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    • 5. 发明授权
    • Nonwoven web with improved barrier properties
    • 具有改进的阻隔性能的无纺网
    • US5213881A
    • 1993-05-25
    • US799929
    • 1991-11-26
    • Terry K. TimmonsPeter KobylivkerLin-Sun Woon
    • Terry K. TimmonsPeter KobylivkerLin-Sun Woon
    • D04H13/00
    • D04H1/56D04H1/559Y10S428/903Y10T442/626Y10T442/68
    • There is disclosed a nonwoven web for use as a barrier layer in an SMS fabric laminate. The web is formed at commercially acceptable polymer melt throughputs (greater than 3 PIH) by using a reactor granule polyolefin, preferably polypropylene, that has been modified by the addition of peroxide in amounts ranging from up to 3000 ppm to reduce the molecular weight distribution from an initial molecular weight distribution of from 4.0 to 4.5 Mw/Mn to a range of from 2.2 to 3.5 Mw/Mn. Also the addition of peroxide increases the melt flow rate (lowers viscosity) to a range between 800 up to 5000 gms/10 min at 230.degree. C. The resulting web has an average fiber size of from 1 to 3 microns and pore sizes distributed predominantly in the range from 7 to 12 microns, with a lesser amount of pores from 12 to 25 microns, with virtually no pores greater than 25 microns, and with the peak of the pore size distribution less than 10 microns.
    • 公开了用作SMS织物层压体中的阻挡层的非织造纤维网。 通过使用反应器颗粒聚烯烃(优选聚丙烯),以商业上可接受的聚合物熔体通过量(大于3PIH)形成所述网,所述反应器颗粒聚烯烃优选为聚丙烯,所述反应器颗粒聚烯烃优选为聚丙烯,其通过加入量为至多3000ppm的过氧化物而被改性, 4.0至4.5Mw / Mn的初始分子量分布范围为2.2-3.5Mw / Mn。 此外,过氧化物的加入使熔体流动速率(降低粘度)在230℃下在800至5000gms / 10min之间的范围内。所得到的纤维网的平均纤维尺寸为1至3微米,孔径主要分布 在7至12微米的范围内,具有较少量的12至25微米的孔,实际上没有孔大于25微米,孔径分布的峰值小于10微米。
    • 6. 发明授权
    • Nonwoven web laminates with improved barrier properties
    • 具有改进的阻隔性能的无纺布层压板
    • US5464688A
    • 1995-11-07
    • US296822
    • 1994-08-26
    • Terry K. TimmonsPeter KobylivkerLin-Sun WoonLaura E. KeckJerald T. Jascomb
    • Terry K. TimmonsPeter KobylivkerLin-Sun WoonLaura E. KeckJerald T. Jascomb
    • D04H13/00B32B5/06
    • D04H3/14D04H1/559D04H1/56Y10S428/903Y10T428/249953Y10T442/659Y10T442/66
    • There is disclosed a nonwoven web for use as a barrier layer in an SMS fabric laminate. The web is formed at commercially acceptable polymer melt throughputs (greater than 3 PIH) by using a reactor granule polyolefin, preferably polypropylene, that has been modified by the addition of peroxide in amounts ranging from up to 3000 ppm to reduce the molecular weight distribution from an initial molecular weight distribution of from 4.0 to 4.5 Mw/Mn to a range of from 2.2 to 3.5 Mw/Mn. Also the addition of peroxide increases the melt flow rate (lowers viscosity) to a range between 800 up to 5000 gms/10 min at 230.degree. C. The resulting web has an average fiber size of from 1 to 3 microns and pore sizes distributed predominantly in the range from 7 to 12 microns, with a lesser amount of pores from 12 to 25 microns, with virtually no pores greater than 25 microns, and with the peak of the pore size distribution less than 10 microns.
    • 公开了用作SMS织物层压体中的阻挡层的非织造纤维网。 通过使用反应器颗粒聚烯烃(优选聚丙烯),以商业上可接受的聚合物熔体通过量(大于3PIH)形成所述网,所述反应器颗粒聚烯烃优选为聚丙烯,所述反应器颗粒聚烯烃优选为聚丙烯,其通过加入量为至多3000ppm的过氧化物而被改性, 4.0至4.5Mw / Mn的初始分子量分布范围为2.2-3.5Mw / Mn。 此外,过氧化物的加入使熔体流动速率(降低粘度)在230℃下在800至5000gms / 10min之间的范围内。所得到的纤维网的平均纤维尺寸为1至3微米,孔径主要分布 在7至12微米的范围内,具有较少量的12至25微米的孔,实际上没有孔大于25微米,孔径分布的峰值小于10微米。
    • 7. 发明授权
    • Method of making nonwoven web with improved barrier properties
    • 制造具有改善的阻隔性能的非织造纤维网的方法
    • US5271883A
    • 1993-12-21
    • US976774
    • 1992-11-16
    • Terry K. TimmonsPeter KobylivkerLin-Sun Woon
    • Terry K. TimmonsPeter KobylivkerLin-Sun Woon
    • D04H13/00D04H3/16
    • D04H1/56D04H1/4291D04H1/544D04H1/559
    • There is disclosed a nonwoven web for use as a barrier layer in an SMS fabric laminate. The web is formed at commercially acceptable polymer melt throughputs (greater than 3 PIH) by using a reactor granule polyolefin, preferably polypropylene, that has been modified by the addition of peroxide in amounts ranging from up to 3000 ppm to reduce the molecular weight distribution from an initial molecular weight distribution of from 4.0 to 4.5 Mw/Mn to a range of from 2.2 to 3.5 Mw/Mn. Also the addition of peroxide increases the melt flow rate (lowers viscosity) to a range between 800 up to 5000 gms/10 min at 230.degree. C. The resulting web has an average fiber size of from 1 to 3 microns and pore sizes distributed predominantly in the range from 7 to 12 microns, with a lesser amount of pores from 12 to 25 microns, with virtually no pores greater than 25 microns, and with the peak of the pore size distribution less than 10 microns.
    • 公开了用作SMS织物层压体中的阻挡层的非织造纤维网。 通过使用反应器颗粒聚烯烃(优选聚丙烯),以商业上可接受的聚合物熔体通过量(大于3PIH)形成所述网,所述反应器颗粒聚烯烃优选为聚丙烯,所述反应器颗粒聚烯烃优选为聚丙烯,其通过加入量为至多3000ppm的过氧化物而被改性, 4.0至4.5Mw / Mn的初始分子量分布范围为2.2-3.5Mw / Mn。 此外,过氧化物的加入使熔体流动速率(降低粘度)在230℃下在800至5000gms / 10min之间的范围内。所得到的纤维网的平均纤维尺寸为1至3微米,孔径主要分布 在7至12微米的范围内,具有较少量的12至25微米的孔,实际上没有孔大于25微米,孔径分布的峰值小于10微米。