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1. 发明授权

US4788764A Method of making a unitized electrode assembly 失效
标题翻译：制造单元电极组件的方法
公开(公告)号：US4788764A
公开(公告)日：1988-12-06
申请号：US149037
申请日：1988-01-26
申请人： Marilyn J. Niksa , Gerald R. Pohto , Leslie K. Lakatos , Douglas J. Wheeler , Frank Solomon , Andrew J. Niksa , Thomas J. Schue , Yury Genodman , Thomas R. Turk , Daniel P. Hagel
发明人： Marilyn J. Niksa , Gerald R. Pohto , Leslie K. Lakatos , Douglas J. Wheeler , Frank Solomon , Andrew J. Niksa , Thomas J. Schue , Yury Genodman , Thomas R. Turk , Daniel P. Hagel
IPC分类号： H01M4/02 , H01M4/86 , H01M12/06 , B23P19/00
CPC分类号： H01M12/065 , H01M4/8626 , H01M2004/024 , Y10T29/49108 , Y10T29/53139
摘要： A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.
摘要翻译：消耗性金属阳极型的电池组件现在已经被构造成用于准备组装以及拆卸。在非导电且至少基本上惰性的电池体中，提供用于容纳开放结构的非消耗性阳极笼的空间。保持架具有用于促进阳极插入的开口顶部。使用模块化阴极，包括以片状形式夹紧在格栅加强空气阴极周围的外围电流导体框架。空气阴极可以是双网格的。阴极框架可以在组装期间用耐电解密封剂以及粘合剂进行密封。所得到的阴极组件可以组装在电池体外部并容易地插入其中，或者可以随后容易地从其中移除。

2. 发明授权

US4756980A Battery with modular air cathode and anode cage 失效
标题翻译：带模块化空气阴极和阳极笼的电池
公开(公告)号：US4756980A
公开(公告)日：1988-07-12
申请号：US64352
申请日：1987-06-22
申请人： Marilyn J. Niksa , Gerald R. Pohto , Leslie K. Lakatos , Douglas J. Wheeler , Andrew J. Niksa , Thomas J. Schue , Thomas R. Turk
发明人： Marilyn J. Niksa , Gerald R. Pohto , Leslie K. Lakatos , Douglas J. Wheeler , Andrew J. Niksa , Thomas J. Schue , Thomas R. Turk
IPC分类号： H01M4/02 , H01M4/86 , H01M12/06
CPC分类号： H01M12/065 , H01M4/8626 , H01M2004/024
摘要： A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.
摘要翻译：消耗性金属阳极型的电池组件现在已经被构造成用于准备组装以及拆卸。在非导电且至少基本上惰性的电池体中，提供用于容纳开放结构的非消耗性阳极笼的空间。保持架具有用于促进阳极插入的开口顶部。使用模块化阴极，包括以片状形式夹紧在格栅加强空气阴极周围的外围电流导体框架。空气阴极可以是双网格的。阴极框架可以在组装期间用耐电解密封剂以及粘合剂进行密封。所得到的阴极组件可以组装在电池体的外部并容易地插入其中，或者可以随后容易地从其中移除。

3. 发明授权

US4693946A Battery with modular air cathode and anode cage 失效
公开(公告)号：US4693946A
公开(公告)日：1987-09-15
申请号：US838484
申请日：1986-03-11
申请人： Marilyn J. Niksa , Gerald R. Pohto , Leslie K. Lakatos , Douglas J. Wheeler , Andrew J. Niksa , Thomas J. Schue
发明人： Marilyn J. Niksa , Gerald R. Pohto , Leslie K. Lakatos , Douglas J. Wheeler , Andrew J. Niksa , Thomas J. Schue
IPC分类号： H01M4/02 , H01M4/86 , H01M12/06 , H01M2/10
CPC分类号： H01M4/8626 , H01M12/065 , H01M2004/024
摘要： A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.

4. 发明授权

US4927717A Bipolar metal/air battery 失效
标题翻译：双极金属/空气电池
公开(公告)号：US4927717A
公开(公告)日：1990-05-22
申请号：US332086
申请日：1989-04-03
申请人： Homer L. Turley , Marilyn J. Niksa , Gerald R. Pohto , Andrew J. Niksa
发明人： Homer L. Turley , Marilyn J. Niksa , Gerald R. Pohto , Andrew J. Niksa
IPC分类号： H01M4/02 , H01M4/86 , H01M6/48 , H01M8/02 , H01M10/04 , H01M12/06
CPC分类号： H01M8/0247 , H01M10/0413 , H01M10/0468 , H01M12/065 , H01M4/8626 , H01M8/0232 , H01M2004/024 , H01M6/48
摘要： A bipolar battery assembly of the consumable metal anode type is described. Contact between internal battery elements is now enhanced by air assisted, internally exerted compressive force. Battery elements are constructed in modular manner that assists in the ease of battery assembly and disassembly. Furthermore, ease of anode replenishment is maintained. A multitude of individual cells can now be joined together in an efficient bipolar assembly cell stack for augmented electrical energy generation. In addition to being bipolar, the battery is of rugged construction, providing for dependable, long-life operation that is desirably maintenance-free.
摘要翻译：描述了可消耗金属阳极型的双极电池组件。内部电池元件之间的接触现在通过空气辅助，内部施加的压力增强。电池元件以模块化方式构造，有助于电池组装和拆卸的便利。此外，维持阳极充电的容易性。现在可以在有效的双极组装电池堆中连接多个单个电池，以增强电能产生。除了双极性之外，电池具有坚固的结构，提供可靠的，长寿命的操作，这是理想的免维护的。

5. 发明授权

US4828939A Bipolar metal/air battery 失效
标题翻译：双极金属/空气电池
公开(公告)号：US4828939A
公开(公告)日：1989-05-09
申请号：US56567
申请日：1987-06-01
申请人： Homer L. Turley , Marilyn J. Niksa , Gerald R. Pohto , Andrew J. Niksa
发明人： Homer L. Turley , Marilyn J. Niksa , Gerald R. Pohto , Andrew J. Niksa
IPC分类号： H01M4/02 , H01M4/86 , H01M6/48 , H01M8/02 , H01M10/04 , H01M12/06
CPC分类号： H01M8/0232 , H01M10/0413 , H01M10/0468 , H01M12/065 , H01M4/8626 , H01M2004/024 , H01M6/48
摘要： A bipolar battery assembly of the consumable metal anode type is described. Contact between internal battery elements is now enhanced by air assisted, internally exerted compressive force. Battery elements are constructed in modular manner that assists in the ease of battery assembly and disassembly. Furthermore, ease of anode replenishment is maintained. A multitude of individual cells can now be joined together in an efficient bipolar assembly cell stack for augmented electrical energy generation. In addition to being bipolar, the battery is of rugged construction, providing for dependable, long-life operation that is desirably maintenance-free.

6. 发明申请

US20120085571A1 MULTI-LAYER MIXED METAL OXIDE ELECTRODE AND METHOD FOR MAKING SAME 有权
标题翻译：多层混合金属氧化物电极及其制造方法
公开(公告)号：US20120085571A1
公开(公告)日：2012-04-12
申请号：US13117373
申请日：2011-05-27
申请人： Marilyn J. Niksa , Andrew J. Niksa
发明人： Marilyn J. Niksa , Andrew J. Niksa
IPC分类号： H05K1/05
CPC分类号： C25B11/0484 , C23C18/1216 , C23C18/1225 , C23C26/00 , C23C26/02 , C23C28/04
摘要： A composition and method of manufacture of electrodes having controlled electrochemical activity to allow the electrodes to be designed for a variety of electro-oxidation processes. The electrodes are comprised of a compact coating deposited onto a conductive substrate, the coating being formed as multiple layers of a mixture of one or more platinum group metal oxides and one or more valve metal oxides. The formation of multiple layers allows the concentrations of platinum group metal and valve metal to be varied for each layer as desired for an application. For example, an electrode structure can be manufactured for use as an anode in electroplating processes, such that the oxidation of the organic additives in the electrolyte is markedly inhibited. Another electrode can be manufactured to operate at high anodic potentials in aqueous electrolytes to generate strong oxidants, e.g., hydrogen peroxide or ozone.
摘要翻译：具有受控的电化学活性以使电极被设计用于各种电氧化工艺的电极的组合物和方法。电极由沉积在导电基底上的致密涂层组成，涂层形成为多层由一种或多种铂族金属氧化物和一种或多种阀金属氧化物的混合物形成。多层的形成允许根据需要为每层改变铂族金属和阀金属的浓度。例如，可以在电镀工艺中制造用作阳极的电极结构，使得电解质中的有机添加剂的氧化被显着抑制。可以制造另一电极以在水性电解质中在高阳极电位下操作，以产生强氧化剂，例如过氧化氢或臭氧。

7. 发明授权

US4911993A Bipolar, filter-press, consumable metal anode battery 失效
标题翻译：双极，压滤，消耗式金属阳极电池
公开(公告)号：US4911993A
公开(公告)日：1990-03-27
申请号：US150797
申请日：1988-02-01
申请人： Homer L. Turley , Marilyn J. Niksa , Richard J. Coin , Thomas J. Schue
发明人： Homer L. Turley , Marilyn J. Niksa , Richard J. Coin , Thomas J. Schue
IPC分类号： H01M12/08 , H01M4/00 , H01M4/86 , H01M6/48 , H01M10/04 , H01M12/06
CPC分类号： H01M4/8631 , H01M10/0418 , H01M12/065 , H01M4/00 , H01M6/48
摘要： A bipolar battery having a consumable metal anode and being of the filter-press type is described. Internal battery contact is obtained by pressure connection transmitted virtually all, to completely, by end bulkheads. A multitude of adjoning cells can be placed together in a bipolar assembly cell stack. Yet the battery is compact and lightweight.

8. 发明授权

US08580091B2 Multi-layer mixed metal oxide electrode and method for making same 有权
标题翻译：多层混合金属氧化物电极及其制造方法
公开(公告)号：US08580091B2
公开(公告)日：2013-11-12
申请号：US13117373
申请日：2011-05-27
申请人： Marilyn J. Niksa , Andrew J. Niksa
发明人： Marilyn J. Niksa , Andrew J. Niksa
IPC分类号： C25B11/08 , C25B11/10 , C25B11/06
CPC分类号： C25B11/0484 , C23C18/1216 , C23C18/1225 , C23C26/00 , C23C26/02 , C23C28/04
摘要： A composition and method of manufacture of electrodes having controlled electrochemical activity to allow the electrodes to be designed for a variety of electro-oxidation processes. The electrodes are comprised of a compact coating deposited onto a conductive substrate, the coating being formed as multiple layers of a mixture of one or more platinum group metal oxides and one or more valve metal oxides. The formation of multiple layers allows the concentrations of platinum group metal and valve metal to be varied for each layer as desired for an application. For example, an electrode structure can be manufactured for use as an anode in electroplating processes, such that the oxidation of the organic additives in the electrolyte is markedly inhibited. Another electrode can be manufactured to operate at high anodic potentials in aqueous electrolytes to generate strong oxidants, e.g., hydrogen peroxide or ozone.
摘要翻译：具有受控的电化学活性以使电极被设计用于各种电氧化工艺的电极的组合物和方法。电极由沉积在导电基底上的致密涂层组成，涂层形成为多层由一种或多种铂族金属氧化物和一种或多种阀金属氧化物的混合物形成。多层的形成允许根据需要为每层改变铂族金属和阀金属的浓度。例如，可以在电镀工艺中制造用作阳极的电极结构，使得电解质中的有机添加剂的氧化被显着抑制。可以制造另一电极以在水性电解质中在高阳极电位下操作，以产生强氧化剂，例如过氧化氢或臭氧。

9. 发明授权

US5049457A Electrolyte for an aluminum air-battery comprising an anti-foaming agent and corrosion exhibitor 失效
标题翻译：用于包含消泡剂和腐蚀参展商的铝空气电池的电解液
公开(公告)号：US5049457A
公开(公告)日：1991-09-17
申请号：US473767
申请日：1990-02-02
申请人： Marilyn J. Niksa , Andrew J. Niksa , Jay M. Noscal
发明人： Marilyn J. Niksa , Andrew J. Niksa , Jay M. Noscal
IPC分类号： H01M2/12 , H01M6/48 , H01M6/50 , H01M10/50 , H01M10/52 , H01M12/06
CPC分类号： H01M2/1264 , H01M10/52 , H01M12/065 , H01M6/50 , H01M6/48
摘要： An aqueous electrolyte aluminum-air battery comprises one or more cells, each cell comprising a frame which defines an electrolyte chamber. The frame is made of a rigid material inactive to the electrolyte. The cell has a consumable aluminum anode and an air cathode spaced from the anode by said electrolyte chamber. Means are provided for admitting electrolyte solution into the electrolyte chamber. A vent exposes the electrolyte chamber to atmosphere. A hydrophobic membrane which is impermeable to the passage of electrolyte but permeable to the passage of hydrogen closes the vent. A surface of each cell anode is exposed to the flow of air. The amount of surface exposed is effective to dissipate heat generated at the anode.
摘要翻译：含水电解质铝 - 空气电池包括一个或多个电池，每个电池包括限定电解质室的框架。框架由对电解质无活性的刚性材料制成。电池具有可消耗的铝阳极和通过所述电解质室与阳极隔开的空气阴极。提供了用于将电解质溶液引入电解质室的装置。通风孔将电解液室暴露在大气中。对电解液通过而不透气但可透过氢气的疏水膜封闭通气孔。每个电池阳极的表面暴露于空气流中。暴露的表面的量有效地散发在阳极产生的热量。

10. 发明申请

US20110135562A1 TWO STAGE PROCESS FOR ELECTROCHEMICALLY GENERATING HYPOCHLOROUS ACID THROUGH CLOSED LOOP, CONTINUOUS BATCH PROCESSING OF BRINE 审中-公开
标题翻译：通过闭合环路电化学产生高氯酸的两步法，连续加工
公开(公告)号：US20110135562A1
公开(公告)日：2011-06-09
申请号：US12952570
申请日：2010-11-23
申请人： Marilyn J. Niksa , Andrew J. Niksa , Marc J. Epstein , Steven Seiden
发明人： Marilyn J. Niksa , Andrew J. Niksa , Marc J. Epstein , Steven Seiden
IPC分类号： C25B1/26 , C01B11/04 , C25B9/00 , C25B15/00
CPC分类号： C25B1/26 , C01B11/04 , C01B11/062 , C25B15/00
摘要： High concentrations of hypochlorous acid can be produced from, most typically, brine using an system of simple design with minimum residual salt production, reduced power consumption, and at high operating efficiencies. This is accomplished by separating the system into two operations, each of which is preferably optimized. This process employs at least two electrochemical cells, the first of which has no separator between the anode and cathode and generates a high-strength hypochlorite solution. The hypochlorite is then diluted to a desired chlorine concentration and/or pH and fed into the anode compartment of a second electrochemical cell wherein the electrodes are separated by a barrier, such as, for example, a membrane or diaphragm. The separated cell produces a solution containing predominantly hypochlorous acid. Separation of the neutralization processes allows storage of hypochlorite which has a much greater stability in regards to temperature which can then be subsequently converted into hypochlorous acid at point of use or as needed or desired.
摘要翻译：可以使用简单设计的系统，最常见的盐水生产高浓度的次氯酸，具有最小的残留盐产量，降低的功率消耗和高运行效率。这通过将系统分离成两个操作来实现，每个操作优选地被优化。该方法采用至少两个电化学电池，其中第一个电池在阳极和阴极之间没有隔板，并产生高强度的次氯酸盐溶液。然后将次氯酸盐稀释至所需的氯浓度和/或pH，并进料到第二电化学电池的阳极室中，其中电极被隔离物隔离，例如隔膜或隔膜。分离的细胞产生主要含有次氯酸的溶液。中和过程的分离允许存储相对于温度具有更大稳定性的次氯酸盐，然后随后可以在使用点或根据需要或期望的情况下将其转化为次氯酸。

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