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1. 发明授权

US6048627A Biaxially oriented polyethylene naphthalate copolymer film 失效
标题翻译：双轴取向聚萘二甲酸乙二醇酯共聚物膜
公开(公告)号：US6048627A
公开(公告)日：2000-04-11
申请号：US214435
申请日：1999-01-05
申请人： Ryoji Tsukamoto , Mitsuru Teramoto , Seiji Ito , Masahiko Kosuge
发明人： Ryoji Tsukamoto , Mitsuru Teramoto , Seiji Ito , Masahiko Kosuge
IPC分类号： C08G63/193 , C08G63/60 , C08J5/18 , G03C1/795 , G11B5/73 , G03C3/02 , C08G63/02
CPC分类号： C08J5/18 , C08G63/193 , C08G63/60 , G03C1/7954 , G11B5/7305 , C08J2367/02 , Y10S428/908
摘要： A biaxially oriented film which is made substantially of (1) a polyethylene naphthalate copolymer comprising an ethylene naphthalate unit in an amount of 92 to 99.5 mol % based on all recurring units and at least one copolymer component selected from the group consisting of (a) a glycol having a fluorene skeleton in the molecule, (b) p-hydroxymethylbenzoic acid, (c) p-hydroxyethoxybenzoic acid and (d) p-hydroxyethoxyethoxybenzoic acid in an amount of 0.5 to 8 mol % based on the total of all dicarboxylic acid components, and which has (2) Young's moduli in both longitudinal and transverse directions of 500 kg/mm.sup.2 or more and (3) a delamination resistance of 10% or less in terms of fold line whitening ratio. Since this biaxially oriented film of the present invention is excellent in delamination resistance, curling resistance, mechanical strength, color and transparency, it is of great value as a base film for a photo film.
摘要翻译： PCT No.PCT / JP98 / 02002 Sec。 371日期1999年1月5日 102（e）日期1999年1月5日PCT提交1998年5月1日PCT公布。公开号WO98 / 50456 日期1998年11月12日一种双轴取向膜，其基本上由（1）聚萘二甲酸乙二醇酯共聚物制成，所述聚萘二甲酸乙二醇酯共聚物包含基于所有重复单元的92至99.5mol％的萘二甲酸乙二醇酯单元和至少一种选自以下的共聚物组分由（a）分子中具有芴骨架的二醇，（b）对羟基甲基苯甲酸，（c）对羟基乙氧基苯甲酸和（d）对羟基乙氧基乙氧基苯甲酸，其量为0.5〜8摩尔％所有二羧酸组分的总和，（2）纵向和横向上的杨氏模量为500kg / mm 2以上，（3）折线增白率为10％以下的耐层压性。由于本发明的双轴取向膜具有优异的耐分层性，抗卷曲性，机械强度，颜色和透明性，因此作为照相胶片的基膜具有很大的价值。

2. 发明授权

US6124043A Biaxially oriented film 有权
标题翻译：双轴取向薄膜
公开(公告)号：US6124043A
公开(公告)日：2000-09-26
申请号：US331848
申请日：1999-06-28
申请人： Ryoji Tsukamoto , Seiji Ito , Mitsuru Teramoto , Shinya Watanabe , Koji Furuya , Shinichi Kawai , Kenji Suzuki
发明人： Ryoji Tsukamoto , Seiji Ito , Mitsuru Teramoto , Shinya Watanabe , Koji Furuya , Shinichi Kawai , Kenji Suzuki
IPC分类号： B29C55/12 , C08J5/18 , G03C1/795 , G11B5/73 , B32B27/06 , G03C1/76 , C08G63/18
CPC分类号： C08J5/18 , B29C55/12 , G03C1/7954 , G11B5/73 , B29K2067/00 , C08J2367/02 , Y10S428/90 , Y10S428/902
摘要： A biaxially oriented film (1) which is substantially formed from a polyethylene naphthalate copolymer comprising ethylene-2,6-naphthalate units in an amount of 90 to 99.9 mol % based on the total of all recurring units and an isophthalic acid component or a decalin-2,6-dicarboxylic acid component in an amount of 0.1 to 10 mol % based on the total of all dicarboxylic acid components and which has (2) Young's modulus of 500 kg/mm.sup.2 or more in each of a longitudinal direction and a transverse direction, (3) a plane orientation coefficient of 0.230 to 0.275 and (4) a density of 1.350 g/cm.sup.3 or more.
摘要翻译： PCT No.PCT / JP98 / 04871 Sec。 371日期1999年6月28日第 102（e）1999年6月28日PCT PCT 1998年10月28日PCT公布。出版物WO99 / 21912 PCT 日期1999年5月6日一种双轴取向膜（1），其基本上由聚萘二甲酸乙二醇酯共聚物形成，该聚萘二甲酸乙二醇酯共聚物包含基于所有重复单元总数为90-99.9摩尔％的乙烯 - 2,6-萘二甲酸酯单元和间苯二甲酸组分或十氢化萘-2,6-二羧酸组分，其量相对于所有二羧酸组分的总量为0.1至10mol％，并且其具有（2）每个纵向中的杨氏模量为500kg / mm 2或更大方向和横向，（3）平面取向系数为0.230〜0.275，（4）密度为1.350g / cm3以上。

3. 发明授权

US06525165B1 Trimethylene-2, 6-naphthalene dicarboxylate (co)polymer film, quaternary phosphonium sulfonate copolymer and compositions thereof 有权
标题翻译：三亚甲基-2,6-萘二甲酸酯（共）聚合物膜，季鏻磺酸盐共聚物及其组合物
公开(公告)号：US06525165B1
公开(公告)日：2003-02-25
申请号：US09720991
申请日：2001-01-03
申请人： Ryoji Tsukamoto , Takafumi Kudo , Masahiko Kosuge , Tomokatsu Ura , Hideshi Kurihara , Shinichi Kawai , Shinya Watanabe , Koji Furuya , Makoto Handa , Kenji Suzuki
发明人： Ryoji Tsukamoto , Takafumi Kudo , Masahiko Kosuge , Tomokatsu Ura , Hideshi Kurihara , Shinichi Kawai , Shinya Watanabe , Koji Furuya , Makoto Handa , Kenji Suzuki
IPC分类号： C08G6300
CPC分类号： B32B27/36 , B32B27/08 , B32B2307/412 , B32B2307/518 , B32B2307/54 , B32B2307/5825 , B32B2307/7145 , B32B2307/72 , B32B2307/7242 , B32B2367/00 , B32B2439/70 , C08G63/189 , C08G63/6926 , C08G63/85 , C08J5/18 , C08J2367/02
摘要： An aromatic polyester film, which comprises an aromatic polyester comprising 2,6-naphthalenedicarboxylic acid as the main dicarboxylic acid component and 1,3-propanediol as the main diol component and having a density of at least 1.310 g/cm3. A laminated film comprising another polyester layer can be formed from this aromatic polyester film. An aromatic polyester containing a small amount of a sulfonic acid phosphonium salt used as one of the aromatic polyesters forming this laminated film is excellent in electrostatic casting properties and resistance to the contamination of an electrostatic wire, and an aromatic polyester containing an inorganic anti-fungus agent is used for antifungal application.
摘要翻译：一种芳族聚酯膜，其包含以2,6-萘二甲酸为主要二羧酸组分的芳族聚酯和1,3-丙二醇作为主要二醇组分，其密度至少为1.310g / cm3。可以由该芳族聚酯膜形成包含另一聚酯层的层叠膜。作为形成该层叠膜的芳香族聚酯之一，含有少量磺酸鏻盐的芳香族聚酯具有优异的静电铸造性和抗静电丝的污染性，以及含有无机抗真菌的芳香族聚酯试剂用于抗真菌应用。

4. 发明授权

US07544762B2 Catalyst for preparation of polyester and process for preparing polyester using the catalyst 有权
标题翻译：用于制备聚酯的催化剂和使用该催化剂制备聚酯的方法
公开(公告)号：US07544762B2
公开(公告)日：2009-06-09
申请号：US10483611
申请日：2002-07-16
申请人： Tomoyoshi Yamamoto , Hiroki Nagano , Minoru Suzuki , Hiroshi Toyao , Tomoyuki Kishino , Nobuo Minobe , Ryoji Tsukamoto , Kenichi Ishihara
发明人： Tomoyoshi Yamamoto , Hiroki Nagano , Minoru Suzuki , Hiroshi Toyao , Tomoyuki Kishino , Nobuo Minobe , Ryoji Tsukamoto , Kenichi Ishihara
IPC分类号： C08G63/00 , C08G63/85
CPC分类号： C08J5/18 , C08G63/127 , C08G63/85 , C08G63/87 , C08J2367/02 , D01F6/62
摘要： A polyester having a good color tone (a high L value and a low b value) and a low acetaldehyde content is obtained by using a catalyst containing a reaction product of (A) a titanium compound (1) represented by the general formula (I) and/or a titanium compound (2) obtained by reacting the titanium compound (1) of the general formula (I) with an aromatic polyhydric carboxylic acid represented by the general formula (II) or an anhydride thereof, with (B) a phosphorus compound (3) represented by the general formula (III). [wherein R1, R2, R3, R4 and R5=a C2-C10 alkyl group, k=1 to 3, m=2 to 4, and R6=a substituted or non-substituted C6-C20 aryl group or a C6-C20 alkyl group].
摘要翻译：通过使用含有（A）由通式（I）表示的钛化合物（1）的反应产物的催化剂，得到具有良好色调（高L值和低b值）和低乙醛含量的聚酯）和/或通过使通式（I）的钛化合物（1）与由通式（II）表示的芳族多元羧酸或其酸酐反应得到的钛化合物（2）与（B）由通式（III）表示的磷化合物（3）。 [其中R1，R2，R3，R4和R5 = C2-C10烷基，k = 1〜3，m = 2〜4，R6 =取代或未取代的C6〜C20芳基或C6-C20 烷基]。

5. 发明申请

US20060210797A1 Modified cross-section polyester fibers 审中-公开
标题翻译：改性横截面聚酯纤维
公开(公告)号：US20060210797A1
公开(公告)日：2006-09-21
申请号：US10542048
申请日：2003-12-25
申请人： Tsuyoshi Masuda , Mie Kamiyama , Tomoo Mizumura , Nobuyoshi Miyasaka , Ryoji Tsukamoto , Keijiro Hattori , Suguru Nakajima , Katushi Kikuchi , Hiroyuki Osaka
发明人： Tsuyoshi Masuda , Mie Kamiyama , Tomoo Mizumura , Nobuyoshi Miyasaka , Ryoji Tsukamoto , Keijiro Hattori , Suguru Nakajima , Katushi Kikuchi , Hiroyuki Osaka
IPC分类号： D02G3/00
CPC分类号： D01D5/253 , C08G63/181 , C08G63/85 , C08K5/51 , D01F6/62 , Y10T428/2973 , Y10T428/2975 , Y10T428/2976 , Y10T428/2978
摘要： Polyester fibers having a deformed section are produced from a polyester polymer which is obtained by polycondensing an aromatic dicarboxylate ester in the presence of a catalyst containing a mixture of a Ti component (A) comprising at least one a titanium alkoxide or a reaction product thereof with a specific carboxylic acid or its anhydride with a P compound component (B) represented by the following general formula (III) and/or a reaction product of a Ti compound component (C) with a P compound component (D) represented by the following general formula (IV). The obtained fibers have a favorable color tone and excellent qualities without showing fluffing.
摘要翻译：具有变形部分的聚酯纤维由聚酯聚合物制成，所述聚酯聚合物通过在含有包含至少一种钛醇盐或其反应产物的Ti组分（A）或其反应产物的混合物的催化剂存在下使芳族二羧酸酯缩聚得到，具有下述通式（III）表示的P化合物成分（B）和/或Ti化合物成分（C）与P化合物成分（D）的反应产物的特定羧酸或其酸酐与下述通式通式（IV）。得到的纤维具有良好的色调和优异的品质而不显示起毛。

6. 发明授权

US07462682B2 Orthochromatic polyester resin composition and molding product thereof 有权
标题翻译：正色聚酯树脂组合物及其成型产品
公开(公告)号：US07462682B2
公开(公告)日：2008-12-09
申请号：US10526664
申请日：2004-06-30
申请人： Ryoji Tsukamoto
发明人： Ryoji Tsukamoto
IPC分类号： C08G63/00
CPC分类号： D01F6/92 , C08K5/0041 , C08L67/02
摘要： A tinted polyester resin composition having good color and useful for many uses (fibers, films and other formed articles) contains an aromatic polyester polymer and a tinting agent; the tinting agent is contained in a content of 0.1 to 10 ppm by mass in the composition, and has a maximum absorption wavelength in the range of from 540 to 600 nm in the absorption spectrum in the wavelength band of from 380 to 780 nm, determined in a solution of the tinting agent in a concentration of 20 mg/liter in chloroform in an optical path having a length of 1 cm; and ratios of optical absorbances A400, A500, A600 and A700 of visible light spectra at wavelengths of 400 nm, 500 nm, 600 nm and 700 nm respectively to an optical absorbance Amax in the visible light spectrum at the maximum absorption wavelength, determined in the above-mentioned chloroform solution at a optical path having a length of 1 cm, satisfy the requirements of 0.00≦A400/Amax≦0.20, 0.10≦A500/Amax≦0.70, 0.55≦A600/Amax≦1.00 and 0.00≦A700/Amax≦0.05.
摘要翻译：具有良好颜色并可用于许多用途（纤维，薄膜和其它成型制品）的有色聚酯树脂组合物含有芳族聚酯聚合物和着色剂; 在组合物中，着色剂的含量为0.1〜10质量ppm，在波长范围为380〜780nm的吸收光谱中，在540〜600nm的范围内具有最大吸收波长，测定在浓度为20mg /升的着色剂的溶液中，在长度为1cm的光路中的氯仿中，以及在400nm，500nm，600nm和700nm波长处的可见光光谱的光吸收值A400，A500，A600和A700的比值分别与在最大吸收波长处的可见光光谱中的光吸收率Amax 在长度为1cm的光路上的上述氯仿溶液满足要求0.00 <= A400 /Amax≤0.20,0.10<= A500 / Amax <= 0.70,0.55 <= A600 / Amax <= 1.00和 0.00 <= A700 / Amax <= 0.05。

7. 发明授权

US06521552B1 Water vapor-permeable, waterproof fabric 失效
标题翻译：水蒸气渗透，防水面料
公开(公告)号：US06521552B1
公开(公告)日：2003-02-18
申请号：US09496284
申请日：2000-02-01
申请人： Hiroshi Honna , Ryoji Tsukamoto , Makoto Yoshida , Michikage Matsui
发明人： Hiroshi Honna , Ryoji Tsukamoto , Makoto Yoshida , Michikage Matsui
IPC分类号： B32B502
CPC分类号： D06N3/10 , D06N3/183 , D06N7/00 , Y10T442/2041 , Y10T442/2098 , Y10T442/2139 , Y10T442/2148 , Y10T442/2221
摘要： A water vapor-permeable waterproof fabric free from an environmental pollution problem upon being discarded is formed by coating a substrate fiber fabric with a composite coating layer including a lower layer (A) directly formed on the substrate fabric and an upper layer (B) formed on the lower layer (B), wherein the lower and upper layers are formed from one of polyetherester elastomers different from each other and each containing polyalkylene glycol (PAG) residues, and satisfy the following requirements: (a) in the polyetherester elastomer (PEEA), the polyalkylene glycol residues contain 90% by weight or more of polytetramethylene glycol residues; (b) in the polyetherester elastomer (PEEB), the polyalkylene glycol residues contain 50% by weight or more of polyethylene glycol residues; (c) the thickness of the composite coating layer is 5 to 50 &mgr;m; and (d) the lower layer (A) is in an amount of 5 to 40% by weight based on the total weight of the composite coating layer.
摘要翻译：通过用直接形成在基底织物上的下层（A）和形成的上层（B）的复合涂层涂布基底纤维织物，形成无废水时的环境污染问题的透水性防水布，在下层（B）上，其中下层和上层由彼此不同的聚醚酯弹性体之一形成，并且各自含有聚亚烷基二醇（PAG）残基，并且满足以下要求：（a）在聚醚酯弹性体（PEEA ），聚亚烷基二醇残基含有90重量％以上的聚四亚甲基二醇残基; （b）在聚醚酯弹性体（PEEB）中，聚亚烷基二醇残基含有50重量％以上的聚乙二醇残基; （c）复合涂层的厚度为5〜50μm; 和（d）下层（A）的含量相对于复合涂层的总重量为5〜40重量％。

8. 发明授权

US06740402B2 Polyester fiber 失效
标题翻译：聚酯纤维
公开(公告)号：US06740402B2
公开(公告)日：2004-05-25
申请号：US10312981
申请日：2003-01-03
申请人： Ryoji Tsukamoto
发明人： Ryoji Tsukamoto
IPC分类号： D02G300
CPC分类号： D01F6/84 , Y10T428/2913 , Y10T428/2969
摘要： Polyester fibers comprising a copolyester which simultaneously satisfies the following respective requirements (a) to (c), (a) a terephthalic acid component in an amount of 0 to 100 mol % and a 2,6-naphthalenedicarboxylic acid component in an amount of 100 to 0 mol % respectively based on the whole dicarbxylic acid component, wherein the total amount, of the terephthalic acid component and the 2,6-naphthalenedicarboxylic acid component, accounts for 90 mol % or more based on the whole dicarboxylic acid component, (b) a trimethylene glycol component accounts for 0 to 100 mol % and a 1,4-cyclohexanedimethanol component accounts for 100 to 0 mol % respectively based on the whole glycol component, wherein the total amount, of the trimethylene glycol component and the 1,4-cyclohexanedimethanol component, accounts for 90 mol % or more based on the whole glycol component and (c) the sum total value of mol % of the 2,6-naphthalenedicarboxylic acid component and mol % of the 1,4-cyclohexanedimethanol component is 2 mol % or more.
摘要翻译：包含共聚酯的聚酯纤维，其同时满足以下各要求（a）至（c），（a）0至100摩尔％的对苯二甲酸组分和100重量％的2,6-萘二甲酸组分相对于全部二羧酸成分，分别为0mol％，其中对苯二甲酸成分和2,6-萘二甲酸成分的总量相对于全部二羧酸成分为90mol％以上（b ）三聚乙二醇成分为0〜100摩尔％，1,4-环己烷二甲醇成分分别占全部二醇成分的100〜0摩尔％，其中，三甘醇成分和1,4 - 环己烷二甲醇成分占全部二醇成分的90摩尔％以上，（c）2,6-萘二甲酸成分的摩尔％的总和和1,4-环己烷二甲醇的摩尔％ nol成分为2摩尔％以上。

9. 发明授权

US06177192B1 Polyethylene naphthalate fiber 失效
标题翻译：聚萘二甲酸乙二醇酯纤维
公开(公告)号：US06177192B1
公开(公告)日：2001-01-23
申请号：US09424083
申请日：1999-11-19
申请人： Makoto Asano , Toshimasa Kuroda , Ryoji Tsukamoto , Toshihiro Santa
发明人： Makoto Asano , Toshimasa Kuroda , Ryoji Tsukamoto , Toshihiro Santa
IPC分类号： D01F600
CPC分类号： D01F6/84 , Y10T428/2913 , Y10T428/2969
摘要： A polyethylene naphthalate fiber of the present invention comprises a naphthalate-based copolyester in which at least 85 mol % or more of the total of recurring units is an ethylene 2,6-naphthalate unit, and it is obtained by copolymerizing an alkylene oxide adduct of a divalent phenol expressed by the following general formula (I) in an amount of 1 to 15 mol % as a part of the diol component. H—(OA)m—O—Ar—O—(AO)n—H (I) In the formula, A expresses an alkylene group having a carbon number of 2 to 4, m and n are same as or different from each other, and each express an integer of 1 to 5, and Ar expresses a p-phenylene group, an m-phenylene group or a group of the following general formula (II) —Ph—X—Ph— (II) In the formula, Ph expresses a p-phenylene group, and X expresses a 2,2-propylene group, a sulfone group, a methylene group, an oxygen atom or a sulfur atom. This fiber has high retention ratios of tensile strength and knot strength, and is excellent in durability, and the fiber is suited for applications such as a dryer canvas for papermaking which is used under severe conditions in which especially wet heat treatments and dry heat treatments are repeated.
摘要翻译：本发明的聚萘二甲酸乙二醇酯纤维包括萘二甲酸酯类共聚酯，其中重复单元总数的至少85摩尔％以上为2,6-萘二甲酸乙二醇酯单元，其通过将作为二醇成分的一部分，由以下通式（I）表示的二价酚以1〜15摩尔％的量表示。在式中，A表示碳数为2〜4的亚烷基，m和n 彼此相同或不同，各自表示1〜5的整数，Ar表示对亚苯基，间亚苯基或下述通式（II）的基团。在式中，Ph表示对亚苯基，X表示2,2-亚丙基，砜基，亚甲基，氧原子或硫原子。该纤维的拉伸强度和结强度保持率高，优异的耐用性，并且该纤维适用于诸如烘干机帆布的应用用于在特别湿热处理和干热处理重复的恶劣条件下使用的造纸。

10. 发明申请

US20090022989A1 POLYESTER DIFFERENT-CONTRACTION COMMINGLED YARN 审中-公开
标题翻译：聚酯不均匀收缩纱
公开(公告)号：US20090022989A1
公开(公告)日：2009-01-22
申请号：US12180369
申请日：2008-07-25
申请人： Tomoo Mizumura , Nobuyoshi Miyasaka , Ryoji Tsukamoto , Keijiro Hattori , Hiroyuki Osaka
发明人： Tomoo Mizumura , Nobuyoshi Miyasaka , Ryoji Tsukamoto , Keijiro Hattori , Hiroyuki Osaka
IPC分类号： D02G3/02
CPC分类号： C08G63/85 , D02G1/18 , D02J1/08 , Y10T428/2929 , Y10T428/2931
摘要： High-quality differential-shrinkage polyester combined filament yarn having good color tone and being free from fluffing can be made from a polyester polymer produced by using a catalyst comprising (I) a mixture consisting of a Ti compound component composed of one or more members selected from among titanium alkoxides of the general formula (I) and products of reaction of these alkoxides with carboxylic acids of the general formula (II) or anhydrides thereof and a P compound component consisting of a compound of the general formula (III) and/or (2) a product obtained by reacting a Ti compound component composed of one or more members selected from among titanium alkoxides of the general formula (I) and products of reaction of these alkoxides with carboxylic acids of the general formula (II) or anhydrides thereof with a P compound component consisting of a compound of the general formula (IV).
摘要翻译：具有良好色调且不起毛的高品质差示收缩聚酯复合长丝纱线可以由通过使用催化剂制备的聚酯聚合物制成，所述聚酯聚合物包含（I）由选自以下的一种或多种成分组成的Ti化合物组分由通式（I）的钛醇盐和这些醇盐与通式（II）的羧酸或其酸酐反应的产物和由通式（III）的化合物和/或（2）通过使由选自通式（I）的钛醇盐和这些醇盐与通式（II）的羧酸反应的产物或其酸酐的一种或多种成分组成的Ti化合物组分与由通式（IV）的化合物组成的P化合物组分。

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