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1. 发明授权

US06579915B2 Radiation curable adhesive compositions comprising block copolymers having vinyl functionalized polydiene blocks 失效
公开(公告)号：US06579915B2
公开(公告)日：2003-06-17
申请号：US09771764
申请日：2001-01-29
申请人： Mark S. Kroll , Margarita Acevedo , Janelle C. Cameron , Thomas F. Kauffman , Jeffrey S. Lindquist , Eugene R. Simmons , David B. Malcolm , Kathryn A. Coleman
发明人： Mark S. Kroll , Margarita Acevedo , Janelle C. Cameron , Thomas F. Kauffman , Jeffrey S. Lindquist , Eugene R. Simmons , David B. Malcolm , Kathryn A. Coleman
IPC分类号： C08F246
CPC分类号： C09J153/02 , A61L15/585 , C08L2666/02 , C08L2666/24 , C09J7/387 , C09J153/025 , C09J2201/128 , Y10S526/931 , Y10S526/935 , Y10T428/28 , Y10T428/2809 , Y10T428/2826 , Y10T428/2852 , Y10T428/2878 , Y10T428/2883 , Y10T428/31855 , C08L53/02 , C08L25/04 , C08L23/22 , C08L23/16 , C08L23/12 , C08L23/06 , C08L9/00
摘要： The invention is directed to a radiation curable adhesive composition comprising at least one vinyl modified block copolymer having a first polyvinyl aromatic block and a second polydiene block having vinyl functionality, and at least one tackifier. Optionally, the composition may comprises at least one second block copolymer that has not been vinyl modified, at least one platicizer, and at least one wax. The invention is also directed to a double-faced label formed from the composition and the method of producing said label.

2. 发明授权

US06926959B2 Radiation curable adhesive compositions comprising block copolymers having vinyl functionalized polydiene blocks 失效
标题翻译：包含具有乙烯基官能化聚二烯嵌段的嵌段共聚物的可辐射固化粘合剂组合物
公开(公告)号：US06926959B2
公开(公告)日：2005-08-09
申请号：US10425776
申请日：2003-04-29
申请人： Mark S. Kroll , Margarita Acevedo , Janelle C. Cameron , Thomas F. Kauffman , Jeffrey S. Lindquist , Eugene R. Simmons , David B. Malcolm , Kathryn A. Coleman
发明人： Mark S. Kroll , Margarita Acevedo , Janelle C. Cameron , Thomas F. Kauffman , Jeffrey S. Lindquist , Eugene R. Simmons , David B. Malcolm , Kathryn A. Coleman
IPC分类号： A61L24/00 , A61L15/00 , A61L15/58 , C08F2/46 , C08F8/00 , C09J7/02 , C09J123/04 , C09J123/18 , C09J153/02
CPC分类号： C09J153/02 , A61L15/585 , C08L2666/02 , C08L2666/24 , C09J7/387 , C09J153/025 , C09J2201/128 , Y10S526/931 , Y10S526/935 , Y10T428/28 , Y10T428/2809 , Y10T428/2826 , Y10T428/2852 , Y10T428/2878 , Y10T428/2883 , Y10T428/31855 , C08L53/02 , C08L25/04 , C08L23/22 , C08L23/16 , C08L23/12 , C08L23/06 , C08L9/00
摘要： The invention is directed to a radiation curable adhesive composition comprising at least one vinyl modified block copolymer having a first polyvinyl aromatic block and a second polydiene block having vinyl functionality, and at least one tackifier. Optionally, the composition may comprises at least one second block copolymer that has not been vinyl modified, at least one platicizer, and at least one wax. The invention is also directed to a double-faced label formed from the composition and the method of producing said label.
摘要翻译：本发明涉及一种可辐射固化的粘合剂组合物，其包含至少一种具有第一聚乙烯基芳族嵌段和乙烯基官能团的第二聚二烯嵌段的乙烯基改性嵌段共聚物和至少一种增粘剂。任选地，组合物可以包含至少一种未经乙烯基改性的第二嵌段共聚物，至少一种固化剂和至少一种蜡。本发明还涉及由组合物形成的双面标签和制备所述标签的方法。

3. 发明授权

US5869562A Hot melt pressure sensitive adhesive designed for use on high density spun polyolefin film 失效
标题翻译：设计用于高密度聚丙烯薄膜的热熔压敏胶
公开(公告)号：US5869562A
公开(公告)日：1999-02-09
申请号：US829712
申请日：1997-03-28
申请人： Jeffrey S. Lindquist , Janelle C. Cameron , Eugene R. Simmons
发明人： Jeffrey S. Lindquist , Janelle C. Cameron , Eugene R. Simmons
IPC分类号： C09J153/02 , C08L53/02 , C08L57/02 , C08L93/04
CPC分类号： C09J153/02
摘要： This invention relates to an envelope coated with a hot melt pressure sensitive adhesive composition preferably comprising a) from about 10% to about 40% by weight in the adhesive of at least one block copolymer selected from the group consisting of styrene-isoprene-styrene block copolymers, styrene-butadiene-styrene block copolymers and mixtures thereof wherein the block copolymers comprise from about 15% to about 35% styrene by weight in the copolymer and diblock contents from about 0% to about 90% by weight in the copolymer; and b) from about 60% to about 90% by weight in the adhesive of a modifier selected from the group consisting of solid tackifying resins, liquid tackifying resins, liquid elastomers and mixtures thereof. The invention further relates to an improved oil-free pressure sensitive adhesive that is low in viscosity and provides a destructive bond and resists deformation of high density spun polyolefin materials.
摘要翻译：本发明涉及涂覆有热熔压敏粘合剂组合物的外壳，优选地包含a）粘合剂中约10％至约40％重量的至少一种选自苯乙烯 - 异戊二烯 - 苯乙烯嵌段共聚物，苯乙烯 - 丁二烯 - 苯乙烯嵌段共聚物及其混合物，其中嵌段共聚物在共聚物中包含约15重量％至约35重量％的苯乙烯，在共聚物中包含约0重量％至约90重量％的二嵌段含量; 和b）在选自固体增粘树脂，液体增粘树脂，液体弹性体及其混合物的改性剂的粘合剂中约60重量％至约90重量％。本发明还涉及一种改进的无油压敏粘合剂，该粘合剂具有低粘度并提供破坏性粘合并且抵抗高密度纺丝聚烯烃材料的变形。

4. 发明授权

US06582829B1 Hot melt adhesive composition comprising homogeneous ethylene interpolymer and block copolymer 有权
标题翻译：包含均相乙烯互聚物和嵌段共聚物的热熔粘合剂组合物
公开(公告)号：US06582829B1
公开(公告)日：2003-06-24
申请号：US09345684
申请日：1999-06-30
申请人： Thomas H. Quinn , Janelle C. Cameron , Beth M. Eichler-Johnson , Michael S. Keehr , Jeffrey S. Lindquist , David B. Malcolm , Kevin W. McKay , Deepak R. Parikh
发明人： Thomas H. Quinn , Janelle C. Cameron , Beth M. Eichler-Johnson , Michael S. Keehr , Jeffrey S. Lindquist , David B. Malcolm , Kevin W. McKay , Deepak R. Parikh
IPC分类号： B32B2308
CPC分类号： C09J153/02 , C08F210/16 , C08J9/122 , C08J2207/02 , C08J2323/04 , C08L23/0815 , C08L53/02 , C08L93/00 , C08L2205/02 , C08L2205/03 , C08L2666/02 , C08L2666/04 , C08L2666/06 , C08L2666/24 , C09J5/08 , C09J123/0815 , C09J153/025 , C09J2423/00 , C09J2453/00 , C09J2493/00 , Y02P20/582 , Y10T428/31902 , C08F210/14 , C08F2500/08 , C08F2500/02 , C08F2500/03 , C08F2500/12
摘要： A hot melt adhesive composition comprising a) from about 5 wt-% to about 50 wt-% of at least one homogeneous linear or substantially linear ethylene/alpha-olefin interpolymer characterized as having a density from 0.850 to 0.965 g/cm3; b) from about 1 wt-% to about 40 wt-% of at least one block copolymer; and c) from about 10 wt-% to about 75 wt-% of at least one tackifying resin wherein said adhesive does not fail cohesively.
摘要翻译：一种热熔粘合剂组合物，其包含a）约5重量％至约50重量％的至少一种均匀的线性或基本上线性的乙烯/α-烯烃互聚物，其特征在于密度为0.850至0.965g / cm 3; b）约1重量％至约40重量％的至少一种嵌段共聚物; 和c）约10重量％至约75重量％的至少一种增粘树脂，其中所述粘合剂不会内聚失效。

5. 发明授权

US5863977A High molecular weight S-EB-S hot melt adhesive 失效
标题翻译：高分子量S-EB-S热熔胶
公开(公告)号：US5863977A
公开(公告)日：1999-01-26
申请号：US798808
申请日：1997-02-12
申请人： Carolyn A. Fischer , Eugene R. Simmons , Mark S. Kroll , Jeffrey S. Lindquist
发明人： Carolyn A. Fischer , Eugene R. Simmons , Mark S. Kroll , Jeffrey S. Lindquist
IPC分类号： A61L15/58 , C09J153/02 , C08L9/06 , C08L53/02
CPC分类号： C09J153/025 , A61L15/58
摘要： This invention relates to hot melt adhesives comprising a high molecular weight polystyrene-ethylene/butylene-polystyrene block copolymer and articles constructed therefrom. This polymer is useful in a variety of hot melt adhesive applications such as food packaging adhesives, rodent traps, skin attachment adhesives, positioning adhesives, diaper tapes, low tack diaper fastening systems, foam in place gaskets, etc.
摘要翻译：本发明涉及包含高分子量聚苯乙烯 - 乙烯/丁烯 - 聚苯乙烯嵌段共聚物和由其构成的制品的热熔粘合剂。该聚合物可用于各种热熔粘合剂应用，例如食品包装粘合剂，啮齿动物捕集器，皮肤附着粘合剂，定位粘合剂，尿布带，低粘性尿布紧固系统，泡沫垫片等。

6. 发明授权

US06238732B1 Method for making hot melt adhesive pellet comprising continuous coating of pelletizing aid 失效
标题翻译：制备热熔胶片的方法，其包括造粒助剂的连续包衣
公开(公告)号：US06238732B1
公开(公告)日：2001-05-29
申请号：US09583937
申请日：2000-05-31
申请人： Janelle C. Cameron , Carolyn A. Fischer , Nicholas C. Lehman , Jeffrey S. Lindquist , Christopher E. Olson , Steve A. Fox
发明人： Janelle C. Cameron , Carolyn A. Fischer , Nicholas C. Lehman , Jeffrey S. Lindquist , Christopher E. Olson , Steve A. Fox
IPC分类号： B05D510
CPC分类号： C08J3/124 , C08L53/00 , C08L53/02 , C08L53/025 , C08L2666/02 , C08L2666/04 , C08L2666/24 , C09J123/02 , C09J151/00 , C09J153/00 , C09J153/02 , C09J153/025
摘要： This invention relates to a hot melt adhesive composition in pellet form. The hot melt adhesive composition is pressure sensitive, having a storage modulus, G′, at 25° C., of less than about 5×106 dynes/cm2. The pellets are coated with a pelletizing aid on the surface at a concentration preferably ranging from about 1 wt-% to about 30 wt-%. The pelletizing aid is a hot melt adhesive component or a material which does not substantially adversely affect the adhesive properties. The pellets are free-flowing and have a substantially tack-free surface
摘要翻译：本发明涉及一种颗粒形式的热熔粘合剂组合物。热熔粘合剂组合物是压敏的，在25℃下的储能模量G'小于约5×10 6达因/ cm 2。颗粒在表面上用造粒助剂涂覆，浓度优选为约1重量％至约30重量％。造粒助剂是热熔粘合剂组分或对粘合性能没有实质上不利影响的材料。颗粒是自由流动的并且具有基本上无粘性的表面

7. 发明授权

US06120899A Hot melt adhesive pellet comprising continuous coating of pelletizing aid 有权
标题翻译：包含造粒助剂的连续包衣的热熔胶片
公开(公告)号：US06120899A
公开(公告)日：2000-09-19
申请号：US168830
申请日：1998-10-08
申请人： Janelle C. Cameron , Carolyn A. Fischer , Nicholas C. Lehman , Jeffrey S. Lindquist , Christopher E. Olson , Steve A. Fox
发明人： Janelle C. Cameron , Carolyn A. Fischer , Nicholas C. Lehman , Jeffrey S. Lindquist , Christopher E. Olson , Steve A. Fox
IPC分类号： C08J3/12 , C09J5/06 , B32B27/08
CPC分类号： C08J3/124 , Y10T428/2998
摘要： This invention relates to a hot melt adhesive composition in pellet form. The hot melt adhesive composition is pressure sensitive, having a storage modulus, G', at 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2. The pellets are coated with a pelletizing aid on the surface at a concentration preferably ranging from about 1 wt-% to about 30 wt-%. The pelletizing aid is a hot melt adhesive component or a material which does not substantially adversely affect the adhesive properties. The pellets are free-flowing and have a substantially tack-free surface.
摘要翻译：本发明涉及一种颗粒形式的热熔粘合剂组合物。热熔粘合剂组合物是压敏的，在25℃下的储能模量G'小于约5×10 6达因/ cm 2。颗粒在表面上用造粒助剂涂覆，浓度优选为约1重量％至约30重量％。造粒助剂是热熔粘合剂组分或对粘合性能没有实质上不利影响的材料。颗粒是自由流动的并且具有基本上无粘性的表面。

8. 发明授权

US6025071A Removable grade hot melt pressure sensitive adhesive 失效
标题翻译：可拆卸级热熔压敏胶
公开(公告)号：US6025071A
公开(公告)日：2000-02-15
申请号：US956887
申请日：1997-10-23
申请人： Janelle C. Cameron , Jeffrey S. Lindquist
发明人： Janelle C. Cameron , Jeffrey S. Lindquist
IPC分类号： C08L53/02 , C09J7/02 , C09J153/02 , C09J153/00
CPC分类号： C09J7/0221 , C08L53/025 , C09J153/02 , C09J153/025 , C09J2203/334 , Y10T428/2861 , Y10T428/2883
摘要： A removable grade hot melt pressure sensitive adhesive, comprising from about 10% to about 50% by weight of the adhesive of at least one styrene-isoprene-styrene block copolymer having a diblock content of greater than about 50% a melt index of less than about 30 grams/10 minutes; from about 10% to about 40% by weight of the adhesive of at least one tackifying resin having a softening point of less than about 120.degree. C. and from about 10% to about 50% by weight of the adhesive of a liquid plasticizer. The resultant adhesive has 180.degree. peel values to stainless steel of less than about 4.0 pounds per linear inch.
摘要翻译：一种可拆卸的热熔压敏粘合剂，其包含约10重量％至约50重量％的至少一种苯乙烯 - 异戊二烯 - 苯乙烯嵌段共聚物的粘合剂，其具有大于约50％的二嵌段含量，熔体指数小于约30克/ 10分钟; 约10重量％至约40重量％的粘合剂，其具有软化点小于约120℃的粘合剂和约10重量％至约50重量％的液体增塑剂粘合剂。所得到的粘合剂具有180°剥离值至小于约4.0磅/线性英寸的不锈钢。

9. 发明授权

US5869555A Polymeric composition in pellet form 失效
公开(公告)号：US5869555A
公开(公告)日：1999-02-09
申请号：US751828
申请日：1996-11-18
申请人： Eugene R. Simmons , Kevin J. Sweeney , Jeffrey S. Lindquist , Christopher E. Olson , Freddie C. Carter , James R. Farmer
发明人： Eugene R. Simmons , Kevin J. Sweeney , Jeffrey S. Lindquist , Christopher E. Olson , Freddie C. Carter , James R. Farmer
IPC分类号： C08J3/12 , C08J5/12 , C08L23/02 , C08L53/00 , C08L53/02 , C08L101/00 , C09J5/06 , C09J123/02 , C09J151/00 , C09J153/00 , C09J153/02 , C09J201/00 , G06F3/033 , G06F3/039 , C08K5/20 , C08K5/01 , C08L93/04
CPC分类号： C09J153/02 , C08J3/124 , C08L23/02 , C08L53/00 , C08L53/02 , C08L53/025 , C09J123/02 , C09J151/00 , C09J153/00 , C09J153/025
摘要： A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5% by weight to about 90% by weight of a thermoplastic polymer, b) from about 0% by weight to about 65% by weight of a tackifying resin, c) from about 0% to about 50% by weight of a plasticizer, d) up to about 2% by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition has some minimum amount of tackifier or plasticizer and is a pressure sensitive adhesive having a storage modulus, G', at about 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2, and each pellet has a substantially tack-free surface.This invention further discloses a polymeric composition in pellet form suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid. The pelletizing aid substantially surrounds the tacky composition such that the molded articles are substantially free from surface tack.A method of forming the pellets is also disclosed.

10. 发明授权

US5942569A Polymeric composition in pellet form 有权
标题翻译：颗粒形式的聚合物组合物
公开(公告)号：US5942569A
公开(公告)日：1999-08-24
申请号：US143757
申请日：1998-08-31
申请人： Eugene R. Simmons , Kevin J. Sweeney , Jeffrey S. Lindquist , Christopher E. Olson , Freddie C. Carter , James R. Farmer
发明人： Eugene R. Simmons , Kevin J. Sweeney , Jeffrey S. Lindquist , Christopher E. Olson , Freddie C. Carter , James R. Farmer
IPC分类号： C08J3/12 , C08J5/12 , C08L23/02 , C08L53/00 , C08L53/02 , C08L101/00 , C09J5/06 , C09J123/02 , C09J151/00 , C09J153/00 , C09J153/02 , C09J201/00 , G06F3/033 , G06F3/039 , B29C47/38 , B29C47/60 , C08L91/06 , C08L93/04
CPC分类号： C09J153/02 , C08J3/124 , C08L23/02 , C08L53/00 , C08L53/02 , C08L53/025 , C09J123/02 , C09J151/00 , C09J153/00 , C09J153/025
摘要： A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5% by weight to about 90% by weight of a thermoplastic polymer, b) from about 0% by weight to about 65% by weight of a tackifying resin, c) from about 0% to about 50% by weight of a plasticizer, d) up to about 2% by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition has some minimum amount of tackifier or plasticizer and is a pressure sensitive adhesive having a storage modulus, G', at about 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2, and each pellet has a substantially tack-free surface.This invention further discloses a polymeric composition in pellet form suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid. The pelletizing aid substantially surrounds the tacky composition such that the molded articles are substantially free from surface tack.A method of forming the pellets is also disclosed.
摘要翻译：颗粒形式的聚合物组合物包含粘性热熔组合物，其包含a）约5重量％至约90重量％的热塑性聚合物，b）约0重量％至约65重量％的增粘剂树脂，c）约0重量％至约50重量％的增塑剂，d）至多约2重量％的抗氧化剂和造粒助剂，其中该粘性热熔组合物具有一些最小量的增粘剂或增塑剂并且是在约25℃下具有小于约5×10 6达因/ cm 2的储能模量G'的压敏粘合剂，并且每个颗粒具有基本上无粘性的表面。本发明还公开了一种适于模制制品的颗粒形式的聚合物组合物。该组合物包含粘性热熔组合物，其包含至少一种通式A-B-A的高分子量三嵌段共聚物和增塑剂和造粒助剂。造粒助剂基本上包围粘性组合物，使得模塑制品基本上没有表面粘性。还公开了一种形成颗粒的方法。

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