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1. 发明授权

US08486312B2 Photochromic naphthopyrans having a double-bridged terphenyl sub-unit 有权
标题翻译：具有双桥连三联体子单元的光致变色萘并吡喃
公开(公告)号：US08486312B2
公开(公告)日：2013-07-16
申请号：US12937414
申请日：2009-04-29
申请人： Manfred Melzig , Yven Rohlfing , Udo Weigand
发明人： Manfred Melzig , Yven Rohlfing , Udo Weigand
IPC分类号： G02B5/23 , B05D5/06 , C07D311/94
CPC分类号： C07D311/92
摘要： The present invention relates to photochromic naphthopyrancs having a double-bridged terphenyl sub-unit, and to the use thereof in plastics of all types, particularly for ophthalmic purposes.
摘要翻译：本发明涉及具有双桥连三联子基单元的光致变色萘并及其在所有类型的塑料中的用途，特别是用于眼用目的。

2. 发明授权

US07892296B2 Photochromic benzopyrans 失效
标题翻译：光致变色苯并吡喃
公开(公告)号：US07892296B2
公开(公告)日：2011-02-22
申请号：US12738124
申请日：2008-11-25
申请人： Manfred Melzig , Yven Rohlfing , Udo Weigand
发明人： Manfred Melzig , Yven Rohlfing , Udo Weigand
IPC分类号： C07D311/00
CPC分类号： G03C1/73 , C07D311/94 , C09B57/00 , G02B5/23
摘要： The present invention relates to photochromic benzopyrans and to the use thereof in plastics of all kinds, especially for ophthalmic purposes. The inventive compounds are photochromic benzopyran compounds in which a polycyclic aromatic is joined to the 5 and 6 positions of a benzopyran, where the bond in the 6 position is direct and the bond in the 5 position is via a mono- or diatomic bridge.
摘要翻译：本发明涉及光致变色苯并吡喃及其在各种塑料中的用途，特别是用于眼用目的。本发明化合物是其中多环芳族化合物连接到苯并吡喃的5和6位的光致变色苯并吡喃化合物，其中6位上的键是直接的，并且5位的键通过单原子或双原子桥。

3. 发明授权

US07459555B2 Photochromic naphthopyrans 失效
标题翻译：光致变色萘并吡喃
公开(公告)号：US07459555B2
公开(公告)日：2008-12-02
申请号：US10013518
申请日：2001-12-13
申请人： Manfred Melzig , Claudia Mann , Udo Weigand
发明人： Manfred Melzig , Claudia Mann , Udo Weigand
IPC分类号： C07D265/30 , C07D405/00 , C07D311/78 , C07D307/77
CPC分类号： C07D493/04 , C07D311/78 , C07D311/94 , C07D311/96 , C07D493/10 , G02B5/23
摘要： The present invention relates to photochromic 2H-naphtho[1,2-b]pyrans as well as their use in synthetic resins of all types, especially for ophthalmic purposes. In particular, the present invention relates to photochromic naphthopyran compounds, for which a further ring system is bonded to the f side of the naphthopyran. The inventive photochromic dyes generally have the general formula (I) wherein n, R1, R2, R3, X, B and B′ are defined as in claim 1. The inventive compounds are distinguished by good darkening and decolorizing properties and a very good service life.
摘要翻译：本发明涉及光致变色2H-萘并[1,2-b]吡喃，以及它们在所有类型的合成树脂中的用途，特别是用于眼用目的。特别地，本发明涉及光致变色萘并吡喃化合物，其另外的环系结合在萘并吡喃的f侧。本发明的光致变色染料通常具有通式（I），其中n，R 1，R 2，R 3，X，B和B'如权利要求1中所定义。本发明化合物的特征在于良好的变暗和脱色性能以及良好的服务生活。

4. 发明申请

US20080251772A1 Photochromic Plastic Object 有权
标题翻译：光致变色塑料对象
公开(公告)号：US20080251772A1
公开(公告)日：2008-10-16
申请号：US12138117
申请日：2008-06-12
申请人： Yven Rohlfing , Udo Weigand , Manfred Melzig
发明人： Yven Rohlfing , Udo Weigand , Manfred Melzig
IPC分类号： G02B5/23 , G02C7/10
CPC分类号： G03C1/73 , B82Y20/00 , B82Y30/00 , C09K9/02 , G02B1/04 , G02B5/23
摘要： A photochromic plastic object which is composed of a transparent polymeric synthetic resin material, into or onto which at least one substantially mesoporous inorganic host structure is introduced or applied containing one or more embedded organic photochromic dye molecules so as to form a photochromic nanocomposite material. In contrast to prior techniques of adding or applying the photochromic organic dyes to the monomer mixture or prepolymer of a transparent synthetic resin material in a molecular form, in the photochromic plastic article of the present invention color is generated by using the photochromic nanocomposite particles or photochromic nanocomposite structures.
摘要翻译：由透明聚合物合成树脂材料构成的光致变色塑料物体被引入或涂覆有至少一个基本上介孔的无机主体结构，其中含有一个或多个嵌入的有机光致变色染料分子以形成光致变色纳米复合材料。与将光致变色有机染料加入或应用于分子形式的透明合成树脂材料的单体混合物或预聚物的现有技术相反，在本发明的光致变色塑料制品中，通过使用光致变色纳米复合材料颗粒或光致变色纳米复合结构。

5. 发明授权

US06881850B2 Heterocyclically annellated indenochromene derivatives 失效
标题翻译：杂环取代的茚色烯衍生物
公开(公告)号：US06881850B2
公开(公告)日：2005-04-19
申请号：US10720442
申请日：2003-11-25
申请人： Claudia Mann , Manfred Melzig , Udo Weigand
发明人： Claudia Mann , Manfred Melzig , Udo Weigand
IPC分类号： G02C7/04 , C07D491/04 , C07D491/052 , C07D493/04 , C07D495/04 , C08K5/00 , C08K5/1535 , C09K9/02 , G02B5/23 , G02C7/10 , C07D311/78 , A61K31/33 , A61K31/35 , C07D311/94 , C07D311/96
CPC分类号： C07D491/04 , C07D493/04 , C07D495/04 , C08K5/0041 , C08K5/1535 , C09K9/02 , G02B5/23
摘要： The present invention relates to specific photochromic heterocyclically annellated indenochromene derivatives and the use thereof in plastics of all types, particularly for ophthalmic applications. In particular, the present invention relates to indeno[1,2-h]chromene derivatives having the following general formula (I) and indeno[2,1-f]chromene derivatives having the following general formula (II):
摘要翻译：本发明涉及特定的光致变色杂环环烯烃色烯衍生物及其在所有类型的塑料中的用途，特别是用于眼科应用。特别地，本发明涉及具有以下通式（I）的茚并[1,2-h]色烯衍生物和具有以下通式（II）的茚并[2,1-f]色烯衍生物：

6. 发明授权

US6102543A Photochromically colored object 失效
标题翻译：光彩色物体
公开(公告)号：US6102543A
公开(公告)日：2000-08-15
申请号：US878
申请日：1997-12-30
申请人： Manfred Melzig
发明人： Manfred Melzig
IPC分类号： C08F20/10 , C08F220/20 , C08J7/00 , C08K5/34 , C08L31/04 , C08L33/08 , C09B57/00 , C09K3/00 , C09K9/02 , G02B1/04 , G02B5/23 , G02C7/10
CPC分类号： C09K9/02 , G02B5/23 , G02C7/102
摘要： Disclosed is an object made of plastic material, in particular a plastic ophthalmic lens, colored with at least one photochromic substance which is also excited by light in the UV range of the spectrum and has a higher absorption in the excited state, judged by the spectral light sensitivity of the human eye, than in the not excited state and to which, in addition, at least one UV absorbing material is added in such a concentration that darkening of the photochromic substance(s) is independent of the UV fraction of the excitation light.But rather the intensity of the darkening depends on brightness, i.e. the intensity integrated over the spectral light sensitivity of the human eye V.sub.2.
摘要翻译：公开了由塑料材料制成的物体，特别是用至少一种光致变色物质着色的塑料眼镜片，该光致变色物质在光谱的UV范围内被光激发，并且在激发状态下具有更高的吸收，由光谱人的眼睛的光敏感性比在非激发状态下还要加入至少一种UV吸收材料，其浓度使得光致变色物质的变暗与激发的紫外分数无关光。而是，变暗的强度取决于亮度，即在人眼V2的光谱光敏度上积分的强度。

7. 发明授权

US4927239A Anti-reflection film for an optical element consisting of an organic material 失效
标题翻译：用于由有机材料组成的光学元件的防反射膜
公开(公告)号：US4927239A
公开(公告)日：1990-05-22
申请号：US300192
申请日：1989-01-23
申请人： Manfred Melzig , Horst Rosler , Medardus Schobl
发明人： Manfred Melzig , Horst Rosler , Medardus Schobl
IPC分类号： G02B1/04 , G02B1/115
CPC分类号： G02B1/115
摘要： An anti-reflection film for a clearly transparent optical element consisting of an organic material, for example an ophthalmic spectacle lens, is described. The anti-reflection film comprises a number of layers of which at least one consists of a metallic oxide. In one version of this invention, at least one layer consists of erbium oxide, terbium oxide, dysprosium oxide or holmium oxide. In another version of this invention, one layer consisting of samarium oxide, europium oxide, neodymium oxide or ytterbium oxide with a thickness of lambda/10 to lambda/20 is provided. In a third version of this invention, one layer consisting of yttrium oxide is deposited by evaporation on a layer of silicon dioxide, where the latter is deposited directly on the optical element consisting of an organic material.
摘要翻译：描述了由有机材料例如眼镜片组成的清晰透明的光学元件的抗反射膜。抗反射膜包括至少一层由金属氧化物组成的多层。在本发明的一个版本中，至少一层由氧化铒，氧化铽，氧化镝或氧化钬组成。在本发明的另一个版本中，提供由氧化钐，氧化铕，氧化钕或氧化镱组成的厚度为λ/ 10至λ/ 20的一层。在本发明的第三个版本中，由氧化钇组成的一层通过蒸发沉积在二氧化硅层上，其中二氧化硅直接沉积在由有机材料组成的光学元件上。

8. 发明授权

US07544315B2 Photochromic h-annellated benzo[f]chromene compounds 有权
标题翻译：光致变色的h-环形苯并[f]色烯化合物
公开(公告)号：US07544315B2
公开(公告)日：2009-06-09
申请号：US11785899
申请日：2007-04-20
申请人： Manfred Melzig , Yven Rohlfing , Udo Weigand
发明人： Manfred Melzig , Yven Rohlfing , Udo Weigand
IPC分类号： G02B5/23
CPC分类号： C07D493/04 , C07D311/94 , C07D495/04 , C09K9/02 , C09K2211/1011 , C09K2211/1088 , G02B5/23
摘要： Photochromic h-annellated benzo[f]chromene compounds, especially photochromic compounds derived from benzo[f]chromenes, which compounds have particular long wavelength absorption maxima in their closed form and exhibit good performance in the open, colored form, so that good compatibility is achieved with indenonaphthopyrans which are diffused in phototropic glasses used in phototropic glass applications, and the use of such photochromic h-annellated benzo[f]chromene compounds in photochromic synthetic resin articles, particularly ophthalmic lenses.
摘要翻译：光致变色的h-环形苯并[f]色烯化合物，特别是衍生自苯并[f]色烯的光致变色化合物，该化合物在封闭形式中具有特别长的波长吸收最大值，并且在开放着色的形式下表现出良好的性能，因此良好的相容性在用于光热玻璃应用中的光热玻璃中扩散的茚并萘并吡喃衍生物，以及在光致变色合成树脂制品中，特别是眼用透镜中使用这种光致变色h-环形苯并[f]色烯化合物。

9. 发明申请

US20060011898A1 Neutral-color gray photochromic synthetic resin article 审中-公开
标题翻译：中性色灰色光致变色合成树脂制品
公开(公告)号：US20060011898A1
公开(公告)日：2006-01-19
申请号：US11206088
申请日：2005-08-18
申请人： Manfred Melzig , Udo Weigand , Claudia Mann
发明人： Manfred Melzig , Udo Weigand , Claudia Mann
IPC分类号： G02B5/23 , G02F1/361
CPC分类号： G03C1/685 , G02B5/23
摘要： A neutral-color gray photochromic synthetic resin article which remains almost completely color-neutral or gray both during darkening as well as during fade. The synthetic resin article according to the invention may be employed as a neutral-color gray photochromic ophthalmic lens.
摘要翻译：中性色灰色光致变色合成树脂制品，在变色期间以及在褪色期间，几乎完全保持颜色中性或灰色。根据本发明的合成树脂制品可以用作中性色灰色光致变色眼镜。

10. 发明授权

US06686468B2 H-annellated benzo[f]chromenes 失效
标题翻译： H环形苯并[f]色烯
公开(公告)号：US06686468B2
公开(公告)日：2004-02-03
申请号：US10129736
申请日：2002-05-10
申请人： Claudia Mann , Manfred Melzig , Udo Weigand
发明人： Claudia Mann , Manfred Melzig , Udo Weigand
IPC分类号： C07D41300
CPC分类号： C07D493/04 , C07D311/78 , C07D311/94
摘要： The present invention relates to specific photochromic h-annellated benzo[f]chromene derivatives and their use in synthetic resins of all types, especially for ophthalmic applications. In particular, the present invention relates to photochromic compounds derived from benzo[f]chromenes, which in the open form have especially long-wave absorption maxima making it possible to obtain violet to blue tints when used in phototropic glasses.
摘要翻译：本发明涉及特定的光致变色h-环形苯并[f]色烯衍生物及其在所有类型的合成树脂中的用途，特别是用于眼科应用。特别地，本发明涉及衍生自苯并[f]色烯的光致变色化合物，其以开放形式具有特别的长波吸收最大值，使得当用于光热反射玻璃时可获得紫色至蓝色。

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