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1. 发明授权

US5670697A Preparation of cyclopropane esters 失效
标题翻译：制备环丙烷酯
公开(公告)号：US5670697A
公开(公告)日：1997-09-23
申请号：US451288
申请日：1995-05-26
申请人： Martin Charles Bowden , Michael Drysdale Turnbull
发明人： Martin Charles Bowden , Michael Drysdale Turnbull
IPC分类号： B01J21/16 , B01J31/02 , B01J31/04 , C07B61/00 , C07C20060101 , C07C41/60 , C07C43/32 , C07C67/27 , C07C67/30 , C07C67/317 , C07C69/65 , C07C69/743 , C07C69/747 , C07C69/74
CPC分类号： C07C43/32 , C07C69/65 , C07C69/743
摘要： There is disclosed a process for the preparation of a lower alkyl ester of 3-(2-chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2-dimethylcyclopropane carboxylic acid which comprises the steps of (a) reacting a compound of formula: CF.sub.3 --CXCl--CH(OH)--CH.dbd.C(CH.sub.3).sub.2 (I) wherein X is chloro or bromo, with a tri-lower-alkyl orthoacetate containing up to four carbon atoms in each alkyl groups in the presence of at least a catalytic amount of an acid catalyst at an elevated temperature for a sufficient time to obtain a compound of formula: CF.sub.3 --CXCl--CH.dbd.CH--C(CH.sub.3).sub.2 --CH.sub.2 CO.sub.2 R(III) wherein R is an alkyl group containing up to four carbon atoms, and (b) treating said compound of formula (III) with at least one molar equivalent of a base to obtain said alkyl ester of 3-(2-chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2-dimethylcyclopropane carboxylic acid. The products are useful as intermediates for insecticides.
摘要翻译：公开了制备3-（2-氯-3,3,3-三氟丙-1-烯-1-基）-2,2-二甲基环丙烷羧酸的低级烷基酯的方法，该方法包括以下步骤：（a）使其中X是氯或溴的式：CF 3 -CClCl-CH（OH）-CH = C（CH 3）2（I）的化合物与含有至多四个碳原子的三低级烷基原乙酸酯反应每个烷基在至少一种催化量的酸催化剂存在下在升高的温度下持续足够的时间以得到式CF 3 -CClCl-CH = CH-C（CH 3）2 -CH 2 CO 2 R（III）的化合物，其中 R是含有至多4个碳原子的烷基，和（b）用至少一摩尔当量碱处理式（III）化合物，得到所述3-（2-氯-3,3， 3-三氟丙-1-烯-1-基）-2,2-二甲基环丙烷羧酸。该产品可用作杀虫剂的中间体。

2. 发明授权

US5731475A Preparation of cyclopropane esters 失效
标题翻译：制备环丙烷酯
公开(公告)号：US5731475A
公开(公告)日：1998-03-24
申请号：US826650
申请日：1997-04-04
申请人： Martin Charles Bowden , Michael Drysdale Turnbull
发明人： Martin Charles Bowden , Michael Drysdale Turnbull
IPC分类号： B01J21/16 , B01J31/02 , B01J31/04 , C07B61/00 , C07C20060101 , C07C41/60 , C07C43/32 , C07C67/27 , C07C67/30 , C07C67/317 , C07C69/65 , C07C69/743 , C07C69/747 , C07C43/30
CPC分类号： C07C43/32 , C07C69/65 , C07C69/743
摘要： There is disclosed a process for the preparation of a lower alkyl ester of 3-(2-chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2-dimethylcyclopropane carboxylic acid which comprises the steps of (a) reacting a compound of formula: CF.sub.3 --CXCl--CH(OH)--CH.dbd.C(CH.sub.3).sub.2 (I) wherein X is chloro or bromo, with a tri-lower-alkyl orthoacetate containing up to four carbon atoms in each alkyl groups in the presence of at least a catalytic amount of an acid catalyst at an elevated temperature for a sufficient time to obtain a compound of formula: CF.sub.3 --CXCl--CH.dbd.CH--C(CH.sub.3).sub.2 --CH.sub.2 CO.sub.2 R (III) wherein R is an alkyl group containing up to four carbon atoms, and (b) treating said compound of formula (III) with at least one molar equivalent of a base to obtain said alkyl ester of 3-(2-chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2-dimethylcyclopropane carboxylic acid. The products are useful as intermediates for insecticides.
摘要翻译：公开了制备3-（2-氯-3,3,3-三氟丙-1-烯-1-基）-2,2-二甲基环丙烷羧酸的低级烷基酯的方法，该方法包括以下步骤：（a）使其中X是氯或溴的式：CF 3 -CClCl-CH（OH）-CH = C（CH 3）2（I）的化合物与含有至多四个碳原子的三低级烷基原乙酸酯反应每个烷基在至少一种催化量的酸催化剂存在下在升高的温度下持续足够的时间以获得式CF 3 -CClCl-CH = CH-C（CH 3）2 -CH 2 CO 2 R（III）的化合物，其中 R是含有至多4个碳原子的烷基，和（b）用至少一摩尔当量碱处理式（III）化合物，得到所述3-（2-氯-3,3， 3-三氟丙-1-烯-1-基）-2,2-二甲基环丙烷羧酸。该产品可用作杀虫剂的中间体。

3. 发明授权

US08133849B2 Herbicidal compounds 有权
标题翻译：除草剂
公开(公告)号：US08133849B2
公开(公告)日：2012-03-13
申请号：US12742840
申请日：2008-11-10
申请人： Nigel James Willetts , Matthew Robert Cordingley , Patrick Jelf Crowley , Suzanna Jane Riley , Michael Drysdale Turnbull
发明人： Nigel James Willetts , Matthew Robert Cordingley , Patrick Jelf Crowley , Suzanna Jane Riley , Michael Drysdale Turnbull
IPC分类号： C07D241/26 , C07D513/04 , A01N43/72 , A01N43/90
CPC分类号： C07D241/26 , A01N43/90 , C07D513/04
摘要： The present invention relates to compounds of formula (I), wherein R1, R2, R3, R4 and R5 are as defined in claim 1; or a salt or N-oxide thereof. Furthermore, the present invention relates to processes for preparing compounds of formula (I), to intermediates used in the preparation of compounds of formula (I), to methods of controlling plants and compositions comprising compounds of formula (I).
摘要翻译：本发明涉及式（I）化合物，其中R 1，R 2，R 3，R 4和R 5如权利要求1所定义; 或其盐或N-氧化物。此外，本发明涉及制备式（I）化合物，用于制备式（I）化合物的中间体的方法，用于控制包含式（I）化合物的植物和组合物的方法。

4. 发明授权

US5705516A Oxazoles and their agricultural compositions 失效
标题翻译：恶唑及其农作物
公开(公告)号：US5705516A
公开(公告)日：1998-01-06
申请号：US400912
申请日：1995-03-08
申请人： Michael Drysdale Turnbull , Alison Mary Smith , Roger Salmon
发明人： Michael Drysdale Turnbull , Alison Mary Smith , Roger Salmon
IPC分类号： A01N33/22 , A01N41/10 , A01N43/06 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/50 , A01N43/54 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/64 , A01N43/66 , A01N43/707 , A01N43/713 , A01N43/74 , A01N43/76 , A01N43/80 , A01N43/82 , A01N43/824 , A01N43/836 , A01P5/00 , A01P7/02 , A01P7/04 , C07C17/087 , C07C17/23 , C07C317/14 , C07C323/05 , C07C323/09 , C07D213/70 , C07D213/71 , C07D213/80 , C07D213/81 , C07D213/82 , C07D213/84 , C07D213/85 , C07D231/18 , C07D231/28 , C07D231/30 , C07D233/84 , C07D233/86 , C07D233/90 , C07D233/92 , C07D237/10 , C07D237/18 , C07D237/30 , C07D241/12 , C07D241/18 , C07D241/44 , C07D251/22 , C07D253/04 , C07D253/06 , C07D253/07 , C07D253/075 , C07D253/10 , C07D257/04 , C07D261/10 , C07D261/14 , C07D261/18 , C07D263/34 , C07D263/46 , C07D271/06 , C07D271/07 , C07D271/10 , C07D271/113 , C07D275/02 , C07D275/03 , C07D277/20 , C07D277/36 , C07D277/40 , C07D277/56 , C07D277/58 , C07D285/08 , C07D285/12 , C07D285/125 , C07D285/135 , C07D307/64 , C07D333/34 , C07D333/36 , C07D333/38 , C07D333/62 , C07D409/04 , C07D413/04 , C07D417/04 , C07D471/04 , A61K31/42
CPC分类号： C07D213/70 , A01N33/22 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/50 , A01N43/54 , A01N43/56 , A01N43/58 , A01N43/64 , A01N43/66 , A01N43/707 , A01N43/713 , A01N43/74 , A01N43/80 , A01N43/82 , C07C17/087 , C07C17/23 , C07C323/09 , C07D213/71 , C07D213/80 , C07D213/82 , C07D213/85 , C07D231/18 , C07D231/28 , C07D231/30 , C07D233/86 , C07D233/90 , C07D233/92 , C07D237/18 , C07D237/30 , C07D241/18 , C07D241/44 , C07D251/22 , C07D253/04 , C07D253/07 , C07D253/075 , C07D253/10 , C07D257/04 , C07D261/10 , C07D261/18 , C07D263/34 , C07D263/46 , C07D271/07 , C07D271/113 , C07D275/03 , C07D277/36 , C07D277/56 , C07D277/58 , C07D285/08 , C07D285/125 , C07D285/135 , C07D307/64 , C07D333/34 , C07D333/38 , C07D333/62 , C07D409/04 , C07D413/04 , C07D417/04 , C07D471/04
摘要： A compound having the formula R--S(O).sub.n CH.sub.2 CH.sub.2 CH.dbd.CF.sub.2, wherein R is a phenyl group or a heterocyclic group selected from furyl, thienyl, isoxazolyl, isothiazolyl, oxazolyl, thiazolyl, imidazolyl, pyrazolyl, 1,2,4-oxadiazolyl, 1,2,4-thiadiazolyl, 1,3,4-oxadiazolyl, 1,3,4-thidiazolyl, tetrazolyl, pyridyl, pyridazinyl, pyrazinyl, 1,2,3-triazinyl, 1,3,4-triazinyl, and 1,3,5-triazinyl groups, said phenyl or heterocyclic group being optionally substituted by optionally substituted alkyl, optionally substituted alkenyl, alkynyl, cycloalkyl, alkylcycloalkyl, alkoxy, alkenyloxy, alkynyloxy, hydroxyalkyl, alkoxyalkyl, optionally substituted aryl, optionally substituted arylalkyl, optionally substituted heteroaryl, optionally substituted heteroarylalkyl, optionally substituted aryloxy, optionally substituted arylalkoxy, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxy, optionally substituted heteroarylalkoxy, optionally substituted heteroaryloxyalkyl, haloalkyl, haloalkenyl, haloalkynyl, haloalkoxy, haloalkenyloxy, haloalkynyloxy, halogen, hydroxy, cyano, nitro, --NR7R8, --NR7COR8, --NR7CSR8, --NR7SO2R8, --N(SO2R7)(SO2R8), --COR7, --CONR7R8, -alkylCONR7R8, --CR7NR8, --COOR7, --OCOR7, --SR7, --SOR7, --SO2R7, -alkylSR7, -alkylSOR7, -alkylSO2R7, --OSO2R7, --SO2NR7R8, --CSNR7R8, --SiR7R8R9, --OCH2CO2R7, --OCH2CH2CO2R7, --CONR7SO2R8, -alkylCONR7SO2R8, --NHCONR7R8, --NHCSNR7R8, or an adjacent pair of R1, R2, R3, R4, R5 and R6 when taken together form a fused 5- or 6-membered carbocyclic or heterocyclic ring; R7, R8 and R9 are each independently hydrogen, optionally substituted alkyl, optionally substituted alkenyl, alkynyl, optionally substituted aryl or optionally substituted arylalkyl, haloalkyl, haloalkenyl, haloalkynyl, halogen or hydroxy.
摘要翻译：具有式RS（O）nCH 2 CH 2 CH = CF 2的化合物，其中R是苯基或选自呋喃基，噻吩基，异恶唑基，异噻唑基，恶唑基，噻唑基，咪唑基，吡唑基，1,2,4-恶二唑基，1 2,4,4-噻二唑基，1,3,4-恶二唑基，1,3,4-噻二唑基，四唑基，吡啶基，哒嗪基，吡嗪基，1,2,3-三嗪基，1,3,4-三嗪基和1，所述苯基或杂环基团任选被任选取代的烷基，任选取代的烯基，炔基，环烷基，烷基环烷基，烷氧基，烯氧基，炔氧基，羟基烷基，烷氧基烷基，任选取代的芳基，任选取代的芳基烷基，杂芳基，任选取代的杂芳基烷基，任选取代的芳氧基，任选取代的芳基烷氧基，任选取代的芳氧基烷基，任选取代的杂芳氧基，任选取代的杂芳基烷氧基，任选取代的杂芳氧基烷基，卤代烷基，卤代烯基，卤代炔基，卤代烷氧基，卤代烯氧基，卤代炔氧基，卤素，羟基，氰基，硝基，-NR7R8，-NR7COR8，-NR7CSR8，-NR7SO2R8，-N（SO2R7）（SO2R8），-COR7，-CONR7R8， - 烷基CONR7R8，-CR7NR8， COOR 7，-OCOR 7，-SR 7，-SOR 7，-SO 2 R 7， - 烷基R 7， - 烷基SOR 7， - 烷基SO 2 R 7，-OSO 2 R 7，-SO 2 NR 7 R 8，-CSNR 7 R 8，-SiR 7 R 8 R 9，-OCH 2 CO 2 R 7，-OCH 2 CH 2 CO 2 R 7，-CONR 7 SO 2 R 8， - 烷基CONR 7 SO 2 R 8，-NHCONR 7 R 8， -NHCSNR7R8或R 1，R 2，R 3，R 4，R 5和R 6的相邻对一起形成稠合的5元或6元碳环或杂环; R 7，R 8和R 9各自独立地为氢，任选取代的烷基，任选取代的烯基，炔基，任选取代的芳基或任选取代的芳基烷基，卤代烷基，卤代烯基，卤代炔基，卤素或羟基。

5. 发明授权

US5684011A Pyrimidine derivatives useful as nematicides 失效
标题翻译：用作杀线虫剂的嘧啶衍生物
公开(公告)号：US5684011A
公开(公告)日：1997-11-04
申请号：US653099
申请日：1996-05-24
申请人： Steven Fitzjohn , Michael Peter Robinson , Michael Drysdale Turnbull
发明人： Steven Fitzjohn , Michael Peter Robinson , Michael Drysdale Turnbull
IPC分类号： A01N43/54 , A01N55/00 , C07C17/087 , C07C309/66 , C07C335/32 , C07D239/38 , C07D239/46 , C07D239/48 , C07D239/56 , C07D239/58 , C07D239/60 , C07D239/86 , A61K31/505
CPC分类号： C07D239/48 , A01N43/54 , C07C17/087 , C07C309/66 , C07C335/32 , C07D239/38 , C07D239/56 , C07D239/58 , C07D239/86
摘要： The invention provides novel compounds of formula (I) having nematicidal, insecticidal, acaricidal and fungicidal properties, compositions comprising them and processes and intermediates for their preparation: ##STR1## wherein R.sup.1 is --S(O).sub.n CH.sub.2 CH.sub.2 CH.dbd.CF.sub.2 ; n is selected from 0, 1 and 2; R.sup.2, R.sup.3, and R.sup.4 are independently selected from hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, alkylcycloalkyl, optionally substituted aryl, optionally substituted arylalkyl, optionally substituted aryloxy, optionally substituted arylalkoxy, alkoxy, alkenyloxy, alkynyloxy, hydroxyalkyl, alkoxyalkyl, alkylthio, alkenylthio, alkynylthio, haloalkyl, haloalkenyl, haloalkynyl, haloalkoxy, haloalkenyloxy, haloalkynyloxy, haloalkylthio, haloalkenylthio, haloalkynylthio, halogen, hydroxy, cyano, nitro, --NR.sup.5 R.sup.6, --NR.sup.7 COR.sup.8, --NR.sup.9 SO.sub.2 R.sup.10, --N(SO.sub.2 --R.sup.11)(SO.sub.2 --R.sup.12), --COR.sup.13, --CONR.sup.14 R.sup.15, --COOR.sup.16, --OCOR.sup.17, --OSO.sub.2 R.sup.18, --SO.sub.2 NR.sup.19 R.sup.20, --SO.sub.2 R.sup.21, --SOR.sup.22, --CSNR.sup.23 R.sup.24, --SiR.sup.25 R.sup.26 R.sup.27, --OCH.sub.2 CO.sub.2 R.sup.28, --OCH.sub.2 CH.sub.2 CO.sub.2 R.sup.29, --CONR.sup.30 SO.sub.2 R.sup.31, --SO.sub.2 Z, or an adjacent pair of R.sup.2, R.sup.3 and R.sup.4 when taken together form a fused 5- or 6-membered carbocyclic or heterocyclic ring; R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12, R.sup.13, R.sup.14, R.sup.15, R.sup.16, R.sup.17, R.sup.18, R.sup.19, R.sup.20, R.sup.21, R.sup.22, R.sup.23, R.sup.24, R.sup.25, R.sup.26, R.sup.27, R.sup.28, R.sup.29, R.sup.30 and R.sup.31 are independently selected from hydrogen, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, optionally substituted aryl and optionally substituted arylalkyl; and Z is halogen.
摘要翻译：本发明提供具有杀线虫，杀虫，杀螨和杀真菌性质的新颖的式（I）化合物，包含它们的组合物及其制备方法和中间体：其中R 1为-S（O）n CH 2 CH 2 CH = CF 2; n选自0,1和2; R2，R3和R4独立地选自氢，烷基，烯基，炔基，环烷基，烷基环烷基，任选取代的芳基，任选取代的芳烷基，任选取代的芳氧基，任选取代的芳基烷氧基，烷氧基，烯氧基，炔氧基，羟烷基，烷氧基烷基，烷硫基，炔基硫基，卤代烷基，卤代烯基，卤代炔基，卤代烷氧基，卤代烯基氧基，卤代炔基氧基，卤代烷硫基，卤代烯基硫基，卤代炔基硫代，卤素，羟基，氰基，硝基，-NR5R6，-NR7COR8，-NR9SO2R10，-N（SO2-R11）），-COR 13，-CONR 14 R 15，-COOR 16，-OCOR 17，-OSO 2 R 18，-SO 2 NR 19 R 20，-SO 2 R 21，-SOR 22，-CSNR 23 R 24，-SiR 25 R 26 R 27，-OCH 2 CO 2 R 28，-OCH 2 CH 2 CO 2 R 29，-CONR 30 SO 2 R 31，-SO 2 Z或相邻的一对R 2 当R3和R4一起形成稠合的5或6元碳环或杂环时; R5，R6，R7，R8，R9，R10，R11，R12，R13，R14，R15，R16，R17，R18，R19，R20，R21，R22，R23，R24，R25，R26，R27，R28， R30和R31独立地选自氢，烷基，烯基，炔基，卤代烷基，卤代烯基，卤代炔基，任选取代的芳基和任选取代的芳基烷基; Z是卤素。

6. 发明授权

US08338598B2 Herbicidal pyrido[2,3-B]pyrazines and their use as herbicides 有权
标题翻译：除草吡啶并[2,3-B]吡嗪及其作为除草剂的用途
公开(公告)号：US08338598B2
公开(公告)日：2012-12-25
申请号：US12863286
申请日：2009-01-16
申请人： Matthew Robert Cordingley , Michael Drysdale Turnbull , Neil Brian Carter , Patrick Jelf Crowley
发明人： Matthew Robert Cordingley , Michael Drysdale Turnbull , Neil Brian Carter , Patrick Jelf Crowley
IPC分类号： C07D471/00
CPC分类号： C07D471/04 , A01N43/90
摘要： The present invention relates to a method of controlling plants or inhibiting plant growth which comprises applying to the plants or to the locus thereof a herbicidally effective amount of a compound of formula (I) wherein R1, R2, R3, R4 and R5 are as defined in claim 1; or a salt or TV-oxide thereof. Furthermore, the present invention relates to processes for preparing compounds of formula (I), to intermediates used in the preparation of compounds of formula (I), to herbicidal compositions comprising compounds of formula (I) and to certain novel pyridopyridines.
摘要翻译：本发明涉及一种控制植物或抑制植物生长的方法，其包括将除草有效量的式（I）化合物（其中R 1，R 2，R 3，R 4和R 5如上定义）施用于植物或其所在地在权利要求1中; 或其盐或电子 - 氧化物。此外，本发明涉及制备式（I）化合物，用于制备式（I）化合物的中间体的方法，其包含式（I）化合物和某些新的吡啶并吡啶类除草组合物。

7. 发明授权

US08217055B2 Pyrido-pyrazine derivatives useful as herbicidal compounds 有权
标题翻译：用作除草化合物的吡啶并吡嗪衍生物
公开(公告)号：US08217055B2
公开(公告)日：2012-07-10
申请号：US12518923
申请日：2007-12-06
申请人： Neil Brian Carter , Matthew Robert Cordingley , Patrick Jelf Crowley , Michael Drysdale Turnbull
发明人： Neil Brian Carter , Matthew Robert Cordingley , Patrick Jelf Crowley , Michael Drysdale Turnbull
IPC分类号： A61K31/44
CPC分类号： C07D471/04 , A01N43/90
摘要： The present invention relates to compounds of formula (I): wherein R1, R2, R3, R4 and R5 are as defined in claim 1; or a salt or N-oxide thereof. Furthermore, the present invention relates to processes for preparing compounds of formula (I), to methods of controlling plants and compositions comprising compounds of formula (I).
摘要翻译：本发明涉及式（I）化合物：其中R1，R2，R3，R4和R5如权利要求1所定义; 或其盐或N-氧化物。此外，本发明涉及制备式（I）化合物的方法，涉及含有式（I）化合物的植物和组合物的控制方法。

8. 发明授权

US5952359A Thiazoles and their agricultural compositions 失效
标题翻译：噻唑及其农业成分
公开(公告)号：US5952359A
公开(公告)日：1999-09-14
申请号：US887858
申请日：1997-07-03
申请人： Christopher Richard Ayles Godfrey , Matthew Brian Hotson , Nan Catherine Sillars , Alan John Dowling , Michael Drysdale Turnbull , Harjinder Singh Bansal , Allison Mary Smith , Roger Salmon , Steven Fitzjohn
发明人： Christopher Richard Ayles Godfrey , Matthew Brian Hotson , Nan Catherine Sillars , Alan John Dowling , Michael Drysdale Turnbull , Harjinder Singh Bansal , Allison Mary Smith , Roger Salmon , Steven Fitzjohn
IPC分类号： A01N33/22 , A01N41/10 , A01N43/06 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/50 , A01N43/54 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/64 , A01N43/66 , A01N43/707 , A01N43/713 , A01N43/74 , A01N43/76 , A01N43/80 , A01N43/82 , A01N43/824 , A01N43/836 , A01P5/00 , A01P7/02 , A01P7/04 , C07C17/087 , C07C17/23 , C07C317/14 , C07C323/05 , C07C323/09 , C07D213/70 , C07D213/71 , C07D213/80 , C07D213/81 , C07D213/82 , C07D213/84 , C07D213/85 , C07D231/18 , C07D231/28 , C07D231/30 , C07D233/84 , C07D233/86 , C07D233/90 , C07D233/92 , C07D237/10 , C07D237/18 , C07D237/30 , C07D241/12 , C07D241/18 , C07D241/44 , C07D251/22 , C07D253/04 , C07D253/06 , C07D253/07 , C07D253/075 , C07D253/10 , C07D257/04 , C07D261/10 , C07D261/14 , C07D261/18 , C07D263/34 , C07D263/46 , C07D271/06 , C07D271/07 , C07D271/10 , C07D271/113 , C07D275/02 , C07D275/03 , C07D277/20 , C07D277/36 , C07D277/40 , C07D277/56 , C07D277/58 , C07D285/08 , C07D285/12 , C07D285/125 , C07D285/135 , C07D307/64 , C07D333/34 , C07D333/36 , C07D333/38 , C07D333/62 , C07D409/04 , C07D413/04 , C07D417/04 , C07D471/04 , A61K31/425
CPC分类号： C07D213/70 , A01N33/22 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/50 , A01N43/54 , A01N43/56 , A01N43/58 , A01N43/64 , A01N43/66 , A01N43/707 , A01N43/713 , A01N43/74 , A01N43/80 , A01N43/82 , C07C17/087 , C07C17/23 , C07C323/09 , C07D213/71 , C07D213/80 , C07D213/82 , C07D213/85 , C07D231/18 , C07D231/28 , C07D231/30 , C07D233/86 , C07D233/90 , C07D233/92 , C07D237/18 , C07D237/30 , C07D241/18 , C07D241/44 , C07D251/22 , C07D253/04 , C07D253/07 , C07D253/075 , C07D253/10 , C07D257/04 , C07D261/10 , C07D261/18 , C07D263/34 , C07D263/46 , C07D271/07 , C07D271/113 , C07D275/03 , C07D277/36 , C07D277/56 , C07D277/58 , C07D285/08 , C07D285/125 , C07D285/135 , C07D307/64 , C07D333/34 , C07D333/38 , C07D333/62 , C07D409/04 , C07D413/04 , C07D417/04 , C07D471/04
摘要： A compound of formula (I),R--S(O).sub.n CH.sub.2 CH.sub.2 CH.dbd.CF.sub.2or a salt thereof, wherein n is 0, 1 or 2; and R is a group of formula (V) or (VII) ##STR1## wherein: at least one of R.sup.2, R.sup.3, R.sup.4 or R.sup.5 is a S(O)nCH.sub.2 CH.sub.2 CH.dbd.CF.sub.2 group; and the remainder of R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each independently hydrogen, optionally substituted alkyl, optionally substituted alkenyl, alkynyl, cycloalkyl, alkylcycloalkyl, alkoxy, alkenyloxy, alkynyloxy, hydroxyalkyl, alkoxyalkyl, optionally substituted aryl, optionally substituted arylalkyl, optionally substituted heteroaryl, optionally substituted heteroarylalkyl, optionally substituted aryloxy, optionally substituted arylalkoxy, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxy, optionally substituted heteroarylalkoxy, optionally substituted heteroaryloxyalkyl, haloalkyl, haloalkenyl, haloalkynyl, haloalkoxy, haloalkenyloxy, haloalkynyloxy, halogen, hydroxy, cyano, nitro, --NR.sup.7 R.sup.8, --NR.sup.7 COR.sup.8, --NR.sup.7 CSR.sup.8, --NR.sup.7 SO.sub.2 R.sup.8, --NR.sup.7 SO.sub.2 R.sup.8, --N(SO.sub.2 R.sup.7)(SO.sub.2 R.sup.8), --COR.sup.7, --CONR.sup.7 R.sup.8, -alkylCONR.sup.7 R.sup.8, --CR.sup.7 NR.sup.8, --COR.sup.7, --OCOR.sup.7, --SR.sup.7, --SOR.sup.7, --SO.sub.2 R.sup.7, -alkylSR.sup.7, -alkylSOR.sup.7, -alkylSO.sub.2 R.sup.7, --OSO.sub.2 R.sup.7, --SO.sub.2 NR.sup.7 R.sup.8, --CSNR.sup.7 R.sup.8, --CSNR.sup.7 R.sup.8, --SiR.sup.7 R.sup.8 R.sup.9, --OCH.sub.2 CO.sub.2 R.sup.7, --OCH.sub.2 CH.sub.2 SO.sub.2 R.sup.7, --CONR.sup.7 SO.sub.2 R.sup.8, -alkylCONR.sup.7 SO.sub.2 R.sup.8, --NHCONR.sup.7 R.sup.8, --NHCSNR.sup.7 R.sup.8 ; and R.sup.7, R.sup.8 and R.sup.9 are each independently hydrogen, optionally substituted alkyl, optionally substituted alkenyl, alkynyl, optionally substituted aryl or optionally substituted arylalkyl, haloalkyl, haloalkenyl, haloalkynyl, halogen, or hydroxy; and agricultural compositions, and processes for preparing agricultural compositions made thereby.
摘要翻译：式（I）化合物，R-S（O）nCH 2 CH 2 CH = CF 2或其盐，其中n为0,1或2; 并且R是式（V）或（VII）的基团，其中：R 2，R 3，R 4或R 5中的至少一个是S（O）n CH 2 CH 2 CH = CF 2基团; R 2，R 3，R 4和R 5的其余部分各自独立地为氢，任选取代的烷基，任选取代的烯基，炔基，环烷基，烷基环烷基，烷氧基，烯氧基，炔氧基，羟基烷基，烷氧基烷基，任选取代的芳基，任选取代的芳基烷基，杂芳基，任选取代的杂芳基烷基，任选取代的芳氧基，任选取代的芳基烷氧基，任选取代的芳氧基烷基，任选取代的杂芳氧基，任选取代的杂芳基烷氧基，任选取代的杂芳基烷基，卤代烷基，卤代烯基，卤代炔基，卤代烷氧基，卤代烯氧基，卤代炔氧基，卤素，羟基，氰基，硝基， -NR7R8，-NR7COR8，-NR7CSR8，-NR7SO2R8，-NR7SO2R8，-N（SO2R7）（SO2R8），-COR7，-CONR7R8， - 烷基CONR7R8，-CR7NR8，-COR7，-OCOR7，-SR7，-SOR7，-SO2R7 ， - 烷基-SR7， - 烷基-SOR7， - 烷基SO2R7，-OSO2R7，-SO2NR7R8，-CSNR7R8，-CSNR7R8，-SiR7R8R9，-OCH2CO2R7，-OCH2CH2SO2R7，-CONR7SO2R8， - 烷基CONR7SO2R8，-N HCONR7R8，-NHCSNR7R8; 任选取代的烯基，炔基，任选取代的芳基或任选取代的芳基烷基，卤代烷基，卤代烯基，卤代炔基，卤素或羟基; R 7，R 8和R 9各自独立地为氢，任选取代的烷基，农业组合物，以及由此制备农业组合物的方法。

9. 发明授权

US5912243A (4,4-difluorobut-3-enylthio)-substituted heterocyclic or carbocyclic ring compounds having pesticidal activity 失效
公开(公告)号：US5912243A
公开(公告)日：1999-06-15
申请号：US702623
申请日：1996-08-28
申请人： Alan John Dowling , Alison Mary Craig , Christopher Richard Ayles Godfrey , Harjinder Singh Bansal , Matthew Brian Hotson , Michael Drysdale Turnbull , Nan Catherine Sillars , Roger Salmon , Steven Fitzjohn
发明人： Alan John Dowling , Alison Mary Craig , Christopher Richard Ayles Godfrey , Harjinder Singh Bansal , Matthew Brian Hotson , Michael Drysdale Turnbull , Nan Catherine Sillars , Roger Salmon , Steven Fitzjohn
IPC分类号： A01N33/22 , A01N41/10 , A01N43/06 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/50 , A01N43/54 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/64 , A01N43/66 , A01N43/707 , A01N43/713 , A01N43/74 , A01N43/76 , A01N43/80 , A01N43/82 , A01N43/824 , A01N43/836 , A01P5/00 , A01P7/02 , A01P7/04 , C07C17/087 , C07C17/23 , C07C317/14 , C07C323/05 , C07C323/09 , C07D213/70 , C07D213/71 , C07D213/80 , C07D213/81 , C07D213/82 , C07D213/84 , C07D213/85 , C07D231/18 , C07D231/28 , C07D231/30 , C07D233/84 , C07D233/86 , C07D233/90 , C07D233/92 , C07D237/10 , C07D237/18 , C07D237/30 , C07D241/12 , C07D241/18 , C07D241/44 , C07D251/22 , C07D253/04 , C07D253/06 , C07D253/07 , C07D253/075 , C07D253/10 , C07D257/04 , C07D261/10 , C07D261/14 , C07D261/18 , C07D263/34 , C07D263/46 , C07D271/06 , C07D271/07 , C07D271/10 , C07D271/113 , C07D275/02 , C07D275/03 , C07D277/20 , C07D277/36 , C07D277/40 , C07D277/56 , C07D277/58 , C07D285/08 , C07D285/12 , C07D285/125 , C07D285/135 , C07D307/64 , C07D333/34 , C07D333/36 , C07D333/38 , C07D333/62 , C07D409/04 , C07D413/04 , C07D417/04 , C07D471/04 , C04B35/52 , C07D251/00 , C07D253/00
CPC分类号： C07D213/70 , A01N33/22 , A01N43/08 , A01N43/10 , A01N43/40 , A01N43/50 , A01N43/54 , A01N43/56 , A01N43/58 , A01N43/64 , A01N43/66 , A01N43/707 , A01N43/713 , A01N43/74 , A01N43/80 , A01N43/82 , C07C17/087 , C07C17/23 , C07C323/09 , C07D213/71 , C07D213/80 , C07D213/82 , C07D213/85 , C07D231/18 , C07D231/28 , C07D231/30 , C07D233/86 , C07D233/90 , C07D233/92 , C07D237/18 , C07D237/30 , C07D241/18 , C07D241/44 , C07D251/22 , C07D253/04 , C07D253/07 , C07D253/075 , C07D253/10 , C07D257/04 , C07D261/10 , C07D261/18 , C07D263/34 , C07D263/46 , C07D271/07 , C07D271/113 , C07D275/03 , C07D277/36 , C07D277/56 , C07D277/58 , C07D285/08 , C07D285/125 , C07D285/135 , C07D307/64 , C07D333/34 , C07D333/38 , C07D333/62 , C07D409/04 , C07D413/04 , C07D417/04 , C07D471/04
摘要： A compound having the formula R--S(O).sub.n CH.sub.2 CH.sub.2 CH.dbd.CF.sub.2, or a salt thereof, wherein R is a phenyl group or a heterocyclic group selected from furyl, thienyl, isoxazolyl, isothiazolyl, oxazolyl, thiazolyl, imidazolyl, pyrazolyl, 1,2,4-oxadiazolyl, 1,2,4-thiadiazolyl, 1,3,4-oxadiazolyl, 1,3,4-thiadiazolyl, tetrazolyl, pyridyl, pyridazinyl, pyrazinyl, 1,2,3-triazinyl, 1,3,4-triazinyl and 1,3,5-triazinyl groups, said phenyl or heterocyclic group being optionally substituted by optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, cycloalkyl, alkylcycloalkyl, alkoxy, alkenyloxy, alkynyloxy, hydroxyalkyl, alkoxyalkyl, optionally substituted aryl, optionally substituted arylalkyl, optionally substituted heteroaryl, optionally substituted heteroarylalkyl, optionally substituted aryloxy, optionally substituted arylalkoxy, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxy, optionally substituted heteroarylalkoxy, optionally substituted heteroaryloxyalkyl, haloalkyl, haloalkenyl, haloalkynyl, haloalkoxy, haloalkenyloxy, haloalkynyloxy, halogen, hydroxy, cyano, nitro, --NR7R8, --NR7COR8, --NR7CSR8, --NR7SO2R8, --N(SO2R7)(SO2R8), --COR7, --CONR7R8, -alkylCONR7R8, --CR7NR8, --COOR7, --OCOR7, --SR7, --SOR7, --SO2R7, -alkylSR7, -alkylSOR7, -alkylSO2R7, --OSO2R7, --SO2NR7R8, --CSNR7R8, --SiR7R8R9, --OCH2CO2R7, --OCH2CH2CO2R7, --CONR7SO2R8, -alkylCONR7SO2R8, --NHCONR7R8, --NHCSNR7R8, or an adjacent pair of R1, R2, R3, R4, R5 and R6 when taken together form a fused 5- or 6-membered carbocyclic or heterocyclic ring; and R7, R8 and R9 are each independently hydrogen, optionally substituted alkyl, optionally substituted alkenyl, alkynyl, optionally substituted aryl or optionally substituted arylalkyl, haloalkyl, haloalkenyl, haloalkynyl, halogen, or hydroxy.

10. 发明授权

US08133847B2 Pyrido[2,3-B]pyrazine derivatives useful as herbicidal compounds 有权
标题翻译：可用作除草化合物的吡啶并[2,3-B]吡嗪衍生物
公开(公告)号：US08133847B2
公开(公告)日：2012-03-13
申请号：US12374079
申请日：2007-07-16
申请人： Neil Brian Carter , Matthew Robert Cordingley , Patrick Jelf Crowley , Michael Drysdale Turnbull
发明人： Neil Brian Carter , Matthew Robert Cordingley , Patrick Jelf Crowley , Michael Drysdale Turnbull
IPC分类号： A01N43/60 , A01N43/00 , A01N43/40 , C07D293/10 , C07D237/00 , C07D237/02 , C07D241/00 , C07D241/02 , C07D241/36 , C07D471/00
CPC分类号： C07D471/04 , A01N43/90
摘要： The present invention relates to a method of controlling plants or inhibiting plant growth which comprises applying to the plants or to the locus thereof a herbicidally effective amount of a compound of formula (I) wherein R1, R2, R3, R4 and R5 are as defined in claim 1; or salts or N-oxides thereof. Furthermore, the present invention relates to processes for preparing compounds of formula (I), to herbicidal compositions comprising compounds of formula (I) and to certain novel pyrido[2,3-b]pyrazines.
摘要翻译：本发明涉及一种控制植物或抑制植物生长的方法，其包括将除草有效量的式（I）化合物（其中R 1，R 2，R 3，R 4和R 5如上定义）施用于植物或其所在地在权利要求1中; 或其盐或N-氧化物。此外，本发明涉及制备式（I）化合物的方法，包括式（I）化合物和某些新的吡啶并[2,3-b]吡嗪的除草组合物。

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