B1/122H01M8/1011H01M8/1025H01M8/1027H01M8/1032H01M8/1067H01M8/1072H01M2300/0082Y02E60/523Y02P70/56
    • The present invention is to provide a polymer electrolyte material realizing excellent proton conductivity even when it comes into direct contact with liquid fuel at high temperature and high concentration, and excellent fuel barrier property and mechanical strength, as well as to provide a polymer electrolyte fuel cell of high efficiency. A polymer electrolyte material of the present invention is characterized in that fraction Rw of non-freezing water shown by the equation (S1) below is 75 to 100% by weight, and an ionic group is included, in a moisture state taken out after 12-hour immersion in 1 to 30% by weight methanol aqueous solution at 40 to 80° C. and then 24-hour immersion in pure water at 20°: Rw=[Wnf/(Wfc+Wnf)]×100  (S1) (wherein, Wnf represents an amount of non-freezing water per 1 g of dry weight of polymer electrolyte material, Wfc represents an amount of lower-melting point water per 1 g of dry weight of polymer electrolyte material). A polymer electrolyte part of the present invention is characterized by being made from such a polymer electrolyte material, a membrane electrode assembly of the present invention is characterized by being made from such a polymer electrolyte part, and a polymer electrolyte fuel cell of the present invention is formed by using by being made from such a membrane electrode assembly.
    • 本发明提供即使在与高温高浓度的液体燃料直接接触的情况下也能实现优异的质子传导性,优异的燃料阻隔性和机械强度,以及提供聚合物电解质燃料电池 高效率。 本发明的高分子电解质材料的特征在于,下述式(S1)所示的非冷冻水的分数Rw为75〜100重量%,并且包含离子性基团,在12 在40〜80℃下浸渍在1〜30重量%的甲醇水溶液中,然后在20℃的纯水中浸渍24小时:<?in-line-formula description =“In-line Formulas”end = “lead”?> Rw = [Wnf /(Wfc + Wnf)] x100(S1)<?in-line-formula description =“In-line Formulas”end =“tail”?>(其中,Wnf表示 非凝固水每1克干重的聚合物电解质材料,Wfc表示每1g干重的聚合物电解质材料的低熔点水的量)。 本发明的高分子电解质部件的特征在于,由这种高分子电解质材料制成,本发明的膜电极组件的特征在于,由这样的高分子电解质部件和本发明的固体高分子型燃料电池 通过由这种膜电极组件制成而形成。