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1. 发明授权

US5863439A Process for separation and preconcentration of radium from water 失效
标题翻译：从水中分离和预浓缩镭的方法
公开(公告)号：US5863439A
公开(公告)日：1999-01-26
申请号：US870914
申请日：1997-06-06
申请人： Mark Dietz , E. Philip Horwitz , Renato Chiarizia , Richard A. Bartsch
发明人： Mark Dietz , E. Philip Horwitz , Renato Chiarizia , Richard A. Bartsch
IPC分类号： C22B60/00 , G21F9/12 , C02F1/42
CPC分类号： C22B60/00 , G21F9/12 , Y10S423/14
摘要： A process for preconcentrating and separating radium from a contaminated solution containing at least water and radium includes the steps of adding a quantity of a water-soluble macrocyclic polyether to the contaminated solution to form a combined solution. An acid is added to the combined solution to form an acidic combined solution having an �H.sup.+ ! concentration of about 0.5M. The acidic combined solution is contacted with a sulfonic acid-based strong acid cation exchange medium or a organophilic sulfonic acid medium having a plurality of binding sites thereon to bind the radium thereto and to form a radium-depleted solution. The radium-depleted solution is separated from the strong acid cation exchange medium or organophilic sulfonic acid medium. The radium remaining bound to the exchange medium or organophilic reagent is then stripped from the exchange medium or organophilic medium and the activity of the radium is measured.
摘要翻译：用于将镭从至少含有水和镭的污染溶液中预浓缩和分离的方法包括以下步骤：向受污染的溶液中加入一定数量的水溶性大环聚醚以形成组合溶液。向合并的溶液中加入酸以形成[H +]浓度为约0.5M的酸性组合溶液。将酸性组合溶液与其上具有多个结合位点的磺酸基强酸阳离子交换介质或亲能性磺酸介质接触，以将镭与其结合并形成贫铀溶液。从强酸阳离子交换介质或亲有机磺酸介质中分离贫铀溶液。然后从交换介质或亲有机介质中剥离剩余与交换介质或亲有机试剂结合的镭，并测定镭的活性。

2. 发明授权

US5888398A Composition and process for separating cesium ions from an acidic aqueous solution also containing other ions 失效
标题翻译：从含有其他离子的酸性水溶液中分离铯离子的组成和方法
公开(公告)号：US5888398A
公开(公告)日：1999-03-30
申请号：US789653
申请日：1997-01-27
申请人： Mark L. Dietz , E. Philip Horwitz , Richard A. Bartsch , Richard E. Barrans, Jr. , David Rausch
发明人： Mark L. Dietz , E. Philip Horwitz , Richard A. Bartsch , Richard E. Barrans, Jr. , David Rausch
IPC分类号： C07D323/00 , C22B3/26 , C22B26/10 , B01D11/00 , B01D11/02 , C01D17/00
CPC分类号： C07D323/00 , C22B26/10 , C22B3/002 , Y02P10/234
摘要： A crown ether cesium ion extractant is disclosed as is its synthesis. The crown ether cesium ion extractant is useful for the selective purification of cesium ions from aqueous acidic media, and more particularly useful for the isolation of radioactive cesium-137 from nuclear waste streams. Processes for isolating cesium ions from aqueous acidic media using the crown ether cesium extractant are disclosed as are processes for recycling the crown ether cesium extractant and processes for recovering cesium from a crown ether cesium extractant solution.
摘要翻译：公开了冠醚铯离子提取剂的合成。冠醚铯离子萃取剂可用于从酸性水溶液中选择性纯化铯离子，更特别适用于从核废料流中分离放射性铯-137。公开了使用冠醚铯提取剂从含水酸性介质中分离铯离子的方法，用于回收冠醚铯提取剂的方法和从冠醚铯提取剂溶液回收铯的方法。

3. 发明授权

US5670550A Ion exchange polymers for anion separations 失效
标题翻译：用于阴离子分离的离子交换聚合物
公开(公告)号：US5670550A
公开(公告)日：1997-09-23
申请号：US476964
申请日：1995-06-07
申请人： Gordon D. Jarvinen , S. Fredric Marsh , Richard A. Bartsch
发明人： Gordon D. Jarvinen , S. Fredric Marsh , Richard A. Bartsch
IPC分类号： B01J41/04 , B01J41/14 , C02F1/42 , C08F8/30 , C08F8/32 , C08F8/44 , C08F26/06 , C08F226/06 , C08F226/08 , B01J41/06 , C08F8/40
CPC分类号： C08F226/06 , B01J41/04 , B01J41/14 , C02F1/42 , C08F8/44
摘要： Anion exchange resins including at least two positively charged sites and aell-defined spacing between the positive sites are provided together with a process of removing anions or anionic metal complexes from aqueous solutions by use of such resins. The resins can be substituted poly(vinylpyridine) and substituted polystyrene.
摘要翻译：提供包含至少两个带正电点的阴离子交换树脂和阳性位点之间明确界定的间隔，以及通过使用这种树脂从水溶液中除去阴离子或阴离子金属络合物的方法。树脂可以是取代的聚（乙烯基吡啶）和取代的聚苯乙烯。

4. 发明授权

US08158088B2 Extractant compositions for co-extracting cesium and strontium, a method of separating cesium and strontium from an aqueous feed, and calixarene compounds 失效
标题翻译：共萃取铯和锶的萃取剂组合物，从含水原料中分离铯和锶的方法和杯芳烃化合物
公开(公告)号：US08158088B2
公开(公告)日：2012-04-17
申请号：US12268189
申请日：2008-11-10
申请人： Dean R. Peterman , David H. Meikrantz , Jack D. Law , Catherine L. Riddle , Terry A. Todd , Mitchell R. Greenhalgh , Richard D. Tillotson , Richard A. Bartsch , Bruce A. Moyer , Laetitia H. Delmau , Peter V. Bonnesen
发明人： Dean R. Peterman , David H. Meikrantz , Jack D. Law , Catherine L. Riddle , Terry A. Todd , Mitchell R. Greenhalgh , Richard D. Tillotson , Richard A. Bartsch , Bruce A. Moyer , Laetitia H. Delmau , Peter V. Bonnesen
IPC分类号： B01D11/00
CPC分类号： C07D323/00 , C07C43/23
摘要： A mixed extractant solvent that includes at least one dialkyloxycalix[4]arenebenzocrown-6 compound, 4′,4′,(5′)-di-(t-butyldicyclohexano)-18-crown-6, at least one modifier, and, optionally, a diluent. The dialkyloxycalix[4]arenebenzocrown-6 compound is 1,3-alternate-25,27-di(octyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(decyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(dodecyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(2-ethylhexyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(3,7-dimethyloctyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(4-butyloctyl-1-oxy)calix[4]arenebenzocrown-6, or combinations thereof. The modifier is a primary alcohol. A method of separating cesium and strontium from an aqueous feed is also disclosed, as are dialkyloxycalix[4]arenebenzocrown-6 compounds and an alcohol modifier.
摘要翻译：包含至少一种二烷氧基钙[4]芳基苯并呋喃-6化合物，4'，4'，（5'） - 二 - （叔丁基二环己基）-18-冠-6的混合萃取剂溶剂，至少一种改性剂，任选地，稀释剂。二烷氧基钙[4]芳烃基苯并呋喃-6化合物是1,3-交替的25,27-二（辛氧基）杯[4]芳烃基苯并噻唑-6，1,3-交替的25,27-二（癸氧基）杯[4] 芳族苯并茂-6，1,3-交替的25,27-二（十二烷氧基）杯[4]芳烃基苯并茂-6，1,3-交替的25,27-二（2-乙基己基-1-氧）杯[4] （3,7-二甲基辛基-1-氧基）杯[4]芳烃基苯并呋喃-6,1,3交替的25,27-二（4-丁基辛基 - 1-氧基）杯[4]芳烃基苯并呋喃-6或其组合。改性剂是伯醇。还公开了一种从含水原料中分离铯和锶的方法，二烷基氧基钙[4]芳烃基苯并呋喃-6化合物和醇改性剂也是如此。

5. 发明授权

US4421923A Ring substituted crown ethers and method of producing same 失效
标题翻译：环取代的冠醚及其制备方法
公开(公告)号：US4421923A
公开(公告)日：1983-12-20
申请号：US215680
申请日：1980-12-12
申请人： Richard A. Bartsch
发明人： Richard A. Bartsch
IPC分类号： C02F1/68 , C07D323/00 , C07D498/10 , C22B3/36
CPC分类号： C07D323/00 , C02F1/683 , C22B3/0036 , Y02P10/234
摘要： There is provided a new class of crown ethers characterized by an --OH functional group attached to a carbon atom in the heterocyclic ether ring portion and derivatives thereof. A novel process for making such crown ethers is also provided which is characterized by reacting a bisphenol ether with an epihalohydrin to effect ring closure and provide the appendant --OH group.These products are especially useful as complexing agents.
摘要翻译：提供了一类新的冠醚，其特征在于连接到杂环醚环部分中的碳原子上的-OH官能团及其衍生物。还提供了制备这种冠醚的新方法，其特征在于使双酚醚与表卤代醇反应以实现闭环并提供上述的-OH基团。这些产品特别用作络合剂。

6. 发明授权

US5478953A Process for the preparation of cis-syn-cis-4,4' (5')-[di-t-butyldicyclohexano]-18-crown-6 失效
标题翻译：顺式顺式-4,4'（5'） - [二叔丁基二环己基] -18-冠-6的制备方法
公开(公告)号：US5478953A
公开(公告)日：1995-12-26
申请号：US333783
申请日：1994-11-03
申请人： Michael J. Gula , Richard A. Bartsch
发明人： Michael J. Gula , Richard A. Bartsch
IPC分类号： C07D323/00
CPC分类号： C07D323/00
摘要： A process for preparing 4,4'(5')-[di-t-butyldicyclohexano]-18-crown-6 containing an enhanced amount of an isomer that extracts strontium ions from aqueous solution is disclosed. According to the process, an anhydrous reaction mixture is prepared containing 4,4'(5')-[di-t-butyldibenzo]-18-crown-6 as substrate dissolved in a C.sub.2 -C.sub.6 alcohol-containing solvent that can also contain benzene, toluene or xylene, a C.sub.2 -C.sub.6 carboxylic acid or anhydride and a 5 percent of rhodium on alumina particle catalyst. The resulting reaction medium is hydrogenated at about 200-1000 psi, at a temperature of about 35.degree.-120.degree. C. for a time period sufficient to reduce at least 90 percent of the substrate.
摘要翻译：公开了一种制备含有增加量的从水溶液中提取锶离子的异构体的4,4'（5'） - [二叔丁基二环己基] -18-冠-6的方法。根据该方法，制备含有4,4'（5'） - [二叔丁基二苯并] -18-冠-6作为底物的无水反应混合物，所述底物溶于含C2-C6醇的溶剂中，所述溶剂也可含有苯，甲苯或二甲苯，C 2 -C 6羧酸或酸酐和5％的氧化铀颗粒催化剂上的铑。所得反应介质在约200-1000psi，约35-120℃的温度下氢化一段足以减少至少90％底物的时间。

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