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1. 发明授权

US09266808B2 Method for the hydroformylation of olefins 有权
标题翻译：烯烃加氢甲酰化的方法
公开(公告)号：US09266808B2
公开(公告)日：2016-02-23
申请号：US12516855
申请日：2007-11-29
申请人： Marcus Sigl , Frank Poplow , Rainer Papp , Thomas Mackewitz , Dag Wiebelhaus , Rocco Paciello , Thomas Heldemann , Frank Heimann , Stefan Bitterlich , Martin Volland , Sven Crone , Christoph Obler
发明人： Marcus Sigl , Frank Poplow , Rainer Papp , Thomas Mackewitz , Dag Wiebelhaus , Rocco Paciello , Thomas Heldemann , Frank Heimann , Stefan Bitterlich , Martin Volland , Sven Crone , Christoph Obler
IPC分类号： C07C29/141 , C07C45/50 , C07C5/25 , C07C45/74
CPC分类号： C07C45/50 , C07C5/2506 , C07C29/141 , C07C45/74 , C07C47/02 , C07C11/08 , C07C31/125 , C07C47/21
摘要： The present invention relates to a process for preparing hydroformylation products of olefins having at least four carbon atoms, in which a high proportion of both the linear Ci-olefins having a terminal double bond comprised in the olefin-comprising feed used and of the linear Ci-olefins having an internal double bond is converted into hydroformylation products. Furthermore, the invention relates to a process for preparing 2-propylheptanol which comprises such a hydroformylation process.
摘要翻译：本发明涉及一种制备具有至少四个碳原子的烯烃的加氢甲酰化产物的方法，其中在所用含烯烃的原料中包含的具有末端双键的直链C 1 -C 20烯烃和线性C 1 具有内部双键的烯烃转化为加氢甲酰化产物。此外，本发明涉及一种制备2-丙基庚醇的方法，其包括这种加氢甲酰化方法。

2. 发明申请

US20100048959A1 METHOD FOR THE HYDROFORMYLATION OF OLEFINS 有权
标题翻译：烯烃氢化方法
公开(公告)号：US20100048959A1
公开(公告)日：2010-02-25
申请号：US12516855
申请日：2007-11-29
申请人： Marcus Sigl , Frank Poplow , Rainer Papp , Thomas Mackewitz , Dag Wiebelhaus , Rocco Paciello , Thomas Heldemann , Frank Heimann , Stefan Bitterlich , Martin Volland , Sven Crone , Christoph Obler
发明人： Marcus Sigl , Frank Poplow , Rainer Papp , Thomas Mackewitz , Dag Wiebelhaus , Rocco Paciello , Thomas Heldemann , Frank Heimann , Stefan Bitterlich , Martin Volland , Sven Crone , Christoph Obler
IPC分类号： C07C45/41 , C07C29/151
CPC分类号： C07C45/50 , C07C5/2506 , C07C29/141 , C07C45/74 , C07C47/02 , C07C11/08 , C07C31/125 , C07C47/21
摘要： The present invention relates to a process for preparing hydroformylation products of olefins having at least four carbon atoms, in which a high proportion of both the linear Ci-olefins having a terminal double bond comprised in the olefin-comprising feed used and of the linear Ci-olefins having an internal double bond is converted into hydroformylation products. Furthermore, the invention relates to a process for preparing 2-propylheptanol which comprises such a hydroformylation process.
摘要翻译：本发明涉及一种制备具有至少四个碳原子的烯烃的加氢甲酰化产物的方法，其中在所用含烯烃的原料中包含的具有末端双键的直链C 1 -C 20烯烃和线性C 1 具有内部双键的烯烃转化为加氢甲酰化产物。此外，本发明涉及一种制备2-丙基庚醇的方法，其包括这种加氢甲酰化方法。

3. 发明授权

US07714179B2 Method for the production of C5 aldehydes and propene from a C4 stream containing 1-butene and 2-butene 有权
标题翻译：从含有1-丁烯和2-丁烯的C4流中生产C5醛和丙烯的方法
公开(公告)号：US07714179B2
公开(公告)日：2010-05-11
申请号：US11661543
申请日：2005-08-06
申请人： Marcus Sigl , Markus Schubert , Jürgen Stephan , Rainer Papp , Frank Poplow
发明人： Marcus Sigl , Markus Schubert , Jürgen Stephan , Rainer Papp , Frank Poplow
IPC分类号： C07C6/00 , C07C45/49
CPC分类号： C07C6/04 , C07C7/13 , C07C45/50 , C07C11/06 , C07C11/08 , C07C47/02
摘要： Processes for preparing a C5 aldehyde and propene are disclosed, the processes comprising: (a) providing a feedstream, the feedstream comprising butane, 1-butene, 2-butene and 1,3-butadiene, the 1,3-butadiene present in the feedstream in an amount up to 1000 ppm; (b) contacting the feedstream with hydrogen and carbon monoxide in the presence of a hydroformylation catalyst to form a 2-butene-rich butane stream and a C5 aldehyde; (c) separating the 2-butene-rich butane stream and the C5 aldehyde; and (d) contacting the 2-butene-rich butane stream with ethene in the presence of a metathesis catalyst to form a propene-containing hydrocarbon stream.
摘要翻译：公开了制备C5醛和丙烯的方法，所述方法包括：（a）提供进料流，所述进料流包含丁烷，1-丁烯，2-丁烯和1,3-丁二烯，所述1,3-丁二烯存在于进料流量高达1000 ppm; （b）在加氢甲酰化催化剂存在下使进料流与氢气和一氧化碳接触以形成富含2-丁烯的丁烷流和C5醛; （c）分离富含2-丁烯的丁烷流和C5醛; 和（d）在复分解催化剂存在下使富含2-丁烯的丁烷流与乙烯接触以形成含丙烯烃流。

4. 发明申请

US20090023882A1 PROCESS FOR PREPARATION OF POLYISOBUTYLENE WHOSE CONTENT OF TERMINAL DOUBLE BONDS IS MORE THAN 50% FROM AN INDUSTRIAL C4 HYDROCARBON STREAM COMPRISING 1-BUTENE, 2-BUTENE AND ISOBUTENE 审中-公开
标题翻译：用于制备聚异丁烯的方法包含1-BOTENE，2-BOTENE和ISOBUTENE的端子双重含量的含量超过了工业C4烃类流体的50％以上
公开(公告)号：US20090023882A1
公开(公告)日：2009-01-22
申请号：US12278590
申请日：2007-02-15
申请人： Phillip Hanefeld , Hans-Michael Walter , Matthias Kiefer , Helmut Mach , Thomas Wettling , Marcus Sigl , Markus Schubert , Jurgen Stephan , Rainer Papp , Frank Poplow
发明人： Phillip Hanefeld , Hans-Michael Walter , Matthias Kiefer , Helmut Mach , Thomas Wettling , Marcus Sigl , Markus Schubert , Jurgen Stephan , Rainer Papp , Frank Poplow
IPC分类号： C08F110/10
CPC分类号： C10G57/02 , C08F110/10 , C10G25/00 , C10G2300/1044 , C10G2300/1092 , C08F2/00
摘要： Preparation of polyisobutylene having a content of terminal double bonds of more than 50% by polymerizing isobutene using a polymerization catalyst customary therefor from a technical 1-butene-, 2-butene- and isobutene-containing C4 hydrocarbon stream which may comprise up to 3000 ppm by weight, of 1,3-butadiene, by reducing the content of oxygenates in the C4 hydrocarbon stream before the polymerization of the isobutene by contacting it with an inorganic adsorbent at a pressure of from 1 to 20 bar and a temperature of from 20 to 220° C.
摘要翻译：通过聚合催化剂制备具有大于50％的末端双键的聚异丁烯，所用的聚合催化剂通常来自可以包含高达3000ppm的1-丁烯，2-丁烯和异丁烷的C4烃流通过在异丁烯聚合之前通过将其与无机吸附剂在1至20巴的压力和20至20℃的温度下接触来降低C4烃流中的含氧化合物的含量，从而降低1,3-丁二烯的含量 220°C

5. 发明申请

US20080033223A1 Method for the Production of C5 Aldehydes and Propene from a C4 Stream Containing 1-Butene and 2-Butene 有权
标题翻译：从含有1-丁烯和2-丁烯的C4流中制备C5醛和丙烯的方法
公开(公告)号：US20080033223A1
公开(公告)日：2008-02-07
申请号：US11661543
申请日：2005-08-06
申请人： Marcus Sigl , Markus Schubert , Jurgen Stephan , Rainer Papp , Frank Poplow
发明人： Marcus Sigl , Markus Schubert , Jurgen Stephan , Rainer Papp , Frank Poplow
IPC分类号： C07C6/04
CPC分类号： C07C6/04 , C07C7/13 , C07C45/50 , C07C11/06 , C07C11/08 , C07C47/02
摘要： Processes for preparing a C5 aldehyde and propene are disclosed, the processes comprising: (a) providing a feedstream, the feedstream comprising butane, 1-butene, 2-butene and 1,3-butadiene, the 1,3-butadiene present in the feedstream in an amount up to 1000 ppm; (b) contacting the feedstream with hydrogen and carbon monoxide in the presence of a hydroformylation catalsyt to form a 2-butene-rich butane stream and a C5 aldehyde; (c) separating the 2-butene-rich butane stream and the C5 aldehyde; and (d) contacting the 2-butene-rich butane stream with ethene in the presence of a metathesis catalyst to form a propene-containing hydrocarbon stream.
摘要翻译：公开了制备C 5 H 5醛和丙烯的方法，所述方法包括：（a）提供进料流，所述进料流包含丁烷，1-丁烯，2-丁烯和1,3-丁二烯，存在于进料流中的1,3-丁二烯以高达1000ppm的量存在; （b）在加氢甲酰化催化剂存在下使进料流与氢气和一氧化碳接触以形成富含2-丁烯的丁烷流和C 5 H 5醛; （c）分离富含2-丁烯的丁烷流和C 5 H 5醛; 和（d）在复分解催化剂存在下使富含2-丁烯的丁烷流与乙烯接触以形成含丙烯烃流。

6. 发明申请

US20080200745A1 Method For Producing Propene From 2-Butene And Isobutene-Rich Feeding Flows 审中-公开
标题翻译：从2-丁烯和异丁烯丰富的进料流中生产丙烯的方法
公开(公告)号：US20080200745A1
公开(公告)日：2008-08-21
申请号：US11817250
申请日：2006-02-24
申请人： Marcus Sigl , Markus Schubert , Jurgen Stephan , Frank Poplow
发明人： Marcus Sigl , Markus Schubert , Jurgen Stephan , Frank Poplow
IPC分类号： C07C2/00
CPC分类号： C07C11/02 , C07C6/04 , C07C2521/04 , C07C2523/30 , C07C2523/36 , Y02P30/464
摘要： Process for preparing a stream consisting essentially of ethene (stream C2=), a stream consisting essentially of propene (stream C3=), a stream consisting essentially of isobutene and possibly other olefins having 4 carbon atoms (stream C4=) and a stream consisting essentially of 2-methyl-2-butene and possibly 2-butene (stream C5=), and, if appropriate, a stream which comprises other hydrocarbons (stream Cx) and may consist of a plurality of separate substreams, which comprises a metathesis step in which a C4-hydrocarbon stream comprising at least 15% by weight of 2-butenes, at least 5% by weight of isobutene and not more than 5% by weight of 1-butene (feed stream) is brought into contact with ethene in the presence of a customary metathesis catalyst and the resulting hydrocarbon stream is fractionated to give the streams C2=, C3=, C4= and, if appropriate, Cx and all or part of the stream C5= is recirculated to the metathesis step.
摘要翻译：用于制备基本上由乙烯（料流C 2 H 2）组成的料流的方法，基本上由丙烯（料流C 3 H 3） =基本上由异丁烯和可能的具有4个碳原子的其它烯烃（流C 4 H 4）组成的料流）和基本上由2-甲基 -2-丁烯和可能的2-丁烯（流C 5 H 5），以及如果合适的话，包含其它烃（流C 1 H 2 O） SUB>），并且可以由多个单独的子流组成，其包括复分解步骤，其中包含至少15重量％的2-丁烯的C 4 - 烃烃流，至少5％的在常规复分解催化剂的存在下，异丁烯的重量和不超过5％（重量）的1-丁烯（进料流）与乙烯接触，并将所得烃流分馏，得到料流C 2， / SUB> ^{= ，C 3 = 并且如果合适的话，C＆gt; x＆gt;和全部或部分流C＆lt; 5＆gt;＆lt; / SUP>再循环到复分解步骤。}

7. 发明授权

US08658849B2 Process for the separation of unbranched hydrocarbons from their branched isomers 失效
标题翻译：从支链异构体中分离未分支烃的方法
公开(公告)号：US08658849B2
公开(公告)日：2014-02-25
申请号：US12668436
申请日：2008-06-30
申请人： Markus Schubert , Ulrich Mueller , Christoph Kiener , Ingo Richter , William Dolan , Frank Poplow
发明人： Markus Schubert , Ulrich Mueller , Christoph Kiener , Ingo Richter , William Dolan , Frank Poplow
IPC分类号： C07C7/13
CPC分类号： C07C7/12 , B01J20/22 , B01J20/226 , B01J2220/56 , C07C7/135 , C10G25/003 , C07C9/00
摘要： The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of—contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.
摘要翻译：本发明涉及从含有非支链烃和非支链烃的至少一种支链异构体的流体混合物中分离至少一种未分支的C 4 -C 20烃的方法，其包括使流体混合物与吸附剂，其包含多孔金属有机骨架材料，该材料包含与至少一种金属离子配位结合的至少一种至少二齿有机化合物，以获得非支化烃被吸附，其中至少一种至少二齿有机化合物是单环，衍生自选自吡咯，α-吡啶酮和γ-吡啶酮的至少一种杂环的双环或多环系统，并且具有至少两个环氮并且是未取代的或带有一个或多个独立地选自以下的取代基：的卤素，C 1-6 - 烷基，苯基，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，苯基和OC 1-6 - 烷基，其中取代基C 1-6 - 烷基和苯基是未取代的或具有一个或多个独立地选自卤素，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，和OC 1-6烷基。本发明还涉及所述多孔金属 - 有机骨架材料在从其支化异构体中分离未分支烃的方法中的用途。

8. 发明申请

US20110160504A1 PROCESS FOR PREPARING A C4-OLEFIN MIXTURE BY SELECTIVE HYDROGENATION AND METATHESIS PROCESS FOR USING THIS STREAM 有权
标题翻译：通过选择性氢化和使用本流程的METATHESIS过程制备C4-烯烃混合物的方法
公开(公告)号：US20110160504A1
公开(公告)日：2011-06-30
申请号：US13042142
申请日：2011-03-07
申请人： Jürgen Stephan , Andreas Brodhagen , Markus Schubert , Frank Poplow , Michael Röper , Thomas Hill
发明人： Jürgen Stephan , Andreas Brodhagen , Markus Schubert , Frank Poplow , Michael Röper , Thomas Hill
IPC分类号： C07C5/05
CPC分类号： C07C11/08 , C07C6/04 , C07C2523/44 , C07C11/107 , C07C11/10
摘要： A C4-olefin mixture having a 1,3-butadiene content of from 100 to 500 ppm and a content of 1,2-dienes of less than 10 ppm is described. The present invention further provides a process for preparing this C4-olefin mixture and provides for its use in a metathesis reaction for preparing 2-pentene and/or 3-hexene.
摘要翻译：描述1,3-丁二烯含量为100-500ppm，1,2-二烯含量小于10ppm的C 4 - 烯烃混合物。本发明还提供了一种制备该C 4烯烃混合物的方法，并提供其在复分解反应中用于制备2-戊烯和/或3-己烯的用途。

9. 发明授权

US07518020B2 Method for controlling the reactor admission temperature during the production of methylamine 有权
标题翻译：在甲胺生产过程中控制反应器入口温度的方法
公开(公告)号：US07518020B2
公开(公告)日：2009-04-14
申请号：US10573185
申请日：2004-09-24
申请人： Werner Reutemann , Rolf Wambsganβ , Frank Poplow , Theodor Weber , Karl-Heinz Roβ , Manfred Julius
发明人： Werner Reutemann , Rolf Wambsganβ , Frank Poplow , Theodor Weber , Karl-Heinz Roβ , Manfred Julius
IPC分类号： C07C209/16
CPC分类号： C07C209/16 , C07C211/04
摘要： The invention relates to a process for preparing methylamines by gas-phase reaction of methanol and ammonia as starting materials at a pressure in the range from 15 to 30 bar in the presence of heterogeneous catalyst. The starting materials are vaporized in one or more heat exchangers (1, 2, 3), superheated to produce a feed gas stream and subsequently fed into a reactor (4), with the mixing of the starting materials being able to be carried out in the feed stream to one of the heat exchangers (1, 2, 3) or at any desired position in a heat exchanger (1, 2, 3). A product gas stream comprising monomethylamine, dimethylamine and trimethylamine and also reaction by-products is taken off from the reactor (4). To control the reactor inlet temperature of the starting materials to a temperature in the range from 360° C. to 370° C., all or some of the feed gas stream or the product gas stream is passed through an adjustable valve (5) in order to vary the pressure and thus the condensation temperature.
摘要翻译：本发明涉及通过甲醇和氨作为起始原料在非均相催化剂存在下在15至30巴的压力下气相反应制备甲胺的方法。起始材料在一个或多个热交换器（1,2,3）中蒸发，过热以产生进料气流，并随后进料到反应器（4）中，原料的混合能够进行到一个热交换器（1,2,3）或在热交换器（1,2,3）中的任何期望位置的进料流。从反应器（4）中取出包含一甲胺，二甲胺和三甲胺以及反应副产物的产物气流。为了将原料的反应器入口温度控制在360℃至370℃的温度范围内，所有或一些进料气流或产物气流通过可调节阀（5），其中以改变压力，从而改变冷凝温度。

10. 发明申请

US20080254976A1 ACTIVATED METATHESIS CATALYSTS 失效
标题翻译：活化的METATHESIS催化剂
公开(公告)号：US20080254976A1
公开(公告)日：2008-10-16
申请号：US12098165
申请日：2008-04-04
申请人： Markus SCHUBERT , Michael Hesse , Jurgen Stephan , Volker Bohm , Andreas Brodhagen , Frank Poplow , Martina Sinner-Lang , Uwe Diehlmann , Gerhard Cox , Jochen Pfeifer
发明人： Markus SCHUBERT , Michael Hesse , Jurgen Stephan , Volker Bohm , Andreas Brodhagen , Frank Poplow , Martina Sinner-Lang , Uwe Diehlmann , Gerhard Cox , Jochen Pfeifer
IPC分类号： B01J21/08
CPC分类号： C07C6/04 , B01J21/08 , B01J23/28 , B01J23/30 , B01J23/36 , B01J27/22 , B01J37/0203 , B01J37/082 , C07C2523/28 , C07C2523/30 , C07C2523/36 , Y02P20/52 , C07C11/02 , C07C11/107 , C07C11/06
摘要： The present invention provides a process for preparing a supported catalyst (catalyst C) having a support (support S) selected from among oxides, phosphates, silicates, carbides, borides and nitrides of main group elements and elements of transition groups VI and II and mixtures of the abovementioned compounds and an active component (activator A) comprising one or more compounds containing one or more elements of transition groups V, VI and VII customary for the catalysis of metathesis reactions.
摘要翻译：本发明提供一种制备负载型催化剂（催化剂C）的方法，所述负载型催化剂（催化剂C）具有选自主要元素的氧化物，磷酸盐，硅酸盐，碳化物，硼化物和氮化物中的载体（载体S）和转变基团VI和II的元素以及混合物的上述化合物和包含一种或多种含有一种或多种通常用于复分解反应催化的过渡基团V，VI和VII元素的化合物（活化剂A）。

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