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    • 2. 发明授权
    • Process and apparatus for generating hydrogen
    • 用于产生氢气的方法和装置
    • US07931709B2
    • 2011-04-26
    • US11869577
    • 2007-10-09
    • Marcus FranzGeorg HartelJurgen Kunzel
    • Marcus FranzGeorg HartelJurgen Kunzel
    • B01J7/00B01J8/04
    • B01J8/0496B01J8/025B01J8/0285B01J8/0411B01J2208/00141B01J2208/00203B01J2208/00309B01J2208/0053B01J2219/00265C01B3/363C01B3/386C01B2203/0255C01B2203/0261C01B2203/066C01B2203/142H01M8/0618H01M8/0631Y02P20/129
    • A process is described for generating hydrogen through the oxidation of fuels that contain chemically bound hydrogen, in particular hydrocarbons, having the following process steps: a) introducing the fuel (1) as well as the oxidation agent (2) into a reactor (3) having a porous material (4′) that is embodied in such a way that flame propagation in a direction opposite the direction of flow is prevented, and b) reacting the fuel with the oxidation agent in partial oxidation so that hydrogen is obtained in gaseous form. In addition, an apparatus for generating hydrogen that has a reactor that contains a porous material (4, 4′), and the reactor (3) is embodied as a tubular reactor that has a central chamber (5) to introduce the fuel and the oxidation agent that extends in the axial direction and is delimited radially toward the outside by a first wall that has porous material (4), and the first wall is delimited radially toward the outside by a second wall that contains the porous material (4′). Also described is an apparatus to generate hydrogen that has a reactor that contains a porous material and is characterized by the fact that its porosity in the direction of flame generation changes so that the pores are larger, that the porous material is disposed in a first zone and a second zone, which zones are adjacent to each other, and that a zone that has a porous material follows the one zone, seen in the direction of flow.
    • 描述了通过氧化包含化学键合的氢,特别是烃的燃料产生氢的方法,具有以下工艺步骤:a)将燃料(1)以及氧化剂(2)引入反应器(3) )具有多孔材料(4'),该多孔材料(4')以如下方式被实施:使得在与流动方向相反的方向上的火焰传播被阻止,以及b)使部分氧化中的燃料与氧化剂反应,使得气体中获得氢气 形成。 此外,具有含有多孔材料(4,4')的反应器和反应器(3)的产生氢气的装置被实施为具有中心室(5)以引入燃料和管状反应器的管式反应器, 氧化剂,其在轴向方向上延伸并且通过具有多孔材料(4)的第一壁径向限定在外部,并且第一壁通过包含多孔材料(4')的第二壁径向限定在外部, 。 还描述了一种产生氢的装置,其具有含有多孔材料的反应器,其特征在于其在火焰产生方向上的孔隙度变化使得孔更大,多孔材料设置在第一区域 以及第二区域,这些区域彼此相邻,并且具有多孔材料的区域沿着沿流动方向观察的一个区域。
    • 3. 发明申请
    • PROCESS AND APPARATUS FOR GENERATING HYDROGEN
    • 用于生成氢的方法和装置
    • US20080031800A1
    • 2008-02-07
    • US11869577
    • 2007-10-09
    • Marcus FranzGeorg HartelJurgen Kunzel
    • Marcus FranzGeorg HartelJurgen Kunzel
    • C01B3/24B01J8/02C01B31/20
    • B01J8/0496B01J8/025B01J8/0285B01J8/0411B01J2208/00141B01J2208/00203B01J2208/00309B01J2208/0053B01J2219/00265C01B3/363C01B3/386C01B2203/0255C01B2203/0261C01B2203/066C01B2203/142H01M8/0618H01M8/0631Y02P20/129
    • A process is described for generating hydrogen through the oxidation of fuels that contain chemically bound hydrogen, in particular hydrocarbons, having the following process steps: a) introducing the fuel (1) as well as the oxidation agent (2) into a reactor (3) having a porous material (4′) that is embodied in such a way that flame propagation in a direction opposite the direction of flow is prevented, and b) reacting the fuel with the oxidation agent in partial oxidation so that hydrogen is obtained in gaseous form. In addition, an apparatus for generating hydrogen that has a reactor that contains a porous material (4, 4′), and the reactor (3) is embodied as a tubular reactor that has a central chamber (5) to introduce the fuel and the oxidation agent that extends in the axial direction and is delimited radially toward the outside by a first wall that has porous material (4), and the first wall is delimited radially toward the outside by a second wall that contains the porous material (4′). Also described is an apparatus to generate hydrogen that has a reactor that contains a porous material and is characterized by the fact that its porosity in the direction of flame generation changes so that the pores are larger, that the porous material is disposed in a first zone and a second zone, which zones are adjacent to each other, and that a zone that has a porous material follows the one zone, seen in the direction of flow.
    • 描述了通过氧化包含化学键合的氢,特别是烃的燃料产生氢的方法,具有以下工艺步骤:a)将燃料(1)以及氧化剂(2)引入反应器(3) )具有多孔材料(4'),该多孔材料(4')以如下方式被实施:使得在与流动方向相反的方向上的火焰传播被阻止,以及b)使部分氧化中的燃料与氧化剂反应,使得气体中获得氢气 形成。 此外,具有含有多孔材料(4,4')的反应器和反应器(3)的产生氢气的装置被实施为具有中心室(5)以引入燃料和管状反应器的管式反应器, 氧化剂,其在轴向方向上延伸并且通过具有多孔材料(4)的第一壁径向限定在外部,并且第一壁通过包含多孔材料(4')的第二壁径向限定在外部, 。 还描述了一种产生氢的装置,其具有含有多孔材料的反应器,其特征在于其在火焰产生方向上的孔隙度变化使得孔更大,多孔材料设置在第一区域 以及第二区域,这些区域彼此相邻,并且具有多孔材料的区域沿着沿流动方向观察的一个区域。
    • 5. 发明申请
    • DEVICE FOR BURNING A FUEL/OXIDANT MIXTURE
    • 用于燃烧燃料/氧化剂混合物的装置
    • US20110229835A1
    • 2011-09-22
    • US13069133
    • 2011-03-22
    • Marcus FranzSören Götz
    • Marcus FranzSören Götz
    • F23D14/46
    • F23C99/006
    • A device for burning a fuel/oxidant mixture in a strongly exothermic reaction, consists of a reactor with a combustion chamber containing at least one first porous material and at least one second porous material in separate zones A and C. The zones are designed in such a way that an exothermic reaction can only occur in zone B, and with one or more feed lines for the fuel and for the oxidant, whereby zone A, which consists of the first porous material, is separated by a distance of approximately 10 mm to 4000 mm, for example approximately 20 mm to 500 mm, equating to one zone B, from zone C which consists of the second porous material and is located before zone C in a flow direction of the fuel/oxidant mixture.
    • 用于在强放热反应中燃烧燃料/氧化剂混合物的装置由具有燃烧室的反应器组成,所述燃烧室含有至少一种第一多孔材料和至少一种第二多孔材料在分开的区域A和C中。 放热反应只能发生在B区以及一条或多条用于燃料和氧化剂的进料管道,其中由第一多孔材料构成的区域A被分开约10mm的距离, 4000mm,例如约20mm至500mm,等于一个区域B,C区由第二多孔材料构成,位于燃料/氧化剂混合物流动方向的C区之前。
    • 9. 发明授权
    • Device for burning a fuel/oxidant mixture
    • 用于燃烧燃料/氧化剂混合物的装置
    • US08926319B2
    • 2015-01-06
    • US13069133
    • 2011-03-22
    • Marcus FranzSören Götz
    • Marcus FranzSören Götz
    • F23D14/46F23C99/00
    • F23C99/006
    • A device for burning a fuel/oxidant mixture in a strongly exothermic reaction, consists of a reactor with a combustion chamber containing at least one first porous material and at least one second porous material in separate zones A and C. The zones are designed in such a way that an exothermic reaction can only occur in zone B, and with one or more feed lines for the fuel and for the oxidant, whereby zone A, which consists of the first porous material, is separated by a distance of approximately 10 mm to 4000 mm, for example approximately 20 mm to 500 mm, equating to one zone B, from zone C which consists of the second porous material and is located before zone C in a flow direction of the fuel/oxidant mixture.
    • 用于在强放热反应中燃烧燃料/氧化剂混合物的装置由具有燃烧室的反应器组成,所述燃烧室含有至少一种第一多孔材料和至少一种第二多孔材料在分开的区域A和C中。 放热反应只能发生在B区以及一条或多条用于燃料和氧化剂的进料管道,其中由第一多孔材料构成的区域A被分开约10mm的距离, 4000mm,例如约20mm至500mm,等于一个区域B,C区由第二多孔材料构成,位于燃料/氧化剂混合物流动方向的C区之前。