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    • 8. 发明授权
    • Polyisocyanate compound, process for producing the same and optical materials using the same
    • 多异氰酸酯化合物,其制造方法和使用其的光学材料
    • US06194603B1
    • 2001-02-27
    • US09362094
    • 1999-07-28
    • Yoshitaka KitaharaJian Jiang
    • Yoshitaka KitaharaJian Jiang
    • C07C24900
    • C07C323/25C08G18/3876C08G18/775G02B1/04C08L75/04
    • A novel polyisocyanate compound, which compound is useful as a starting material for an optical material having excellent optical characteristics such as a high refractive index and a low dispersion, and a process for producing this compound at good efficiency. Specifically, a polyisocyanate compound represented by general formula (I): wherein Z represents a direct bond, or —CH2—. The invention also relates to processes for producing the desired polyisocyanate compound through a tricarboxylic acid ester and a tricarbonyl hydrazide using a dihalogeno-aliphatic carboxylic acid lower alkyl ester and a thioglycolic acid lower alkyl ester. In addition, the invention relates to optical materials, such as lenses, etc., made by a polyaddition reaction of compounds of formula (I) and other monomers.
    • 一种新颖的多异氰酸酯化合物,该化合物可用作具有优异的光学特性如高折射率和低分散性的光学材料的起始材料,以及以高效率生产该化合物的方法。 具体地,由通式(I)表示的多异氰酸酯化合物:其中Z表示直接键或-CH 2 - 。 本发明还涉及使用二卤代脂族羧酸低级烷基酯和巯基乙酸低级烷基酯通过三羧酸酯和三羰基酰肼生产所需多异氰酸酯化合物的方法。 此外,本发明涉及通过式(I)化合物与其它单体的加成反应制备的光学材料,例如透镜等。
    • 10. 发明申请
    • Transparent molded article
    • 透明成型品
    • US20060149018A1
    • 2006-07-06
    • US11296526
    • 2005-12-08
    • Yoshitaka Kitahara
    • Yoshitaka Kitahara
    • C08G18/00
    • C08G18/792C08G18/3876C08G18/6254G02B1/04C08L75/04
    • Provided are a transparent molded article comprised of polythiourethane obtained by polymerizing monomer components comprising the following component (A) and component (131) and a transparent molded article obtained by polymerizing monomer components comprising the following component (A), component (B1), component (B2) and component (C). Component (A): One or More Polythiol Compound Denoted by General Formula (I) General Formula (I) (In general formula (I), m is 1, 2, 3, 4, 5 or 6.) Component (B1): One or More Polyisocyanate Compound Denoted by General Formula (II) General Formula (II) (In general formula (II), n1, n2 and n3 are each independently 3, 4, 5, 6, 7 or 8.) Component (B2): One or More Aliphatic Dilsocyanate Compound Having an Intramolecular Cyclic Stucture Component (C): aliphatic diol compound
    • 本发明提供一种透明的模制品,其由通过聚合包含以下组分(A)和组分(131)的单体组分得到的聚硫氨酯和通过聚合包含以下组分(A),组分(B1),组分 (B2)和组分(C)。 组分(A):通式(I)表示的一种或多种聚硫醇化合物通式(I)(通式(I)中,m为1,2,3,4,5或6.)组分(B1): 一种或多种通式(II)表示的多异氰酸酯化合物通式(II)(通式(II)中,n 1,n 2和n 3 组分(B2):具有分子内环状结构的一种或多种脂肪族二异氰酸酯化合物组分(C):脂族二醇化合物