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    • 3. 发明授权
    • Adhesive of epoxy resin, amine-terminated ban and conductive filler
    • 环氧树脂粘合剂,胺封端和导电填料
    • US5929141A
    • 1999-07-27
    • US901153
    • 1997-07-28
    • Steven E. LauDeborah S. HuffRalph D. HermansenE. Dean Johnston
    • Steven E. LauDeborah S. HuffRalph D. HermansenE. Dean Johnston
    • C08G59/22C08G59/50C09J9/02C09J163/00H05K3/32C08K3/08
    • H05K3/321C08G59/22C08G59/50C09J163/00H05K2201/0133
    • A flexible, electrically-conductive, one-component epoxy adhesive composition and method for making the same are provided. The present adhesive composition comprises: (a) at least one polyepoxide resin having a hardness not exceeding a durometer Shore D reading of about 45 when cured with a stoichiometric amount of diethylene triamine; (b) a substantially stoichiometric amount of curing agent including at least one amine-terminated butadiene-acrylonitrile polymer; and (c) an electrically-conductive filler. The epoxy adhesive, upon cure, has a volume resistivity not exceeding about 10.sup.-3 ohm-cm at room temperature and a drop resistance such that a 6-mil-thick (0.015 cm) bond effected by the adhesive can withstand at least six 60-inch (152 cm) drops onto a hard surface. Optional components in the epoxy adhesive include secondary rigid and semi-rigid epoxy resins, secondary amine curing agents, non-reactive flexibilizers, diluents, and processing aids. The adhesive bonds achieved using these epoxy adhesives are non-brittle, flexible, resilient, and drop-resistant, while also exhibiting strong adhesion and good processing characteristics.
    • 提供柔性导电的单组分环氧粘合剂组合物及其制备方法。 本发明的粘合剂组合物包含:(a)当化学计量量的二亚乙基三胺固化时,至少一种聚环氧树脂的硬度不超过肖氏D读数约45; (b)基本上化学计量的固化剂,包括至少一种胺封端的丁二烯 - 丙烯腈聚合物; 和(c)导电填料。 环氧树脂粘合剂在固化时的体积电阻率在室温下不超过约10-3欧姆 - 厘米,并且具有防滴落性,使得由粘合剂实现的6密耳厚(0.015cm)的粘合剂能够承受至少六个60 -inch(152厘米)滴在硬表面上。 环氧树脂粘合剂中的任选组分包括二级刚性和半刚性环氧树脂,仲胺固化剂,非反应性增韧剂,稀释剂和加工助剂。 使用这些环氧树脂粘合剂的粘合剂粘合剂是非脆性的,柔性的,有弹性的和防滴落的,同时还具有很强的附着力和良好的加工特性。
    • 4. 发明授权
    • Room-temperature stable, one-component, electrically-conductive,
flexible epoxy adhesives
    • 室温稳定,单组分,导电,柔性环氧胶粘剂
    • US5575956A
    • 1996-11-19
    • US504002
    • 1995-07-19
    • Ralph D. HermansenSteven E. Lau
    • Ralph D. HermansenSteven E. Lau
    • C08G59/22C08G59/32C08G59/36C08G59/38C08G59/50C08G59/56C08K3/08C08L63/04C09J9/02C09J163/00C09J163/04H01B1/20H01B1/22
    • H01B1/22
    • A flexible electrically-conductive epoxy-based adhesive composition and method for making the same are provided. The present adhesive composition comprises: (a) a polymer mixture comprising at least one polyepoxide resin having a hardness not exceeding a durometer Shore A reading of 45, when cured with a stoichiometric amount of diethylene triamine ("DETA"), and a substantially stoichiometric amount of at least one latent epoxy resin curing agent; and (b) an electrically-conductive filler comprising a metal. Optional components include secondary epoxy resins, non-reactive flexibilizers, diluents, and processing aids. The present adhesive composition is rheologically stable for weeks as a single component mixture at room temperature and is curable in less than two hours at a temperature ranging from about 100.degree. C. to 140.degree. C., whereupon the cured adhesive composition exhibits a durometer Shore A of less than 95 and a volume resistivity less than about 10.sup.-2 ohm-cm at room temperature.
    • 提供柔性导电性环氧类粘合剂组合物及其制造方法。 本发明的粘合剂组合物包括:(a)当用化学计量量的二亚乙基三胺(“DETA”)固化时,包含至少一种硬度不超过硬度的肖氏A读数为45的聚环氧树脂的聚合物混合物和基本上化学计量 至少一种潜在环氧树脂固化剂的量; 和(b)包含金属的导电填料。 可选组分包括二级环氧树脂,非反应性增韧剂,稀释剂和加工助剂。 本粘合剂组合物在室温下作为单一组分混合物流变稳定了几周,并且在约100℃至140℃的温度下在少于两小时内可固化,于是固化的粘合剂组合物显示出硬度为Shore A小于95,体积电阻率小于约10-2欧姆 - 厘米。
    • 6. 发明授权
    • Epoxy-terminated prepolymer of polyepoxide and diamine with curing agent
    • 聚环氧化物和二胺与固化剂的环氧封端预聚物
    • US5965673A
    • 1999-10-12
    • US835671
    • 1997-04-10
    • Ralph D. HermansenSteven E. Lau
    • Ralph D. HermansenSteven E. Lau
    • C08G59/06C08G59/08C08G59/40C08L63/00C08K3/36C08L63/02C08L63/04
    • C08G59/4042C08G59/066C08G59/08
    • A solid, one-component, flexible epoxy-based composition and method for making the same are provided. The present compositions comprise: (a) an epoxy-terminated prepolymer formed by reacting at least four moles of a polyepoxide resin with approximately one mole of a diamine compound, wherein at least one of the polyepoxide resin and diamine compound is solid at room temperature, and wherein the prepolymer is rheologically stable for weeks as a single component mixture at room temperature and, and (b) a substantially stoichiometric amount of an epoxy resin curing agent selected from the group consisting of a heat-curable, latent epoxy resin curing agent and a room temperature-curable ketimine curing agent. Optional components include thixotropic agents, diluents, fillers, anti-oxidants, and processing aids. The present uncured epoxy-based compositions upon cure, exhibit a durometer Shore D of less than about 45 (or a durometer Shore A of less than about 100).
    • 提供固体,单组分,柔性环氧基组合物及其制备方法。 本发明的组合物包括:(a)通过使至少四摩尔的聚环氧树脂与约1摩尔的二胺化合物反应形成的环氧基封端的预聚物,其中至少一种聚环氧树脂和二胺化合物在室温下是固体, 并且其中所述预聚物在室温下作为单一组分混合物流变稳定数周,和(b)基本上化学计量的环氧树脂固化剂,其选自可热固化的潜在环氧树脂固化剂和 室温固化的酮亚胺固化剂。 任选组分包括触变剂,稀释剂,填充剂,抗氧化剂和加工助剂。 目前未固化的环氧基组合物在固化时表现出小于约45的肖氏硬度(或肖氏A的硬度小于约100)。
    • 8. 发明授权
    • Adhesive of flexible epoxy resin and latent dihydrazide
    • 柔性环氧树脂和潜在二酰肼的粘合剂
    • US06723803B1
    • 2004-04-20
    • US08700133
    • 1996-08-20
    • Ralph D. HermansenSteven E. Lau
    • Ralph D. HermansenSteven E. Lau
    • C08G5940
    • C08G59/4035C08G59/20C08G59/22C09J163/00
    • Flexible epoxy-based adhesive compositions which remain Theologically stable at room temperature in an uncured state comprise: (a) at least one flexible polyepoxide resin having a hardness not exceeding a durometer Shore D reading of 45 when cured with a stoichiometric amount of diethylene triamine (“DETA”); and (b) a substantially stoichiometric amount of at least one latent epoxy resin curing agent. Optionally, the adhesive composition may also incorporate one or more semi-flexible resins. Other optional components include fillers, thixotropic agents, and flexibilizers. The adhesive composition provicdes an epoxy-based adhesive composition that is storable for weeks as a single component mixture at room temperature, curable at temperatures ranging from about 100° C. to 125° C. in less than two hours, and flexible upon curing to temperatures as low as minus 50° C., exhibiting a durometer Shore A of less than about 95.
    • 在未固化状态下在室温下保持稳定的柔性环氧基粘合剂组合物包含:(a)当化学计量量的二亚乙基三胺固化时,至少一种硬度不超过硬度的肖氏D读数为45的柔性聚环氧树脂( “DETA”); 和(b)基本上化学计量的至少一种潜在环氧树脂固化剂。 任选地,粘合剂组合物还可以掺入一种或多种半柔性树脂。 其它任选的组分包括填料,触变剂和增韧剂。 粘合剂组合物提供环氧基粘合剂组合物,其可在室温下作为单一组分混合物储存数周,可在不到两小时内在约100℃至125℃的温度范围内固化,并且在固化至 温度低至零下50摄氏度,表现出肖氏A的硬度小于约95。
    • 10. 发明授权
    • Room-temperature stable, one-component, thermally-conductive, flexible
epoxy adhesives
    • 室温稳定,单组分,导热,柔性环氧胶粘剂
    • US6060539A
    • 2000-05-09
    • US877980
    • 1997-06-18
    • Ralph D. HermansenSteven E. Lau
    • Ralph D. HermansenSteven E. Lau
    • C08G59/18C08G59/20C08G59/40C08K3/22C08K3/34C08K3/38C09J163/00C08K3/28
    • C08K3/34C08G59/184C08G59/20C08G59/4035C08K3/22C08K3/38C09J163/00
    • A flexible thermally-conductive epoxy-based adhesive composition and method for making the same are provided. The present adhesive composition comprises (a) a polymer mixture comprising at least one polyepoxide resin having a hardness not exceeding a durometer Shore D reading of about 45, when cured with a stoichiometric amount of diethylene triamine ("DETA"), and a substantially stoichiometric amount of at least one latent epoxy resin curing agent; and (b) a thermally-conductive filler. Optional components include secondary epoxy resins, non-reactive flexibilizers, diluents, and processing aids. The present adhesive composition is rheologically stable for weeks or even months at room temperature and is curable in less than one hour at a temperature ranging from about 100.degree. C. to 140.degree. C., whereupon the cured adhesive composition exhibits a durometer Shore A of less than about 90 and a thermal conductivity exceeding 0.4 BTU/hr-ft-.degree. F. (0.7 W/m-K).
    • 提供柔性导热性环氧系粘合剂组合物及其制造方法。 本发明的粘合剂组合物包含(a)当用化学计量的二亚乙基三胺(“DETA”)固化时,包含至少一种硬度不超过约45的硬度的肖氏D读数的聚环氧树脂的聚合物混合物和基本上化学计量 至少一种潜在环氧树脂固化剂的量; 和(b)导热填料。 可选组分包括二级环氧树脂,非反应性增韧剂,稀释剂和加工助剂。 本粘合剂组合物在室温下流变稳定数周或甚至几个月,并且在约100℃至140℃的温度下在少于1小时内可固化,因此固化的粘合剂组合物显示硬度为肖氏A 小于约90,热导率超过0.4BTU / hr-ft-°F(0.7W / mK)。