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1. 发明授权

US5902765A Solid catalyst components for olefin polymerization 失效
标题翻译：用于烯烃聚合的固体催化剂组分
公开(公告)号：US5902765A
公开(公告)日：1999-05-11
申请号：US799231
申请日：1997-02-14
申请人： Hirotoshi Takahashi , Yasushi Kuroda , Masaki Fushimi , Shintaro Inazawa
发明人： Hirotoshi Takahashi , Yasushi Kuroda , Masaki Fushimi , Shintaro Inazawa
IPC分类号： C08F4/60 , C08F4/654 , C08F10/00 , C08F4/649
CPC分类号： C08F10/00
摘要： Solid catalyst components for olefin polymerization which comprise a solid carrier components comprising a solid substance having the general formulaMgX.sub.2.(E).sub.n ( 1)wherein X is a halogen atom, E is a monoether compound and n is 0.01.about.4, at least a portion of said E being replaced by an eletron donative compound different from said monoether compound (E), and a titanium compound and these catalyst components can produce an olefin polymer having a high stereoregularity in a high polymer yield per unit of a catalyst component in olefin polymerization.
摘要翻译：用于烯烃聚合的固体催化剂组分，其包含固体载体组分，其包含具有通式MX2的固体物质（E）n（1）其中X为卤素原子，E为单醚化合物，n为0.01。所述E的部分被不同于所述单醚化合物（E）的电子捐赠化合物代替，并且钛化合物和这些催化剂组分可以以每单位烯烃中的催化剂组分的高聚合物产率产生具有高立构规整性的烯烃聚合物聚合。

2. 发明授权

US06906154B2 Catalyst for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US06906154B2
公开(公告)日：2005-06-14
申请号：US10181170
申请日：2001-11-12
申请人： Masaki Fushimi , Hirotoshi Takahashi
发明人： Masaki Fushimi , Hirotoshi Takahashi
IPC分类号： C08F4/654 , C08F4/649 , C08F4/651 , C08F10/00 , C08F110/06 , C08F4/42
CPC分类号： C08F110/06 , C08F4/6494 , C08F4/651 , C08F2500/12
摘要： The present invention relates to catalyst components for the polymerization of olefins comprising a titanium compound, having at least a Ti-halogen bond, and at least two electron donor compounds supported on a Mg dihalide, said catalyst component being characterized by the fact that at least one of the electron donor compounds is selected from ethers containing two or more ether groups which are further characterized by the formation of complexes with anhydrous magnesium dichloride in an amount less than 60 mmoles per 100 g of MgCl2 and by the failure of entering into substitution reactions with TiCl4 or by reacting in that way for less than 50% by moles, and at least another electron donor compound is selected from esters of mono or polycarboxylic acids. Said catalyst components are able to produce propylene polymers which, for high values of xylene insolubility, show a broad range of isotacticity.
摘要翻译：本发明涉及用于聚合烯烃的催化剂组分，其包含至少具有Ti-卤键的钛化合物和至少两个负载在二卤化镁上的电子给体化合物，所述催化剂组分的特征在于至少电子给体化合物之一选自含有两个或更多个醚基的醚，其进一步的特征在于与无水二氯化镁形成络合物，其量小于60毫摩尔/ 100g MgCl 2，和由于不能与TiCl 4进行取代反应，或者以这种方式反应少于50摩尔％，并且至少另一个电子给体化合物选自单羧酸或多元羧酸的酯。所述催化剂组分能够生产丙烯聚合物，其对于高二甲苯不溶性值显示出广泛的全同立构规整度。

3. 发明授权

US5049533A Catalyst, process for preparation of same, and process for polymerization of olefins using same 失效
标题翻译：催化剂，其制备方法以及使用其的烯烃的聚合方法
公开(公告)号：US5049533A
公开(公告)日：1991-09-17
申请号：US551238
申请日：1990-07-11
申请人： Tetuo Nakajo , Hisayoshi Yanagihara , Masaki Fushimi , Shigenobu Miyake , Hideki Sakurai
发明人： Tetuo Nakajo , Hisayoshi Yanagihara , Masaki Fushimi , Shigenobu Miyake , Hideki Sakurai
IPC分类号： C08F4/658 , C08F4/60 , C08F4/64 , C08F4/654 , C08F10/00
CPC分类号： C08F10/00
摘要： Disclosed is a catalyst composition for use in the polymerization of olefins, which is comprised of (a) a catalyst component containing magnesium, titanium, a halogen, and an ingredient derived from a keto-ester compound, and (b) an organic aluminum compound. The catalyst activity and capability of providing a highly stereoregular polymer are enhanced by preparing the catalyst component (a) by a process wherein, during or after the formation of a solid catalyst component containing magnesium, titanium, and a halogen, the solid catalyst component is treated with a keto-ester of the formula: ##STR1## wherein R.sup.1, R.sup.2 and Z represent a hydrocarbon group.

4. 发明申请

US20130102744A1 Catalyst Systems for the Polymerization of Olefins 审中-公开
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：US20130102744A1
公开(公告)日：2013-04-25
申请号：US13806641
申请日：2011-06-06
申请人： Masaki Fushimi , Simona Guidotti , Marc Oliver Kristen , Alessandro Mignogna , Giampiero Morini , Joachim T.M. Pater
发明人： Masaki Fushimi , Simona Guidotti , Marc Oliver Kristen , Alessandro Mignogna , Giampiero Morini , Joachim T.M. Pater
IPC分类号： C08F4/649
CPC分类号： C08F4/6494 , C08F10/06 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F4/651
摘要： A catalyst system comprising the product obtained by contacting (a) a solid catalyst component containing Mg, Ti, halogen and at least an electron donor compound selected from 1,3-diethers; (b) an alkylaluminum cocatalyst; and (c) an ester of formula ROOC—(CH2)n—COOR in which n is an integer from 2 to 8, R groups, equal to or different from each other, are C1-C10 alkyl groups.
摘要翻译：一种催化剂体系，其包含通过使（a）含有Mg，Ti，卤素和至少一种选自1,3-二醚的电子给体化合物的固体催化剂组分接触获得的产物; （b）烷基铝助催化剂; 和（c）式为ROOC-（CH 2）n -COOR的酯，其中n为2至8的整数，R基彼此相同或不同，为C 1 -C 10烷基。

5. 发明授权

US06271167B1 Catalyst for olefin polymerization and method for preparing polyolefins 有权
标题翻译：用于烯烃聚合的催化剂和制备聚烯烃的方法
公开(公告)号：US06271167B1
公开(公告)日：2001-08-07
申请号：US09478197
申请日：2000-01-05
申请人： Masaki Fushimi , Toshio Fujita , Shintaro Inazawa
发明人： Masaki Fushimi , Toshio Fujita , Shintaro Inazawa
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C07F7/1804 , C08F4/6465
摘要： Disclosed are a catalyst for polymerizing olefins containing a solid catalyst component containing titanium, magnesium and halogen as essential components (component (A)); an organic aluminum compound (component (B)); and a silane compound (component (C)) represented by general formula (1) wherein R1 and R2 independently represent a straight, branched or cyclic saturated aliphatic hydrocarbon group or a silyl group, a method of preparing polyolefins using the catalyst as well as novel trimethoxysilane compounds represented by the general formula (1) in which R1 is a straight saturated aliphatic hydrocarbon group having 2 to 10 carbon atoms, and R2 represents a methyl group. Use of the catalyst enables efficient production of polyolefins having a low molecular weight (MFR>20 (g/10 minutes)), a broad molecular weight distribution (MLMFR/MFR>22) and a high stereoregularity when applied to polymerization of olefins having 3 or more carbon atoms.
摘要翻译：公开了含有含有钛，镁和卤素作为必要成分的固体催化剂组分（组分（A））的烯烃聚合催化剂; 有机铝化合物（组分（B））; 和由通式（1）表示的硅烷化合物（组分（C）），其中R 1和R 2独立地表示直链，支链或环状饱和脂族烃基或甲硅烷基，使用该催化剂制备聚烯烃的方法以及新颖的由通式（1）表示的三甲氧基硅烷化合物，其中R1是具有2-10个碳原子的直链饱和脂族烃基，R2代表甲基。使用该催化剂可有效地生产具有低分子量（MFR> 20（g / 10分钟）），宽分子量分布（MLMFR / MFR> 22）和高立构规整性的聚烯烃，当用于具有3 或更多的碳原子。

6. 发明授权

US6096844A Catalst for olefin polymerization and process for producing polyolefin using the same 失效
标题翻译：用于烯烃聚合的催化剂和使用其制备聚烯烃的方法
公开(公告)号：US6096844A
公开(公告)日：2000-08-01
申请号：US136747
申请日：1998-08-19
申请人： Masaki Fushimi , Yasushi Kuroda , Shintaro Inazawa
发明人： Masaki Fushimi , Yasushi Kuroda , Shintaro Inazawa
IPC分类号： C07F7/18 , C08F4/646 , C08F4/649 , C08F4/654 , C08F4/658 , C08F10/00
CPC分类号： C07F7/188 , C08F10/00
摘要： A catalyst for olefin polymerization comprising: (A) a solid catalyst component comprising a titanium compound, a magnesium compound, and a halogen compound; (B) an organoaluminum compound; (C) a first organosilicon compound represented by formula (I): ##STR1## wherein R.sup.1 represents a hydrocarbon group having 1 to 4 carbon atoms; R.sup.2 represents a hydrocarbon group having 1 to 6 carbon atoms or a hydrogen atom; R.sup.3 and R.sup.4 each represent a hydrocarbon group having 1 to 6 carbon atoms; and R.sup.2, R.sup.3, and R.sup.4 may be the same or different; and (D) a second organosilicon compound represented by formula (II): ##STR2## wherein R.sup.5 represents a hydrocarbon group having 1 to 4 carbon atoms; and R.sup.6, R.sup.7, and R.sup.8, which may be the same or different, each represent a hydrocarbon group having 1 to 6 carbon atoms or a hydrogen atom.
摘要翻译：一种用于烯烃聚合的催化剂，包括：（A）包含钛化合物，镁化合物和卤素化合物的固体催化剂组分; （B）有机铝化合物; （C）由式（I）表示的第一有机硅化合物：其中R1表示具有1至4个碳原子的烃基; R2表示碳原子数1〜6的烃基或氢原子; R 3和R 4各自表示具有1〜6个碳原子的烃基; 并且R 2，R 3和R 4可以相同或不同; 和（D）由式（II）表示的第二有机硅化合物：其中R 5表示具有1至4个碳原子的烃基; 和R 6，R 7和R 8可以相同或不同，表示碳原子数为1〜6的烃基或氢原子。

7. 发明授权

US6063727A Catalyst for olefin polymerization and method for preparing polyolefins 失效
标题翻译：用于烯烃聚合的催化剂和制备聚烯烃的方法
公开(公告)号：US6063727A
公开(公告)日：2000-05-16
申请号：US868673
申请日：1997-06-04
申请人： Masaki Fushimi , Toshio Fujita , Shintaro Inazawa
发明人： Masaki Fushimi , Toshio Fujita , Shintaro Inazawa
IPC分类号： C07F7/18 , C08F4/646 , C08F4/658 , C08F10/00 , B01J31/00
CPC分类号： C07F7/1836 , C08F10/00
摘要： Disclosed are a catalyst for polymerizing olefins containing a solid catalyst component containing titanium, magnesium and halogen as essential components (component (A)); an organic aluminum compound (component (B)); and a silane compound (component (C)) represented by general formula (1) ##STR1## wherein R.sup.1 and R.sup.2 independently represent a straight, branched or cyclic saturated aliphatic hydrocarbon group or a silyl group, a method of preparing polyolefins using the catalyst as well as novel trimethoxysilane compounds represented by the general formula (1) in which R.sup.1 is a straight saturated aliphatic hydrocarbon group having 2 to 10 carbon atoms, and R.sup.2 represents a methyl group. Use of the catalyst enables efficient production of polyolefins having a low molecular weight (MFR>20 (g/10 minutes)), a broad molecular weight distribution (MLMFR/MFR>22) and a high stereoregularity when applied to polymerization of olefins having 3 or more carbon atoms.
摘要翻译：公开了含有含有钛，镁和卤素作为必要成分的固体催化剂组分（组分（A））的烯烃聚合催化剂; 有机铝化合物（组分（B））; 和由通式（1）表示的硅烷化合物（组分（C）），其中R 1和R 2独立地表示直链，支链或环状饱和脂族烃基或甲硅烷基，使用该催化剂制备聚烯烃的方法以及新颖的由通式（1）表示的三甲氧基硅烷化合物，其中R1是具有2-10个碳原子的直链饱和脂族烃基，R2代表甲基。使用该催化剂可有效地生产具有低分子量（MFR> 20（g / 10分钟）），宽分子量分布（MLMFR / MFR> 22）和高立构规整性的聚烯烃，当用于具有3 或更多的碳原子。

8. 发明授权

US5476825A Catalyst for polymerization of olefin and process for producing olefin polymer 失效
标题翻译：烯烃聚合催化剂和烯烃聚合物生产方法
公开(公告)号：US5476825A
公开(公告)日：1995-12-19
申请号：US085901
申请日：1993-07-06
申请人： Masaki Fushimi , Toshio Fujita , Minoru Suzuki
发明人： Masaki Fushimi , Toshio Fujita , Minoru Suzuki
IPC分类号： C08F4/654 , C08F4/60 , C08F4/646 , C08F10/00 , B01J31/00
CPC分类号： C08F10/00
摘要： A catalyst for polymerization of olefin, which is capable of producing an olefin polymer with high stereoregularity and narrow molecular weight distribution, and which comprises (1) a solid catalyst component essentially containing titanium, magnesium and halogen, 2) an organoaluminum compound, and (3) a contact product of (A) an organometallic compound and (B) an organosilicon compound; and a process for producing a polymer using the above catalyst.
摘要翻译：一种烯烃聚合催化剂，其能够制备具有高立构规整性和窄分子量分布的烯烃聚合物，并且其包括（1）基本上含有钛，镁和卤素的固体催化剂组分，2）有机铝化合物和（ 3）（A）有机金属化合物和（B）有机硅化合物的接触产物; 以及使用上述催化剂制造聚合物的方法。

9. 发明申请

US20120220739A1 Catalyst for the Polymerization of Olefins 审中-公开
标题翻译：烯烃聚合催化剂
公开(公告)号：US20120220739A1
公开(公告)日：2012-08-30
申请号：US13321488
申请日：2010-05-31
申请人： Masaki Fushimi , Martin Schneider , Giampiero Morini
发明人： Masaki Fushimi , Martin Schneider , Giampiero Morini
IPC分类号： C08F4/649 , C08F210/02
CPC分类号： C08F10/02 , C08F4/6465
摘要： The present invention relates to catalysts systems for the polymerization of ethylene and its mixtures with olefins CH2═CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising (A) a solid catalyst component comprising Ti, Mg, halogen, and optionally an electron donor compound in a donor/Ti molar ratio lower than 1, (B) an aluminum alkyl compound and (C) a silicon compound of formula RImSi(ORII)n in which RI is C1-C20 alkyl group, RII is a secondary or tertiary alkyl group or a cycloalkyl having from 3 to 20 carbon atoms, m is an integer ranging from 0 to 3, and n is (4-m). The catalyst of the invention is suitably used in (co)polymerization processes of ethylene to prepare (co)polymers having narrow Molecular Weight Distribution (MWD) and high activity.
摘要翻译：本发明涉及用于乙烯及其与烯烃CH 2 = CHR的混合物的聚合的催化剂体系，其中R是具有1-12个碳原子的烷基，环烷基或芳基，其包含（A）固体催化剂组分，其包含Ti，Mg ，卤素和任选的供体/ Ti摩尔比低于1的电子给体化合物，（B）烷基铝化合物和（C）式RImSi（ORII）n的硅化合物，其中R 1是C 1 -C 20烷基 RII为仲或叔烷基或碳原子数3〜20的环烷基，m为0〜3的整数，n为（4-m）。本发明的催化剂适用于乙烯的（共）聚合方法，以制备具有窄分子量分布（MWD）和高活性的（共）聚合物。

10. 发明申请

US20120130031A1 PROCESS FOR THE PREPARATION OF ETHYLENE POLYMERS WITH NARROW MOLECULAR WEIGHT DISTRIBUTION 审中-公开
标题翻译：制备具有窄分子量分布的乙烯聚合物的方法
公开(公告)号：US20120130031A1
公开(公告)日：2012-05-24
申请号：US13387106
申请日：2010-08-02
申请人： Masaki Fushimi , Dario Liguori , Tiziano Dall'Occo , Giampiero Morini , Joachim T.M. Pater , Gianni Vitale
发明人： Masaki Fushimi , Dario Liguori , Tiziano Dall'Occo , Giampiero Morini , Joachim T.M. Pater , Gianni Vitale
IPC分类号： C08F4/76
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6494 , C08F2500/12 , C08F2500/04 , C08F210/06
摘要： Process for the preparation of ethylene polymers having narrow MWD characterized by a F/E ratio lower than 35 carried out in the presence of a catalyst system comprising (a) a solid catalyst component comprising Ti atoms that are substantially in the +4 oxidation state, Mg, Cl, and optionally OR groups and internal donors in which R is a C1-C20 hydrocarbon group, in which the OR/Ti molar ratio is equal to or lower than 0.35 and the internal donor/Ti ratio is lower than 1, (b) an aluminum alkyl compound and (c) a compound selected from alkoxybenzenes of specified formula.
摘要翻译：制备具有窄MWD的乙烯聚合物的方法，其特征在于在催化剂体系存在下进行F / E比低于35的乙烯聚合物，其包含（a）包含基本上处于+4氧化态的Ti原子的固体催化剂组分， Mg，Cl和任选的OR基团和其中R是C1-C20烃基的内给体，其中OR / Ti摩尔比等于或低于0.35，内给体/ Ti比低于1（ b）烷基铝化合物和（c）选自具有规定式的烷氧基苯的化合物。

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