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    • 6. 发明申请
    • Diene rubber composition and process for producing the same
    • 二烯橡胶组合物及其制备方法
    • US20070037916A1
    • 2007-02-15
    • US10543541
    • 2004-01-30
    • Kazutaka WatanabeOsamu YatabeTakeshi KaratoYoshihiro ChinoTakahiko Fukahori
    • Kazutaka WatanabeOsamu YatabeTakeshi KaratoYoshihiro ChinoTakahiko Fukahori
    • C08K3/34
    • C08K3/36B60C1/00B60C1/0016B60C1/0025B60C15/06B60C2009/0021C08J3/215C08J2321/00C08L21/00C08L101/02C08L2666/02
    • The present invention is to provide a diene rubber composition and a cross-linked diene rubber thereof excellent in tensile strength, wear resistance and processability, keeping compatibility of both good fuel efficiency and high gripping property, and a production method thereof. What is characterized in the composition is that the composition is comprised of 100 parts by weight of a diene rubber having a molecular weight distribution expressed in terms of the ratio of the weight-average molecular weight to the number-average molecular weight of 1.1 to 30, 20 to 200 parts by weight of silica and a cationic polymer, and that a toluene-insoluble rubber content per gram of the silica within the range from 0.2 to 1 g, and diene cross-linked rubber thereof. What is characterized in the production method is that the method comprises steps of allowing rubber latex stabilized by an anionic emulsifying agent to react with an aqueous suspension of silica containing a cationic polymer and effecting co-coagulation of rubber in the rubber latex with the silica in the aqueous suspension within a specific pH range.
    • 本发明提供一种二烯橡胶组合物及其抗拉强度,耐磨性和加工性优异的交联二烯橡胶,兼具良好的燃料效率和高夹持性的兼容性及其制造方法。 组合物的特征在于该组合物由100重量份的二烯橡胶组成,二烯橡胶的分子量分布以重均分子量与数均分子量的比率表示为1.1至30 ,20〜200重量份的二氧化硅和阳离子性聚合物,每克二氧化硅的甲苯不溶性橡胶含量在0.2〜1g的范围内,和二烯交联橡胶。 制造方法的特征在于,该方法包括以下步骤:使由阴离子乳化剂稳定的橡胶胶乳与含有阳离子聚合物的二氧化硅水溶液悬浮液反应,并使橡胶胶乳中的橡胶与二氧化硅共混 水性悬浮液在特定pH范围内。
    • 7. 发明授权
    • Diene rubber composition and process for producing the same
    • 二烯橡胶组合物及其制备方法
    • US07619028B2
    • 2009-11-17
    • US10543541
    • 2004-01-30
    • Kazutake WatanabeOsamu YatabeTakeshi KaratoYoshihiro ChinoTakahiko Fukahori
    • Kazutake WatanabeOsamu YatabeTakeshi KaratoYoshihiro ChinoTakahiko Fukahori
    • C08K3/36C08J3/16
    • C08K3/36B60C1/00B60C1/0016B60C1/0025B60C15/06B60C2009/0021C08J3/215C08J2321/00C08L21/00C08L101/02C08L2666/02
    • The present invention is to provide a diene rubber composition and a cross-linked diene rubber thereof excellent in tensile strength, wear resistance and processability, keeping compatibility of both good fuel efficiency and high gripping property, and a production method thereof. What is characterized in the composition is that the composition is comprised of 100 parts by weight of a diene rubber having a molecular weight distribution expressed in terms of the ratio of the weight-average molecular weight to the number-average molecular weight of 1.1 to 30, 20 to 200 parts by weight of silica and a cationic polymer, and that a toluene-insoluble rubber content per gram of the silica within the range from 0.2 to 1 g, and diene cross-linked rubber thereof. What is characterized in the production method is that the method comprises steps of allowing rubber latex stabilized by an anionic emulsifying agent to react with an aqueous suspension of silica containing a cationic polymer and effecting co-coagulation of rubber in the rubber latex with the silica in the aqueous suspension within a specific pH range.
    • 本发明提供一种二烯橡胶组合物及其抗拉强度,耐磨性和加工性优异的交联二烯橡胶,兼具良好的燃料效率和高夹持性的兼容性及其制造方法。 组合物的特征在于该组合物由100重量份的二烯橡胶组成,二烯橡胶的分子量分布以重均分子量与数均分子量的比率表示为1.1至30 ,20〜200重量份的二氧化硅和阳离子性聚合物,每克二氧化硅的甲苯不溶性橡胶含量在0.2〜1g的范围内,和二烯交联橡胶。 制造方法的特征在于,该方法包括以下步骤:使由阴离子乳化剂稳定的橡胶胶乳与含有阳离子聚合物的二氧化硅水溶液悬浮液反应,并使橡胶胶乳中的橡胶与二氧化硅共混 水性悬浮液在特定pH范围内。
    • 10. 发明授权
    • Modified conjugated diene polymer, process for producing same and
composition comprising same
    • 改性共轭二烯聚合物,其制备方法及其组合物
    • US5844050A
    • 1998-12-01
    • US586813
    • 1996-01-29
    • Takahiko FukahoriKiyoshi Inamura
    • Takahiko FukahoriKiyoshi Inamura
    • C08C19/44C08F36/04C08F8/32
    • C08C19/44C08F36/04
    • A modified polymer prepared by terminally modifying a conjugated diene polymer obtained by polymerization using a lanthanoid-containing catalyst in an organic solvent, with an N-substituted amino active compound, and having Mw of 100,000-1,000,000, a monomodal Mw-distribution, Mw/Mn of 1.3-5, and a terminal modification of at least 50%. The modified polymer is produced by (1) polymerizing a conjugated diene by using a catalyst which is either a mixture of (i) a reaction product of a lanthanoid-containing compound with an organoaluminum hydride and then with a Lewis base, and (ii) a halo-compound, or is a reaction product of (i) with (ii) prepared by reacting a portion of conjugated diene monomer prior to reaction of (ii); and then (2) terminally modifying the obtained living polymer with an N-substituted amino active compound.
    • PCT No.PCT / JP94 / 01258 Sec。 371日期1996年1月29日 102(e)日期1996年1月29日PCT 1994年8月1日PCT PCT。 第WO95 / 04090号公报 日期:1995年2月9日通过使用含有镧系元素的催化剂在有机溶剂中与N-取代的氨基活性化合物进行聚合得到的共轭二烯聚合物,Mw为100,000-1,000,000,单峰Mw 分布,Mw / Mn为1.3-5,末端修饰为至少50%。 改性聚合物通过以下方法制备:(1)通过使用(i)含镧系元素的化合物与有机氢化铝的反应产物然后与路易斯碱的混合物的混合物来共聚共轭二烯,和(ii) 或者(i)与(ii)的反应产物,其通过在(ii)的反应之前使一部分共轭二烯单体反应制备; 然后(2)用N-取代的氨基活性化合物末端改性得到的活性聚合物。