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    • 4. 发明授权
    • Polyimide resins
    • 聚酰亚胺树脂
    • US5260411A
    • 1993-11-09
    • US183721
    • 1988-04-20
    • Giuliana C. TesoroVinod R. Sastri
    • Giuliana C. TesoroVinod R. Sastri
    • C08G73/10C08G73/12C08G69/26C08G75/00C08G75/14
    • C08G73/106C08G73/1064C08G73/12Y02P20/582
    • A method for the preparation of a polyimide containing reversible crosslinks comprising the step of curing a monomer having the formula ##STR1## wherein R and R' may be the same or different and each is H or lower alkyl having 1-5 carbon atoms under conditions conducive to the formation of a polyimide and thereby forming a polyimide having the formula ##STR2## R and R' are as defined above and n is an integer from 10 to 100. The polyimide may be converted to a soluble polymer by cleaving the disulfide bond in the presence of a solvent and a reducing agent. The reduced polymer may be reformed into the polymer in an oxidation step or into a modified polyimide in other reaction steps. Copolymerization processes are also disclosed.
    • 一种制备含有可逆交联的聚酰亚胺的方法,包括固化具有式(I)的单体的步骤,其中R和R'可以相同或不同,并且各自为H或具有1-5个碳的低级烷基 原子在有利于形成聚酰亚胺的条件下形成具有下式的聚酰亚胺(II)R和R'如上所定义,n是10至100的整数。聚酰亚胺可以转化为可溶的 聚合物通过在溶剂和还原剂的存在下裂解二硫键。 在其它反应步骤中,还原的聚合物可以在氧化步骤中重整成聚合物或改性为改性聚酰亚胺。 还公开了共聚过程。
    • 5. 发明授权
    • Epoxy resins having reversible crosslinks
    • 具有可逆交联的环氧树脂
    • US4882399A
    • 1989-11-21
    • US88179
    • 1987-08-21
    • Giuliana C. TesoroVinod R. Sastri
    • Giuliana C. TesoroVinod R. Sastri
    • C08G59/18C08G59/40C08G59/50
    • C08G59/504C08G59/18C08G59/4028C08G59/4035C08G59/4064
    • A method for the preparation of insoluble, infusible epoxy resins containing reversible crosslinks comprising the steps of:(a) forming a reaction mixture of(i) an epoxy compound having two or more epoxy groups, and(ii) a crosslinking agent containing two or more epoxy-reactive groups and further containing a disulfide bond, said crosslinking agent being selected from compounds having the formulaQ--X--S--S--X--Q where Q is an epoxy-reactive functional group selected from ##STR1## and X is a divalent aromatic or aliphatic hydrocarbon radical of one to ten carbon atoms, and(b) curing said reaction mixture under conditions conductive to the formation of a crosslinked resin.The epoxy resin can be solubilized by cleavage of the disulfide bond by reduction in the presence of a solvent. The resultant thiol groups can be reoxidized to form the disulfide linkages or can be modified by other reactions.
    • 一种制备包含可逆交联的不溶性可投入环氧树脂的方法,包括以下步骤:(a)形成(i)具有两个或多个环氧基的环氧化合物的反应混合物,和(ii)含有两个或更多个环氧基的交联剂, 更多的环氧反应性基团并且还含有二硫键,所述交联剂选自具有式QXSSXQ的化合物,其中Q是选自以下的环氧反应性官能团,X是二价芳族或脂族烃基, 10个碳原子,和(b)在导致形成交联树脂的条件下固化所述反应混合物。 环氧树脂可以通过在溶剂存在下还原而溶解二硫键。 所得到的硫醇基团可以被再氧化以形成二硫键,或者可以通过其它反应进行改性。