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1. 发明授权

US07054140B2 Electrolytic capacitor and electrode foil used for electrolytic capacitor 有权
标题翻译：电解电容器和用于电解电容器的电极箔
公开(公告)号：US07054140B2
公开(公告)日：2006-05-30
申请号：US10479650
申请日：2002-05-30
申请人： Masashi Ozawa , Tatsunori Tsuji , Akio Ishii , Kazuhiro Saegusa , Kazuhiro Higuchi , Akihiro Inoue
发明人： Masashi Ozawa , Tatsunori Tsuji , Akio Ishii , Kazuhiro Saegusa , Kazuhiro Higuchi , Akihiro Inoue
IPC分类号： H01G9/00
CPC分类号： H01G9/025 , H01G9/055 , Y10T29/417
摘要： There are provided a solid electrolytic capacitor having a low ESR characteristic and an electrode foil to be used for this electrolytic capacitor. In accordance with the present invention, a capacitor element uses an anode foil with a post-etching void factor of not more than 51% or a cathode foil with another post-etching void factor of not more than 44%, wherein the capacitor element contains a solvent consisting mainly of a water and a water-soluble metal complex being bonded with phosphoric acid ions, whereby the electrode foil increases in conductivity and decreases in resistivity, while an electrolytic solution thereof has a low resistivity, to thereby obtain the solid electrolytic capacitor having the low ESR characteristic and the electrode foil to be used therefor.
摘要翻译：提供了具有低ESR特性的固体电解电容器和用于该电解电容器的电极箔。根据本发明，电容器元件使用具有不大于51％的后蚀刻空隙率的阳极箔或具有不大于44％的另一蚀刻后空隙因数的阴极箔，其中电容器元件包含主要由水和水溶性金属络合物组成的溶剂与磷酸离子结合，由此电极箔的电导率增加，电阻率降低，而电解液的电阻率低，从而得到固体电解电容器具有低ESR特性和用于此的电极箔。

2. 发明授权

US07079378B2 Electrolytic solution for electrolytic capacitor and electrolytic capacitor using the same 有权
标题翻译：电解液用于电解电容器和电解电容器使用
公开(公告)号：US07079378B2
公开(公告)日：2006-07-18
申请号：US10239206
申请日：2001-03-27
申请人： Masayuki Takeda , Takako Takahashi , Makoto Ue , Tatsunori Tsuji , Masashi Ozawa
发明人： Masayuki Takeda , Takako Takahashi , Makoto Ue , Tatsunori Tsuji , Masashi Ozawa
IPC分类号： H01G9/02
CPC分类号： H01G9/022
摘要： An object of the present invention is to provide an electrolyte for an electrolytic capacitor, which is advantageous not only in that both electric conductivity and withstand voltage property are high, but also in that thermal stability is excellent, and an electrolytic capacitor using the electrolyte. Specifically, the present invention provides an electrolyte for an electrolytic capacitor, comprising a solvent, at least one quaternary amidinium salt selected from the group consisting of a quaternary amidinium salt of a hydroxy-substituted aromatic monocarboxylic acid and a quaternary amidinium salt of phthalic acid, and metal oxide particles, and an electrolytic capacitor using the electrolyte.
摘要翻译：本发明的目的是提供一种用于电解电容器的电解质，其优点不仅在于电导率和耐电压性能都高，而且热稳定性优异，而且使用电解质的电解电容器也是有利的。具体地说，本发明提供一种电解电容器用电解液，其含有溶剂，至少一种选自羟基取代的芳香族单羧酸的季脒盐和邻苯二甲酸的季脒盐的季脒盐，和金属氧化物颗粒，以及使用电解质的电解电容器。

3. 发明授权

US09562293B2 Polymerization solution, conductive polymer film obtained from the polymerization solution, polymer electrode, and solid electrolytic capacitor 有权
标题翻译：聚合溶液，由聚合溶液获得的导电聚合物膜，聚合物电极和固体电解电容器
公开(公告)号：US09562293B2
公开(公告)日：2017-02-07
申请号：US14002248
申请日：2012-03-01
申请人： Kenji Machida , Sekihiro Takeda , Ryo Muroi , Nozomu Kamiyama , Masashi Ozawa
发明人： Kenji Machida , Sekihiro Takeda , Ryo Muroi , Nozomu Kamiyama , Masashi Ozawa
IPC分类号： H01G9/02 , H01G9/04 , H01G9/145 , H01G9/00 , C25B3/00 , C25B3/10 , H01G9/028 , H01G9/15 , C08K5/43 , H01B1/12 , H01G9/042
CPC分类号： C25B3/10 , C08G2261/3223 , C08G2261/51 , C08G2261/592 , C08G2261/94 , C08K5/43 , H01B1/127 , H01G9/0036 , H01G9/028 , H01G9/042 , H01G9/15 , Y10T428/31533 , C08L65/00
摘要： Disclosed is a polymerization solution for electrolytic polymerization having a small environmental load, having excellent economic efficiency and capable of producing a conductive polymer exhibiting excellent heat resistance. The polymerization solution has: a solvent consisting of 100 to 80% by mass of water and 0 to 20% by mass of an organic solvent; at least one monomer selected from the group consisting of 3,4-disubstituted thiophenes; and at least one organic non-sulfonate supporting electrolyte having an anion with the molecular weight of 200 or more. A conductive polymer film densely filled with polymer particles is obtained by performing electrolytic polymerization using the polymerization solution. A polymer electrode provided with the conductive polymer film exerts excellent heat resistance and the electrochemical activity of the polymer electrode will hardly deteriorate even when being subjected to high temperatures. Moreover, a solid electrolyte capacitor containing the conductive polymer layer obtained by performing electrolytic polymerization using the polymerization solution exhibits low dielectric loss and equivalent series resistance and exerts excellent heat resistance.
摘要翻译：公开了一种环境负荷小的电解聚合用聚合液，经济效益优异，能够制造具有优异耐热性的导电性聚合物。聚合溶液具有：由100〜80质量％的水和0〜20质量％的有机溶剂构成的溶剂，至少一种选自3,4-二取代噻吩的单体; 和至少一种具有分子量为200以上的阴离子的有机非磺酸盐担载电解质。通过使用聚合溶液进行电解聚合，获得密实地填充有聚合物颗粒的导电聚合物膜。设置有导电性聚合物膜的聚合物电极具有优异的耐热性，并且即使经受高温，聚合物电极的电化学活性也几乎不劣化。此外，含有通过使用聚合溶液的电解聚合获得的导电聚合物层的固体电解质电容器具有低的介电损耗和等效的串联电阻，并且具有优异的耐热性。

4. 发明授权

US09558891B2 Polymerization solution, conductive polymer film obtained from the polymerization solution, and solid electrolytic capacitor 有权
标题翻译：聚合溶液，由聚合溶液获得的导电聚合物膜和固体电解电容器
公开(公告)号：US09558891B2
公开(公告)日：2017-01-31
申请号：US14002281
申请日：2012-03-01
申请人： Kenji Machida , Sekihiro Takeda , Ryo Muroi , Nozomu Kamiyama , Masashi Ozawa
发明人： Kenji Machida , Sekihiro Takeda , Ryo Muroi , Nozomu Kamiyama , Masashi Ozawa
IPC分类号： H01G9/00 , H01G9/02 , H01G9/04 , H01G9/145 , H01G9/028 , H01G9/15
CPC分类号： H01G9/028 , C08G2261/3223 , C08G2261/51 , H01G9/0036 , H01G9/15
摘要： Disclosed is a polymerization solution for electrolytic polymerization containing borodisalicylic acid and/or a salt thereof as a supporting electrolyte, in which precipitation due to the hydrolysis of borodisalicylate ions is inhibited and which provides a conductive polymer exhibiting excellent heat resistance. The polymerization solution has: a solvent consisting of 100 to 80% by mass of water and 0 to 20% by mass of an organic solvent; at least one monomer having a π-conjugated double bond; at least one supporting electrolyte selected from the group consisting of borodisalicylic acid and borodisalicylic salts; and at least one stabilizing agent selected from the group consisting of nitrobenzene and nitrobenzene derivatives, and the content of the stabilizing agent content is more than ⅛ mol per 1 mol of the supporting electrolyte. A complex is formed by the stabilizing agent and borodisalicylic acid, and the formation of precipitation due to the hydrolysis of borodisalicylate ions is inhibited.
摘要翻译：公开了一种含有双水杨酸和/或其盐作为支持电解质的电解聚合的聚合溶液，其中由于硼二水杨酸根离子的水解引起的沉淀被抑制并且提供了具有优异的耐热性的导电聚合物。聚合溶液具有：由100〜80质量％的水和0〜20质量％的有机溶剂构成的溶剂，至少一种具有π共轭双键的单体; 至少一种选自硼二水杨酸和硼二水杨酸盐的支持电解质; 和选自硝基苯和硝基苯衍生物的至少一种稳定剂，并且每1mol支持电解质的稳定剂含量的含量大于⅛mol。络合物由稳定剂和双水杨酸形成，并且由于水杨酸水杨酸根离子形成沉淀物被抑制。

5. 发明授权

US07998360B2 Electrolysis solution for electrolytic capacitor, and electrolytic capacitor 有权
标题翻译：电解电解电解液和电解电容器
公开(公告)号：US07998360B2
公开(公告)日：2011-08-16
申请号：US12088696
申请日：2006-09-29
申请人： Masayuki Takeda , Hiroo Miyauchi , Masashi Ozawa
发明人： Masayuki Takeda , Hiroo Miyauchi , Masashi Ozawa
IPC分类号： H01G9/04
CPC分类号： H01G9/035 , H01G9/145
摘要： Provided is an electrolyte containing tetrafluoroaluminate ions, which is advantageous in that the electrolyte can be prevented from leaking from both the cathode and the anode in an electrolytic capacitor.An electrolyte for electrolytic capacitor, which comprises: (A) a tetrafluoroaluminate ion, and (B) at least one compound selected from the group consisting of: (1) at least one compound selected from the group consisting of a phthalimide, a quinoline, a dioxime, a nitrophenol and an amino group-containing aromatic carboxylic acid; (2) at least one compound selected from the group consisting of an aluminum complex, a boric acid ester and a silicic acid ester; (3) at least one compound selected from the group consisting of a monocyclic quinone compound and a bicyclic quinone compound; (4) a tricyclic or higher polycyclic quinone compound; and (5) at least one compound selected from a heteropoly acid and a salt thereof, an electrolyte for electrolytic capacitor containing a tetrafluoroaluminate ion, which has a self-potential of −0.95 V or more with respect to aluminum in the electrolyte, relative to an I3−/I− reference electrode, and an electrolytic capacitor using the same.
摘要翻译：提供了含有四氟铝酸盐离子的电解质，其优点在于可以防止电解质在电解电容器中从阴极和阳极泄漏。 1.一种电解电容器用电解质，其特征在于：（A）四氟铝酸盐离子，（B）至少一种选自下述的化合物：（1）至少一种选自邻苯二甲酰亚胺，喹啉，二肟，硝基苯酚和含氨基的芳族羧酸; （2）至少一种选自铝络合物，硼酸酯和硅酸酯的化合物; （3）至少一种选自单环醌化合物和双环醌化合物的化合物; （4）三环或更高级多环醌化合物; 和（5）选自杂多酸及其盐中的至少一种化合物，含有四氟铝酸盐离子的电解电容器用电解质，相对于电解液中的铝，其自身电位为-0.95V以上 I3- / I-参比电极和使用该电极的电解电容器。

6. 发明授权

US07256983B2 Electrolytic capacitor 有权
标题翻译：电解电容器
公开(公告)号：US07256983B2
公开(公告)日：2007-08-14
申请号：US10534235
申请日：2003-11-07
申请人： Masashi Ozawa , Masayuki Takeda , Makoto Ue
发明人： Masashi Ozawa , Masayuki Takeda , Makoto Ue
IPC分类号： H01G9/10 , H05K5/06
CPC分类号： H01G9/008 , H01G9/028 , H01G9/10
摘要： An electrolytic capacitor having a low impedance characteristic, and a high withstand voltage characteristic in the 100V class, provides excellent high temperature life and leakage characteristics. An electrolyte solution containing an aluminum tetrafluoride salt is used. Moreover, a ceramics coating layer or an insulating synthetic resin layer is formed at a contact portion with a sealing component of a rivet or a cathode leading means. Alternatively, a partial cross-linking peroxide butyl rubber with added peroxide as a cross-linking agent to a butyl rubber polymer containing isobutylene, isoprene, and divinylbenzene copolymer is used as the sealing member. The electrolytic capacitor of the present invention has a low impedance characteristic, a high withstand voltage characteristic, and an excellent high temperature life characteristic.
摘要翻译：具有低阻抗特性和100V级别的高耐压特性的电解电容器具有优异的高温寿命和漏电特性。使用含有四氟化铝盐的电解液。此外，在与铆钉或阴极引导装置的密封部件的接触部分处形成陶瓷涂层或绝缘合成树脂层。或者，使用将含有过氧化物作为交联剂的部分交联过氧化丁基橡胶与含有异丁烯，异戊二烯和二乙烯基苯共聚物的丁基橡胶聚合物用作密封构件。本发明的电解电容器具有低阻抗特性，高耐压特性和优异的高温寿命特性。

7. 发明申请

US20100326570A1 HIGH-STRENGTH QUENCHED FORMED BODY WITH GOOD CORROSION RESISTANCE AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译：具有良好耐腐蚀性的高强度淬火成型体及其制造方法
公开(公告)号：US20100326570A1
公开(公告)日：2010-12-30
申请号：US12880537
申请日：2010-09-13
申请人： Shinichi Suzuki , Toshimasa Tomokiyo , Shuuji Souma , Katsuji Nakashima , Masashi Ozawa , Kiyohito Kondou
发明人： Shinichi Suzuki , Toshimasa Tomokiyo , Shuuji Souma , Katsuji Nakashima , Masashi Ozawa , Kiyohito Kondou
IPC分类号： C23C2/28 , C21D1/60 , C21D1/613
CPC分类号： B32B15/013 , C21D1/673 , C21D8/0278 , C23C2/26 , C23C2/28 , Y10T428/12493 , Y10T428/12549 , Y10T428/12611 , Y10T428/12618 , Y10T428/12799 , Y10T428/12972 , Y10T428/12979 , Y10T428/273
摘要： A high-strength quenched formed body containing a layer on the surface of an after-quenching formed-body steel material in which layer Zn is a major component and which layer contains 30% by mass or less of Fe, and which layer is present in an amount of 30 g/m2 or more. A quenched formed body is produced by quenching a zinc-plated steel material which includes a zinc-plated layer containing each of Al and Si having alloying-retarding function and readily-oxidizing function independently or compositely, in an amount of 0.15% by mass or more, after heating it to 800° C. or more and 950° C. or less in an oxidizing atmosphere containing 0.1% by volume or more of oxygen.
摘要翻译：一种高强度淬火成型体，其在层状Zn为主要成分的层叠体中含有30质量％以下的Fe的淬火后的成形体钢材的表面上含有层，用量为30g / m2以上。通过淬火镀锌钢材制备淬火成形体，该镀锌钢材包含含有Al和Si的镀层，其具有合金化阻滞功能和容易氧化功能，独立或复合地以0.15质量％的量或在含有0.1体积％以上的氧气的氧化气氛中加热至800℃以上且950℃以下。

8. 发明授权

US07648459B2 Ultrasonic probe 有权
标题翻译：超声波探头
公开(公告)号：US07648459B2
公开(公告)日：2010-01-19
申请号：US10550835
申请日：2004-03-24
申请人： Junichi Takeda , Masashi Ozawa
发明人： Junichi Takeda , Masashi Ozawa
IPC分类号： A61B8/00
CPC分类号： G10K9/18 , A61B8/4455
摘要： An ultrasonic probe according to the present invention includes: an ultrasonic element for transmitting and receiving an ultrasonic signal; a signal line for transmitting an electric signal to or from the ultrasonic element; and a ground line for supplying a ground potential to the ultrasonic element. The ultrasonic element is connected electrically with a sensor signal substrate and a sensor ground substrate. These substrates are connected electrically with the signal line and the ground line, respectively, via a cable substrate. The sensor ground substrate and the cable substrate are connected directly or via a relay ground substrate.
摘要翻译：根据本发明的超声波探头包括：超声波元件，用于发送和接收超声波信号; 用于向超声波元件发送电信号的信号线; 以及用于向超声波元件提供接地电位的接地线。超声波元件与传感器信号基板和传感器接地基板电连接。这些基板分别经由电缆基板与信号线和接地线电连接。传感器接地基板和电缆基板直接连接或通过继电器接地基板连接。

9. 发明申请

US20090303664A1 ELECTROLYTIC CAPACITOR 审中-公开
标题翻译：电解电容器
公开(公告)号：US20090303664A1
公开(公告)日：2009-12-10
申请号：US12093514
申请日：2006-11-15
申请人： Fusayoshi Endoh , Kentaro Nakaaki , Masashi Ozawa , Koichi Yoshida , Osamu Nakamura
发明人： Fusayoshi Endoh , Kentaro Nakaaki , Masashi Ozawa , Koichi Yoshida , Osamu Nakamura
IPC分类号： H01G9/025
CPC分类号： H01G9/045 , H01G9/008 , H01G9/055 , H01G9/145
摘要： An electrolytic capacitor employs a capacitor element wherein an anode foil having an anode internal terminal and a cathode foil having a cathode internal terminal are wound or laminated through a separator. The end of the anode foil faces the cathode foil through the separator and the surface area of the cathode internal terminal is provided with an enlargement treatment, whereby the small area portion of the cathode foil that faces with the anode foil is eliminated, improving the charge/discharge characteristics. Furthermore, in the electrolytic capacitor provided with the capacitor element wherein the anode foil having the anode internal terminal and the cathode foil having the cathode internal terminal are wound or laminated through the separator, the capacitor element being impregnated with an electrolyte, the cathode internal terminal includes an aluminum material, the surface of the cathode internal terminal is etched and iron concentration in the etching layer
摘要翻译：电解电容器采用电容器元件，其中具有阳极内部端子的阳极箔和具有阴极内部端子的阴极箔通过隔板缠绕或层压。阳极箔的端部通过隔膜面向阴极箔，并且阴极内部端子的表面积被提供放大处理，从而消除了与阳极箔面对的阴极箔的小面积部分，从而改善电荷 /放电特性。此外，在设置有电容器元件的电解电容器中，其中具有阳极内部端子的阳极箔和具有阴极内部端子的阴极箔通过隔板卷绕或层压，电容器元件浸渍有电解质，阴极内部端子包括铝材料，阴极内部端子的表面被蚀刻，并且蚀刻层中的铁浓度<300ppm。

10. 发明申请

US20080019079A1 ELECTROLYTIC CAPACITOR 有权
标题翻译：电解电容器
公开(公告)号：US20080019079A1
公开(公告)日：2008-01-24
申请号：US11828829
申请日：2007-07-26
申请人： Masashi Ozawa , Masayuki Takeda , Makoto Ue
发明人： Masashi Ozawa , Masayuki Takeda , Makoto Ue
IPC分类号： H01G9/00 , H01G4/228
CPC分类号： H01G9/008 , H01G9/02 , H01G9/035 , H01G9/045 , H01G9/151 , Y10T29/41 , Y10T29/417
摘要： An electrolytic capacitor having a low impedance characteristic, having a high withstand voltage characteristic of 100V class, wherein the electrolytic capacitor provides an excellent high temperature life characteristic and an excellent leakage characteristic. The electrolyte solution containing the aluminum tetrafluoride salt is used. The electrolytic capacitor of the present invention has a low impedance characteristic, a high withstand voltage characteristic, and an excellent high temperature life characteristic. Moreover, the aforementioned electrolyte solution is used, and a foil showing noble potential at least in the electrolyte solution than the electrode potential of the cathode tab, or a cathode electrode foil subjected to chemical treatment is used as the cathode electrode foil, so as to obtain an excellent leakage characteristic.
摘要翻译：具有低阻抗特性的电解电容器具有100V等级的高耐压特性，其中电解电容器提供优异的高温寿命特性和优异的泄漏特性。使用含有四氟化铝盐的电解液。本发明的电解电容器具有低阻抗特性，高耐压特性和优异的高温寿命特性。此外，使用上述电解质溶液，并且使用至少在电解质溶液中显示比阴极片的电极电位或具有化学处理的阴极箔的电位高的箔作为阴极电极箔，以便获得极好的泄漏特性。

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