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1. 发明申请

US20060266451A1 Method for producing a propellant 审中-公开
标题翻译：制造推进剂的方法
公开(公告)号：US20060266451A1
公开(公告)日：2006-11-30
申请号：US11358049
申请日：2006-02-22
申请人： Markus Fahrni , Beat Vogelsanger , Alfred Steinmann , Bruno Ossola , Ulrike Jeck-Prosch , Alexander Huber , Kurt Ryf
发明人： Markus Fahrni , Beat Vogelsanger , Alfred Steinmann , Bruno Ossola , Ulrike Jeck-Prosch , Alexander Huber , Kurt Ryf
IPC分类号： C06B45/00
CPC分类号： F42B5/16 , C06B21/0083 , C06B45/22
摘要： The proposed propellant powder exhibits a temperature-independent burning behavior and high ballistic stability. The production process starts with a perforated bulk powder grain, which is processed inside a mixing apparatus with a solid material, a plug-stabilizing moderator or deterrent (if necessary also a radical initiator) and a low-viscous liquid. With a minimum amount of solid material, moderator or deterrent and liquid and because of the continuous mixing, the form function is influenced in such a way that the gas-formation rate is practically independent of the propellant powder temperature. As a result, the muzzle energy at the normal temperature and, above all, at a low deployment temperature can be increased markedly as compared to that of a standard propellant powder. With the propellant powder according to the invention, for which the grain has at least one perforation that discharges with an opening to the outside surface of the grain, wherein the opening is closed off with a plug, the plug has a temperature-dependent mobility. As a result, the plug has a higher mobility for a lower deployment temperature than for a higher deployment temperature, so that the plug permits a faster hole burning at a lower deployment temperature than at a higher deployment temperature.
摘要翻译：所提出的推进剂粉末表现出与温度无关的燃烧行为和高弹道稳定性。生产过程开始于穿孔的本体粉末颗粒，其在具有固体材料的混合装置，稳定稳定剂或阻燃剂（如果需要还有自由基引发剂）和低粘度液体的条件下进行处理。使用最少量的固体材料，调节剂或阻燃剂和液体，并且由于连续混合，形式功能受到这样的影响，使得气体形成速率实际上与推进剂粉末温度无关。结果，与标准推进剂粉末相比，正常温度下的喷嘴能量，特别是在低的部署温度下，能够显着增加。使用根据本发明的推进剂粉末，其中颗粒具有至少一个穿孔，该穿孔具有通向颗粒外表面的开口，其中开口用塞子封闭，塞子具有温度依赖性的流动性。因此，插头具有较低的部署温度的移动性，而不是更高的部署温度，因此插头允许在较低的部署温度下比在更高的部署温度下更快的孔燃烧。

2. 发明授权

US07051658B2 Temperature-independent propellant powder 有权
公开(公告)号：US07051658B2
公开(公告)日：2006-05-30
申请号：US10096111
申请日：2002-03-13
申请人： Markus Fahrni , Beat Vogelsanger , Alfred Steinmann , Bruno Ossola , Ulrike Jeck-Prosch , Alexander Huber , Kurt Ryf
发明人： Markus Fahrni , Beat Vogelsanger , Alfred Steinmann , Bruno Ossola , Ulrike Jeck-Prosch , Alexander Huber , Kurt Ryf
IPC分类号： C06B45/00
CPC分类号： F42B5/16 , C06B21/0083 , C06B45/22
摘要： The proposed propellant powder exhibits a temperature-independent burning behavior and high ballistic stability. The production process starts with a perforated bulk powder grain, which is processed inside a mixing apparatus with a solid material, a plug-stabilizing moderator or deterrent (if necessary also a radical initiator) and a low-viscous liquid. With a minimum amount of solid material, moderator or deterrent and liquid and because of the continuous mixing, the form function is influenced in such a way that the gas-formation rate is practically independent of the propellant powder temperature. As a result, the muzzle energy at the normal temperature and, above all, at a low deployment temperature can be increased markedly as compared to that of a standard propellant powder.With the propellant powder according to the invention, for which the grain has at least one perforation that discharges with an opening to the outside surface of the grain, wherein the opening is closed off with a plug, the plug has a temperature-dependent mobility. As a result, the plug has a higher mobility for a lower deployment temperature than for a higher deployment temperature, so that the plug permits a faster hole burning at a lower deployment temperature than at a higher deployment temperature.

3. 发明授权

US5457204A Tetraalkyl-4-(2,3-epoxypropoxy) piperidine compounds as stabilizers 失效
标题翻译：四烷基-4-（2,3-环氧丙氧基）哌啶化合物作为稳定剂
公开(公告)号：US5457204A
公开(公告)日：1995-10-10
申请号：US271706
申请日：1994-07-07
申请人： Alfred Steinmann
发明人： Alfred Steinmann
IPC分类号： C07D211/46 , C07D211/94 , C07D405/12 , C08K5/3432 , C08K5/3435 , C08K5/3492 , C07D251/34
CPC分类号： C08K5/3492 , C07D211/46 , C08K5/3435
摘要： Esters or phenol ethers of the formula I or II ##STR1## in which m and n are each an integer from the range from 1 to 6; A.sup.1 is an m-valent hydrocarbon radical having 1 to 30 carbon atoms; or an m-valent hydrocarbon radical having 2 to 30 carbon atoms, which contains the heteroatoms oxygen, nitrogen and/or sulfur and the free valencies of which are located on carbon atoms; and in which A.sup.1, in the case where m=2, additionally is a direct bond;A.sup.2 is an n-valent aromatic or araliphatic hydrocarbon radical having 6 to 30 carbon atoms; or an n-valent aromatic or araliphatic hydrocarbon radical having 5 to 30 carbon atoms, which contains the heteroatoms oxygen, nitrogen and/or sulfur and n free valencies of which are located on those carbon atoms which are a constituent of aromatic rings;R.sup.1 is hydrogen; a hydrocarbon or hydrocarbonoxy radical having 1 to 36 carbon atoms, which is unsubstituted or substituted by --CO--N(R.sup.3).sub.2 or interrupted by --CO--N(R.sup.3)-- or --N(R.sup.3)--CO-- or 1 to 6 oxygen or sulfur atoms; benzoyl or naphthoyl, each of which is substituted by 1 to 3 C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy radicals; or --CO--R.sup.2 ; in which R.sup.2 is C.sub.1 -C.sub.18 alkyl; C.sub.5 -C.sub.8 cycloalkyl; phenyl; naphthyl; C.sub.7 -C.sub.9 phenylalkyl; or C.sub.11 -C.sub.14 naphthylalkyl; and R.sup.3 has the same meanings as R.sup.2 or is hydrogen, are described.The compounds are suitable for stabilizing organic material against the damaging influence of light, oxygen and/or heat.
摘要翻译：式I或II的酯或酚醚其中m和n各自为1至6的整数;（I）其中m和n各自为1至6的整数; A1是具有1至30个碳原子的m价烃基; 或含有2至30个碳原子的m价烃基，其含有杂原子氧，氮和/或硫并且其自由价位于碳原子上; 并且其中在m = 2的情况下，A1另外是直接键; A2是具有6至30个碳原子的n价芳族或芳脂族烃基; 或具有5至30个碳原子的n价芳族或芳脂族烃基，其含有杂原子氧，氮和/或硫并且n个无定价位于作为芳环的组成部分的那些碳原子上; R1是氢; 未被取代或被-CO-N（R3）2取代或被-CO-N（R3） - 或-N（R3）-CO-或1至6个间隔的碳原子或烃氧基氧或硫原子; 苯甲酰基或萘甲酰基，其各自被1至3个C 1 -C 4烷基或C 1 -C 4烷氧基取代; 或-CO-R 2; 其中R2是C1-C18烷基; C5-C8环烷基; 苯基; 萘基; C7-C9苯基烷基; 或C 11 -C 14萘基烷基; 和R 3具有与R 2相同的含义或氢原子。这些化合物适合于稳定有机材料以抵抗光，氧和/或热的破坏性影响。

4. 发明授权

US5380882A Phenylacetates and the use thereof 失效
标题翻译：苯乙酸酯及其用途
公开(公告)号：US5380882A
公开(公告)日：1995-01-10
申请号：US40230
申请日：1993-03-30
申请人： Alfred Steinmann
发明人： Alfred Steinmann
IPC分类号： C07D307/20 , C07D309/12 , G03F7/004 , G03F7/039 , H01L21/31
CPC分类号： C07D309/12 , C07D307/20 , G03F7/0045
摘要： The invention relates to compounds of formula I ##STR1## wherein A is a radical of formula ##STR2## R.sub.1 and R.sub.2 are each independently of the other hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen or a radical of formula ##STR3## wherein X is --O--, --CH.sub.2 --, --C(CH.sub.3).sub.2 -- or --SO.sub.2 --, and R.sub.3 and R.sub.4 are each independently of the other hydrogen, C.sub.1 -C.sub.4 alkyl or phenyl, as well as compositions comprising these compounds.The compositions are particularly suitable for making integrated circuits.
摘要翻译：本发明涉及式I化合物其中A为式的基团R 1和R 2各自独立地为氢，C 1 -C 4烷基，C 1 -C 4烷氧基，卤素或式其中X是-O - ， - CH 2 - ， - C（CH 3）2 - 或-SO 2 - ，并且R 3和R 4各自独立地为氢，C 1 -C 4烷基或苯基，以及包含这些化合物。组合物特别适用于制造集成电路。

5. 发明授权

US5106932A Benzoates containing a substituent having olefinic unsaturation 失效
标题翻译：含有具有油脂不饱和度的替代物的苯甲酸酯
公开(公告)号：US5106932A
公开(公告)日：1992-04-21
申请号：US731188
申请日：1991-07-15
申请人： Alfred Steinmann
发明人： Alfred Steinmann
IPC分类号： C07C67/08 , C07C67/04 , C07C69/76 , C07D307/20 , C07D309/12 , C08F12/00 , C08F12/22 , C08F16/02 , C08F16/16 , C08F26/00 , C08F118/04 , C08F212/14 , C08F216/02 , C08F216/16 , C08F218/02 , C08F220/42 , C08F226/02 , G03C1/73 , G03F7/00 , G03F7/004 , G03F7/023 , G03F7/039
CPC分类号： G03F7/039 , C07C67/04 , C07C69/76 , C08F12/22 , G03F7/0045 , G03F7/0233
摘要： Polymers suitable for use as positive photoresists can be prepared, in the absence or presence of other olefinically unsaturated monomers, from benzoates comprising an olefinic unsaturated substituent and consisting of formula I ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other a hydrogen atom, C.sub.1 -C.sub.4 alkyl or phenyl, R.sub.3 is a hydrogen atom, methyl or a halogen atom, R.sub.4 is a hydrogen atom or methyl, R.sub.5 is C.sub.1 -C.sub.4 alkyl or C.sub.6 -C.sub.12 aryl, and R.sub.6 and R.sub.7 are each independently of the other a hydrogen atom, C.sub.1 -C.sub.4 alkyl or C.sub.6 -C.sub.12 aryl, and R.sub.5 and R.sub.7, when taken together, may also be an unsubstituted or a C.sub.1 -C.sub.4 alkyl-, C.sub.1 -C.sub.4 alkoxy-, C.sub.6 -C.sub.12 aryl- or C.sub.6 -C.sub.12 aryloxy-substituted ethylene, propylene or butylene radical.
摘要翻译：适合用作阳性光致抗蚀剂的聚合物可以在不存在或存在其它烯属不饱和单体的情况下由包含烯属不饱和取代基的苯甲酸酯制备，并由式I（I）组成，其中R 1和R 2各自独立地为其它氢原子，C1-C4烷基或苯基，R3是氢原子，甲基或卤素原子，R4是氢原子或甲基，R5是C1-C4烷基或C6-C12芳基，R6和R7各自独立地是氢原子，C 1 -C 4烷基或C 6 -C 12芳基，R 5和R 7一起可以是未取代的或C 1 -C 4烷基 - ，C 1 -C 4烷氧基 - ，C 6 -C 12芳基 - 或C 6 -C 12芳氧基取代的亚乙基，丙烯或丁烯基。

6. 发明授权

US4820829A Substituted o-phthalaldehydes 失效
标题翻译：取代的邻苯二甲醛
公开(公告)号：US4820829A
公开(公告)日：1989-04-11
申请号：US1309
申请日：1987-01-08
申请人： Alfred Steinmann
发明人： Alfred Steinmann
IPC分类号： C07F7/08 , C07F7/22 , C07F7/30 , C08G2/00 , C08G2/10 , C08G2/14 , G03F7/039 , G03F7/075 , C07F7/02
CPC分类号： C08G2/00 , C07F7/0818 , G03F7/039 , G03F7/0758
摘要： There are disclosed novel substituted o-phthalaldehydes of formula I ##STR1## wherein at least one of the substituents R.sub.1, R.sub.2, R.sub.3, R.sub.4 is Q(alkyl).sub.3, --CH.sub.2 --Q(alkyl).sub.3, --O--Q(alkyl).sub.3, --Q(aryl).sub.3 or --Q(alkylenearyl).sub.3, wherein Q is Si, Sn or Ge, the alkyl moieties contain 1 to 12 carbon atoms, the aryl groups contain 6 or 12 ring carbon atoms and the alkylene radicals contain 1 to 4 carbon atoms, and each of the remaining substituents R.sub.1 to R.sub.4 is a hydrogen or halogen atom or a cyano, nitro, carboxyl or hydroxyl group, a C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio or an alkoxycarbonyl group containing 1 to 4 carbon atoms in the alkoxy moiety.The novel o-phthalaldehydes can be polymerized to give polymers that can be used as photoresists.
摘要翻译：公开了式I（I）的新型取代邻邻醛，其中至少一个取代基R 1，R 2，R 3，R 4是Q（烷基）3，-CH 2 -Q（烷基）3，-OQ（烷基）3，-Q（芳基）3或-Q（亚烷基硬脂基）3，其中Q是Si，Sn或Ge，烷基部分含有1至12个碳原子，芳基含有6或12个环碳原子，基团含有1至4个碳原子，并且其余的取代基R 1至R 4中的每一个为氢或卤素原子或氰基，硝基，羧基或羟基，C 1 -C 4烷氧基，C 1 -C 4烷硫基或含有1至4个的烷氧基羰基烷氧基部分中的碳原子。可以将新型邻苯二甲醛聚合，得到可用作光致抗蚀剂的聚合物。

7. 发明授权

US06262206B1 Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds 失效
标题翻译：含有衍生自亚硝基或硝酮化合物的烷氧基胺化合物的可聚合组合物
公开(公告)号：US06262206B1
公开(公告)日：2001-07-17
申请号：US09114621
申请日：1998-07-13
申请人： Peter Nesvadba , Andreas Kramer , Alfred Steinmann , Werner Stauffer
发明人： Peter Nesvadba , Andreas Kramer , Alfred Steinmann , Werner Stauffer
IPC分类号： C08F238
CPC分类号： C08F293/00 , C07C255/64 , C07C2601/14 , C07D207/09 , C07D207/20 , C08F4/00
摘要： A polymerizabie composition, comprising a) at least one ethylenically unsaturated monomer or oligomer, and b) an initiator compound of formula (I) wherein n is O or 1. The compounds of formula (I) are prepared from a free radical and a compound of formula R10NO or Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, novel initiator compounds and their use for polymerization, intermediate compounds and also the polymer or copolymer produced by this process.
摘要翻译：一种聚合物组合物，其包含a）至少一种烯键式不饱和单体或低聚物，和b）式（I）的引发剂化合物，其中n为0或1.式（I）化合物由游离基和式R 10 NO 或者本发明的另外的方面是用于聚合烯属不饱和单体，新型引发剂化合物及其聚合用途，中间体化合物以及通过该方法制备的聚合物或共聚物的方法。

8. 发明授权

US6028129A Increasing the molecular weight of polycondensates and stabilizing them, using diepoxides of sterically hindered amines 失效
标题翻译：增加缩聚物的分子量并使其稳定，使用空间位阻胺的二环氧化物
公开(公告)号：US6028129A
公开(公告)日：2000-02-22
申请号：US234254
申请日：1999-01-20
申请人： Rudolf Pfaendner , Alfred Steinmann , Heinz Herbst , Kurt Hoffmann
发明人： Rudolf Pfaendner , Alfred Steinmann , Heinz Herbst , Kurt Hoffmann
IPC分类号： C08G69/48 , C08G59/22 , C08G59/26 , C08G63/91 , C08G64/42 , C08K5/3435 , C08L63/00 , C08L67/00 , C08L69/00 , C08L77/00 , C08K5/34 , C08K3/34 , C08K5/53
CPC分类号： C08L67/00 , C08G59/26 , C08K5/3435 , C08L63/00 , C08L69/00 , C08L77/00
摘要： The invention relates to a process for increasing the molecular weight of polycondensates and at the same time stabilizing them, essentially without crosslinking, which comprises heating a polyamide, a polyester, a polycarbonate or a copolymer or blend of these polymers with addition of at least one diepoxide comprising terminal epoxide groups and as a further structural element a tetramethylpiperidine radical located centrally between the epoxide groups to a temperature which is above the melting point of the polymer in the case of crystalline polycondensates or above the glass point in the case of amorphous polycondensates. The invention additionally relates to mixtures comprising the corresponding diepoxides, to their use, and to polycondensates prepared from them.
摘要翻译：本发明涉及一种提高缩聚物分子量的方法，同时稳定它们，基本上不含交联，其包括加热这些聚合物的聚酰胺，聚酯，聚碳酸酯或共聚物或共混物，加入至少一种二环氧化物包含末端环氧基团，并且作为另外的结构元素，位于环氧基团之间的中心的四甲基哌啶基团，在结晶缩聚物的情况下高于聚合物的熔点或在无定形缩聚物的情况下高于玻璃点的温度。本发明还涉及包含相应的二环氧化物及其用途的混合物和由它们制备的缩聚物。

9. 发明授权

US5892037A Polymeric adducts of hindered amine-epoxides as stabilizers 失效
标题翻译：受阻胺环氧化物作为稳定剂的聚合加合物
公开(公告)号：US5892037A
公开(公告)日：1999-04-06
申请号：US614120
申请日：1996-03-12
申请人： Alfred Steinmann
发明人： Alfred Steinmann
IPC分类号： C07D211/14 , C07D211/20 , C07D211/22 , C07D211/28 , C07D211/74 , C07D211/94 , C07D241/04 , C07D405/12 , C07D471/20 , C07D491/10 , C07D498/10 , C08F12/00 , C08F12/26 , C08F20/34 , C08F20/36 , C08F20/60 , C08F22/36 , C08F212/14 , C08F220/34 , C08F222/40 , C07D241/02 , C07D215/00
CPC分类号： C07D405/12 , C07D211/94 , C08F12/26 , C08F20/36 , C08F20/60
摘要： The invention relates to compounds obtainable by polymerization of esters or phenol ethers of the formula V ##STR1## and/or of the formula VI ##STR2## in which m and n are each 0 or 1, and A, E, R.sup.1 to R.sup.6 and X are as defined in claim 1, and up to 50 mol % of other, ethylenically unsaturated compounds. The homopolymers and copolymers according to the invention can advantageously be employed for the stabilization of organic polymers against the harmful effect of light, oxygen and/or heat.
摘要翻译：本发明涉及通过聚合式V（V）和/或式VI的酯或酚醚而获得的化合物，A，E，R 1至R 6和X如权利要求1中所定义，至50mol％的其它烯属不饱和化合物。根据本发明的均聚物和共聚物可有利地用于稳定有机聚合物以抵抗光，氧和/或热的有害影响。

10. 发明授权

US5521282A Polyethers containing hindered amine side chains as stabilizers 失效
标题翻译：含有受阻胺侧链作为稳定剂的聚醚
公开(公告)号：US5521282A
公开(公告)日：1996-05-28
申请号：US271704
申请日：1994-07-07
申请人： Alfred Steinmann
发明人： Alfred Steinmann
IPC分类号： C08G65/22 , C08K5/3432 , C08K5/3435 , C08L71/02 , C08G65/04
CPC分类号： C08G65/22 , C08L71/02
摘要： The invention relates to polyethers of the formula I ##STR1## in which m is 0 or 1; n is an integer in the range from 3 to 100; R.sup.1, in the case where m is 0 or 1, is C.sub.1 -C.sub.36 alkyl or C.sub.7 -C.sub.36 aralkyl, each of which is unsubstituted or substituted by C.sub.5 -C.sub.8 cycloalkyl, is interrupted in the aliphatic part by C.sub.5 -C.sub.8 cycloalkylene or by oxygen or sulfur or --NR.sup.11 -- or is substituted in the aromatic part by 1 to 3 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.3 -C.sub.36 alkenyl; C.sub.5 -C.sub.12 cycloalkyl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub. alkoxy radicals; and R.sup.1, in the case where m is 0, can alternatively be hydrogen; C.sub.1 -C.sub.36 alkoxy or C.sub.7 -C.sub. 36 aralkoxy, each of which is unsubstituted or substituted by C.sub.5 -C.sub.8 cycloalkyl, interrupted in the aliphatic part by C.sub.5 -C.sub.8 cycloalkylene or by oxygen or sulfur or --NR.sup.11 -- or is substituted in the aromatic part by 1 to 3 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.3 -C.sub.36 alkenyloxy; C.sub.5 -C.sub.12 cycloalkoxy which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; or C.sub.6 -C.sub.10 aryloxy which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; R.sup.11 is C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.8 cycloalkyl, phenyl or C.sub.7 -C.sub.9 phenylalkyl; and X is an oxygen or sulfur atom.
摘要翻译：本发明涉及式I（I）的聚醚，其中m为0或1; n为3〜100的整数; R 1在m为0或1的情况下是C 1 -C 36烷基或C 7 -C 36芳烷基，其各自未被取代或被C 5 -C 8环烷基取代，在脂肪族部分被C 5 -C 8亚环烷基或氧或硫或 - 或者在芳族部分被1至3个C 1 -C 4烷基和/或C 1 -C 4烷氧基取代; C3-C36烯基; 未被取代或被1至4个C 1 -C 4烷基和/或C 1 -C 4烷氧基取代的C 5 -C 12环烷基; 未被取代或被1至4个C 1 -C 4烷基和/或C 1 -C 8烷氧基取代的C 6 -C 10芳基; 而在m为0的情况下，R 1可以是氢; C1-C36烷氧基或C7-C36芳烷氧基，其各自未被取代或被C 5 -C 8环烷基取代，在脂族部分由C 5 -C 8亚环烷基或被氧或硫或-NR 11取代，或者在芳族部分被1至3个取代 C 1 -C 4烷基和/或C 1 -C 4烷氧基; C3-C36烯烃氧基; 未被取代或被1至4个C 1 -C 4烷基和/或C 1 -C 4烷氧基取代的C 5 -C 12环烷氧基; 或未被取代或被1至4个C 1 -C 4烷基和/或C 1 -C 4烷氧基取代的C 6 -C 10芳氧基; R11是C1-C18烷基，C5-C8环烷基，苯基或C7-C9苯基烷基; X是氧或硫原子。

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