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1. 发明申请

US20140073735A1 AQUEOUS RESIN COMPOSITION COMPRISING A POLYESTER-POLYURETHANE RESIN AND A DENDRITIC POLYOL 审中-公开
标题翻译：包含聚酯 - 聚氨酯树脂和疏水性多元醇的水性树脂组合物
公开(公告)号：US20140073735A1
公开(公告)日：2014-03-13
申请号：US14110836
申请日：2012-04-16
申请人： Marc Claudius Schrinner , Heinz-Dietmar Gewiß , Robert Reyer , Nusret Yuva , Martin Melchiors
发明人： Marc Claudius Schrinner , Heinz-Dietmar Gewiß , Robert Reyer , Nusret Yuva , Martin Melchiors
IPC分类号： C09D175/04
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/0828 , C08G18/42 , C08G18/6659 , C08L71/02 , C08L75/04 , C08L75/06 , C08L101/005 , C08L2666/22
摘要： An aqueous resin composition comprises a polyester-polyurethane resin and a dendritic polyol. The polyester-polyurethane resin is obtained by reacting, in a one-stage process or multi-stage process, a reaction mixture comprising a polyester polyol with a number-average molecular weight Mn of ≧400 g/mole to ≦6000 g/mole, at least one compound containing at least two isocyanate-reactive groups and at least one group capable of forming anions, and a polyisocyanate. The dendritic polyol is obtainable from a central initiator molecule or initiator polymer having at least one reactive hydroxyl group (X), which hydroxyl group (X) under formation of an initial tree structure is bonded to a reactive carboxyl group (Y) in a monomeric chain extender having the two reactive groups (X) and (Y), and wherein the chain extender has as least one carboxyl group (Y) and at least two hydroxyl groups (X) or hydroxyalkyl substituted hydroxyl groups (X).
摘要翻译：含水树脂组合物包含聚酯 - 聚氨酯树脂和树枝状多元醇。聚酯聚氨酯树脂通过在一步法或多步法中使包含数均分子量Mn> 400g / mol至6000g / mol的聚酯多元醇的反应混合物，至少一种含有至少两个异氰酸酯反应性基团和至少一个能够形成阴离子的基团的化合物和多异氰酸酯。树枝状多元醇可以从具有至少一个反应性羟基（X）的中心引发剂分子或引发剂聚合物获得，其中初始树结构形成时的羟基（X）与单体的羧基（Y）键合具有两个反应性基团（X）和（Y）的扩链剂，并且其中扩链剂具有至少一个羧基（Y）和至少两个羟基（X）或羟烷基取代的羟基（X）。

2. 发明申请

US20140066569A1 AQUEOUS POLYESTER-POLYURETHANE DISPERSION NOT REQUIRING ORGANIC CO-SOLVENTS 审中-公开
标题翻译：不需要有机溶剂的水性聚酯 - 聚氨酯分散体
公开(公告)号：US20140066569A1
公开(公告)日：2014-03-06
申请号：US14005847
申请日：2012-03-20
申请人： Marc Claudius Schrinner , Heinz-Dietmar Gewiß , Uwe Klippert , Tanja Hebestreit , Martin Melchiors
发明人： Marc Claudius Schrinner , Heinz-Dietmar Gewiß , Uwe Klippert , Tanja Hebestreit , Martin Melchiors
IPC分类号： C09D7/00
CPC分类号： C09D7/00 , C08G18/0823 , C08G18/6659 , C09D175/06
摘要： The present invention relates to an aqueous polyester-polyurethane dispersion comprising a polyester resin, a basic neutralizing agent and water. The invention further relates to a process for the production of these dispersions and to their use. It has been found that by using succinic acid in the formation of the polyester polyol and dimethylol butyric acid in the formation of the polyester-polyurethane no further organic co-solvents such as NMP are necessary to form stable and useful aqueous polymer dispersions.
摘要翻译：本发明涉及含有聚酯树脂，碱性中和剂和水的聚酯 - 聚氨酯水分散液。本发明还涉及生产这些分散体及其用途的方法。已经发现，通过在形成聚酯 - 聚氨酯中使用琥珀酸形成聚酯多元醇和二羟甲基丁酸，不需要其它有机助溶剂如NMP来形成稳定和有用的聚合物水分散体。

3. 发明申请

US20110060090A1 BINDER COMBINATIONS BASED ON POLYACRYLATE DISPERIONS 审中-公开
标题翻译：基于聚丙烯酸酯分散剂的粘合剂组合
公开(公告)号：US20110060090A1
公开(公告)日：2011-03-10
申请号：US12946402
申请日：2010-11-15
申请人： Thomas Münzmay , Sandra Hackbarth , Martin Melchiors , Heinz-Dietmar Gewiß
发明人： Thomas Münzmay , Sandra Hackbarth , Martin Melchiors , Heinz-Dietmar Gewiß
IPC分类号： C08L33/10 , C09D133/10 , C09D133/08 , C08L33/08
CPC分类号： C09D133/08
摘要： Aqueous polyacrylate dispersions comprising hydrophobic co-solvents are provided. The dispersions are prepared from copolymers P) which are comprised of I) a hydroxy-functional, hydrophobic polymer containing as structural monomers Ia) (meth)acrylic acid esters having from C1- to C18-hydrocarbon radicals in the alcohol part and/or vinyl aromatic compounds and/or vinyl esters and Ib) hydroxy-functional monomers; and II) a hydroxy-functional, hydrophilic polymer containing as structural components IIa) (meth)acrylic acid esters having from C1- to C18-hydrocarbon radicals in the alcohol part and/or vinyl aromatic compounds and/or vinyl esters, IIb) hydroxy-functional monomers and IIc) acid-functional monomers, and as solvents C) one or more solvents selected from the group consisting of hydrophobic, water-immiscible hydrocarbons having an initial boiling point of from 170° C. to 250° C. and a dry point of from 200° C. to 280° C., to a process for their preparation and to their use as binders for the production of blister-free coatings.
摘要翻译：提供了包含疏水性共溶剂的聚丙烯酸酯水分散体。分散体由共聚物P）制备，其由I）含有作为结构单体的羟基官能的疏水性聚合物在醇部分中具有C1-至C18-烃基的（甲基）丙烯酸酯和/或乙烯基芳族化合物和/或乙烯基酯和Ib）羟基官能单体; 和II）在醇部分和/或乙烯基芳族化合物和/或乙烯基酯中含有具有C 1 -C 18烃基的结构组分IIa）（甲基）丙烯酸酯的羟基官能的亲水性聚合物，IIb）羟基官能单体和IIc）酸官能单体和溶剂C）一种或多种溶剂，其选自初始沸点为170℃至250℃的疏水性，水不混溶烃，和干燥点为200℃至280℃，涉及其制备方法和用作生产无水蓬涂层的粘合剂。

4. 发明授权

US09273210B2 Use of an aqueous preparation for the coating of wood surfaces to achieve a natural-touch effect 有权
标题翻译：使用水性制剂来涂覆木材表面以达到自然触感
公开(公告)号：US09273210B2
公开(公告)日：2016-03-01
申请号：US14008005
申请日：2012-03-23
申请人： Marc Claudius Schrinner , Christoph Irle , Martin Melchiors , Maria Almato Guiteras , Eva Tejada
发明人： Marc Claudius Schrinner , Christoph Irle , Martin Melchiors , Maria Almato Guiteras , Eva Tejada
IPC分类号： C09D5/00 , B27K3/15 , B05D1/02 , B05D1/18 , C08G18/08 , C08G18/44 , C08G18/62 , C08G18/70 , C09D175/04 , C08L75/04
CPC分类号： C09D5/00 , B27K3/153 , C08G18/0823 , C08G18/44 , C08G18/6229 , C08G18/6254 , C08G18/706 , C08L75/04 , C09D175/04 , Y10T428/662 , C08L2666/20
摘要： The present invention relates to the use of an aqueous preparation for the coating of wood surfaces, characterized in that the aqueous preparation comprises: a hydroxyl-functional polyurethane-polyacrylate dispersion, apolyurethane dispersion, an at least partially hydrophilicized polyisocyanate and ≧0 weight-% to ≦10 weight-% of a matting agent, wherein the combined hydroxyl content of the hydroxyl-functional polyacrylate dispersion and the polyurethane dispersion is ≧1% to ≦12%. The invention further relates to a method of producing a coated wood surface, comprising the step of coating a wood surface with such an aqueous preparation and to a coated wood surface comprising an aqueous preparation whose use has been recited in the context of the use according to the invention.
摘要翻译：本发明涉及用于木材表面涂层的水性制剂的用途，其特征在于所述水性制剂包括：羟基官能聚氨酯 - 聚丙烯酸酯分散体，聚氨酯分散体，至少部分亲水化的多异氰酸酯和≥0重量％至10重量％的消光剂，其中羟基官能的聚丙烯酸酯分散体和聚氨酯分散体的组合羟基含量为≥1％至≤1E; 12％。本发明还涉及一种生产涂覆的木材表面的方法，其包括用这种水性制剂涂覆木材表面和涂覆的木材表面的步骤，所述涂层的木材表面包含水性制剂，其用途已经在根据本发明。

5. 发明申请

US20120259062A1 NOVEL 2C PUR SYSTEMS 审中-公开
标题翻译：新2C系统
公开(公告)号：US20120259062A1
公开(公告)日：2012-10-11
申请号：US13500180
申请日：2010-09-30
申请人： Thomas Münzmay , Alice Münzmay , Sebastian Dörr , Marc Claudius Schrinner , Martin Melchiors , Jürgen Lippemeier
发明人： Thomas Münzmay , Alice Münzmay , Sebastian Dörr , Marc Claudius Schrinner , Martin Melchiors , Jürgen Lippemeier
IPC分类号： C09D175/04 , C09J175/04
CPC分类号： C08G18/225 , C08G18/706 , C09D175/04
摘要： The present invention relates to alkali metal salts of phosphomolybdic acid, especially sodium phosphomolybdate, for the accelerated curing of polyisocyanates with polyols, and to polyurethane Systems in which they are present.
摘要翻译：本发明涉及磷钼酸的碱金属盐，特别是磷钼酸钠，用于多元醇与多元醇的多异氰酸酯的加速固化，以及它们存在的聚氨酯体系。

6. 发明授权

US07232860B2 Aqueous binder dispersions as coating compositions 有权
标题翻译：水性粘合剂分散体作为涂料组合物
公开(公告)号：US07232860B2
公开(公告)日：2007-06-19
申请号：US10640546
申请日：2003-08-13
申请人： Martin Melchiors , Ulrich Freudenberg , Robert Reyer , Raul Pires , Sandra Grosskopf
发明人： Martin Melchiors , Ulrich Freudenberg , Robert Reyer , Raul Pires , Sandra Grosskopf
IPC分类号： C08F6/02 , C08F220/18 , C08L35/02 , B05D3/02
CPC分类号： C08F8/44 , C08F220/00
摘要： An aqueous binder dispersion that includes at least one copolymer (P) containing carboxylic acid and/or carboxylate groups. The copolymer (P) includes structural units of carboxyl-free (meth)acrylic esters with a cycloaliphatic structure, and at least 25 mol % of the carboxylic acid groups of the copolymer (P) in the dispersion being present in triethanolamine-neutralized form. The aqueous binder can be used in aqueous coating materials, which can be used to coat a substrate.
摘要翻译：一种水性粘合剂分散体，其包含至少一种含有羧酸和/或羧酸酯基团的共聚物（P）。共聚物（P）包括具有脂环族结构的无羧酸（甲基）丙烯酸酯的结构单元，分散体中共聚物（P）的至少25摩尔％的羧酸基以三乙醇胺中和的形式存在。水性粘合剂可用于水性涂料中，可用于涂覆基材。

7. 发明申请

US20140051800A1 WATER-EMULSIFIABLE POLYISOCYANATE COMPOSITION COMPRISING A FRAGRANT WITH AT LEAST ONE HYDROXYL AND/OR ALDEHYDE GROUP 审中-公开
标题翻译：含有至少一个羟基和/或二卤代烃基的芳香族的可水解的聚异氰酸酯组合物
公开(公告)号：US20140051800A1
公开(公告)日：2014-02-20
申请号：US14112425
申请日：2012-04-17
申请人： Robert Reyer , Martin Melchiors , Maria Almato Guiteras , Eva Tejada
发明人： Robert Reyer , Martin Melchiors , Maria Almato Guiteras , Eva Tejada
IPC分类号： C09D175/04 , C09J175/04
CPC分类号： C09D175/04 , C08G18/006 , C08G18/0823 , C08G18/0828 , C08G18/2825 , C08G18/706 , C09J175/04
摘要： An aqueous composition comprises a water-emulsifiable polyisocyanate (A), the water-emulsifiable polyisocyanate (A) being a reaction product of a polyisocyanate (B) with a compound (C) which contains at least one sulfonic acid group or its anion, and at least one isocyanate-reactive group. The composition further comprises a fragrant (D1) with at least one hydroxyl and/or aldehyde group. It has been found that the addition of the fragrant (D1) can mask unpleasant odors of the composition. This is particularly the case when organic co-solvents such as propylene glycol-n-butyl ether and/or 3-methoxy-1-butyl acetate are used. The storage stability and performance of the polyisocyanates are not affected by the addition of the fragrant (D1). Further aspects of the invention are the use of a composition according to the invention as an adhesive, a coating or an impregnating material and a substrate coated with a composition according to the invention.
摘要翻译：水性组合物包含水可乳化的多异氰酸酯（A），作为多异氰酸酯（B）与含有至少一个磺酸基或其阴离子的化合物（C）的反应产物的水可乳化多异氰酸酯（A），以及至少一个异氰酸酯反应性基团。组合物还包含具有至少一个羟基和/或醛基的芳香（D1）。已经发现，添加香料（D1）可以掩盖组合物的令人不愉快的气味。当使用有机共溶剂如丙二醇 - 正丁基醚和/或3-甲氧基-1-丁基乙酸酯时，情况尤其如此。多异氰酸酯的储存稳定性和性能不受添加香料（D1）的影响。本发明的其它方面是根据本发明的组合物作为粘合剂，涂层或浸渍材料以及涂覆有根据本发明的组合物的基材的用途。

8. 发明申请

US20080214721A1 POLYESTER-POLACRYLATE DISPERSIONS FOR TWO-COMPONENT COATING COMPOSITIONS 审中-公开
标题翻译：用于两种组分涂料组合物的聚酯 - 聚丙烯酸酯分散体
公开(公告)号：US20080214721A1
公开(公告)日：2008-09-04
申请号：US12040972
申请日：2008-03-03
申请人： Rolf Gertzmann , Martin Melchiors , Sandra Hackbarth
发明人： Rolf Gertzmann , Martin Melchiors , Sandra Hackbarth
IPC分类号： C08L67/02
CPC分类号： C09D175/04
摘要： The invention relates to aqueous polyester-polyacrylate dispersions based on copolymers, to a process for their preparation, and to aqueous coating compositions based thereon and the use thereof as lacquers. The dispersions are prepared from a polyester component A) that comprises the reaction product of A1) one or more saturated, aliphatic and/or aromatic di-, tri- or tetra-carboxylic acids or their anhydrides, and A2)one ore more diols and/or polyols, and a polyacrylate component B) that comprises the reaction product of B1) one or more OH-group-free (meth)acrylic acid esters and/or vinyl aromatic compounds, B2) one or more hydroxy-functional vinyl monomers or hydroxy-functional (meth)acrylic acid esters, and B3) one or more acid-group-containing monomers capable of free-radical copolymerisation, herein te polyester component A) has a hydroxyl number of from 180 to 300 mg KOH/g substance and an acid number of from 0.5 to 30 mg KOH/g, and the polyacrylate component B) has a hydroxyl number of from 10 to 180 mg KOH/g and an acid number of from 10 to 100 mg KOH/g, and the copolymer has an OH number smaller than that of the polyester component A) and greater than 27 mg KOH/g.
摘要翻译：本发明涉及基于共聚物的水性聚酯 - 聚丙烯酸酯分散体，其制备方法以及基于其的水性涂料组合物及其作为漆的用途。分散体由包含A1）一种或多种饱和，脂族和/或芳族二 - ，三 - 或四 - 羧酸或其酸酐的反应产物的聚酯组分A）制备，和A2）一个或多个二醇和 /或多元醇，和聚丙烯酸酯组分B），其包含B1）一种或多种不含羟基的（甲基）丙烯酸酯和/或乙烯基芳族化合物的反应产物，B2）一种或多种羟基官能的乙烯基单体或羟基官能（甲基）丙烯酸酯和B3）一种或多种能够自由基共聚的含酸基的单体，此处聚酯组分A）具有180至300mg KOH / g物质的羟值，酸值为0.5至30mg KOH / g，聚丙烯酸酯组分B）的羟值为10至180mg KOH / g，酸值为10至100mg KOH / g，并且共聚物具有 OH数小于聚酯组分A）和大于27mg KOH / g。

9. 发明申请

US20060100332A1 Polyester-polyacrylate dispersions with reactive diluents based on compounds containing lactone groups 审中-公开
标题翻译：聚酯 - 聚丙烯酸酯分散体与基于含内酯化合物的反应性稀释剂
公开(公告)号：US20060100332A1
公开(公告)日：2006-05-11
申请号：US11270218
申请日：2005-11-09
申请人： Rolf Gertzmann , Heinz-Dietmar Gewiss , Thomas Munzmay , Martin Melchiors
发明人： Rolf Gertzmann , Heinz-Dietmar Gewiss , Thomas Munzmay , Martin Melchiors
IPC分类号： C08K5/05
CPC分类号： C08J3/03 , C08J2367/00 , C08L33/08 , C08L33/10 , C08L67/00 , C08L67/04 , C09D167/00 , C08L2666/02 , C08L2666/18
摘要： The present invention related to a process for preparing aqueous polyester-polyacrylate dispersions having a cosolvent content of 0 to 5% by weight, based on the weight of the dispersion, by preparing a polymer P) in a first step by polymerizing A) a mixture of vinyl monomers that are capable of free-radical copolymerization, in the presence of B) one or more oligoesters prepared from compounds containing lactone groups and having a hydroxyl number of 145 to 710 mg KOH/g, an acid number of ≦0.5 mg KOH/g solids and an average OH functionality of 2.5 to 5 mg KOH/g solids, and then mixing polymer P) in a second step with C) one or more polyester polyols having a hydroxyl number of 10 to 500 mg KOH/g solids and an acid number of >0.5 to ≦30 mg KOH/g solids and dispersing the resulting polymer mixture in water in a further step, before or after addition of a neutralizing agent. The present invention also relates to the aqueous polyester-polyacrylate polymer dispersions obtained in accordance with the process of the invention and to aqueous coating compositions containing the aqueous polyester-polyacrylate polymer dispersions of the invention.
摘要翻译：本发明涉及通过聚合A）混合物在第一步中制备共聚物含量为0-5重量％，基于分散体重量的聚酯 - 聚丙烯酸酯分散体的方法，通过制备聚合物P）的乙烯基单体在B存在下存在下进行自由基共聚的乙烯基单体：一种或多种由含有内酯基团并且羟值为145至710mg KOH / g的化合物制备的低聚酯，酸值<= 0.5mg KOH / g固体，平均OH官能度为2.5至5mg KOH / g固体，然后在第二步中混合聚合物P）和C）一种或多种羟基数为10至500mg KOH / g固体的聚酯多元醇并且酸值> 0.5至<= 30mg KOH / g固体，并且在加入中和剂之前或之后将所得聚合物混合物进一步分散在水中。本发明还涉及根据本发明的方法获得的聚酯 - 聚丙烯酸酯聚合物水分散体和含有本发明的聚酯 - 聚丙烯酸酯聚合物水分散体的水性涂料组合物。

10. 发明申请

US20050165145A1 Low-solvent, OH-functional dispersions 有权
标题翻译：低溶剂，OH官能的分散体
公开(公告)号：US20050165145A1
公开(公告)日：2005-07-28
申请号：US11041774
申请日：2005-01-24
申请人： Martin Melchiors , Thomas Munzmay , Thomas Stingl , Hartmut Ottensmann , Heinz-Dietmar Gewiss
发明人： Martin Melchiors , Thomas Munzmay , Thomas Stingl , Hartmut Ottensmann , Heinz-Dietmar Gewiss
IPC分类号： C08F283/06 , C08K5/103 , C08L33/04 , C08L33/06 , C09D151/08 , C09J133/04 , C08K5/10
CPC分类号： C09J133/04 , C08K5/103 , C08L33/04 , C08L33/066 , C08L2666/04
摘要： A process for preparing copolymer dispersions that includes subjecting A) one or more vinyl monomer mixtures containing a) OH-free (meth)acrylic esters and/or vinylaromatics, b) hydroxy-functional vinyl monomers and/or hydroxy-functional (meth)acrylic esters, c) ionic and/or potentially ionic monomers capable of free-radical copolymerization, and d)optionally further monomers, other than the compounds of components a)-c), capable of free-radical copolymerization; to free-radical polymerization in the presence of e) compounds according to formula (I) where R1 is an aliphatic, araliphatic or aromatic radical having 1 to 18 carbon atoms, R2 is H or CH3, R3, R4 are identical or different aliphatc radicals having 1 to 7 carbon atoms and n is 1 to 4; and subsequently dispersing the resultant copolymer B) before or after addition of a neutralizing agent C) in water. The resulting dispersions can be used to coat substrates.
摘要翻译：一种制备共聚物分散体的方法，其包括使A）一种或多种乙烯基单体混合物含有a）不含OH的（甲基）丙烯酸酯和/或乙烯基芳烃，b）羟基官能的乙烯基单体和/或羟基官能（甲基）丙烯酸酯，c）能够进行自由基共聚的离子和/或潜在的离子单体，和d）任何其它单体，除了能够自由基共聚的组分a）-c）的化合物之外; 在e）根据式（I）的化合物存在下进行自由基聚合，其中R 1是具有1至18个碳原子的脂族，芳脂族或芳族基团，R 2， SUP>是H或CH 3，R 3，R 4是相同或不同的具有1至7个碳原子的烷基，n是1 到4; 随后将所得共聚物B）在加入中和剂C）之前或之后分散在水中。所得到的分散体可用于涂覆底物。

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