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    • 3. 发明授权
    • Biaxially oriented polyester film to be laminated onto metal plate and molded
    • 将双轴取向的聚酯薄膜层压在金属板上并成型
    • US06472046B1
    • 2002-10-29
    • US09367593
    • 1999-08-18
    • Koji KuboHirofumi MurookaMasahiko KosugeHideshi Kurihara
    • Koji KuboHirofumi MurookaMasahiko KosugeHideshi Kurihara
    • B32B516
    • B32B15/09B29C55/12B32B15/08B32B27/20B32B27/36B32B38/12B32B2307/518B32B2367/00B32B2439/66C08J5/18C08J2367/02Y10S428/91Y10T156/1036Y10T156/1038Y10T156/1043Y10T156/1048Y10T428/24355Y10T428/249981Y10T428/25Y10T428/259Y10T428/31681Y10T428/31786
    • A biaxially oriented polyester film to be laminated onto a metal plate and molded, (A) which comprises a copolyester comprising (a) terephthalic acid in an amount of 82 to 100 mol % and 2,6-naphthalenedicarboxylic acid or a combination of 2,6-naphthalenedicarboxylic acid and other dicarboxylic acid in an amount of 0 to 18 mol % of the total of all dicarboxylic acid components and (b) ethylene glycol in an amount of 82 to 100 mol % and cyclohexanedimethanol or a combination of cyclohexanedimethanol and other diol in an amount of 0 to 18 mol % of the total of all diol components, having (c) a glass transition temperature of 78° C. or more and (d) a melting point of 210 to 250° C., and containing (e) porous silica particles with a pore volume of 0.5 to 2.0 ml/g which are agglomerates of primary particles having an average particle diameter of 0.001 to 0.1 &mgr;m; and (B) which has the following relationship between the highest peak temperature (Te, °C.) of loss elastic modulus and the glass transition temperature (Tg, °C.): Te−Tg≦30. This film has improved taste-and-flavor retainabilities, particularly taste and flavor retainabilities after a retort treatment, without losing the excellent moldability, heat resistance, impact resistance and retort resistance of a copolyester film.
    • 将层压在金属板上并成型的双轴取向聚酯膜(A),其包含共聚酯,该共聚酯包含(a)82〜100摩尔%的对苯二甲酸和2,6-萘二羧酸或2〜 (b)82〜100摩尔%的乙二醇和环己烷二甲醇或环己烷二甲醇与其他二醇的组合的量为0〜18摩尔%的二羧酸和6-萘二羧酸 (c)玻璃化转变温度为78℃以上,(d)熔点为210〜250℃,含有( e)孔体积为0.5〜2.0ml / g的多孔二氧化硅粒子,其为平均粒径为0.001〜0.1μm的一次粒子的凝聚体; 和(B),其在损耗弹性模量的最高峰值温度(Te,℃)与玻璃化转变温度(Tg,℃)之间具有以下关系:Te-Tg <= 30。 该膜具有改善的口味和味道保留性,特别是在蒸煮处理后的味道和风味保持性,而不失去共聚聚酯薄膜的优异成型性,耐热性,耐冲击性和耐蒸煮性。
    • 4. 发明授权
    • Biaxially oriented polyester film to be laminated onto a metal plate and
molded
    • 将双轴取向的聚酯薄膜层压到金属板上并成型
    • US6086989A
    • 2000-07-11
    • US91190
    • 1998-06-10
    • Koji KuboHirofumi MurookaMasahiko KosugeManabu Kimura
    • Koji KuboHirofumi MurookaMasahiko KosugeManabu Kimura
    • B32B15/08B32B27/36C08J5/18B32B31/04
    • C08J5/18B32B15/08B32B27/36C08J2367/02Y10S428/91Y10T428/264Y10T428/269
    • A biaxially oriented polyester film to be laminated onto a metal plate and molded, which comprises a copolyester, said copolyester comprising (a) terephthalic acid in an amount of 82 to 100 mol % and 2,6-naphthalenedicarboxylic acid or a combination of 2,6-naphthalenedicarboxylic acid and other dicarboxylic acids in an amount of 0 to 18 mol % of the total of all dicarboxylic acid components and (b) ethylene glycol in an amount of 82 to 100 mol % and cyclohexanedimethanol or a combination of cyclohexanedimethanol and other diols in an amount of 0 to 18 mol % of the total of all diol components, and having (c) a glass transition temperature of 78.degree. C. or higher and (d) a melting point of 210 to 250.degree. C. The said film has the following relationship between the highest peak temperature (Te, .degree. C.) of loss elastic modulus and the glass transition temperature (Tg, .degree. C.): Te-Tg.ltoreq.30, or its content of a free dicarboxylic acid diol ester is 50 ppm or less. The said film has improved flavor retention properties for its contents taste, particularly taste and flavor retention properties after a retort treatment, while retaining excellent moldability, heat resistance, impact resistance.
    • PCT No.PCT / JP97 / 03643 Sec。 371日期:1998年6月10日 102(e)1998年6月10日PCT 1997年10月9日PCT PCT。 公开号WO98 / 16573 日期:1998年4月23日将双轴取向聚酯薄膜层叠在金属板上并成型为包含共聚酯的共聚酯,所述共聚酯包含(a)82至100摩尔%的对苯二甲酸和2,6-萘二羧酸,或 2,6-萘二羧酸和其它二羧酸的组合,其量为所有二羧酸组分总量的0至18摩尔%,和(b)82至100摩尔%的乙二醇和环己烷二甲醇或其组合 的环己烷二甲醇和其它二醇的量为所有二醇组分总量的0至18摩尔%,并且(c)玻璃化转变温度为78℃或更高,(d)熔点为210至250℃ C.所述膜在损耗弹性模量的最高峰值温度(Te,℃)和玻璃化转变温度(Tg,℃)之间具有以下关系:Te-Tg = 30或其含量 游离二羧酸二醇酯的含量为50ppm以下。 所述薄膜在蒸煮处理后具有改善其含量味道,特别是味道和香味保留性能的风味保持性,同时保持优异的成型性,耐热性,耐冲击性。
    • 6. 发明授权
    • Biaxially oriented laminate polyester film for magnetic recording medium
    • 用于磁记录介质的双轴取向叠层聚酯薄膜
    • US06670030B1
    • 2003-12-30
    • US09582820
    • 2000-07-03
    • Toshikazu UchidaMitsuo TojoToshifumi OsawaAkira KameokaTomokatsu UraMasahiko Kosuge
    • Toshikazu UchidaMitsuo TojoToshifumi OsawaAkira KameokaTomokatsu UraMasahiko Kosuge
    • B32B516
    • G11B5/733Y10S428/90Y10S428/923Y10S428/924Y10S428/926Y10T428/25Y10T428/26Y10T428/269Y10T428/31786
    • A biaxially oriented laminate polyester film for magnetic recording medium, which is a laminate film comprising a base layer (A) formed of a polyester resin and a coating layer (B) which exists on one surface of the base layer (A) and contains a binder resin, added fine particles and a surfactant, wherein the base layer (A) is a biaxially oriented film which substantially contains no fine particles added or contains 0.001 to 0.1% by weight of added fine particles having an average particle diameter of 0.005 to 0.3 &mgr;m, the coating layer (B) has a surface having a central plane roughness (SRa) of 5 nm or less, the surface of the coating layer (B) has protrusions having a major diameter of 0.05 &mgr;m or more in a density of 80,000 pieces/mm2 or less and has extra-large protrusions having a major diameter of 10 &mgr;m or more in a density of 20 pieces/cm2 or less. Further, a thin film layer (C) may be further laminated on a surface on the side of the base layer (A) of the laminate polyester film which side is not in contact with the coating layer (B). According to the present invention, there is provided a biaxially oriented laminate polyester film useful as a base film for a magnetic recording medium which has excellent running durability and electromagnetic conversion characteristics and is almost free from drop-out.
    • 一种用于磁记录介质的双轴取向叠层聚酯膜,它是一种层叠膜,它是由聚酯树脂形成的基层(A)和在基层(A)的一个表面上存在的涂层(B))构成的, 粘合剂树脂,添加的微粒和表面活性剂,其中,基层(A)是基本不含有微粒子的双轴取向膜,或者含有0.001〜0.1重量%的平均粒径为0.005〜0.3的微粒子 所述涂布层(B)具有中心平面粗糙度(SRa)为5nm以下的表面,所述涂布层(B)的表面的密度为80,000以下,具有0.05μm以上的大径的突起 片/ mm 2或更小,并且具有20个/ cm 2或更小的密度的大直径为10μm或更大的超大突起。 此外,也可以在层叠聚酯膜的与涂层(B)不接触的一侧的基材层(A)侧的表面上进一步层叠薄膜层(C)。根据本发明 提供了一种双轴取向的层叠聚酯薄膜,其可用作磁记录介质的基膜,其具有优异的运行耐久性和电磁转换特性,几乎不会脱落。
    • 9. 发明授权
    • Biaxially oriented polyethylene naphthalate copolymer film
    • 双轴取向聚萘二甲酸乙二醇酯共聚物膜
    • US6048627A
    • 2000-04-11
    • US214435
    • 1999-01-05
    • Ryoji TsukamotoMitsuru TeramotoSeiji ItoMasahiko Kosuge
    • Ryoji TsukamotoMitsuru TeramotoSeiji ItoMasahiko Kosuge
    • C08G63/193C08G63/60C08J5/18G03C1/795G11B5/73G03C3/02C08G63/02
    • C08J5/18C08G63/193C08G63/60G03C1/7954G11B5/7305C08J2367/02Y10S428/908
    • A biaxially oriented film which is made substantially of (1) a polyethylene naphthalate copolymer comprising an ethylene naphthalate unit in an amount of 92 to 99.5 mol % based on all recurring units and at least one copolymer component selected from the group consisting of (a) a glycol having a fluorene skeleton in the molecule, (b) p-hydroxymethylbenzoic acid, (c) p-hydroxyethoxybenzoic acid and (d) p-hydroxyethoxyethoxybenzoic acid in an amount of 0.5 to 8 mol % based on the total of all dicarboxylic acid components, and which has (2) Young's moduli in both longitudinal and transverse directions of 500 kg/mm.sup.2 or more and (3) a delamination resistance of 10% or less in terms of fold line whitening ratio. Since this biaxially oriented film of the present invention is excellent in delamination resistance, curling resistance, mechanical strength, color and transparency, it is of great value as a base film for a photo film.
    • PCT No.PCT / JP98 / 02002 Sec。 371日期1999年1月5日 102(e)日期1999年1月5日PCT提交1998年5月1日PCT公布。 公开号WO98 / 50456 日期1998年11月12日一种双轴取向膜,其基本上由(1)聚萘二甲酸乙二醇酯共聚物制成,所述聚萘二甲酸乙二醇酯共聚物包含基于所有重复单元的92至99.5mol%的萘二甲酸乙二醇酯单元和至少一种选自以下的共聚物组分 由(a)分子中具有芴骨架的二醇,(b)对羟基甲基苯甲酸,(c)对羟基乙氧基苯甲酸和(d)对羟基乙氧基乙氧基苯甲酸,其量为0.5〜8摩尔% 所有二羧酸组分的总和,(2)纵向和横向上的杨氏模量为500kg / mm 2以上,(3)折线增白率为10%以下的耐层压性。 由于本发明的双轴取向膜具有优异的耐分层性,抗卷曲性,机械强度,颜色和透明性,因此作为照相胶片的基膜具有很大的价值。