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1. 发明授权

US3972923A Process for the preparation of phosphonic acid dihalides 失效
标题翻译：制备膦酸二卤化物的方法
公开(公告)号：US3972923A
公开(公告)日：1976-08-03
申请号：US415341
申请日：1973-11-13
申请人： Manfred Finke , Hans-Jerg Kleiner , Gerhard Stahler , Klaus Dehmer
发明人： Manfred Finke , Hans-Jerg Kleiner , Gerhard Stahler , Klaus Dehmer
IPC分类号： C07F9/42
CPC分类号： C07F9/42
摘要： Process for preparing phosphonic acid dihalides of the formula ##EQU1## wherein R is alkyl of 1 to 18 carbon atoms, cycloalkyl of 4 to 8 carbon atoms, alkenyl of 2 to 18 carbon atoms, phenyl, phenalkyl or alkyl-phenyl of 7 to 8 carbon atoms, phenyl, phenalkyl or alkyl-phenyl of 7 to 8 carbon atoms, all radicals R optionally being substituted by chlorine, bromine, cyano or lower acyloxy, and wherein X is halogen such as 2-chloroethane phosphonic acid dichloride, by reacting phosphonic or thio-phosphonic acids of the formula ##EQU2## wherein Y is oxygen or sulfur, their salts or functional derivatives, with acid halides of the formula(CO).sub.n X.sub.2 (III)wherein X is chlorine or bromine and n is 1 or 2, in the presence of 0.2 - 5% or in the presence of 0.01 to 0.2% by weight of1. compounds containing at least one tri- to pentavalent nitrogen or phosphorus atom, which in the case of nitrogen is bound with 1 to 4, in the case of phosphorus with at least 3 valences to organic radicals having up to 20 carbon atoms, two of these valences optionally forming a double bond, or2. mono-di- or tribasic organic or inorganic fully amidated acids or tri- or pentavalent phosphorus, the N atom of which optionally being substituted by aliphatic radicals having up to 20 carbon atoms, and the organic radicals of which contain up to 20 carbon atoms,If required, in the presence of an inert solvent.
摘要翻译：制备式XRP膦酸二卤化物的方法其中R为1至18个碳原子的烷基，4至8个碳原子的环烷基，2至18个碳原子的烯基，苯基，苯烷基或烷基 - 7至8个碳原子的苯基，7至8个碳原子的苯基，苯烷基或烷基 - 苯基，所有基团R任选被氯，溴，氰基或低级酰氧基取代，其中X是卤素如2-氯乙烷膦酸通过使式YH RP ANGLE（II）PARALLEY YYH的膦酸或硫代膦酸与式（CO）n X 2（III）的酰卤反应，其中Y是氧或硫，其盐或官能衍生物，其中X是氯或溴，n为1或2，在0.2-5％的存在下或在0.01至0.2重量％的存在下。1.含有至少一种三价或多价的硝酸或磷酸盐的化合物氮在1至4之间，至少在磷酸盐的情况下有机碳有机物多达20个碳原子，两个这样的价格可选地形成双重键，或2.单独或有机有机或无机全酰胺或三价或三价硼，其中N原子任选被具有至多20个碳原子的脂族基团取代，并且其有机基团含有至多20个碳原子，如果需要，在惰性溶剂存在下。

2. 发明授权

US4336206A Process for the manufacture of cyanohydrin acylates of aldehydes 失效
标题翻译：制备醛类羟腈酰化物的方法
公开(公告)号：US4336206A
公开(公告)日：1982-06-22
申请号：US149969
申请日：1980-05-15
申请人： Rainer Mundnich , Manfred Finke , Walter Rupp , Klaus Dehmer
发明人： Rainer Mundnich , Manfred Finke , Walter Rupp , Klaus Dehmer
IPC分类号： C07C255/16 , C07C67/00 , C07C253/00 , C07C255/14 , C07C255/31 , C07C255/38 , C07C120/00 , C07C121/38 , C07C121/46 , C07C121/66
CPC分类号： C07C255/00
摘要： Cyanohydrin acylates of aldehydes are manufactured by reacting aldehydes with aqueous solutions of cyanides and organic acid chlorides or anhydrides in the molar ratio of aldehyde:cyanide:acid chloride or anhydride of 1:1:1 with deviations of at most only about 10%, optionally in the presence of an inert organic solvent immiscible with water in a one-stage process. The process products are intermediates mainly in the fields of pharmaceuticals and plant protection.
摘要翻译：醛的氰基醇酰化物通过使醛与氰化物和有机酰氯或酸酐的水溶液以醛：氰化物：酰氯或酸酐的1:1:1的摩尔比反应制备，偏差最多仅为约10％，任选地在一步法中与水不混溶的惰性有机溶剂的存在下进行。过程产品主要是药物和植物保护领域的中间体。

3. 发明授权

US4322271A Process for the preparation of N-vinyl-N-alkyl-carboxylic acid amides 失效
标题翻译：制备N-乙烯基-N-烷基 - 羧酸酰胺的方法
公开(公告)号：US4322271A
公开(公告)日：1982-03-30
申请号：US149742
申请日：1980-05-14
申请人： Harald Jensen , Erwin Schmidt , Michael Mitzlaff , Jurgen Cramer , Rudolf Pistorius , Hartmut Pietsch , Klaus Dehmer
发明人： Harald Jensen , Erwin Schmidt , Michael Mitzlaff , Jurgen Cramer , Rudolf Pistorius , Hartmut Pietsch , Klaus Dehmer
IPC分类号： C07C67/00 , C07C231/00 , C07C231/08 , C07C231/12 , C07C102/00
CPC分类号： C07C231/00
摘要： N-Vinyl-N-alkyl-carboxylic acid amides are prepared, starting from N-ethyl-carboxylic acid amides, in a 3-stage process consisting of the following stages:(a) anodic alkoxylation of the N-ethyl-carboxylic acid amides to give N-.alpha.-alkoxyethyl-carboxylic acid amides;(b) alkylation of these N-.alpha.-alkoxyethyl-carboxylic acid amides with an alkyl halide or dialkyl sulfate in an alkaline medium to give N-.alpha.-alkoxyethyl-N-alkyl-carboxylic acid amides; and(c) splitting off of alcohol from the products of stage (b) by heating to temperatures between about 60.degree. and about 350.degree. C.Instead of stages (b) and (c), it is also possible to carry out the following stages after stage (a):(b.sub.1) splitting off of alcohol from the N-.alpha.-alkoxyethylcarboxylic acid amides obtained in stage (a) by heating to temperatures of about 60.degree. to about 600.degree. C., to give N-vinyl-carboxylic acid amides; and(c.sub.1) alkylation of these N-vinyl-carboxylic acid amides by reaction with an alkylating agent of the same type as in stage (b) in an alkaline medium.The N-vinyl-N-alkyl-carboxylic acid amides obtained by the process are valuable intermediate products, in particular for the manufacture of homopolymers and copolymers with interesting properties.
摘要翻译： N-乙烯基-N-烷基 - 羧酸酰胺由N-乙基 - 羧酸酰胺开始，由以下阶段组成的3阶段方法制备：（a）N-乙基 - 羧酸酰胺的阳极烷氧基化得到N-α-烷氧基乙基 - 羧酸酰胺; （b）在碱性介质中将这些N-α-烷氧基乙基 - 羧酸酰胺与烷基卤化物或二烷基硫酸盐烷基化，得到N-α-烷氧基乙基-N-烷基 - 羧酸酰胺; 和（c）通过加热到约60℃至约350℃的温度，从阶段（b）的产物中分离出醇。代替阶段（b）和（c），还可以进行以下阶段（a）之后的阶段：（b1）通过加热到约60℃至约600℃的温度，从阶段（a）中获得的N-α-烷氧基乙基羧酸酰胺中分离出醇，得到N-乙烯基 - 羧酸酰胺; 和（c1）通过与碱性介质中与阶段（b）相同类型的烷基化剂反应来烷基化这些N-乙烯基羧酸酰胺。通过该方法获得的N-乙烯基-N-烷基 - 羧酸酰胺是有价值的中间产物，特别是用于制造具有有趣特性的均聚物和共聚物。

4. 发明授权

US4355186A Process for the preparation of 4-phenoxy-phenols 失效
标题翻译： 4-苯氧基苯酚的制备方法
公开(公告)号：US4355186A
公开(公告)日：1982-10-19
申请号：US277288
申请日：1981-06-25
申请人： Werner Becker , Klaus Dehmer , Klaus Kaiser , Karl Rehn
发明人： Werner Becker , Klaus Dehmer , Klaus Kaiser , Karl Rehn
IPC分类号： C07C41/26 , C07C149/34 , C07C149/36
CPC分类号： C07C41/26
摘要： Substituted 4-phenoxy-phenols are prepared by adding the corresponding anilines in liquid or molten state together with aqueous sodium nitrite solution in equimolar amounts to excess HCl and introducing the diazonium chloride solution obtained into a boiling mixture of about half-concentrated H.sub.2 SO.sub.4 and an aromatic hydrocarbon.
摘要翻译：通过将液体或熔融状态的相应的苯胺与亚硝酸钠水溶液等量加入到过量的HCl中并将所得重氮氯化物溶液引入约半浓H 2 SO 4和芳族化合物的沸腾混合物中来制备取代的4-苯氧基苯酚烃。

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