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1. 发明授权

US06692906B1 Silver-(carboxylate-azine toner) particles for photothemographic and thermographic imaging 失效
标题翻译：用于光致变色和热成像的银 - （羧酸盐 - 吖嗪调色剂）颗粒
公开(公告)号：US06692906B1
公开(公告)日：2004-02-17
申请号：US10200426
申请日：2002-07-22
申请人： Mark Lelental , Peter J. Ghyzel , John W. Boettcher , James L. Wakley , David A. Dickinson , Joe E. Maskasky , Roger L. Klaus , Victor P. Scaccia , Thomas Blanton
发明人： Mark Lelental , Peter J. Ghyzel , John W. Boettcher , James L. Wakley , David A. Dickinson , Joe E. Maskasky , Roger L. Klaus , Victor P. Scaccia , Thomas Blanton
IPC分类号： G03C1498
CPC分类号： G03C1/49845 , G03C1/005 , G03C1/49809 , Y10S430/165 , Y10S430/166
摘要： The present disclosure relates to aqueous dispersions of silver (carboxylate-azine toner) particles wherein the azine content of the particles is from about 0.01 to 10% by weight relative to silver carboxylate. The carboxylates are typically silver salts of long chain fatty acids and the azine toners are the compounds that function as development accelerators and toning agents such as phthalazine. These silver (carboxylate-azine) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.
摘要翻译：本公开涉及银（羧酸盐 - 吖嗪调色剂）颗粒的水分散体，其中颗粒的吖嗪含量相对于羧酸银为约0.01至10重量％。羧酸盐通常是长链脂肪酸的银盐，吖嗪调色剂是用作显影促进剂和调色剂如酞嗪的化合物。这些银（羧酸盐 - 吖嗪）颗粒可用于配制可用于水性热成像或光热成像成像元件的成像组合物。

2. 发明授权

US06919171B2 Silver-(carboxylate-azine toner) particles for photothermographic and thermographic imaging 失效
标题翻译：用于光热照相和热成像成像的银 - （羧酸盐 - 吖嗪调色剂）颗粒
公开(公告)号：US06919171B2
公开(公告)日：2005-07-19
申请号：US10744923
申请日：2003-12-23
申请人： Mark Lelental , Peter J. Ghyzel , John W. Boettcher , James L. Wakley , David A. Dickinson , Joe E. Maskasky , Roger L. Klaus , Victor P. Scaccia , Thomas Blanton
发明人： Mark Lelental , Peter J. Ghyzel , John W. Boettcher , James L. Wakley , David A. Dickinson , Joe E. Maskasky , Roger L. Klaus , Victor P. Scaccia , Thomas Blanton
IPC分类号： B41M5/323 , G03C1/005 , G03C1/498 , G03C1/35 , G03C1/494
CPC分类号： G03C1/49845 , G03C1/005 , G03C1/49809 , Y10S430/165 , Y10S430/166
摘要： The present disclosure relates to aqueous dispersions of silver (carboxylate-azine toner) particles wherein the azine content of the particles is from about 0.01 to 10% by weight relative to silver carboxylate. The carboxylates are typically silver salts of long chain fatty acids and the azine toners are the compounds that function as development accelerators and toning agents such as phthalazine. These silver (carboxylate-azine) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.
摘要翻译：本公开涉及银（羧酸盐 - 吖嗪调色剂）颗粒的水分散体，其中颗粒的吖嗪含量相对于羧酸银为约0.01至10重量％。羧酸盐通常是长链脂肪酸的银盐，吖嗪调色剂是用作显影促进剂和调色剂如酞嗪的化合物。这些银（羧酸盐 - 吖嗪）颗粒可用于配制可用于水性热成像或光热成像成像元件的成像组合物。

3. 发明授权

US06387611B2 Phosphoric acid ester surface modifiers for silver carboxylate nanoparticles 失效
标题翻译：用于银羧酸盐纳米粒子的磷酸酯表面改性剂
公开(公告)号：US06387611B2
公开(公告)日：2002-05-14
申请号：US09764665
申请日：2001-01-18
申请人： Mark Lelental , David A. Dickinson , James L. Wakley , Michael W. Orem , Peter J. Ghyzel
发明人： Mark Lelental , David A. Dickinson , James L. Wakley , Michael W. Orem , Peter J. Ghyzel
IPC分类号： G03C1498
CPC分类号： G03C1/498 , G03C1/49809 , G03C1/4989
摘要： There is disclosed an oxidation-reduction imaging forming composition comprising an aqueous based dispersion of (i) nanoparticulate silver carboxylate particles having on the surface of the particles a surface modifier which is a phosphoric acid ester and (ii) an organic reducing agent. In particular, the surface modifiers can be mixtures of mono- and di-esters of orthophosphoric acid and hydroxyl-terminated, oxyethylated long-chain alcohols or oxyethylated alkyl phenols or derivatives thereof. Also disclosed are various compositions including the dispersions including oxidation-reduction imaging forming compositions, thermographic elements and photothermographic compositions and elements. The preferred carboxylate is a silver salt of a long chain fatty acid such as silver behenate. A media milling method and a controlled precipitation method of making the dispersions are also disclosed
摘要翻译：公开了一种氧化还原成像组合物，其包含（i）纳米颗粒状羧酸银颗粒的水性分散体，其在颗粒表面上具有作为磷酸酯的表面改性剂和（ii）有机还原剂。特别地，表面改性剂可以是正磷酸和羟基封端的羟乙基化长链醇或羟乙基化烷基酚或其衍生物的单酯和二酯的混合物。还公开了包括包括氧化还原成像组合物，热成像元件和光热成像组合物和元素的分散体的各种组合物。优选的羧酸酯是长链脂肪酸的银盐，例如山嵛酸银。还公开了制备分散体的介质研磨方法和受控沉淀法

4. 发明授权

US06391537B2 Polyacrylamide surface modifiers for silver carboxylate nanoparticles 失效
标题翻译：用于银羧酸盐纳米粒子的聚丙烯酰胺表面改性剂
公开(公告)号：US06391537B2
公开(公告)日：2002-05-21
申请号：US09764677
申请日：2001-01-18
申请人： Mark Lelental , Alan R. Pitt , David A. Dickinson , James L. Wakley , Peter J. Ghyzel
发明人： Mark Lelental , Alan R. Pitt , David A. Dickinson , James L. Wakley , Peter J. Ghyzel
IPC分类号： G03C1498
CPC分类号： G03C1/49809 , G03C1/38 , G03C2001/03594
摘要： There is disclosed a nanoparticulate dispersion of a silver carboxylate particles having on the surface of the particles a surface modifier which is a nonionic oligomeric surfactant based on vinyl polymer with an amido function. In particular, the surface modifier is acrylamide, methacrylamide or derivatives thereof. Also disclosed are various compositions including the dispersions including oxidation-reduction imaging forming compositions, thermographic elements and photothermographic compositions and elements. The preferred carboxylate is a silver salt of a long chain fatty acid such as silver behenate.
摘要翻译：公开了一种具有在颗粒表面上的羧酸银颗粒的纳米颗粒分散体，该表面改性剂是基于具有酰氨基官能团的乙烯基聚合物的非离子低聚表面活性剂。特别地，表面改性剂是丙烯酰胺，甲基丙烯酰胺或其衍生物。还公开了包括包括氧化还原成像组合物，热成像元件和光热成像组合物和元素的分散体的各种组合物。优选的羧酸酯是长链脂肪酸的银盐，例如山嵛酸银。

5. 发明授权

US06365336B1 Aqueous photothermographic imaging elements comprising aqueous silver halide emulsions precipitated in the presence of cationic starch peptizing agent 失效
标题翻译：包含卤化银水溶液的水性光热成像元件在阳离子淀粉胶溶剂的存在下沉淀
公开(公告)号：US06365336B1
公开(公告)日：2002-04-02
申请号：US09703050
申请日：2000-10-31
申请人： Joe E. Maskasky , David A. Dickinson , Mark Lelental
发明人： Joe E. Maskasky , David A. Dickinson , Mark Lelental
IPC分类号： G03C1498
CPC分类号： G03C1/015 , G03C1/04 , G03C1/49818 , G03C1/49836 , G03C1/49845 , G03C1/49863
摘要： There is disclosed an aqueous photothermographic composition comprising a) a photosensitive silver halide emulsion precipitated in a water dispersible cationic starch peptizing agent and b) an oxidation-reduction imaging forming composition comprising (I) a colloidal dispersion of silver compound particles and (ii) an organic reducing agent. The use of a starch peptizing agent reduces the fog in an element using the composition upon thermal processing.
摘要翻译：公开了一种水性光热敏成像组合物，其包含a）在水分散性阳离子淀粉胶溶剂中沉淀的感光卤化银乳剂和b）氧化还原成像组合物，其包含（I）银化合物颗粒的胶态分散体和（ii）有机还原剂。淀粉胶溶剂的使用通过热处理降低了使用组合物的元素中的雾。

6. 发明授权

US06638708B1 Silver (carboxylate-n-alkyl thiolate) particles for photothermographic of thermographic imaging 失效
标题翻译：用于光热成像光热照相的银（羧酸盐 - 正烷基硫醇盐）颗粒
公开(公告)号：US06638708B1
公开(公告)日：2003-10-28
申请号：US10200417
申请日：2002-07-22
申请人： Peter J. Ghyzel , Mark Lelental , David A. Dickinson , Alan R. Pitt , Trevor J. Wear
发明人： Peter J. Ghyzel , Mark Lelental , David A. Dickinson , Alan R. Pitt , Trevor J. Wear
IPC分类号： G03C1498
CPC分类号： G03C1/49845 , G03C1/49809
摘要： The present disclosure relates to dispersions of silver (carboxylate-n-alkyl thiolate). The carboxylates are typically silver salts of long chain fatty acids and the n-alkyl thiolate is preferably 1-dodecanethiol. These silver (carboxylate-n-alkyl thiolate) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.
摘要翻译：本公开涉及银（羧酸盐 - 正烷基硫醇盐）的分散体。羧酸盐通常是长链脂肪酸的银盐，正烷基硫醇盐优选为1-十二烷硫醇。这些银（羧酸盐 - 正烷基硫醇盐）颗粒可用于配制可用于水性热成像或光热成像成像元件的成像组合物。

7. 发明授权

US06733959B2 Chemically sensitized aqueous-based photothermographic emulsions and materials and methods of using same 失效
标题翻译：化学敏化水性光热敏成像乳剂及其使用方法
公开(公告)号：US06733959B2
公开(公告)日：2004-05-11
申请号：US09923039
申请日：2001-08-06
申请人： Henry J. Gysling , David A. Dickinson , Mark Lelental , John W. Boettcher
发明人： Henry J. Gysling , David A. Dickinson , Mark Lelental , John W. Boettcher
IPC分类号： G03C1498
CPC分类号： G03C1/49845 , G03C1/08 , G03C1/09 , G03C1/498 , G03C2001/098 , Y10S430/145 , Y10S430/165
摘要： Photothermographic materials prepared using aqueous formulations include silver halides that are chemically sensitized using certain tellurium-containing compounds. Such tellurium-containing chemical sensitizing compounds are generally provided in aqueous solution or in an aqueous solid particulate dispersion and can be represented by the following Structure I, II, or III: Te(L)m(X1)n (II) Pd(X2)2[Te(R′)2]2 (III) wherein X represents the same or different COR, CSR, CNRRa, CR, PRRa, or P(OR)2 groups, R and Ra are independently alkyl, alkenyl, or aryl groups, L is a ligand derived from a neutral Lewis base, X1 and X2 independently represent a halo, OCN, SCN, S2CNRRa, S2COR, S2CSR S2P(OR)2, S2PRRa, SeCN, TeCN, CN, SR, OR, alkyl, aryl, N3, or O2CR group, R′ is an alkyl or aryl group, p is 2 or 4, m is 0, 1, 2, or 4, and n is 2 or 4 provided that when m is 0 or 2, n is 2 or 4, and when m is 1 or 4, n is 2.
摘要翻译：使用水性制剂制备的光热照相材料包括使用某些含碲化合物化学增感的卤化银。这种含碲的化学增感化合物通常提供在水溶液或水性固体颗粒分散体中，并且可以由以下结构I，II或III表示：其中X表示相同或不同的COR，CSR，CNRRa，CR， PRRa或P（OR）2基团，R和Ra独立地是烷基，烯基或芳基，L是衍生自中性路易斯碱的配体，X 1和X 2独立地表示卤素，OCN， SCN，S2CNRRa，S2COR，S2CSR S2P（OR）2，S2PRRa，SeCN，TeCN，CN，SR，OR，烷基，芳基，N 3或O 2 CR基团，R'为烷基或芳基，p为2或4， m为0,1,2或4，n为2或4，条件是当m为0或2时，n为2或4，当m为1或4时，n为2。

8. 发明授权

US06800429B2 Imaging materials with conductive layers containing electronically conductive polymer particles 失效
标题翻译：具有导电层的成像材料包含电子导电聚合物颗粒
公开(公告)号：US06800429B2
公开(公告)日：2004-10-05
申请号：US10036155
申请日：2001-12-26
申请人： Mark Lelental , Charles C. Anderson , John M. Pochan , James L. Wakley , James F. Elman
发明人： Mark Lelental , Charles C. Anderson , John M. Pochan , James L. Wakley , James F. Elman
IPC分类号： G03C189
CPC分类号： B41M5/44 , G03C1/85 , G03C1/89 , G03G5/10
摘要： An imaging material comprising a support having disposed thereon: a) at least one image-formning layer, and b) at least one transparent electrically conductive antistatic layer that comprises electronically conductive polymer particles, a neutral-charge conductivity enhancer, and a polymeric binder comprising gelatin or gelatin derivatives.
摘要翻译：一种成像材料，包括其上设置有支撑体的方法：a）至少一个成像层，以及b）至少一个透明的导电抗静电层，其包括电子导电聚合物颗粒，中性电荷导电性增强剂和聚合物粘合剂，明胶或明胶衍生物。

9. 发明授权

US06709808B2 Imaging materials comprising electrically conductive polymer particle layers 失效
标题翻译：成像材料包括导电聚合物颗粒层
公开(公告)号：US06709808B2
公开(公告)日：2004-03-23
申请号：US10139684
申请日：2002-05-06
申请人： Mark Lelental , Gary M. Mosehauer , Roger J. Owers , James L. Wakley
发明人： Mark Lelental , Gary M. Mosehauer , Roger J. Owers , James L. Wakley
IPC分类号： G03C183
CPC分类号： B41M5/44 , G03C1/7614 , G03C1/89 , G03F7/093 , G03G7/00 , G03G7/002 , G03G7/0026 , G03G7/0053
摘要： Image-forming materials including photographic, thermographic, and thermally-developable imaging materials include one or more transparent electrically conductive, non-charging layers to provide antistatic control on one or both sides of subbed or unsubbed supports. The electrically conductive, non-charging layers comprise colloidal, electrically conductive polymer particles that can be dispersed in a film-forming binder in an amount to provide from about 10 to about 90 volume % of polymer particles. Particularly useful polymer particles include pyrrole-containing, thiophene-containing, and aniline-containing polymers. The particles generally exhibit a packed powder specific resistivity of 105 ohm-cm or less and generally have a mean diameter of 0.5 &mgr;m or less. The electrically conductive, non-charging layers generally exhibit a surface electrical resistivity of less than 1×1012 ohm per square.
摘要翻译：包括照相，热成像和热显影成像材料的图像形成材料包括一个或多个透明导电的不带电层，以在副床或未支撑的支撑件的一侧或两侧上提供抗静电控制。导电的不带电层包括胶体的导电聚合物颗粒，其可分散在成膜粘合剂中，其量为约10至约90体积％的聚合物颗粒。特别有用的聚合物颗粒包括含吡咯，含噻吩和含苯胺的聚合物。颗粒通常表现出10 -5欧姆 - 厘米或更小的填充粉末电阻率，并且通常具有0.5μm或更小的平均直径。导电的非充电层通常表现出小于1×10 12欧姆/平方的表面电阻率。

10. 发明申请

US20050048391A1 Electrographic patterning of conductive electrode layers containing electrically-conductive polymeric materials 有权
标题翻译：包含导电聚合物材料的导电电极层的电子图案化
公开(公告)号：US20050048391A1
公开(公告)日：2005-03-03
申请号：US10648418
申请日：2003-08-26
申请人： Mark Lelental , Mitchell Burberry , Charles Anderson
发明人： Mark Lelental , Mitchell Burberry , Charles Anderson
IPC分类号： G03G7/00 , G03G9/09 , G03G13/26 , H01L51/00 , G03G15/20 , G03G13/20
CPC分类号： G03G7/0093 , G03G9/0926 , G03G13/26 , H01L51/0015 , H01L51/0021 , H01L51/0022
摘要： A method for producing an electrode pattern in a conductive polymeric layer comprising the steps of: (a) contacting a charge pattern with an electrographic developer composition comprising a carrier and marking particles having a polarity opposite that of said charge pattern thereby producing a developed image pattern, wherein said marking particles contain a conductivity modifier or a precursor thereof; (b) applying the developed image pattern to a conductive layer containing a conductive polymer on a substrate and (c) transferring said image pattern onto a said conductive layer. An element formed by the method is also disclosed.
摘要翻译：一种用于在导电聚合物层中制备电极图案的方法，包括以下步骤：（a）使电荷图案与包含载体的电子显像组合物接触，并且将极性与所述电荷图案的极性相反的标记颗粒接触，从而产生显影图像图案其中所述标记颗粒含有电导率调节剂或其前体; （b）将显影的图像图案应用于在衬底上含有导电聚合物的导电层，和（c）将所述图案图案转印到所述导电层上。还公开了通过该方法形成的元件。

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