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1. 发明授权

US5176941A Process of producing a ceramic/fiber composite using a molten polysilazone 失效
标题翻译：使用熔融聚硅氧烷制造陶瓷/纤维复合材料的方法
公开(公告)号：US5176941A
公开(公告)日：1993-01-05
申请号：US444032
申请日：1989-11-30
申请人： Marcellus Peuckert , Martin Bruck , Thomas Gerdau , Tilo Vaahs , Hans-Jerg Kleiner , Fritz Aldinger
发明人： Marcellus Peuckert , Martin Bruck , Thomas Gerdau , Tilo Vaahs , Hans-Jerg Kleiner , Fritz Aldinger
IPC分类号： C04B35/589 , C04B35/80 , C04B41/45 , C04B41/50 , C04B41/81 , C04B41/87 , C08G77/62
CPC分类号： C04B41/81 , C04B35/589 , C04B35/806 , C04B41/4554 , C04B41/4584 , C04B41/5066 , C04B41/87 , C08G77/62
摘要： The invention relates to a process for the production of a ceramic/fiber composite.The process comprises impregnating fibers with a molten polysilazane in a first step, converting the polysilazane in the fibers into the infusible state in a second step and, in a third step, heating the impregnated fibers to 800.degree. to 2000.degree. C. in an atmosphere of nitrogen, noble gas, or ammonia.
摘要翻译：本发明涉及一种生产陶瓷/纤维复合材料的方法。该方法包括在第一步骤中用熔融的聚硅氮烷浸渍纤维，在第二步中将纤维中的聚硅氮烷转化为不熔状态，并且在第三步中，将浸渍的纤维在气氛中加热至800℃至2000℃ 的氮气，惰性气体或氨气。

2. 发明授权

US5081078A Sinterable ceramic powder, process for its preparation, silicon nitride ceramic manufactured therefrom, process for its manufacture and its use 失效
标题翻译：可烧结陶瓷粉末，其制备方法，其制造的硅酸盐陶瓷，其制造方法及其用途
公开(公告)号：US5081078A
公开(公告)日：1992-01-14
申请号：US443881
申请日：1989-11-30
申请人： Marcellus Peuckert , Martin Bruck , Thomas Gerdau , Hans-Jerg Kleiner , Tilo Vaahs , Fritz Aldinger
发明人： Marcellus Peuckert , Martin Bruck , Thomas Gerdau , Hans-Jerg Kleiner , Tilo Vaahs , Fritz Aldinger
IPC分类号： C01B21/068 , C04B35/589 , C04B35/593 , C08G77/48 , C08G77/62
CPC分类号： C04B35/589 , C04B35/5935
摘要： The invention relates to a novel sinterable ceramic powder, to its preparation, to its processing to form silicon nitride ceramic and to said material itself and its use. The sinterable ceramic powder is prepared by dissolving the polysilazane of formula (I)[CH.sub.3 SiHNH].sub.n [CH.sub.3 SiN].sub.nwhere n is about 10 to 12, in an organic solvent, suspending a pulverulent sinter aid in this solution and then evaporating the solvent and pyrolyzing the residue in an inert gas atmosphere at 500.degree. to 1600.degree. C.The resulting ceramic powder can be used to form a shaped article and then to manufacture silicon nitride ceramic by sintering. It is also possible, however, to form a shaped article from the as yet unpyrolyzed residue obtained after evaporation of the solvent, and then to pyrolyze and sinter said article.The ceramic obtained can be used to manufacture components subject to high mechanical, thermal and corrosive stress.
摘要翻译：本发明涉及一种新型的可烧结陶瓷粉末，用于其制备，以形成氮化硅陶瓷的加工以及所述材料本身及其用途。可烧结陶瓷粉末是通过在有机溶剂中溶解式（I）[CH3SiHNH] n [CH3SiN] n的聚硅氮烷[N，N-二甲基甲酰胺] n [CH3SiN] n，其中n为约10〜12，将粉状烧结助剂悬浮在该溶液中，然后蒸发溶剂，在惰性气体气氛中在500〜1600℃下热解残渣。得到的陶瓷粉末可用于形成成形制品，然后通过烧结制造氮化硅陶瓷。然而，也可以从蒸发溶剂后获得的仍然未裂解的残余物形成成型制品，然后热解并烧结所述制品。获得的陶瓷可用于制造受到高机械，热和腐蚀应力的部件。

3. 发明授权

US5139717A High-strength ceramic composite, process for its preparation and its use 失效
标题翻译：高强度陶瓷复合材料及其制备方法及其应用
公开(公告)号：US5139717A
公开(公告)日：1992-08-18
申请号：US444014
申请日：1989-11-30
申请人： Marcellus Peuckert , Martin Bruck , Tilo Vaahs , Hans-Jerg Kleiner , Fritz Aldinger
发明人： Marcellus Peuckert , Martin Bruck , Tilo Vaahs , Hans-Jerg Kleiner , Fritz Aldinger
IPC分类号： C04B35/589 , C04B35/593 , C04B41/50 , C04B41/84 , C04B41/87
CPC分类号： C04B41/009 , C04B35/589 , C04B35/593 , C04B41/5066 , C04B41/87
摘要： The invention relates to a high-strength ceramic composite, in particular made from silicon nitride, a process for its preparation and its use. The process comprises impregnating an open-pore matrix with a molten polysilazane in a first step and, in a second step, heating the impregnated matrix to 800.degree. to 2500.degree. C. under a blanketing gas, such as nitrogen or a noble gas, or to 800.degree. to 1500.degree. C. under a gas containing ammonia. The high-strength ceramic composite prepared can be used as a component to be subjected to high thermal, mechanical or corrosive stress.
摘要翻译：本发明涉及一种高强度陶瓷复合材料，特别是由氮化硅制成，其制备方法及其应用。该方法包括在第一步骤中用熔融的聚硅氮烷浸渍开孔基质，并且在第二步中，在诸如氮气或惰性气体的覆盖气体下将浸渍的基质加热至800至2500℃，或在含有氨气体的温度下在800〜1500℃下进行。所制备的高强度陶瓷复合材料可用作要承受高热，机械或腐蚀应力的组分。

4. 发明授权

US5084423A Polysilazanes, process for the preparation thereof, silicon, nitride-containing ceramic materials which can be prepared therefrom, and the preparation thereof 失效
标题翻译：聚硅氮烷，其制备方法，可由其制备的含氮化物的含氮陶瓷材料及其制备方法
公开(公告)号：US5084423A
公开(公告)日：1992-01-28
申请号：US502321
申请日：1990-03-30
申请人： Tilo Vaahs , Hans-Jerg Kleiner , Marcellus Peuckert , Martin Bruck , Fritz Aldinger
发明人： Tilo Vaahs , Hans-Jerg Kleiner , Marcellus Peuckert , Martin Bruck , Fritz Aldinger
IPC分类号： C04B35/589 , C08G77/62
CPC分类号： C08G77/62 , C04B35/589
摘要： The invention relates to novel polysilazanes, the preparation thereof, the further processing thereof to form silicon nitride-containing ceramic material, and this material itself. In order to prepare the polysilazanes, dialkylaminoorganyldichlorosilanes of the formula RSiCL.sub.2 --NR'R' are reacted with ammonia. The polysilazanes can then be pyrolyzed to form silicon nitride-containing ceramic material. The polysilazanes according to the invention dissolve in customary aprotic solvents.
摘要翻译：本发明涉及新型聚硅氮烷，其制备方法，其进一步处理以形成含氮化硅的陶瓷材料，以及该材料本身。为了制备聚硅氮烷，式RSiCL2-NR'R'的二烷基氨基有机基二氯硅烷与氨反应。然后可以将聚硅氮烷热解以形成含氮化硅的陶瓷材料。根据本发明的聚硅氮烷溶解在常规的非质子溶剂中。

5. 发明授权

US4935481A Polysilazanes, process for the preparation thereof, silicon nitride-containing ceramic materials which can be prepared therefrom, and the prepaation thereof 失效
标题翻译：聚硅氮烷，其制备方法，可由其制备的含氮化硅的陶瓷材料及其制备
公开(公告)号：US4935481A
公开(公告)日：1990-06-19
申请号：US266513
申请日：1988-11-03
申请人： Tilo Vaahs , Hans-Jerg Kleiner , Marcellus Peuckert , Martin Bruck , Fritz Aldinger
发明人： Tilo Vaahs , Hans-Jerg Kleiner , Marcellus Peuckert , Martin Bruck , Fritz Aldinger
IPC分类号： C04B35/589 , C08G77/62
CPC分类号： C08G77/62 , C04B35/589
摘要： The invention relates to novel polysilazanes, the preparation thereof, the further processing thereof to form silicon nitride-containing ceramic material, and this material itself. In order to prepare the polysilazanes, dialkylaminoorganyldichlorosilanes of the formula RsiCl.sub.2 -Nr'R' are reacted with ammonia. The polysilazanes can then be pyrolyzed to form silicon nitride-containing ceramic material. The polysilazanes according to the invention dissolve in customary aprotic solvents.
摘要翻译：本发明涉及新型聚硅氮烷，其制备方法，其进一步处理以形成含氮化硅的陶瓷材料，以及该材料本身。为了制备聚硅氮烷，式RsiCl 2 -Nr'R'的二烷基氨基有机基二氯硅烷与氨反应。然后可以将聚硅氮烷热解以形成含氮化硅的陶瓷材料。根据本发明的聚硅氮烷溶解在常规的非质子溶剂中。

6. 发明授权

US5189132A Polymeric hydridochlorosilazanes, process for their preparation, ceramic materials containing silicon nitride which can be manufactured therefrom, and their manufacture 失效
标题翻译：聚合氢氯硅氮烷，其制备方法，可由其制造的含氮化硅的陶瓷材料及其制造方法
公开(公告)号：US5189132A
公开(公告)日：1993-02-23
申请号：US759035
申请日：1991-09-05
申请人： Tilo Vaahs , Thomas Gerdau , Hans-Jerg Kleiner , Marcellus Peuckert , Martin Bruck
发明人： Tilo Vaahs , Thomas Gerdau , Hans-Jerg Kleiner , Marcellus Peuckert , Martin Bruck
IPC分类号： C04B35/589 , C08G77/62
CPC分类号： C04B35/589 , C08G77/62
摘要： The invention relates to novel polymeric hydridochlorosilazanes, to their preparation, to their processing to form ceramic materials containing silicon nitride, and to said materials themselves. The polymeric hydridochlorosilazanes are prepared by reacting oligohydridoorganosilazanes of the general formula (R.sup.1 SiHNH).sub.n, in which n is about 3 to about 12, with at least one of the chlorosilanes R.sup.2 SiHCl.sub.2, R.sup.3 SiCl.sub.3, Cl.sub.2 R.sup.4 Si--CH.sub.2 CH.sub.2 --SiR.sup.4 Cl.sub.2 or Cl.sub.3 Si--CH.sub.2 CH.sub.2 --SiR.sup.5 Cl.sub.2 at 30.degree. C. to 300.degree. C., where the radicals independently of one another have the following meanings:R.sup.1 =a C.sub.1 -C.sub.6 alkyl or C.sub.2 -C.sub.6 alkenyl group,R.sup.2 =a C.sub.2 -C.sub.6 alkenyl group if R.sup.2 SiHCl.sub.2 is reacted with the oligosilazanes by itself, orR.sup.2 =a C.sub.1 -C.sub.6 alkyl or C.sub.2 -C.sub.6 alkenyl group if R.sup.2 SiHCl.sub.2 is reacted with the oligosilazanes as a mixture with other chlorosilanes, andR.sup.3, R.sup.4, R.sup.5 =a C.sub.1 -C.sub.6 alkyl or C.sub.C.sub.2 -C.sub.6 alkenyl group,and where R.sup.3 SiCl.sub.3 is used only as a mixture with at least one of the other chlorosilanes (containing R.sup.2, R.sup.4 or R.sup.5).The polymeric hydridochlorosilazanes according to the invention can be converted into polysilazanes by reaction with ammonia, and these in turn can be pyrolyzed to form ceramic materials containing silicon nitride.
摘要翻译：本发明涉及新型的聚合氯化二氯硅氮烷，用于其制备，以形成含有氮化硅的陶瓷材料的加工，以及所述材料本身。通过使通式（R1SiHNH）n的低聚氢化有机硅氮烷（其中n为约3至约12）与至少一种氯代硅烷R 2 SiHCl 2，R 3 SiCl 3，Cl 2 R 4 Si-CH 2 CH 2 -SiR 4 Cl 2或Cl 3 Si-CH 2 CH 2 -SiR 5 Cl 2中的至少一种反应来制备聚合的氢氯硅氮烷， 30℃至300℃，其中彼此独立的基团具有以下含义：R 1 = C 1 -C 6烷基或C 2 -C 6烯基，如果R 2 SiHCl 2与C 2 -C 6烯基反应，则R 2 = C 2 -C 6烯基如果R2SiHCl2与低聚硅氮烷作为与其它氯硅烷的混合物反应，则R2 = C1-C6烷基或C2-C6烯基，R3，R4，R5 = C1-C6烷基或CC2-C6烯基，并且其中R 3 SiCl 3仅与至少一种其它氯硅烷（包含R 2，R 4或R 5）一起使用。根据本发明的聚合物氯化硅烷可以通过与氨的反应转化为聚硅氮烷，并且这些可以热解而形成含有氮化硅的陶瓷材料。

7. 发明授权

US5162272A Sinterable ceramic powder, process for its production, silicon nitride ceramic produced therefrom, process for its production and its use 失效
公开(公告)号：US5162272A
公开(公告)日：1992-11-10
申请号：US498266
申请日：1990-03-23
申请人： Marcellus Peuckert , Tilo Vaahs , Martin Bruck , Hans-Jerg Kleiner , Ralf Riedel , Martin Sehr , Gunter Petzow
发明人： Marcellus Peuckert , Tilo Vaahs , Martin Bruck , Hans-Jerg Kleiner , Ralf Riedel , Martin Sehr , Gunter Petzow
IPC分类号： C01B21/068 , C04B35/589 , C04B35/626
CPC分类号： C04B35/589
摘要： The invention relates to a novel sinterable ceramic powder, to its preparation and to its further processing to give a silicon nitride ceramic, and to this material itself and its use. The sinterable ceramic powder is produced by melting a polysilazane or dissolving it in an organic solvent, suspending a powdered sinter aid in this melt or solution, then pyrolyzing the melt, or the residue obtained after evaporation of the solvent, at 500.degree. to 1600.degree. C. in a protective gas atmosphere, the polysilazane eitherA) being obtainable by reacting at least one of the oligosilazanes of the formula (I) ##STR1## in which a, b, c and d are the mole fractions of the respective structural units and where 0.ltoreq.a.ltoreq.1, 0.ltoreq.b.ltoreq.1, 0.ltoreq.c.ltoreq.0.7, 0.ltoreq.d.ltoreq.0.7, 0.3.ltoreq.a+b, c+d.ltoreq.0.7 and n is approximately 2 to approximately 12, with at least one of the chlorosilanes R.sup.6 R.sup.7 SiCl.sub.2, R.sup.8 SiCl.sub.3, Cl.sub.2 R.sup.9 Si--CH.sub.2 CH.sub.2 --SiR.sup.9 Cl.sub.2 and Cl.sub.3 Si--CH.sub.2 CH.sub.2 SiR.sup.10 Cl.sub.2 at 30.degree. to 300.degree. C., where, independently of one another, R.sup.1, R.sup.2, R.sup.4, R.sup.6, R.sup.7 and R.sup.8 are H, C.sub.1 -C.sub.6 -alkyl or C.sub.2 -C.sub.6 -alkenyl and R.sup.3, R.sup.5, R.sup.9 and R.sup.10 are C.sub.1 -C.sub.6 -alkyl or C.sub.2 -C.sub.6 -alkenyl, orB) having the following formula ##STR2## in which R and R* can be identical or different and R and R* are C.sub.1 -C.sub.4 -alkyl, vinyl or phenyl and R' is C.sub.1 -C.sub.4 -alkyl and x and y are the mole fractions of the two structural units, where x+y=1 and x=0.7-0.95.A molded article can be formed from the ceramic powder thus obtained and a silicon nitride ceramic then produced by sintering. However, a molded article can also be formed from the solidified melt or the still unpyrolyzed residue obtained after evaporating the solvent and this article can then by pyrolyzed and sintered.Components subject to severe mechanical, thermal and corrosive stress can be produced from the ceramic obtained.

8. 发明授权

US4952670A Polymeric hydridothiosilazanes, processes for the preparation thereof, silicon nitride-containing ceramic materials which can be prepared therefrom, and the preparation thereof 失效
标题翻译：聚合氢硫代硅氮烷，其制备方法，可由其制备的含氮化硅的陶瓷材料及其制备方法
公开(公告)号：US4952670A
公开(公告)日：1990-08-28
申请号：US290627
申请日：1988-12-22
申请人： Tilo Vaahs , Hans-Jerg Kleiner , Marcellus Peuckert , Martin Bruck
发明人： Tilo Vaahs , Hans-Jerg Kleiner , Marcellus Peuckert , Martin Bruck
IPC分类号： C04B35/589 , C08G77/48 , C08G77/60 , C08G77/62 , D01F9/10
CPC分类号： C08G77/60 , C04B35/589
摘要： Polymeric hydridothiosilazanes, processes for the preparation thereof, silicon nitride-containing ceramic materials which can be prepared therefrom, and the preparation thereof.The invention relates to novel polymeric hydridothiosilazanes, the preparation thereof, the conversion thereof into silicon nitride-containing ceramic material, and this material itself. To prepare the polymeric hydridothiosilazanes, oligohydridoalkylsilazanes (RSiHNH).sub.n are reacted with elemental sulfur and ether as solvents. The polymeric hydridothiosilazanes can then be pyrolyzed to form silicon nitride-containing ceramic material.
摘要翻译：聚合氢硫代硅氮烷，其制备方法，可由其制备的含氮化硅的陶瓷材料及其制备。本发明涉及新颖的聚合氢硫代硅氮烷，其制备方法，将其转化成含氮化硅的陶瓷材料，以及该材料本身。为了制备聚合的硫代氨基硅氮烷，将寡聚氢化烷基硅氮烷（RSiHNH）n与元素硫和醚作为溶剂反应。然后可以将聚合的氢硫代硅氮烷热解形成含氮化硅的陶瓷材料。

9. 发明授权

US4946920A Polysilazanes, processes for their preparation, ceramic materials which contain silicon nitride and can be prepared from them, and preparation thereof 失效
标题翻译：聚硅氮烷，其制备方法，含有氮化硅的陶瓷材料并可由它们制备，以及其制备
公开(公告)号：US4946920A
公开(公告)日：1990-08-07
申请号：US279402
申请日：1988-12-02
申请人： Tilo Vaahs , Hans-Jerg Kleiner , Marcellus Peuckert , Martin Bruck
发明人： Tilo Vaahs , Hans-Jerg Kleiner , Marcellus Peuckert , Martin Bruck
IPC分类号： C01B21/068 , C04B35/589 , C04B41/87 , C08G77/48 , C08G77/60 , C08G77/62 , D01F9/10
CPC分类号： C08G77/62 , C04B35/589
摘要： The invention relates to novel polysilazanes, their preparation, their further processing to ceramic material containing silicon nitride and this material itself. To prepare the polysilazanes, Si,Si'-diorganyl-N-alkyl-tetrachloro-disilazanes of the formula RSiCl.sub.2 -NR'-SiCl.sub.2 R are reacted with ammonia. The polysilazanes can then be pyrolyzed to ceramic material containing silicon nitride. The polysilazanes according to the invention dissolve in the customary aprotic solvents.
摘要翻译：本发明涉及新型聚硅氮烷，其制备方法，它们进一步加工含有氮化硅的陶瓷材料及其本身。为了制备聚硅氮烷，式RSiCl2-NR'-SiCl 2 R的Si，Si'-二有机基-N-烷基 - 四氯 - 二硅氮烷与氨反应。然后可以将聚硅氮烷热解成含有氮化硅的陶瓷材料。根据本发明的聚硅氮烷溶于常规非质子溶剂中。

10. 发明授权

US5225243A Fiber-reinforced composite materials and process for their preparation 失效
标题翻译：纤维增强复合材料及其制备方法
公开(公告)号：US5225243A
公开(公告)日：1993-07-06
申请号：US661885
申请日：1991-02-27
申请人： Martin Bruck , Tilo Vaahs , Hans-Jerg Kleiner , Marcellus Peuckert
发明人： Martin Bruck , Tilo Vaahs , Hans-Jerg Kleiner , Marcellus Peuckert
IPC分类号： B29C70/06 , B29K105/06 , C08G77/48 , C08G77/62 , C08J5/24
CPC分类号： C08J5/24 , C08J2383/16
摘要： The invention relates to fiber composite materials and a process for their preparation.The process comprises impregnating fibers with a molten polysilazane in a first step, converting the polysilazane in the fibers into the non-fusible state in a second step, and heating the impregnated fibers to 800.degree. to 2000.degree. C. in a nitrogen, noble gas or ammonia atmosphere in a third step.
摘要翻译：本发明涉及纤维复合材料及其制备方法。该方法包括在第一步骤中用熔融的聚硅氮烷浸渍纤维，在第二步中将纤维中的聚硅氮烷转化为不可熔状态，并在氮气惰性气体中将浸渍的纤维加热至800至2000℃ 或氨气氛。

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