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1. 发明授权

US4853307A Imaging member containing a copolymer of styrene and ethyl acrylate 失效
标题翻译：含有苯乙烯和丙烯酸乙酯共聚物的成像构件
公开(公告)号：US4853307A
公开(公告)日：1989-08-01
申请号：US140441
申请日：1988-01-04
申请人： Man C. Tam , Steven Bloembergen , Gregory J. Kovacs , Carol A. Jennings , Rafik O. Loutfy , Sandra J. Gardner , Michael G. Taylor
发明人： Man C. Tam , Steven Bloembergen , Gregory J. Kovacs , Carol A. Jennings , Rafik O. Loutfy , Sandra J. Gardner , Michael G. Taylor
IPC分类号： G03G5/02 , G03G13/22 , G03G17/08
CPC分类号： G03G13/22 , G03G17/08
摘要： An imaging system including a migration imaging member comprising a substrate and an electrically insulating softening layer adjacent the substrate, the softenable layer comprising a fracturable layer of electrically photosensitive migration marking material located substantially at or near the surface of the softenable layer spaced from the substrate, and a copolymer of styrene and ethyl acrylate in at least one layer adjacent the substrate, the copolymer comprising between about 40 and about 80 mole percent styrene, between about 20 and about 60 mole percent ethyl acrylate, the copolymer having a M.sub.n between about 4,000 and about 35,000, a M.sub.w between about 10,000 and about 80,000, a T.sub.g between about 30.degree. C. and about 75.degree. C., and a melt viscosity between about 1.times.10.sup.2 poise and about 1.times.10.sup.6 poise at 115.degree. C.The migration imaging member may be imaged by charging, imagewise exposing to activating radiation and developing with heat, solvent vapor, or solvent vapor pretreatment followed by heat. Some embodiments of the imaged member, wherein the softenable layer contains a charge transport material, may be utilized as a master in a zeroprinting process. The copolymer of styrene and ethyl acrylate may be in an adhesive layer of charge transport spacing layer between the substrate and the sofenable layer, or in the softenable layer itself. If desired, the copolymer in any of the aforesaid layers may be a terpolymer of styrene, ethyl acrylate and a copolymerizable organic acid having carbon-to-carbon unsaturation or a copolymerizable derivative of the organic acid.
摘要翻译：一种成像系统，其包括迁移成像构件，所述迁移成像构件包括基底和邻近所述基底的电绝缘软化层，所述可软化层包括位于所述可软化层的与所述基底隔开的表面的表面附近或附近的电光敏迁移标记材料的可破裂层，和苯乙烯和丙烯酸乙酯在邻近基材的至少一层中的共聚物，所述共聚物包含约40至约80摩尔％的苯乙烯，约20至约60摩尔％的丙烯酸乙酯，所述共聚物的Mn在约4,000和约35,000，约10,000至约80,000的Mw，约30℃至约75℃之间的Tg，以及在115℃下约1×102泊至约1×10 6泊的熔体粘度。迁移成像构件可以是通过充电成像，成像暴露于活化辐射并用热，溶剂蒸气或溶剂蒸气预处理进行显影加热。成像构件的一些实施方案，其中可软化层含有电荷传输材料，可以在压印过程中用作母体。苯乙烯和丙烯酸乙酯的共聚物可以在基材和可渗透层之间或在可软化层本身中的电荷输送间隔层的粘合剂层中。如果需要，任何上述层中的共聚物可以是苯乙烯，丙烯酸乙酯和具有碳 - 碳不饱和键的可共聚有机酸或有机酸的可共聚衍生物的三元共聚物。

2. 发明授权

US09662824B2 Process for producing biopolymer nanoparticles 有权
公开(公告)号：US09662824B2
公开(公告)日：2017-05-30
申请号：US12377501
申请日：2007-08-14
申请人： Robert H. Wildi , Edward Van Egdom , Steven Bloembergen
发明人： Robert H. Wildi , Edward Van Egdom , Steven Bloembergen
IPC分类号： B29C47/36 , B29C47/60 , C08B31/00 , C08J3/24 , C08L3/02 , B29B9/00 , B29B9/08 , B29B9/06 , B29C47/00 , B29C47/10 , B29K105/00 , C08K5/00 , B29B9/12
CPC分类号： B29C47/6056 , B29B9/00 , B29B9/06 , B29B9/08 , B29B2009/125 , B29C47/0004 , B29C47/0014 , B29C47/1063 , B29C47/1081 , B29C47/60 , B29C47/6031 , B29C47/6037 , B29C47/6062 , B29C47/6087 , B29K2003/00 , B29K2105/0005 , B29K2105/0038 , C08B31/003 , C08J3/24 , C08J2303/02 , C08K5/0025 , C08L3/02
摘要： A process for producing a biopolymer nanoparticles product is disclosed. In this process, biopolymer feedstock and a plasticizer are fed to a feed zone of an extruder having a screw configuration in which the feedstock is process using shear forces in the extruder, and a crosslinking agent is added to the extruder downstream of the feed zone. The biopolymer feedstock and plasticizer are preferably added separately to the feed zone. The screw configuration may include two or more steam seal sections. Shear forces in a first section of the extruder may be greater than shear forces in an adjacent second section of the extruder downstream of the first section. In a post reaction section located after a point in which the crosslinking reaction has been completed, water may be added to improve die performance.

3. 发明申请

US20120309246A1 CURABLE BIOPOLYMER NANOPARTICLE LATEX BINDER FOR MINERAL, NATURAL ORGANIC, OR SYNTHETIC FIBER PRODUCTS AND NON-WOVEN MATS 审中-公开
标题翻译：适用于矿物，天然有机或合成纤维产品和非织造布的可固化生物聚合物纳米颗粒LATEX BINDER
公开(公告)号：US20120309246A1
公开(公告)日：2012-12-06
申请号：US13486555
申请日：2012-06-01
申请人： Alexander Tseitlin , David Van Alstyne , Steven Bloembergen
发明人： Alexander Tseitlin , David Van Alstyne , Steven Bloembergen
IPC分类号： C09D103/00 , B32B17/04 , C09D197/02 , C09D161/24 , B82Y30/00
CPC分类号： D04H1/587 , B29C39/003 , C03B37/04 , C08J5/24 , C08J2303/02 , C08J2303/04 , C08K5/0025 , C08L1/02 , C08L3/04 , C08L23/00 , C08L33/08 , C08L61/24 , C08L67/00 , C08L77/00 , C08L77/02 , C08L89/00 , C08L97/02 , C08L2205/16 , C08L2205/18 , C09J103/04 , C09J161/24 , Y10T442/2992 , C08K7/04 , C08K7/14
摘要： A curable aqueous binder composition includes a dispersion of biopolymer particles, optionally with and an inter-particle crosslinking agent, for use in the formation of composite materials such as mineral, natural organic, or synthetic fiber products, including mineral fiber insulation, non-woven mats, fiberglass insulation and related glass fiber products, and wood based products, and construction materials. In an application of the curable aqueous composition to making fiberglass insulation, the composition may be blended with a second resin which may be a non-formaldehyde resin. In an application of the composition to making fiberglass roofing shingles, the biopolymer particles may be mixed into a formaldehyde based resin during or after the polymerization of the resin.
摘要翻译：可固化水性粘合剂组合物包括生物聚合物颗粒的分散体，任选与颗粒间交联剂，用于形成复合材料如矿物，天然有机或合成纤维产品，包括矿物纤维绝缘层，无纺布垫子，玻璃纤维绝缘和相关玻璃纤维制品，木制品和建筑材料。在可固化水性组合物在制备玻璃纤维绝缘体的应用中，组合物可以与可以是非甲醛树脂的第二树脂共混。在组合物用于制造玻璃纤维屋顶瓦的应用中，生物聚合物颗粒可以在树脂聚合期间或之后混合成甲醛基树脂。

4. 发明申请

US20120263894A1 METHODS OF USING BIOBASED LATEX BINDERS FOR IMPROVED PRINTING PERFORMANCE 有权
标题翻译：使用生物化的LATEX粘合剂改进印刷性能的方法
公开(公告)号：US20120263894A1
公开(公告)日：2012-10-18
申请号：US13514635
申请日：2010-12-17
申请人： Steven Bloembergen
发明人： Steven Bloembergen
IPC分类号： B32B27/10 , B41M5/52
CPC分类号： D21H19/54 , B41J2/2107 , C09D103/02 , C09D109/04 , C09D109/08 , D21H17/28 , D21H19/48 , Y10T428/25
摘要： The invention therefore provides a method of improving print performance in a paper product comprising applying a coating composition comprising (i) a pigment and (ii) a starch dispersion of discrete crosslinked native starch particles in an aqueous liquid, wherein the particle size of the starch particles in the starch dispersion ranges from about 40 nm to about 400 μm, to the paper product, wherein the print performance of the paper product is improved. In one embodiment, the coating composition comprises a solids content of from 5 to about 75% weight and comprises (i) about 100 parts by weight of pigment, and (ii) about 1 to about 300 parts by weight of starch, all based on dry weight.
摘要翻译：因此，本发明提供了一种提高纸产品印刷性能的方法，包括涂覆一种涂料组合物，该涂料组合物包含（i）颜料和（ii）在水性液体中的离散交联天然淀粉颗粒的淀粉分散体，其中淀粉的粒度淀粉分散体中的颗粒的范围为约40nm至约400μm，其中纸产品的印刷性能得到改善。在一个实施方案中，涂料组合物包含5至约75重量％的固体含量，并包含（i）约100重量份的颜料，和（ii）约1至约300重量份的淀粉，全部基于净重。

5. 发明申请

US20100143738A1 Process for Producing Biopolymer Nanoparticle Biolatex Compositions Having Enhanced Performance and Compositions Based Thereon 审中-公开
标题翻译：具有增强性能和组合的生物聚合物纳米粒子Biolatex组合物的生产方法
公开(公告)号：US20100143738A1
公开(公告)日：2010-06-10
申请号：US12630526
申请日：2009-12-03
申请人： Steven Bloembergen , Do I. Lee , Ian J. McLennan , Robert H. Wildi , Edward Van Egdom
发明人： Steven Bloembergen , Do I. Lee , Ian J. McLennan , Robert H. Wildi , Edward Van Egdom
IPC分类号： B32B27/10 , B32B29/00 , C08L89/00 , C08K3/22 , C08K5/053 , C08L97/02
CPC分类号： C09D1/00 , B29B7/483 , B29B7/488 , B29B7/489 , B29B7/603 , B29B7/726 , B29B7/823 , B29B7/94 , B29C48/022 , B29C48/05 , B29C48/286 , B29C48/288 , B29C48/297 , B29C48/37 , B29C48/40 , B29C48/54 , B29C48/55 , B29C48/57 , B29C48/575 , B29C48/625 , B29C48/64 , B29C48/92 , B29C2948/92019 , B29C2948/92104 , B29C2948/92333 , B29C2948/924 , B29C2948/92514 , B29C2948/9259 , B29C2948/92695 , B29C2948/92704 , B29C2948/92885 , B29C2948/92895 , B29C2948/92933 , B29K2105/162 , B29K2995/0056 , C08B31/003 , C09D103/02 , D21H19/54 , Y02P70/263 , Y10T428/31993
摘要： The present invention provides novel biolatex conjugate compositions and methods of production and use thereof. The novel biolatex conjugate compositions comprise a biopolymer-additive complex (prepared by co-extruding a biopolymer feedstock, at least one performance-enhancing additive, and at least one plasticizer under shear forces) reacted with a crosslinking agent under shear forces. The biolatex conjugate compositions exhibit enhanced performance properties for coated paper, paperboard, and other applications using extremely low levels of performance-enhancing additives.
摘要翻译：本发明提供了新的生物素共轭组合物及其生产和使用方法。新型生物素共轭组合物包含在剪切力下与交联剂反应的生物聚合物 - 添加剂复合物（通过共挤出生物聚合物原料，至少一种性能增强添加剂和至少一种剪切力下的增塑剂制备）。生物素复合物组合物对于涂布纸，纸板和其它使用极低水平的性能增强添加剂的应用表现出增强的性能。

6. 发明授权

US5462983A Biodegradable moldable products and films comprising blends of starch esters and polyesters 失效
标题翻译：可生物降解的可成型产品和薄膜包括淀粉酯和聚酯的共混物
公开(公告)号：US5462983A
公开(公告)日：1995-10-31
申请号：US097563
申请日：1993-07-27
申请人： Steven Bloembergen , Ramani Narayan
发明人： Steven Bloembergen , Ramani Narayan
IPC分类号： C08K3/34 , C08K5/103 , C08L1/00 , C08L3/06 , C08L67/00 , C08L67/02 , C08L67/04 , C08L99/00 , C08L101/16
CPC分类号： C08L3/06 , C08L67/02 , C08L67/04 , C08L2201/06
摘要： Biodegradable moldable products and films prepared from a compatible blend containing a biodegradable, hydrophobic, starch ester and a biodegradable polyester, and optionally a biodegradable and miscible plasticizer and/or a compatible filler.
摘要翻译：由可生物降解的，疏水的，淀粉酯和可生物降解的聚酯以及任选的可生物降解和可混溶的增塑剂和/或相容填料的相容混合物制备的可生物降解的可成型产品和膜。

7. 发明授权

US09157187B2 Methods of using biobased latex binders for improved printing performance 有权
标题翻译：使用生物基胶乳粘合剂改善印刷性能的方法
公开(公告)号：US09157187B2
公开(公告)日：2015-10-13
申请号：US13514635
申请日：2010-12-17
申请人： Steven Bloembergen
发明人： Steven Bloembergen
IPC分类号： B41J2/01 , D21H19/54 , B41J2/21 , D21H17/28 , C09D103/02 , C09D109/04 , C09D109/08 , D21H19/48
CPC分类号： D21H19/54 , B41J2/2107 , C09D103/02 , C09D109/04 , C09D109/08 , D21H17/28 , D21H19/48 , Y10T428/25
摘要： The invention therefore provides a method of improving print performance in a paper product including applying a coating composition having (i) a pigment and (ii) a starch dispersion of discrete crosslinked native starch particles in an aqueous liquid, wherein the particle size of the starch particles in the starch dispersion ranges from about 40 nm to about 400 μm, to the paper product, wherein the print performance of the paper product is improved. In one embodiment, the coating composition includes a solids content of from 5 to about 75% weight and includes (i) about 100 parts by weight of pigment, and (ii) about 1 to about 300 parts by weight of starch, all based on dry weight.
摘要翻译：因此，本发明提供了一种提高纸制品中的印刷性能的方法，包括应用具有（i）颜料的涂料组合物和（ii）在水性液体中的离散交联的天然淀粉颗粒的淀粉分散体，其中淀粉的颗粒尺寸淀粉分散体中的颗粒的范围为约40nm至约400μm，其中纸产品的印刷性能得到改善。在一个实施方案中，涂料组合物包含5至约75重量％的固体含量，并且包括（i）约100重量份的颜料和（ii）约1至约300重量份的淀粉，全部基于净重。

8. 发明申请

US20130062807A1 PROCESS FOR PRODUCING BIOPOLYMER NANOPARTICLES 有权
标题翻译：制备生物聚合物纳米粒子的方法
公开(公告)号：US20130062807A1
公开(公告)日：2013-03-14
申请号：US13618075
申请日：2012-09-14
申请人： Robert H. Wildi , Edward Van Egdom , Steven Bloembergen
发明人： Robert H. Wildi , Edward Van Egdom , Steven Bloembergen
IPC分类号： B29B9/08 , B29B9/00
CPC分类号： B29C47/6056 , B29B9/00 , B29B9/06 , B29B9/08 , B29B2009/125 , B29C47/0004 , B29C47/0014 , B29C47/1063 , B29C47/1081 , B29C47/60 , B29C47/6031 , B29C47/6037 , B29C47/6062 , B29C47/6087 , B29K2003/00 , B29K2105/0005 , B29K2105/0038 , C08B31/003 , C08J3/24 , C08J2303/02 , C08K5/0025 , C08L3/02
摘要： In a process for producing a biopolymer nanoparticles, biopolymer feedstock and a plasticizer are fed to a feed zone of an extruder and the biopolymer feedstock is processed using shear forces. A crosslinking agent is added to the extruder downstream of the feed zone. The process has a production rate of at least 1.0 metric tons per hour. The feedstock and the plasticizer are preferably added separately to the feed zone. The extruder may have single flight elements in the feed zone. The temperatures in the intermediate section of the extruder are preferably kept above 100 C. The screw configuration may include two or more steam seal sections. Shear forces in a first section of the extruder may be greater than shear forces in an adjacent downstream section of the first section. In a post reaction section, water may be added to improve die performance.
摘要翻译：在制备生物聚合物纳米颗粒的方法中，将生物聚合物原料和增塑剂进料到挤出机的进料区，并使用剪切力来处理生物聚合物原料。在进料区下游的挤出机中加入交联剂。该方法的生产速度至少为每小时1.0公吨。原料和增塑剂优选分开加入进料区。挤出机可以在进料区域中具有单个飞行元件。挤出机的中间部分的温度优选保持在100℃以上。螺杆构造可以包括两个或更多个蒸汽密封部分。在挤出机的第一部分中的剪切力可能大于第一部分的相邻下游部分中的剪切力。在后反应段中，可以加入水以改善模具性能。

9. 发明授权

US06921430B2 Environmentally friendly biopolymer adhesives and applications based thereon 有权
标题翻译：环保型生物聚合物粘合剂及其应用
公开(公告)号：US06921430B2
公开(公告)日：2005-07-26
申请号：US10476436
申请日：2002-05-02
申请人： Steven Bloembergen , Frans Kappen , Brigit Beelen
发明人： Steven Bloembergen , Frans Kappen , Brigit Beelen
IPC分类号： C09J201/00 , C09J11/00 , C09J103/02 , C09J103/04 , D06M15/333 , D06M15/693 , D06M23/08 , C09J103/12
CPC分类号： C09J103/04 , C08L2666/28 , C09J103/02
摘要： Environmentally friendly biopolymer adhesives are described, wherein the adhesives comprise biopolymer particles, more preferably starch microparticles, and most preferably starch nanoparticles, and their aqueous dispersions. Applications for the biopolymer particle adhesives are described, that are environmentally friendly alternatives to petroleum based synthetic adhesives. The biopolymer particle adhesives provide are biodegradable as well as repulpable, and thus provide bio-based recycling-friendly alternatives to synthetic adhesives derived from petroleum resources.
摘要翻译：描述了环保生物聚合物粘合剂，其中粘合剂包括生物聚合物颗粒，更优选淀粉微粒，最优选淀粉纳米颗粒及其水分散体。描述了用于生物聚合物颗粒粘合剂的应用，其是对石油基合成粘合剂是环境友好的替代物。生物聚合物颗粒粘合剂提供是可生物降解的并且可再生的，因此为从石油资源衍生的合成粘合剂提供生物基回收友好的替代品。

10. 发明授权

US5869647A Method of preparing biodegradable modified-starch moldable products and films 失效
标题翻译：生物降解改性淀粉可模塑产品和薄膜的制备方法
公开(公告)号：US5869647A
公开(公告)日：1999-02-09
申请号：US97550
申请日：1993-07-27
申请人： Ramani Narayan , Steven Bloembergen , Amit Lathia
发明人： Ramani Narayan , Steven Bloembergen , Amit Lathia
IPC分类号： C08B30/20 , C08B31/04 , C08B33/02 , C08J5/18 , C08L3/00 , C08L3/06 , C08L3/16 , D21H27/00
CPC分类号： C08J5/18 , C08B31/04 , C08B33/02 , C08L3/06 , C08L3/16 , C08J2303/06 , C08J2303/16 , C08L2201/06
摘要： A method of preparing biodegradable moldable products and films includes the steps of preparing biodegradable, hydrophobic, modified starch, and forming a thermoplastic product, comprising the modified starch, and optionally a miscible and biodegradable plasticizer, and/or a compatible filler.
摘要翻译：制备可生物降解的可成型产品和薄膜的方法包括制备可生物降解的，疏水的，改性的淀粉和形成包含改性淀粉的热塑性产品和任选的可混溶和可生物降解的增塑剂和/或相容填料的步骤。

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