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    • 5. 发明授权
    • Quaternary ammonium hydroxides as mercaptan scavengers
    • 季铵氢氧化物作为硫醇清除剂
    • US6013175A
    • 2000-01-11
    • US152807
    • 1998-09-14
    • Jerry J. WeersDavid R. Gentry
    • Jerry J. WeersDavid R. Gentry
    • C07C213/04C10G29/20C10G19/02
    • C10G29/20C07C213/04
    • A method for scavenging mercaptans in a hydrocarbon fluid is disclosed. According to the method, an effective mercaptan-scavenging amount of an aqueous scavenging composition is added to the fluid. The composition comprises a quaternary ammonium hydroxide of the formula R.sup.1 R.sup.2 R.sup.3 R.sup.4 NOH. R.sup.1 and R.sup.2 are, independently, alkyl groups of from one to about eighteen carbon atoms, aryl groups of from six to about eighteen carbon atoms or alkylaryl groups of from seven to about eighteen carbon atoms. R.sup.3 is an alkyl group of from two to about eighteen carbon atoms, an aryl group of from two to about eighteen carbon atoms or an alkylaryl group of from four to about eighteen carbon atoms. R.sup.2 and R.sup.3 may be joined to form a heterocyclic ring including the N and optionally an oxygen atom. R.sup.4 is --(CH.sub.2 CH.sub.2 O).sub.n H, wherein n is an integer from one to about eighteen, or --CHR.sup.5 CHR.sup.6 Y, wherein R.sup.5 and R.sup.6 are, independently, hydrogen, alkyl groups of from one to about eighteen carbon atoms, aryl groups of from six to about eighteen carbon atoms or alkylaryl groups of from seven to about eighteen carbon atoms. Y is a non-acidic group. Related compositions and methods are also disclosed.
    • 公开了一种在烃流体中清除硫醇的方法。 根据该方法,将有效的硫醇清除量的除水组合物加入到流体中。 组合物包含式R1R2R3R4NOH的季铵氢氧化物。 R1和R2独立地为1至约18个碳原子的烷基,6至约18个碳原子的芳基或7至约18个碳原子的烷基芳基。 R3是具有2至约18个碳原子的烷基,2至约18个碳原子的芳基或4至约18个碳原子的烷基芳基。 R2和R3可以连接形成包括N和任选的氧原子的杂环。 R4为 - (CH2CH2O)nH,其中n为1至约18的整数,或-CHR 5 CHR 6 Y,其中R 5和R 6独立地为氢,1至约18个碳原子的烷基,6至 约十八个碳原子或七至十八个碳原子的烷基芳基。 Y是非酸性基团。 还公开了相关的组合物和方法。
    • 6. 发明授权
    • Use of olefinic imines to scavenge sulfur species
    • 使用烯属亚胺清除硫物质
    • US5567213A
    • 1996-10-22
    • US636813
    • 1996-04-25
    • David R. GentryGerald T. PancioJerry J. Weers
    • David R. GentryGerald T. PancioJerry J. Weers
    • C10G21/20C09K8/532C10G29/20C10L1/228C10L1/22
    • C10L1/2283C09K8/532C10G29/20
    • A method for scavenging sulfur species from a petroleum-derived medium is disclosed. The method comprises contacting the medium with sulfur species scavenging amount of an imine of the formula ##STR1## wherein x is an integer from 1 to 10, R' is an organic moiety having a number of valences equal to x, R.sub.1 is hydrogen or a mono-valent organic moieties and R is a mono-valent olefin moiety, provided that R and R.sub.1 contain a total of from about four to about forty carbon atoms. In an alternative embodiment, the imine is produced by a condensation reactionic between an amine having at least one primary amino group and a carbonyl of the formula ##STR2## wherein R.sub.1 is hydrogen or a mono-valent organic moieties and R is a mono-valent olefin moiety, provided that R and R.sub.1 contain a total of from about four to about forty carbon atoms. In yet other embodiments, the imine is produced by a condensation reaction between an amine having at least one primary amino group and an aldehyde having at least one alpha-hydrogen in an aldehyde to primary amino group molar ratio of at least about 2:1, are also disclosed.
    • 公开了一种从石油衍生的介质中清除硫物质的方法。 该方法包括使培养基与清除硫的物质接触式为式的亚胺,其中x是1至10的整数,R'是具有等于x的价数的有机部分,R 1是氢或 一价有机部分,R是一价烯烃部分,条件是R和R 1含有总共约4至约40个碳原子。 在替代实施方案中,亚胺通过具有至少一个伯氨基的胺与式有机部分的羰基之间的缩合反应产生,R是一价烯烃部分,条件是R和R 1含有 约4至约40个碳原子。 在其它实施方案中,亚胺通过具有至少一个伯氨基的胺与具有至少一个α-羟基的醛与醛与伯氨基摩尔比至少约2:1的缩合反应产生, 也被披露。
    • 8. 发明授权
    • Quaternary ammonium hydroxides as mercaptan scavengers
    • US5840177A
    • 1998-11-24
    • US931675
    • 1997-09-16
    • Jerry J. WeersDavid R. Gentry
    • Jerry J. WeersDavid R. Gentry
    • C07C213/04C10G29/20C10G19/02
    • C10G29/20C07C213/04
    • A method for scavenging mercaptans in a hydrocarbon fluid is disclosed. According to the method, an effective mercaptan-scavenging amount of an aqueous scavenging composition is added to the fluid. The composition comprises a quaternary ammonium hydroxide of the formula R.sup.1 R.sup.2 R.sup.3 R.sup.4 NOH. R.sup.1 and R.sup.2 are, independently, alkyl groups of from one to about eighteen carbon atoms, aryl groups of from six to about eighteen carbon atoms or alkylaryl groups of from seven to about eighteen carbon atoms. R.sup.3 is an alkyl group of from two to about eighteen carbon atoms, an aryl group of from two to about eighteen carbon atoms or an alkylaryl group of from four to about eighteen carbon atoms. R.sup.2 and R.sup.3 may be joined to form a heterocyclic ring including the N and optionally an oxygen atom. R.sup.4 is --(CH.sub.2 CH.sub.2 O).sub.n H, wherein n is an integer from one to about eighteen, or --CHR.sup.5 CHR.sup.6 Y, wherein R.sup.5 and R.sup.6 are, independently, hydrogen, alkyl groups of from one to about eighteen carbon atoms, aryl groups of from six to about eighteen carbon atoms or alkylaryl groups of from seven to about eighteen carbon atoms. Y is a non-acidic group. Related compositions and methods are also disclosed.
    • 9. 发明授权
    • Use of olefinic imines to scavenge sulfur species
    • 使用烯属亚胺清除硫物质
    • US5567212A
    • 1996-10-22
    • US430208
    • 1995-04-27
    • David R. GentryGerald T. PancioJerry J. Weers
    • David R. GentryGerald T. PancioJerry J. Weers
    • C10G21/20C09K8/532C10G29/20C10L1/228C10L1/22
    • C10L1/2283C09K8/532C10G29/20
    • A method for scavenging sulfur species from a petroleum-derived medium is disclosed. The method comprises contacting the medium with sulfur species scavenging amount of an imine of the formula ##STR1## wherein x is an integer from 1 to 10, R' is an organic moiety having a number of valences equal to x, R.sub.1 is hydrogen or a mono-valent organic moieties and R is a mono-valent olefin moiety, provided that R and R.sub.1 contain a total of from about four to about forty carbon atoms. In an alternative embodiment, the imine is produced by a condensation reaction between an amine having at least one primary amino group and a carbonyl of the formula ##STR2## wherein R.sub.1 is hydrogen or a mono-valent organic moieties and R is a mono-valent olefin moiety, provided that R and R.sub.1 contain a total of from about four to about forty carbon atoms. In yet other embodiments, the imine is produced by a condensation reaction between an amine having at least one primary amino group and an aldehyde having at least one alpha-hydrogen in an aldehyde to primary amino group molar ratio of at least about 2:1, are also disclosed.
    • 公开了一种从石油衍生的介质中清除硫物质的方法。 该方法包括使培养基与清除硫的物质接触式为式的亚胺,其中x是1至10的整数,R'是具有等于x的价数的有机部分,R 1是氢或 一价有机部分,R是一价烯烃部分,条件是R和R 1含有总共约4至约40个碳原子。 在另一个实施方案中,亚胺是通过具有至少一个伯氨基的胺和式的羰基之间的缩合反应产生的,其中R1是氢或一价有机部分,R是一价的 烯烃部分,条件是R和R 1含有总共约4至约40个碳原子。 在其它实施方案中,亚胺通过具有至少一个伯氨基的胺与具有至少一个α-羟基的醛与醛与伯氨基摩尔比至少约2:1的缩合反应产生, 也被披露。