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    • 1. 发明授权
    • Method for reducing carbon dioxide
    • 减少二氧化碳的方法
    • US08597488B2
    • 2013-12-03
    • US13485285
    • 2012-05-31
    • Masahiro DeguchiYuji ZenitaniReiko TaniguchiSatoshi Yotsuhashi
    • Masahiro DeguchiYuji ZenitaniReiko TaniguchiSatoshi Yotsuhashi
    • C25B3/00C25B1/00
    • C25B3/04B01J27/24
    • The method for reducing carbon dioxide of the present disclosure includes a step (a) and a step (b) as follows. A step (a) of preparing an electrochemical cell. The electrochemical cell comprises a working electrode, a counter electrode and a vessel. The vessel stores an electrolytic solution. The working electrode contains at least one nitride selected from the group consisting of titanium nitride, zirconium nitride, hafnium nitride, tantalum nitride, molybdenum nitride and iron nitride. The electrolytic solution contains carbon dioxide. The working electrode and the counter electrode are in contact with the electrolytic solution. A step (b) of applying a negative voltage and a positive voltage to the working electrode and the counter electrode, respectively, to reduce the carbon dioxide.
    • 本公开的减少二氧化碳的方法包括如下步骤(a)和步骤(b)。 制备电化学电池的步骤(a)。 电化学电池包括工作电极,对电极和容器。 容器存储电解液。 工作电极含有选自氮化钛,氮化锆,氮化铪,氮化钽,氮化钼和氮化铁中的至少一种氮化物。 电解液含有二氧化碳。 工作电极和对电极与电解液接触。 分别对工作电极和对电极施加负电压和正电压以减少二氧化碳的步骤(b)。
    • 2. 发明申请
    • METHOD FOR REDUCING CARBON DIOXIDE
    • 减少二氧化碳的方法
    • US20120234691A1
    • 2012-09-20
    • US13485285
    • 2012-05-31
    • Masahiro DeguchiYuji ZenitaniReiko TaniguchiSatoshi Yotsuhashi
    • Masahiro DeguchiYuji ZenitaniReiko TaniguchiSatoshi Yotsuhashi
    • C25B3/04
    • C25B3/04B01J27/24
    • The method for reducing carbon dioxide of the present disclosure includes a step (a) and a step (b) as follows. A step (a) of preparing an electrochemical cell. The electrochemical cell comprises a working electrode, a counter electrode and a vessel. The vessel stores an electrolytic solution. The working electrode contains at least one nitride selected from the group consisting of titanium nitride, zirconium nitride, hafnium nitride, tantalum nitride, molybdenum nitride and iron nitride. The electrolytic solution contains carbon dioxide. The working electrode and the counter electrode are in contact with the electrolytic solution. A step (b) of applying a negative voltage and a positive voltage to the working electrode and the counter electrode, respectively, to reduce the carbon dioxide.
    • 本公开的减少二氧化碳的方法包括如下步骤(a)和步骤(b)。 制备电化学电池的步骤(a)。 电化学电池包括工作电极,对电极和容器。 容器存储电解液。 工作电极含有选自氮化钛,氮化锆,氮化铪,氮化钽,氮化钼和氮化铁中的至少一种氮化物。 电解液含有二氧化碳。 工作电极和对电极与电解液接触。 分别对工作电极和对电极施加负电压和正电压以减少二氧化碳的步骤(b)。
    • 6. 发明授权
    • Method for reducing carbon dioxide
    • 减少二氧化碳的方法
    • US08414758B2
    • 2013-04-09
    • US13453669
    • 2012-04-23
    • Masahiro DeguchiSatoshi YotsuhashiYuka Yamada
    • Masahiro DeguchiSatoshi YotsuhashiYuka Yamada
    • C25B3/04H01M6/30H01M8/22
    • C25B1/003C25B1/00C25B3/04
    • A device for reducing carbon dioxide includes a cathode chamber including a cathode electrolyte solution and a cathode electrode, an anode chamber including an anode electrolyte solution and an anode electrode, and a solid electrolyte membrane. The anode electrode includes a nitride semiconductor region on which a metal layer is formed. The metal layer includes at least one of nickel and titanium. A method for reducing carbon dioxide by using a device for reducing carbon dioxide includes steps of providing carbon dioxide into the cathode solution, and irradiating at least part of the nitride semiconductor region and the metal layer with a light having a wavelength of 250 nanometers to 400 nanometers, thereby reducing the carbon dioxide contained in the cathode electrolyte solution.
    • 一种二氧化碳还原装置包括阴极室,包括阴极电解质溶液和阴极电极,阳极室包括阳极电解质溶液和阳极电极以及固体电解质膜。 阳极包括形成有金属层的氮化物半导体区域。 金属层包括镍和钛中的至少一种。 通过使用用于还原二氧化碳的装置来还原二氧化碳的方法包括向阴极溶液中提供二氧化碳的步骤,以及使用波长为250纳米至400埃的光照射至少部分氮化物半导体区域和金属层 纳米,从而减少阴极电解质溶液中所含的二氧化碳。
    • 8. 发明申请
    • Thermoelectric conversion element and method of manufacturing the same, and thermoelectric conversion device using the element
    • 热电转换元件及其制造方法,以及使用该元件的热电转换元件
    • US20060107990A1
    • 2006-05-25
    • US11194698
    • 2005-08-02
    • Hideaki AdachiSatoshi YotsuhashiYasunari SugitaTsutomu Kanno
    • Hideaki AdachiSatoshi YotsuhashiYasunari SugitaTsutomu Kanno
    • H01L35/30H01L35/28
    • H01L35/32
    • The present invention provides a thermoelectric conversion element that has high efficiency even at reduced thickness. In this thermoelectric conversion element, striped p-type thermoelectric conversion parts are arranged on one surface of an insulating layer, and striped n-type thermoelectric conversion parts are arranged on the other surface. The two sets of stripes form overlapped portions. At one or more of the overlapped portions, a first p-type thermoelectric conversion part and a first n-type thermoelectric conversion part are electrically connected via a first conducting portion arranged within the insulating layer, a second p-type thermoelectric conversion part and a second n-type thermoelectric conversion part are electrically connected via a second conducting portion arranged within the insulating layer, and the first conducting portion and the second conducting portion are electrically isolated. The element of the present invention provides two junctions in a region where a conventional element would provide only one junction.
    • 本发明提供即使在减小的厚度下也具有高效率的热电转换元件。 在该热电转换元件中,在绝缘层的一个表面上配置有条纹p型热电转换部,在另一面上配置有条纹状的n型热电转换部。 两组条纹形成重叠部分。 在一个或多个重叠部分中,第一p型热电转换部分和第一n型热电转换部分经由布置在绝缘层内的第一导电部分,第二p型热电转换部分和 第二n型热电转换部分经由布置在绝缘层内的第二导电部分电连接,并且第一导电部分和第二导电部分电隔离。 本发明的元件在常规元件仅提供一个结的区域中提供两个结。
    • 9. 发明授权
    • Power generation method using thermoelectric element, thermoelectric element and fabrication method thereof, and thermoelectric device
    • 使用热电元件的发电方法,热电元件及其制造方法以及热电元件
    • US07601909B2
    • 2009-10-13
    • US12013795
    • 2008-01-14
    • Tsutomu KannoHideaki AdachiSatoshi Yotsuhashi
    • Tsutomu KannoHideaki AdachiSatoshi Yotsuhashi
    • H01L35/12
    • H01L35/32H01L35/18H01L35/34Y10T29/49112
    • The invention provides a power generation method using a thermoelectric element, a thermoelectric element, and a thermoelectric device that excel in thermoelectric performance and are applicable to a wider range of applications over conventional counterparts. The element includes a first electrode and a second electrode that are disposed to oppose each other, and a laminate interposed between the first and second electrodes and electrically connected to both of the electrodes. The laminate has a structure in which a Bi layer and a metal layer made of a metal other than Bi are alternately layered, and the Bi layer and the metal layer having layer surfaces that are slanted with respect to a direction in which the first and second electrodes oppose each other. The element generates a potential difference between the electrodes by a temperature difference created along a direction perpendicular to the opposing direction of the first and second electrodes in the element. The power generation method and the thermoelectric device use this element.
    • 本发明提供一种使用热电性能优异的热电元件,热电元件和热电元件的发电方法,并且适用于比现有技术的更广泛的应用。 元件包括彼此相对设置的第一电极和第二电极,以及插入在第一和第二电极之间并且电连接到两个电极的层压体。 层叠体具有Bi层和由Bi以外的金属构成的金属层交替层叠的结构,并且Bi层和金属层具有相对于第一和第二层的方向倾斜的层表面 电极彼此相对。 该元件通过沿着与元件中的第一和第二电极的相反方向垂直的方向产生的温度差产生电极之间的电位差。 发电方法和热电装置使用这个元件。
    • 10. 发明授权
    • Electric power generation method using thermoelectric power generation element, thermoelectric power generation element and method of producing the same, and thermoelectric power generation device
    • 使用热电发电元件的发电方法,热电发电元件及其制造方法以及热电发电装置
    • US07560639B2
    • 2009-07-14
    • US12055882
    • 2008-03-26
    • Tsutomu KannoHideaki AdachiSatoshi Yotsuhashi
    • Tsutomu KannoHideaki AdachiSatoshi Yotsuhashi
    • H01L35/34H01L35/16
    • H01L35/16H01L35/32H01L35/34Y10T156/1062
    • The present invention provides an electric power generation method using a thermoelectric power generation element, a thermoelectric power generation element, and a thermoelectric power generation device, each of which has higher thermoelectric power generation performance than conventional ones and can be used for more applications. The thermoelectric power generation element includes a first electrode and a second electrode that are disposed to oppose each other, and a laminate that is interposed between the first and second electrodes and that is electrically connected to both the first and second electrodes, where the laminate has a structure in which Bi2Te3 layers and metal layers containing Al, Cu, Ag, or Au are laminated alternately, a thickness ratio between the metal layer and the Bi2Te3 layer is in a range of metal layer:Bi2Te3 layer=400:1 to 20:1, lamination surfaces of the Bi2Te3 layers and the metal layers are inclined at an inclination angle θ of 15° to 60° with respect to a direction in which the first electrode and the second electrode oppose each other, and a temperature difference applied in a direction perpendicular to the direction in the element generates a potential difference between the first and second electrodes. The electric power generation method and thermoelectric power generation device each use the element.
    • 本发明提供了一种使用热电发电元件,热电发电元件和热电发电装置的发电方法,其具有比常规热电发电性能更高的热电发电性能,并且可用于更多应用。 热电发电元件包括​​彼此相对设置的第一电极和第二电极,以及插入在第一和第二电极之间并且与第一和第二电极两者电连接的层压体,其中层压体 其中Bi 2 Te 3层和含有Al,Cu,Ag或Au的金属层交替层叠的结构,金属层和Bi 2 Te 3层之间的厚度比在金属层的范围内:Bi 2 Te 3层= 400:1〜20: 如图1所示,Bi2Te3层和金属层的层压面以相对于第一电极和第二电极相对的方向为15°〜60°的倾斜角θ倾斜,并且在 与元件中的方向垂直的方向产生第一和第二电极之间的电位差。 发电方法和热电发电装置均使用该元件。