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    • 1. 发明授权
    • Mesopore molecular sieve and process for the production thereof
    • Mesopore分子筛及其制备方法
    • US06284696B1
    • 2001-09-04
    • US09202046
    • 1999-03-23
    • Masahiko KoyaHitoshi NakajimaItsuho Aishima
    • Masahiko KoyaHitoshi NakajimaItsuho Aishima
    • B01J2906
    • B01J29/0308C01B37/00C01B37/02
    • A mesopore molecular sieve having a hydrocarbon group bonded directly to a silicon atom in the metal oxide skeleton constituting the molecular sieve, wherein the content of said hydrocarbon group is from 0.01 to 0.6 mol per mol of the metal oxide. Also disclosed is a process for producing a mesopore molecular sieve having a hydrocarbon atom bonded to a silicon atom in the molecular sieve skeleton, which comprises synthesizing the mesopore molecular sieve, in the presence of a template, from: a silane compound represented by the following formula (1): RnSiX(4−n)  (1) wherein R represents a hydrocarbon group selected from C1-16 hydrocarbon groups and hydrocarbon groups substituted with an N—, O-, S-, P- or halogen-containing group; n represents 1, 2 or 3; and X is selected from C1-6 alkoxy groups, aryloxy groups, a hydroxyl group and halogen atoms and a plurality of X may be the same or different; and a metal oxide and/or a precursor thereof. According to this process for producing a mesopore molecular sieve, a mesopore molecular sieve can be readily synthesized in one stage and, in addition, a mesopore molecular sieve having an excellent performance as an acid catalyst or oxidation catalyst can be obtained because the kind and amount of the hydrocarbon group can be easily adjusted.
    • 具有直接结合构成分子筛的金属氧化物骨架中的硅原子的烃基的中孔分子筛,其中所述烃基的含量相对于每摩尔金属氧化物为0.01〜0.6摩尔。 还公开了一种制备具有与分子筛骨架中的硅原子键合的烃原子的中孔分子筛的方法,该方法包括在模板存在下合成中孔分子筛:由以下化合物表示的硅烷化合物 式(1):其中R表示选自C 1-6烃基和被N,O-,S-,P-或卤素基团取代的烃基的烃基; n表示1,2或3; X选自C 1-6烷氧基,芳氧基,羟基和卤原子,多个X可以相同或不同; 和金属氧化物和/或其前体。 根据该中孔分子筛的制造方法,可以在一个阶段容易地合成中孔分子筛,另外可以得到作为酸催化剂或氧化催化剂的具有优异性能的中孔分子筛,因为种类和量 的烃基可以容易地调节。
    • 9. 发明授权
    • Thermal deformation member for electron tube and color picture tube
using thereof, and thermal deformation member for electric current
control and circuit breaker and using thereof
    • 用于电子管和彩色显像管的热变形构件,以及用于电流控制和断路器的热变形构件及其使用
    • US6069437A
    • 2000-05-30
    • US29089
    • 1998-02-19
    • Toshiharu MatsukiSatoru HabuHitoshi Nakajima
    • Toshiharu MatsukiSatoru HabuHitoshi Nakajima
    • H01H71/16H01J29/07H01J29/96H01J29/80
    • H01H71/16H01J29/073H01J29/96H01H2037/526H01H2037/528H01J2229/0711
    • A high thermal expansion member consisting of such as an Fe--Ni--Cr based alloy, a low thermal expansion member consisting of such as an Fe--Ni based alloy, and an intermediary member, which comprises one kind of metal selected from Fe, Al and Cu or an alloy comprising these metals, possesses a thermal expansion coefficient .alpha..sub.3 which is located between those of the high thermal expansion member (thermal expansion coefficient .alpha..sub.1) and the low thermal expansion member (thermal expansion coefficient .alpha..sub.2) (.alpha..sub.1 >.alpha..sub.3 >.alpha..sub.2), and is interposed therebetween, are laminated to form a thermal deformation member for an electron tube or a thermal deformation member for electric control. The intermediary member, without adversely affecting strength or long term reliability of the thermal deformation member, contributes to manufacturing cost reduction and improvement of workability. In a color picture tube, the above described thermal deformation member for an electron tube is employed in a thermal deformation portion of a frame holder which one edge is solidly stuck to a panel and the other edge thereof is solidly stuck to a mask frame of a shadow mask. In an overcurrent protection, the above described thermal deformation member for electric current control is employed in a thermal deformation portion which opens a contact point.
    • PCT No.PCT / JP97 / 02101 Sec。 371日期1998年2月19日 102(e)日期1998年2月19日PCT提交1997年6月19日PCT公布。 公开号WO97 / 49110 日期:1997年12月24日由Fe-Ni-Cr系合金,Fe-Ni系合金等构成的低热膨胀部件和中间部件构成的高热膨胀部件,包括一种金属 选自Fe,Al和Cu或包含这些金属的合金,具有位于高热膨胀构件(热膨胀系数α1)和低热膨胀构件(热膨胀系数α1)的热膨胀系数α3之间的热膨胀系数α3 2)(α1α3>α2),并且夹在它们之间,以形成用于电子管的热变形构件或用于电控制的热变形构件。 中间构件不会不利地影响热变形构件的强度或长期可靠性,有助于制造成本降低和可加工性的提高。 在彩色显象管中,将上述的电子管用热变形部件用于框架保持件的热变形部分,其中一个边缘牢固地粘到面板上,另一个边缘坚固地粘贴在面罩框架上 阴影面具 在过电流保护中,上述用于电流控制的热变形部件被用于打开接触点的热变形部分。