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    • 5. 发明授权
    • Silica-rich porous substrates with reduced tendencies for breaking or
cracking
    • 富含二氧化硅的多孔基材具有降低的破裂或破裂倾向
    • US4933307A
    • 1990-06-12
    • US184304
    • 1988-04-21
    • William P. MarshallJoseph J. HammelHerbert W. BarchRoy D. HegedusWalter J. Robertson
    • William P. MarshallJoseph J. HammelHerbert W. BarchRoy D. HegedusWalter J. Robertson
    • C03C11/00
    • C03C11/00
    • Porous, silica-rich shapes have improved strength and abrasion resistance by leaching the precursor glass shape in preconditioned acid having silica ion and at least one common ion that is also present in the precursor glass shape. The precursor glass shapes have shapes such as fibers, hollow fibers, tubes, rods, beads, hollow spheres and plates and compositions having 30-75 volume percent silica and at least 10-65 volume percent nonsiliceous acid extractable components. Preconditioning of the acid solution results from a pretreatment of the acid with compounds that dissociate into the ions when added to the acid solution or with shapes, particles or fragments of glass compositions different from or similar to the glass shape to be leached so long as the glass composition has extractable material to provide the silica ion and at least one common ion.
    • 多孔,二氧化硅的形状通过在具有二氧化硅离子的预处理酸和在前体玻璃形状中也存在的至少一种共同离子浸出前体玻璃形状而提高了强度和耐磨性。 前体玻璃形状具有诸如纤维,中空纤维,管,棒,珠,中空球和板的形状以及具有30-75体积%二氧化硅和至少10-65体积百分比的非硅酸可萃取组分的组合物。 酸溶液的预处理是由于当加入到酸溶液中时与分解成离子的化合物或与要浸出的玻璃形状不同或类似的玻璃组合物的形状,颗粒或碎片的酸预处理,只要 玻璃组合物具有可提取材料以提供二氧化硅离子和至少一种共同离子。
    • 6. 发明授权
    • Process of gas enrichment with porous siliceous-containing material
    • 含多孔含硅质材料的气体富集过程
    • US4842620A
    • 1989-06-27
    • US127150
    • 1987-12-01
    • Joseph J. HammelWalter J. RobertsonWilliam P. MarshallHerbert W. BarchBalbhadra DaasMichael A. SmootRichard P. Beaver
    • Joseph J. HammelWalter J. RobertsonWilliam P. MarshallHerbert W. BarchBalbhadra DaasMichael A. SmootRichard P. Beaver
    • B01D53/22B01D71/04C03C11/00C03C13/00
    • B01D53/22B01D71/04C03C11/005C03C13/00
    • A hollow, porous, silica-rich fiber, a process for producing same, and a process for enriching at least one gas from a gaseous mixture utilizing at least one fiber to result in gas separations with good permeability and good selectivity. The fiber is non-crystalline and has pore sizes having a range of 1 to around 50 Angstroms in diameter and a mean pore size of around less than 20 Angstroms in diameter and a filament diameter in the range of 1 to around 250 microns and a wall thickness in the range of around 1 to 50 microns. The fibers with a fine pore structure and thin walls are produced by forming hollow glass fibers hindered or fully phase-separable boron and/or alkali metal glass composition, by attenuation from melt at speeds in the range of 500 ft/min to around 30,000 ft/min. The phase-separable glass fibers are heat treated to yield limited phase-separated hollow glass fibers and these fibers are leached to extract acid and/or water soluble components. For fully phase-separable, hollow glass fibers, a limited heat treatment is used before leaching, where the heat treatment is at a temperature of around 300 to less than 480.degree. C. for a time of around 5 minutes to 24 hours. The hindered, phase-separable, hollow glass fibers are heat treated at a temperature in the range of about 400 to about 600.degree. C. At least one hollow, porous, silica-rich fiber is used in a device suitable to contain a gaseous mixture and the permeate is withdrawn from the silica-rich fiber at the opposite side from that at which the gaseous mixture contacts the hollow, porous fiber.
    • 中空的,多孔的,富二氧化硅的纤维,其制造方法,以及利用至少一种纤维从气体混合物中富集至少一种气体的方法,以产生具有良好渗透性和良好选择性的气体分离。 纤维是非结晶的,并且具有直径为1至约50埃范围的孔径,平均孔径直径小于20埃,丝直径在1至约250微米的范围内,壁厚 厚度在1到50微米的范围内。 具有细孔结构和薄壁的纤维通过形成受阻或完全相分离的硼和/或碱金属玻璃组合物的中空玻璃纤维,通过从500英尺/分钟至约30,000英尺 /分钟 相分离玻璃纤维被热处理以产生有限的相分离中空玻璃纤维,并且将这些纤维浸出以提取酸和/或水溶性组分。 对于完全相分离的中空玻璃纤维,在浸出之前使用有限的热处理,其中热处理在约300至小于480℃的温度下约5分钟至24小时。 受阻的可相分离的中空玻璃纤维在约400至约600℃的温度范围内进行热处理。至少一种中空多孔的富含二氧化硅的纤维用于适于容纳气体混合物的装置 并且渗透物在与二氧化硅富集的纤维相反侧的气体混合物与中空的多孔纤维接触的相反侧排出。