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1. 发明申请

US20080142066A1 Method for producing a nanostructure based on interconnected nanowires, nanostructure and use as thermoelectric converter 有权
标题翻译：基于互连的纳米线，纳米结构和用作热电转换器的纳米结构的制造方法
公开(公告)号：US20080142066A1
公开(公告)日：2008-06-19
申请号：US11826293
申请日：2007-07-13
申请人： Marc Plissonnier , Frederic Gaillard , Raphael Salot , Jean-Antoine Gruss
发明人： Marc Plissonnier , Frederic Gaillard , Raphael Salot , Jean-Antoine Gruss
IPC分类号： H01L21/44 , H01L35/00
CPC分类号： H01L35/34 , H01L35/32 , Y10S977/89 , Y10T428/2971
摘要： Method for producing a nanostructure based on interconnected nanowires, nanostructure and use as thermoelectric converter The nanostructure comprises two arrays of nanowires made from respectively n-doped and p-doped semi-conducting material. The nanowires of the first array, for example of n type, are formed for example by VLS growth. A droplet of electrically conducting material that acted as catalyst during the growth step remains on the tip of each nanowire of the first array at the end of growth. A nanowire of the second array is then formed around each nanowire of the first array by covering a layer of electrically insulating material formed around each nanowire of the first array, and the associated droplet, with a layer of p-type semi-conducting material. A droplet thus automatically connects a nanowire of the first array with a single coaxial nanowire of the second array. This type of nanostructure can be used in particular to form a thermoelectric converter.
摘要翻译：用于制备基于互连纳米线，纳米结构并用作热电转换器的纳米结构的方法纳米结构包括由分别掺杂n型掺杂和p掺杂半导体材料制成的两个纳米线阵列。第一阵列的纳米线，例如n型，例如通过VLS生长形成。在生长步骤中用作催化剂的导电材料液滴在生长结束时保留在第一阵列的每个纳米线的尖端上。然后通过用一层p型半导体材料覆盖形成在第一阵列的每个纳米线周围的电绝缘材料层和相关联的液滴，形成在第一阵列的每个纳米线周围的第二阵列的纳米线。因此，液滴自动地将第一阵列的纳米线与第二阵列的单个同轴纳米线连接。这种类型的纳米结构可以特别用于形成热电转换器。

2. 发明授权

US07868243B2 Method for producing a nanostructure based on interconnected nanowires, nanostructure and use as thermoelectric converter 有权
标题翻译：基于互连的纳米线，纳米结构和用作热电转换器的纳米结构的制造方法
公开(公告)号：US07868243B2
公开(公告)日：2011-01-11
申请号：US11826293
申请日：2007-07-13
申请人： Marc Plissonnier , Frederic Gaillard , Raphael Salot , Jean-Antoine Gruss
发明人： Marc Plissonnier , Frederic Gaillard , Raphael Salot , Jean-Antoine Gruss
IPC分类号： H01L35/00 , H01L21/44
CPC分类号： H01L35/34 , H01L35/32 , Y10S977/89 , Y10T428/2971
摘要： Method for producing a nanostructure based on interconnected nanowires, nanostructure and use as thermoelectric converter The nanostructure comprises two arrays of nanowires made from respectively n-doped and p-doped semi-conducting material. The nanowires of the first array, for example of n type, are formed for example by VLS growth. A droplet of electrically conducting material that acted as catalyst during the growth step remains on the tip of each nanowire of the first array at the end of growth. A nanowire of the second array is then formed around each nanowire of the first array by covering a layer of electrically insulating material formed around each nanowire of the first array, and the associated droplet, with a layer of p-type semi-conducting material. A droplet thus automatically connects a nanowire of the first array with a single coaxial nanowire of the second array. This type of nanostructure can be used in particular to form a thermoelectric converter.
摘要翻译：用于制备基于互连纳米线，纳米结构并用作热电转换器的纳米结构的方法纳米结构包括由分别掺杂n型掺杂和p掺杂半导体材料制成的两个纳米线阵列。第一阵列的纳米线，例如n型，例如通过VLS生长形成。在生长步骤中用作催化剂的导电材料液滴在生长结束时保留在第一阵列的每个纳米线的尖端上。然后通过用一层p型半导体材料覆盖形成在第一阵列的每个纳米线周围的电绝缘材料层和相关联的液滴，形成在第一阵列的每个纳米线周围的第二阵列的纳米线。因此，液滴自动地将第一阵列的纳米线与第二阵列的单个同轴纳米线连接。这种类型的纳米结构可以特别用于形成热电转换器。

3. 发明授权

US07695531B2 Method for producing a lithium microbattery 有权
标题翻译：锂微电池的制造方法
公开(公告)号：US07695531B2
公开(公告)日：2010-04-13
申请号：US10576511
申请日：2004-11-04
申请人： Frederic Gaillard , Marc Plissonnier , Raphael Salot , Stephanie Roche
发明人： Frederic Gaillard , Marc Plissonnier , Raphael Salot , Stephanie Roche
IPC分类号： H01M10/04
CPC分类号： H01M10/0436 , H01M4/04 , H01M10/0562 , H01M10/38 , H01M10/4235 , Y10T29/49108 , Y10T29/4911 , Y10T29/49115
摘要： During the production of a lithium microbattery, the electrolyte containing a lithiated compound is formed by successively depositing an electrolytic thin film, a first protective thin film that is chemically inert in relation to the lithium, and a first masking thin film on a substrate provided with current collectors and a cathode. A photolithography step is carried out on the first masking thin film in order to create a mask for selectively etching the first masking thin layer, and the first protective thin layer and the electrolytic thin film are then selectively etched in such a way as to form the electrolyte in the electrolytic thin film. This technique enables the electrolyte to be formed by photolithography and etching without causing any damage thereto.
摘要翻译：在制造锂微电池期间，含有锂化合物的电解质是通过依次沉积电解薄膜，相对于锂而化学惰性的第一保护薄膜和在基板上设置的第一掩模薄膜集电器和阴极。在第一掩模薄膜上进行光刻步骤，以便产生用于选择性地蚀刻第一掩模薄层的掩模，然后选择性地蚀刻第一保护薄层和电解薄膜，以形成电解质在电解薄膜中。这种技术可以通过光刻和蚀刻来形成电解质，而不会对其造成任何损害。

4. 发明申请

US20070048604A1 Lithium microbattery provided with a protective envelope, and method for producing one such microbattery 审中-公开
标题翻译：锂微电池提供保护性封套，以及生产这种微电池的方法
公开(公告)号：US20070048604A1
公开(公告)日：2007-03-01
申请号：US10577242
申请日：2004-11-04
申请人： Frederic Gaillard , Marc Plissonnier , Raphael Salot , Stephanie Roche
发明人： Frederic Gaillard , Marc Plissonnier , Raphael Salot , Stephanie Roche
IPC分类号： H01M2/02 , H01M2/04 , H01M10/04
CPC分类号： H01M10/0436 , H01M2/0275 , H01M10/052 , H01M10/0562 , H01M10/0585 , Y10T29/49115
摘要： A lithium microbattery comprises a substrate on which at least one stack is arranged successively comprising a cathode, an electrolyte containing lithium and an anode consisting of metallic lithium. A protective envelope comprising at least first and second distinct superposed layers covers the stack to protect the same against external contamination. The first layer, deposited on the whole of the anode, comprises at least one material that is chemically inert with regard to lithium, selected from the group consisting of a hydrogenated amorphous silicon carbide, a hydrogenated amorphous silicon oxycarbide, hydrogenated amorphous carbon, fluorinated amorphous carbon and hydrogenated amorphous silicon. The second layer comprises a material selected from the group consisting of a hydrogenated amorphous silicon carbonitride, a hydrogenated amorphous silicon nitride and a fluorinated amorphous carbon.
摘要翻译：锂微电池包括其上至少一个堆叠依次布置的衬底，其包括阴极，含锂的电解质和由金属锂组成的阳极。包括至少第一和第二不同重叠层的保护性封套覆盖该堆叠以保护其免受外部污染。沉积在整个阳极上的第一层包含至少一种关于锂化学惰性的材料，其选自氢化非晶碳化硅，氢化非晶硅碳氢化合物，氢化无定形碳，氟化非晶态碳和氢化非晶硅。第二层包括选自氢化非晶硅碳氮化物，氢化非晶氮化硅和氟化非晶碳的材料。

5. 发明授权

US07807279B2 Integrated microcomponent combining energy recovery and storage functions 有权
标题翻译：集成微型组件结合能量回收和存储功能
公开(公告)号：US07807279B2
公开(公告)日：2010-10-05
申请号：US11749828
申请日：2007-05-17
申请人： Raphael Salot , Frederic Gaillard , Jean-Yves Laurent , Marc Plissonnier
发明人： Raphael Salot , Frederic Gaillard , Jean-Yves Laurent , Marc Plissonnier
IPC分类号： H01M2/02
CPC分类号： H01M10/0436 , H01G9/016 , H01G11/74 , H01G11/80 , H01L2224/48145 , H01M2/0202 , H01M2/0257 , H01M6/40 , H01M10/052 , H01M10/0563 , H01M10/058 , H01M10/425 , Y02E60/13 , H01L2924/00012
摘要： A microcomponent including: an electrochemical storage source; a first substrate including a first contact face; a second substrate including a second contact face; “at least one internal cavity formed from a first cavity recessed into the first contact face of the first substrate, or from a second cavity recessed into the second contact face of the second substrate, or from the first cavity recessed into the first contact face of the first substrate and the second cavity recessed into the second contact face of the second substrate, wherein the two substrates are integrated together via their respective contact faces and a sealing member, and said internal cavity contains the electrochemical storage source; and electrical connections between the electrochemical storage source and an external environment.
摘要翻译：微量元件包括：电化学储存源; 第一基板，包括第一接触面; 第二基板，包括第二接触面; “至少一个内腔，其由凹入第一衬底的第一接触面的第一腔或从凹入第二衬底的第二接触面的第二腔或从凹入第一接触面的第一接触面的第一腔体形成所述第一衬底和所述第二腔凹入所述第二衬底的所述第二接触面中，其中所述两个衬底经由其相应的接触面和密封构件一体化在一起，并且所述内腔包含所述电化学存储源; 以及电化学存储源和外部环境之间的电气连接。

6. 发明申请

US20070275300A1 INTEGRATED MICROCOMPONENT COMBINING ENERGY RECOVERY AND STORAGE FUNCTIONS 有权
标题翻译：综合微机组合能源恢复与存储功能
公开(公告)号：US20070275300A1
公开(公告)日：2007-11-29
申请号：US11749828
申请日：2007-05-17
申请人： Raphael Salot , Frederic Gaillard , Jean-Yves Laurent , Marc Plissonnier
发明人： Raphael Salot , Frederic Gaillard , Jean-Yves Laurent , Marc Plissonnier
IPC分类号： H01M2/00 , H01M2/06
CPC分类号： H01M10/0436 , H01G9/016 , H01G11/74 , H01G11/80 , H01L2224/48145 , H01M2/0202 , H01M2/0257 , H01M6/40 , H01M10/052 , H01M10/0563 , H01M10/058 , H01M10/425 , Y02E60/13 , H01L2924/00012
摘要： The invention relates to a microcomponent including an electrochemical storage source. It includes a first substrate (1) having a contact face (3) and a second substrate (10) having a contact face (13), at least one cavity (5) being formed in at least one of the substrates from the contact face, the two substrates (1, 10) being integrated with said contact faces by sealing means (18), wherein said cavity, thus sealed, contains the electrochemical storage source, and the microcomponent provides the electrical connections between the electrochemical storage source and the external environment.
摘要翻译：本发明涉及包括电化学存储源的微组件。它包括具有接触面（3）的第一基板（1）和具有接触面（13）的第二基板（10），至少一个空腔（5）从接触面形成在至少一个基板，所述两个基板（1,10）通过密封装置（18）与所述接触面一体化，其中所述密封的所述空腔包含电化学存储源，并且所述微型部件提供所述电化学存储源与所述外部电极之间的电连接环境。

7. 发明申请

US20070067984A1 Method for producing a lithium microbattery 有权
标题翻译：锂微电池的制造方法
公开(公告)号：US20070067984A1
公开(公告)日：2007-03-29
申请号：US10576511
申请日：2004-11-04
申请人： Frederic Gaillard , Marc Plissonnier , Raphael Salot , Stephanie Roche
发明人： Frederic Gaillard , Marc Plissonnier , Raphael Salot , Stephanie Roche
IPC分类号： H01M10/04
CPC分类号： H01M10/0436 , H01M4/04 , H01M10/0562 , H01M10/38 , H01M10/4235 , Y10T29/49108 , Y10T29/4911 , Y10T29/49115
摘要： During the production of a lithium microbattery, the electrolyte containing a lithiated compound is formed by successively depositing an electrolytic thin film, a first protective thin film that is chemically inert in relation to the lithium, and a first masking thin film on a substrate provided with current collectors and a cathode. A photolithography step is carried out on the first masking thin film in order to create a mask for selectively etching the first masking thin layer, and the first protective thin layer and the electrolytic thin film are then selectively etched in such a way as to form the electrolyte in the electrolytic thin film. This technique enables the electrolyte to be formed by photolithography and etching without causing any damage thereto.
摘要翻译：在制造锂微电池期间，含有锂化合物的电解质是通过依次沉积电解薄膜，相对于锂而化学惰性的第一保护薄膜和在基板上设置的第一掩模薄膜集电器和阴极。在第一掩模薄膜上进行光刻步骤，以便产生用于选择性地蚀刻第一掩模薄层的掩模，然后选择性地蚀刻第一保护薄层和电解薄膜，以形成电解质在电解薄膜中。这种技术可以通过光刻和蚀刻来形成电解质，而不会对其造成任何损害。

8. 发明申请

US20120260962A1 ELECTRICAL GENERATOR USING THE THERMOELECTRIC EFFECT AND TWO CHEMICAL REACTIONS, I.E. EXOTHERMIC AND ENDOTHERMIC REACTIONS, TO GENERATE AND DISSIPATE HEAT, RESPECTIVELY 审中-公开
标题翻译：使用热电效应和两种化学反应的电力发电机，I.E. 发热和内毒素反应，产生和消除热量，反应性
公开(公告)号：US20120260962A1
公开(公告)日：2012-10-18
申请号：US13510746
申请日：2010-11-16
申请人： Tristan Caroff , Philippe Coronel , Jean-Antoine Gruss , Marc Plissonnier
发明人： Tristan Caroff , Philippe Coronel , Jean-Antoine Gruss , Marc Plissonnier
IPC分类号： H01L35/30 , H01L35/34
CPC分类号： H01L35/30 , C01B3/323 , C01B2203/0233 , C01B2203/066 , C01B2203/1223 , C01B2203/84 , H01L35/34
摘要： An electric generator based on a thermoelectric effect includes at least a heat source, a heat dissipator and a thermoelectric converter provided with at least two areas respectively in contact with the heat source and the heat dissipator. The heat source is the center of an exothermic chemical reaction, such as the catalytic combustion of hydrogen. The heat dissipator is the center of an endothermic chemical reaction, at least one product of which forms one of the reagents of the exothermic chemical reaction. Once it is formed by the heat dissipator, said product is then directed towards the input of the heat source in order to react there. The endothermic chemical reaction is more particularly a steam reforming reaction for methanol.
摘要翻译：基于热电效应的发电机至少包括热源，散热器和设置有分别与热源和散热器接触的至少两个区域的热电转换器。热源是放热化学反应的中心，例如氢的催化燃烧。散热器是吸热化学反应的中心，其中至少一种产物形成放热化学反应的试剂之一。一旦它被散热器形成，所述产品然后被引向热源的输入端，以便在那里反应。吸热化学反应更特别是甲醇的蒸汽重整反应。

9. 发明授权

US07802437B2 Electronic component with heat transfer by boiling and condensation and method for producing same 有权
标题翻译：通过沸腾冷凝进行热传递的电子部件及其制造方法
公开(公告)号：US07802437B2
公开(公告)日：2010-09-28
申请号：US11826294
申请日：2007-07-13
申请人： Jean-Antoine Gruss , Marc Plissonnier
发明人： Jean-Antoine Gruss , Marc Plissonnier
IPC分类号： F25D21/02 , G01N21/00 , H01L35/30
CPC分类号： H01L35/30 , F28D15/02 , F28F3/022 , H01L23/427 , H01L2924/0002 , Y10T29/49353 , Y10T436/114998 , H01L2924/00
摘要： The electronic component with heat transfer by boiling and condensation comprises heat exchange surfaces immersed in a heat conducting fluid constituted by the free ends of nanowires of a thermoelectric converter. An electrically insulating coating material with a low thermal conduction partially covers the nanowires above the heat conducting fluid. Each nanowire forms a thermocouple composed of two coaxial branches made from materials of different natures separated by a layer of electrically insulating material and electrically connected individually to the free end of the nanowire.
摘要翻译：通过沸腾和冷凝进行热传递的电子部件包括浸渍在由热电转换器的纳米线的自由端构成的导热流体中的热交换表面。具有低导热性的电绝缘涂层材料部分地覆盖导热流体上方的纳米线。每个纳米线形成热电偶，该热电偶由两层由不同性质的材料制成的同轴分支组成，这些材料由一层电绝缘材料隔开，并分别电连接到纳米线的自由端。

10. 发明申请

US20080017356A1 Electronic component with heat transfer by boiling and condensation and method for producing same 有权
标题翻译：通过沸腾冷凝进行热传递的电子部件及其制造方法
公开(公告)号：US20080017356A1
公开(公告)日：2008-01-24
申请号：US11826294
申请日：2007-07-13
申请人： Jean-Antoine Gruss , Marc Plissonnier
发明人： Jean-Antoine Gruss , Marc Plissonnier
IPC分类号： F28D15/02 , B23P15/26
CPC分类号： H01L35/30 , F28D15/02 , F28F3/022 , H01L23/427 , H01L2924/0002 , Y10T29/49353 , Y10T436/114998 , H01L2924/00
摘要： The electronic component with heat transfer by boiling and condensation comprises heat exchange surfaces immersed in a heat conducting fluid constituted by the free ends of nanowires of a thermoelectric converter. An electrically insulating coating material with a low thermal conduction partially covers the nanowires above the heat conducting fluid. Each nanowire forms a thermocouple composed of two coaxial branches made from materials of different natures separated by a layer of electrically insulating material and electrically connected individually to the free end of the nanowire.
摘要翻译：通过沸腾和冷凝进行热传递的电子部件包括浸渍在由热电转换器的纳米线的自由端构成的导热流体中的热交换表面。具有低导热性的电绝缘涂层材料部分地覆盖导热流体上方的纳米线。每个纳米线形成热电偶，该热电偶由两层由不同性质的材料制成的同轴分支组成，这些材料由一层电绝缘材料隔开，并分别电连接到纳米线的自由端。

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