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1. 发明申请

US20090258780A1 POROUS INORGANIC OXIDE SUPPORT AND HYDROTREATING CATALYST OF CATALYTIC CRACKING GASOLINE USING THE SAME 有权
标题翻译：使用相同的催化裂化汽油的多孔无机氧化物支持和加氢催化剂
公开(公告)号：US20090258780A1
公开(公告)日：2009-10-15
申请号：US11885414
申请日：2006-02-28
申请人： Makoto Toba , Yuji Yoshimura , Nobuyuki Matsubayashi , Takashi Matsui
发明人： Makoto Toba , Yuji Yoshimura , Nobuyuki Matsubayashi , Takashi Matsui
IPC分类号： B01J27/19 , B01J27/22 , B01J21/04
CPC分类号： B01J23/882 , B01J23/88 , B01J27/22 , B01J31/0201 , B01J35/002 , B01J37/0203 , C10G2300/104 , C10G2400/02
摘要： A porous inorganic oxide support comprising an oxygen-containing carbonaceous material supported thereon, preferably a porous inorganic oxide support wherein the oxygen-containing carbonaceous material is a carbide of an oxygen-containing organic compound, wherein the ratio of the supported carbon amount with respect to the mass of the support for preparing the catalyst is from 0.05 to 0.2, the atomic ratio of the supported hydrogen amount with respect to the supported carbon amount is from 0.4 to 1.0, and the atomic ratio of the supported oxygen amount with respect to the supported carbon amount is from 0.1 to 0.6; and a hydrotreating catalyst of catalytic cracking gasoline which comprises the support and a catalyst containing a Group 8 metal of the periodic table, molybdenum (Mo), phosphorus and sulfur which is supported on the support are useful as a desulfurization catalyst of, for example, catalytic cracking gasoline at a hyperdesulfurized level, because of having functions of suppressing the hydrogenation activity of olefins and minimizing the decrease in the octane number even under reaction conditions with a high desulfurization ratio.
摘要翻译：一种多孔无机氧化物载体，其包含负载在其上的含氧碳质材料，优选多孔无机氧化物载体，其中所述含氧碳质材料是含氧有机化合物的碳化物，其中所述负载碳量相对于用于制备催化剂的载体的质量为0.05至0.2，负载氢量相对于负载碳量的原子比为0.4至1.0，并且负载氧量相对于负载的碳原子比碳量为0.1〜0.6; 和催化裂化汽油的加氢处理催化剂，其包含载体和含有周期表第8族金属的催化剂，负载在载体上的钼（Mo），磷和硫，可用作例如脱硫催化剂，催化裂化汽油处于高脱硫水平，因为即使在高脱硫比的反应条件下也具有抑制烯烃的氢化活性和最小化辛烷值降低的作用。

2. 发明授权

US07393807B2 Hydrotreating catalyst of catalytic cracking gasoline 有权
标题翻译：催化裂化汽油加氢催化剂
公开(公告)号：US07393807B2
公开(公告)日：2008-07-01
申请号：US11131239
申请日：2005-05-18
申请人： Yuji Yoshimura , Makoto Toba , Nobuyuki Matsubayashi , Takashi Matsui
发明人： Yuji Yoshimura , Makoto Toba , Nobuyuki Matsubayashi , Takashi Matsui
IPC分类号： B01J27/19 , B01J27/185 , B01J27/043 , B01J27/049
CPC分类号： B01J37/0203 , B01J23/88 , B01J23/882 , B01J35/002 , B01J37/20 , B01J37/28 , B01J37/346 , C10G45/04 , C10G45/08 , Y10S502/506 , Y10S502/512
摘要： A hydrotreating catalyst comprising a Group 8 metal of the periodic table, molybdenum (Mo), phosphorus and sulfur, wherein the average coordination number [N(Mo)] of the molybdenum atoms around the molybdenum atom is from 1.5 to 2.5 and the average coordination number [N(S)] of the sulfur atoms around the molybdenum atom is from 3.5 to 5.0 when MoS2 structure in the catalyst is measured in accordance with extended X-ray absorption fine structure (EXAFS) analysis.
摘要翻译：包含周期表第8族金属的加氢处理催化剂，钼（Mo），磷和硫，其中钼原子周围的钼原子的平均配位数[N（Mo）]为1.5-2.5，平均配位根据扩展的X射线吸收精细结构（EXAFS）分析测量催化剂中的MoS 2 H 2结构，钼原子周围的硫原子的数量[N（S）]为3.5〜5.0 。

3. 发明申请

US20050261124A1 Hydrotreating catalyst of catalytic cracking gasoline 有权
标题翻译：催化裂化汽油加氢催化剂
公开(公告)号：US20050261124A1
公开(公告)日：2005-11-24
申请号：US11131239
申请日：2005-05-18
申请人： Yuji Yoshimura , Makoto Toba , Nobuyuki Matsubayashi , Takashi Matsui
发明人： Yuji Yoshimura , Makoto Toba , Nobuyuki Matsubayashi , Takashi Matsui
IPC分类号： B01J27/19 , B01J23/88 , B01J23/882 , B01J27/188 , B01J35/00 , B01J37/02 , B01J37/20 , B01J37/28 , B01J37/34 , C10G45/04 , C10G45/08 , C10G69/04
CPC分类号： B01J37/0203 , B01J23/88 , B01J23/882 , B01J35/002 , B01J37/20 , B01J37/28 , B01J37/346 , C10G45/04 , C10G45/08 , Y10S502/506 , Y10S502/512
摘要： A hydrotreating catalyst comprising a Group 8 metal of the periodic table, molybdenum (Mo), phosphorus and sulfur, wherein the average coordination number [N(Mo)] of the molybdenum atoms around the molybdenum atom is from 1.5 to 2.5 and the average coordination number [N(S)] of the sulfur atoms around the molybdenum atom is from 3.5 to 5.0 when MoS2 structure in the catalyst is measured in accordance with extended X-ray absorption fine structure (EXAFS) analysis.
摘要翻译：包含周期表第8族金属的加氢处理催化剂，钼（Mo），磷和硫，其中钼原子周围的钼原子的平均配位数[N（Mo）]为1.5-2.5，平均配位根据扩展的X射线吸收精细结构（EXAFS）分析测量催化剂中的MoS 2 H 2结构，钼原子周围的硫原子的数量[N（S）]为3.5〜5.0 。

4. 发明授权

US07795168B2 Porous inorganic oxide support and hydrotreating catalyst of catalytic cracking gasoline using the same 有权
标题翻译：多孔无机氧化物载体和催化裂化汽油加氢处理催化剂使用相同
公开(公告)号：US07795168B2
公开(公告)日：2010-09-14
申请号：US11885414
申请日：2006-02-28
申请人： Makoto Toba , Yuji Yoshimura , Nobuyuki Matsubayashi , Takashi Matsui
发明人： Makoto Toba , Yuji Yoshimura , Nobuyuki Matsubayashi , Takashi Matsui
IPC分类号： B01J27/20
CPC分类号： B01J23/882 , B01J23/88 , B01J27/22 , B01J31/0201 , B01J35/002 , B01J37/0203 , C10G2300/104 , C10G2400/02
摘要： A porous inorganic oxide support comprising an oxygen-containing carbonaceous material supported thereon, preferably a porous inorganic oxide support wherein the oxygen-containing carbonaceous material is a carbide of an oxygen-containing organic compound, wherein the ratio of the supported carbon amount with respect to the mass of the support for preparing the catalyst is from 0.05 to 0.2, the atomic ratio of the supported hydrogen amount with respect to the supported carbon amount is from 0.4 to 1.0, and the atomic ratio of the supported oxygen amount with respect to the supported carbon amount is from 0.1 to 0.6; and a hydrotreating catalyst of catalytic cracking gasoline which comprises the support and a catalyst containing a Group 8 metal of the periodic table, molybdenum (Mo), phosphorus and sulfur which is supported on the support are useful as a desulfurization catalyst of, for example, catalytic cracking gasoline at a hyperdesulfurized level, because of having functions of suppressing the hydrogenation activity of olefins and minimizing the decrease in the octane number even under reaction conditions with a high desulfurization ratio.
摘要翻译：一种多孔无机氧化物载体，其包含负载在其上的含氧碳质材料，优选多孔无机氧化物载体，其中所述含氧碳质材料是含氧有机化合物的碳化物，其中所述负载碳量相对于用于制备催化剂的载体的质量为0.05至0.2，负载氢量相对于负载碳量的原子比为0.4至1.0，并且负载氧量相对于负载的碳原子比碳量为0.1〜0.6; 和催化裂化汽油的加氢处理催化剂，其包含载体和含有周期表第8族金属的催化剂，负载在载体上的钼（Mo），磷和硫，可用作例如脱硫催化剂，催化裂化汽油处于高脱硫水平，因为即使在高脱硫比的反应条件下也具有抑制烯烃的氢化活性和最小化辛烷值降低的作用。

5. 发明申请

US20120295991A1 METHOD FOR PRODUCING FORMIC ACID 失效
标题翻译：生产形式酸的方法
公开(公告)号：US20120295991A1
公开(公告)日：2012-11-22
申请号：US13574859
申请日：2011-01-24
申请人： Masaru Nakahara , Nobuyuki Matsubayashi , Yoshiro Yasaka
发明人： Masaru Nakahara , Nobuyuki Matsubayashi , Yoshiro Yasaka
IPC分类号： C07C51/00
CPC分类号： C07C51/00 , B01J31/0284 , B01J31/0288 , B01J31/2404 , B01J2231/625 , B01J2531/821 , Y02P20/544 , C07C53/02
摘要： An object of the present invention is providing a method for producing formic acid under mild reaction conditions and by a simple procedure. As a means for achieving the object, the method for producing formic acid of the present invention is characterized by a reaction between carbon dioxide and hydrogen in the presence of an ionic liquid. According to the present invention, it is possible to generate formic acid effectively, because the method does not require that carbon dioxide be brought into a supercritical state and because no basic substances are required to be added to the reaction system.
摘要翻译：本发明的目的是提供一种在温和的反应条件下通过简单的方法生产甲酸的方法。作为实现该目的的手段，本发明的甲酸的制造方法的特征在于，在离子液体的存在下，二氧化碳与氢的反应。根据本发明，可以有效地生成甲酸，因为该方法不要求将二氧化碳置于超临界状态，并且由于不需要将碱性物质加入到反应体系中。

6. 发明授权

US07345484B2 NMR probe for high-temperature measurements 有权
标题翻译： NMR探头用于高温测量
公开(公告)号：US07345484B2
公开(公告)日：2008-03-18
申请号：US10569854
申请日：2004-08-27
申请人： Masaru Nakahara , Nobuyuki Matsubayashi , Chihiro Wakai , Takeyoshi Ikeda
发明人： Masaru Nakahara , Nobuyuki Matsubayashi , Chihiro Wakai , Takeyoshi Ikeda
IPC分类号： G01V3/00
CPC分类号： G01R33/31 , G01R33/465
摘要： An NMR probe for high-temperature NMR measurements includes tubular heating means mounted respectively immediately below and immediately above an area to be measured. A sample tube is inserted inside the tube formed by the two heating means. A sample placed in the sample tube is heated. Heat from the two heating means is transmitted to the sample via at least one heat transfer pipe of a good thermal conductivity. The heat transfer pipe is disposed inside the tube of the heating means.
摘要翻译：用于高温NMR测量的NMR探针包括分别安装在待测区域的正上方和正上方的管状加热装置。样品管插入由两个加热装置形成的管内。放置在样品管中的样品被加热。来自两个加热装置的热量通过至少一个导热性良好的传热管传送到样品。传热管设置在加热装置的管内。

7. 发明授权

US06422294B1 Casting apparatus and casting method of cylinder head 失效
标题翻译：气缸盖铸造设备和铸造方法
公开(公告)号：US06422294B1
公开(公告)日：2002-07-23
申请号：US09719741
申请日：2000-12-15
申请人： Akira Murata , Akihiro Nakano , Nobuyuki Matsubayashi , Takayuki Shouju , Tomoyuki Nozaki , Shigeo Yano
发明人： Akira Murata , Akihiro Nakano , Nobuyuki Matsubayashi , Takayuki Shouju , Tomoyuki Nozaki , Shigeo Yano
IPC分类号： B22D1712
CPC分类号： B22D18/04 , B22D27/04 , B22D27/045
摘要： To obtain a high-quality cast product of a cylinder head, a proper directivity to the cooling process of the molten metal after a pouring process by utilizing the shape of a cylinder head is discussed. In a process where molten metal is injected to a casting mold cavity formed between upper and lower molds to fill it therewith so that the molten metal is solidified to form a cylinder head of an engine, a plurality of core protrusions corresponding to holes (plug holes and bolt holes) are formed in the upper mold, and a cooling means is attached to each of the core protrusions. With respect to cooling means attached to the plurality of core protrusions, those attached to the inner core protrusions comparatively closer to the center of the casting mold are designed so as to have a greater cooling capability than those attached to the outer core protrusions; therefore, with respect to the center portion and the outer portion of the casting mold cavity.
摘要翻译：为了获得气缸盖的高质量铸造产品，讨论了通过利用气缸盖的形状在浇注过程之后熔融金属的冷却过程的适当方向性。在将熔融金属注射到形成在上模和下模之间的铸模腔中以填充其中以使熔融金属固化以形成发动机的气缸盖的过程中，对应于孔的多个芯突起（插塞孔和螺栓孔），并且将冷却装置附接到每个芯突起。对于连接到多个芯突起的冷却装置，相对于相对靠近铸模中心的内芯突起设置的那些被设计成具有比附接到外芯突起的那些更大的冷却能力; 因此，相对于铸模腔的中心部分和外部部分。

8. 发明申请

US20110158899A1 METHOD FOR PRODUCING HYDROGEN 失效
标题翻译：生产氢的方法
公开(公告)号：US20110158899A1
公开(公告)日：2011-06-30
申请号：US13056036
申请日：2009-07-28
申请人： Masaru Nakahara , Nobuyuki Matsubayashi , Yoshiro Yasaka
发明人： Masaru Nakahara , Nobuyuki Matsubayashi , Yoshiro Yasaka
IPC分类号： C01B3/02
CPC分类号： C01B3/22 , C01B2203/0272 , C01B2203/0277 , C01B2203/0405 , C01B2203/0805
摘要： An object of the present invention is to provide a method for producing hydrogen by using formic acid as a feedstock, which provides a solution to problems to be solved for the production of hydrogen on an industrial scale, such as problems of production cost, storability and transportability, and also offers improved convenience. The method for producing hydrogen of the present invention is characterized by heating an ionic liquid containing formic acid. The ionic liquid is preferably an ionic liquid in which a counteranion is a formate anion (i.e., formic acid salt). Such an ionic liquid is, as a medium for the production of hydrogen from formic acid as a feedstock, excellent in terms of reaction selectivity (high-purity hydrogen is produced) and reaction velocity.
摘要翻译：本发明的目的是提供一种通过使用甲酸作为原料生产氢的方法，其提供了在工业规模上生产氢的问题的解决方案，例如生产成本，储存性和运输能力，还提供了便利性。本发明的制造氢的方法的特征在于加热含有甲酸的离子液体。离子液体优选是其中抗衡阴离子是甲酸根阴离子（即甲酸盐）的离子液体。作为用于从作为原料的甲酸生产氢的介质，这种离子液体在反应选择性（产生高纯度氢）和反应速度方面优异。

9. 发明申请

US20070257673A1 Nmr Probe for High-Temperature Measurements 有权
标题翻译： Nmr高温测量探头
公开(公告)号：US20070257673A1
公开(公告)日：2007-11-08
申请号：US10569854
申请日：2004-08-27
申请人： Masaru Nakahara , Nobuyuki Matsubayashi , Chihiro Wakai , Takeyoshi Ikeda
发明人： Masaru Nakahara , Nobuyuki Matsubayashi , Chihiro Wakai , Takeyoshi Ikeda
IPC分类号： G01V3/08
CPC分类号： G01R33/31 , G01R33/465
摘要： An NMR probe for high-temperature NMR measurements includes tubular heating means mounted respectively immediately below and immediately above an area to be measured. A sample tube is inserted inside the tube formed by the two heating means. A sample placed in the sample tube is heated. Heat from the two heating means is transmitted to the sample via at least one heat transfer pipe of a good thermal conductivity. The heat transfer pipe is disposed inside the tube of the heating means.
摘要翻译：用于高温NMR测量的NMR探针包括分别安装在待测区域的正上方和正上方的管状加热装置。样品管插入由两个加热装置形成的管内。放置在样品管中的样品被加热。来自两个加热装置的热量通过至少一个导热性良好的传热管传送到样品。传热管设置在加热装置的管内。

10. 发明授权

US08449862B2 Method for producing hydrogen 失效
标题翻译：生产氢气的方法
公开(公告)号：US08449862B2
公开(公告)日：2013-05-28
申请号：US13056036
申请日：2009-07-28
申请人： Masaru Nakahara , Nobuyuki Matsubayashi , Yoshiro Yasaka
发明人： Masaru Nakahara , Nobuyuki Matsubayashi , Yoshiro Yasaka
IPC分类号： C01B3/22
CPC分类号： C01B3/22 , C01B2203/0272 , C01B2203/0277 , C01B2203/0405 , C01B2203/0805
摘要： An object of the present invention is to provide a method for producing hydrogen by using formic acid as a feedstock, which provides a solution to problems to be solved for the production of hydrogen on an industrial scale, such as problems of production cost, storability and transportability, and also offers improved convenience. The method for producing hydrogen of the present invention is characterized by heating an ionic liquid containing formic acid. The ionic liquid is preferably an ionic liquid in which a counteranion is a formate anion (i.e., formic acid salt). Such an ionic liquid is, as a medium for the production of hydrogen from formic acid as a feedstock, excellent in terms of reaction selectivity (high-purity hydrogen is produced) and reaction velocity.
摘要翻译：本发明的目的是提供一种通过使用甲酸作为原料生产氢的方法，其提供了在工业规模上生产氢的问题的解决方案，例如生产成本，储存性和运输能力，还提供了便利性。本发明的制造氢的方法的特征在于加热含有甲酸的离子液体。离子液体优选是其中抗衡阴离子是甲酸根阴离子（即甲酸盐）的离子液体。作为用于从作为原料的甲酸生产氢的介质，这种离子液体在反应选择性（产生高纯度氢）和反应速度方面优异。

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